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RESEARCH PAPER · Accounts of Chemical Research · 2004

Olefin Epoxidation with Inorganic Peroxides. Solutions to Four Long-Standing Controversies on the Mechanism of Oxygen Transfer

Dirk V. Deubel, Gernot Frenking, Philip Gisdakis, Wolfgang Anton Herrmann, Notker Rösch, Jörg Sundermeyer

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Olefin Epoxidation with Inorganic Peroxides. Solutions to Four Long-Standing Controversies on the Mechanism of Oxygen TransferOriginal2 Synthetic methods : Part (ii) Oxidation and reduction methods8Gas phase oxidation of alkoxo ligands in bis(peroxo)[MO(O2)2(OR)]? and trisoxo [MO3(OR)]? anions (M = Cr, Mo, W)9Olefin Epoxidation with Inorganic Peroxides. Solutions to Four Long‐Standing Controversies on the Mechanism of Oxygen Transfer02 Synthetic methods : Part (ii) Oxidation and reduction methods3Grafting of [CpMo(CO)3]−Na+ on 3,6-dichloro-pyridazine modified mesoporous MCM-41 and MCM-48 molecular sieves4Loss of Ammine from Platinum( II ) Complexes: Implications for Cisplatin Inactivation, Storage, and Resistance87Siloxane functionalized cyclopentadienyl-molybdenum complexes: Synthesis, characterization and catalytic application30Why Do Peroxomolybdenum Complexes Chemoselectively Oxidize the Sulfur Centers of Unsaturated Sulfides and Sulfoxides? A DFT Analysis21Epoxidation of Simple Alkenes with O2and Isobutyraldehyde Catalyzed by Ni Catalysts Deposited on Nanoporous Carbon23In situ grafting of cyclopentadienyl-molybdenum complexes on mesoporous materials: The reaction of [η5-CpMo(CO)3]−Na+ with surface fixed iodo-benzyl siloxane20Grafting of the η5-CpMo(CO)3 moiety on pure and surface modified SBA-15 molecular sieves35Rhenium, Aquamethyloxodiperoxy1Olefin Oxygenation by the Hydroperoxide Adduct of a Nonheme Manganese(IV) Complex: Epoxidations by a Metallo−Peracid Produces Gentle Selective Oxidations79Grafting of η5-Cp(COOMe)MoCl(CO)3 on the surface of mesoporous MCM-41 and MCM-48 materials35Preparation and Catalytic Performances of Ultralarge-Pore TiSBA-15 Mesoporous Molecular Sieves with Very High Ti Content104Olefin epoxidation with tert-butyl hydroperoxide catalyzed by MoO2X2L complexes: a DFT mechanistic study100The Literature of Heterocyclic Chemistry, Part IX, 2002–200414Synthesis, characterisation and reactivity of oxodiperoxo-[2-(1-pyrazolyl)-6-menthylpyridine]molybdenum(VI): The first chiral 2-(1-pyrazole)pyridineoxodiperoxomolybdenum(VI) complex23Olefin Epoxidation by the Hydrogen Peroxide Adduct of a Novel Non-heme Mangangese(IV) Complex: Demonstration of Oxygen Transfer by Multiple Mechanisms73The chemical reactivity of some terpenes investigated by alumina catalyzed epoxidation with hydrogen peroxide and by DFT calculations23Enantioselective Oxidation of Olefins Catalyzed by a Chiral Bishydroxamic Acid Complex of Molybdenum116Enantioselective Oxidation of Olefins Catalyzed by a Chiral Bishydroxamic Acid Complex of Molybdenum30Trimanganese Complexes Bearing Bidentate Nitrogen Ligands as a Highly Efficient Catalyst Precursor in the Epoxidation of Alkenes35Catalysis and Organometallic Chemistry of Rhodium and Iridium in the Oxidation of Organic Substrates36Olefin Epoxidation with Hydrogen Peroxide Catalyzed by Lacunary Polyoxometalate [γ‐SiW10O34(H2O)2]4−147Tuning the acidic properties of aluminas via sol-gel synthesis: New findings on the active site of alumina-catalyzed epoxidation with hydrogen peroxide60Mechanism of olefin epoxidation with transition metal peroxo complexes: DFT study35Three-membered ring systems (2004)6Mechanism of [γ-H2SiV2W10O40]4--Catalyzed Epoxidation of Alkenes with Hydrogen Peroxide77Understanding the Selectivity of a Moderate Oxidation Catalyst: Hydrogen Abstraction by a Fully Characterized, Activated Catalyst, the Robust Dihydroxo Manganese(IV) Complex of a Bridged Cyclam88Development and application of versatile bis-hydroxamic acids for catalytic asymmetric oxidation77Synthesis, characterization and catalytic activity of a new peroxomolybdenum(VI) complex-based coordination polymer30Chiral oxoperoxomolybdenum(VI) complexes for enantioselective olefin epoxidation: Some mechanistic and stereochemical reflections71Mechanism of Cis-Dihydroxylation and Epoxidation of Alkenes by Highly H2O2 Efficient Dinuclear Manganese Catalysts106Quantum Chemical Modeling of Ethene Epoxidation with Hydrogen Peroxide: The Effect of Microsolvation with Water24Lewis Acid Catalyzed Epoxidation of Olefins Using Hydrogen Peroxide4Oxiranes and Oxirenes: Monocyclic12Rates, Kinetics, and Mechanisms of Epoxidation56From Olefins to Ketones via a 2‐Rhodaoxetane Complex30From Olefins to Ketones via a 2‐Rhodaoxetane Complex18Alumina-catalyzed Baeyer–Villiger oxidation of cyclohexanone with hydrogen peroxide31Dioxobis(2,4-pentanedionato)molybdenum, MoO2(acac)21Computational Modeling of a Stereoselective Epoxidation: Reaction of Carene with Peroxyformic Acid23Enantioselective Epoxidation of Electrophilic Olefins by Using Glycosyl Hydroperoxides19Theoretical study on selective oxidation of olefin and alcohol with Mo–peroxo amine complex using “paired interacting orbitals (PIOs)” analysis3Gel derived niobium–silicon mixed oxides: Characterization and catalytic activity for cyclooctene epoxidation41((2-Hydroxynapthalen-1-yl)methylene)aniline derived Schiff base adducts of MTO: Synthesis and catalytic application26Radical Formation in the [MeReO3]-Catalyzed Aqueous Peroxidative Oxidation of Alkanes: A Theoretical Mechanistic Study98(N‐Salicylidene)aniline Derived Schiff Base Complexes of Methyltrioxorhenium(VII): Ligand Influence and Catalytic Performance27Kinetic Studies on the Oxidation of η5-Cyclopentadienyl Methyl Tricarbonyl Molybdenum(II) and the Use of Its Oxidation Products as Olefin Epoxidation Catalysts67Expanding the role of oxo-molybdenum(vi) catalysts: a DFT interpretation of X–H activation leading to reduction or oxidation35Synthesis, Characterization, and Application of Vanadium−Salan Complexes in Oxygen Transfer Reactions198Novel sea urchin-like polyaniline microspheres-supported molybdenum catalyst: Preparation, characteristic and functionality21Hydrogen-Bond-Assisted Epoxidation of Homoallylic and Allylic Alcohols with Hydrogen Peroxide Catalyzed by Selenium-Containing Dinuclear Peroxotungstate107An investigation into oxo analogues of molybdenum olefin metathesis complexes as epoxidation catalysts for alkenes12Kinetic study of hydroperoxide epoxidation of 1‐octene in the presence of molybdenum disilicide as a catalyst in a low concentration range of olefin3Microwave-Assisted Synthesis and Crystal Structure of Oxo(diperoxo)(4,4'-di-tert-butyl-2,2'-bipyridine)-molybdenum(VI)23Layered Transition Metal Carboxylates: Efficient Reusable Heterogeneous Catalyst for Epoxidation of Olefins42General and Theoretical Aspects of the Peroxide Group3Olefin Epoxidation Catalyzed by η5-Cyclopentadienyl Molybdenum Compounds: A Computational Study91Olefin epoxidation by hydrogen peroxide catalysed by molybdenum complexes in ionic liquids and structural characterisation of the proposed intermediate dioxoperoxomolybdenum species45Stickstofffixierung0A Computational Study of the Olefin Epoxidation Mechanism Catalyzed by Cyclopentadienyloxidomolybdenum(VI) Complexes91Catalytic performance of Mn3O4 and Co3O4 nanocrystals prepared by sonochemical method in epoxidation of styrene and cyclooctene90Mechanistic Insights into Alkene Epoxidation with H2O2by Ti- and other TM-Containing Polyoxometalates: Role of the Metal Nature and Coordination Environment166Manganese Catalysts for C−H Activation: An Experimental/Theoretical Study Identifies the Stereoelectronic Factor That Controls the Switch between Hydroxylation and Desaturation Pathways104Olefin Epoxidation by H2O2/MeCN Catalysed by Cyclopentadienyloxidotungsten(VI) and Molybdenum(VI) Complexes: Experiments and Computations78Kinetic study of cyclooctene epoxidation with aqueous hydrogen peroxide over silica-supported calixarene–Ta(V)30Recent Progress in the Heterogenization of Complexes for Single‐Site Epoxidation Catalysis66Epoxidation of Alkenes with H2O2 Catalyzed by Dititanium‐Containing 19‐Tungstodiarsenate(III): Experimental and Theoretical Studies45Molybdenum(VI) Amino Triphenolate Complexes as Catalysts for Sulfoxidation, Epoxidation and Haloperoxidation57Matériaux lamellaires nanocomposites : synthèse et applications0Competition of methyltrioxorhenium (MTO) with osmium tetroxide (OsO4) for pyridines binding: Ligand binding assay3Olefin Epoxidation by Molybdenum Peroxo Compound: Molecular Mechanism Characterized by the Electron Localization Function and Catastrophe Theory29Direct synthesis of cyclic carbonates from olefins and CO2 catalyzed by a MoO2(acac)2-quaternary ammonium salt system89Structural considerations and reactivity of peroxocomplexes of V(v), Mo(vi) and W(vi)37Synthesis, characterization, reactivity and catalytic activity of oxidovanadium(iv), oxidovanadium(v) and dioxidovanadium(v) complexes of benzimidazole modified ligands82Reaction of a monomeric titanium hydride with dioxygen does not produce a stable titanium hydroperoxide13Chemoselective Sulfide and Sulfoxide Oxidations by CpMo(CO)3Cl/HOOR: a DFT Mechanistic Study26Oxoperoxomolybdenum(VI) complexes of catalytic and biomedical relevance: Synthesis, characterization, antibacterial activity and 3D-molecular modeling of some oxoperoxomolybdenum(VI) chelates in mixed (O,O) coordination environment involving maltol and β-diketoenolates5Mechanistic aspects of vanadium catalysed oxidations with peroxides225Tethering of nickel(II) Schiff-base complex onto mesoporous silica: An efficient heterogeneous catalyst for epoxidation of olefins78The catalytic function of a silica gel-immobilized Mn(II)-hydrazide complex for alkene epoxidation with H2O249Efficient Epoxidation of Electron‐Deficient Alkenes with Hydrogen Peroxide Catalyzed by [γ‐PW10O38V2(μ‐OH)2]3−81Polyoxometalate-based hybrid mesostructured catalysts for green epoxidation of olefins39Oxidovanadium(IV) Complexes of Tetradentate Ligands Encapsulated in Zeolite‐Y as Catalysts for the Oxidation of Styrene, Cyclohexene and Methyl Phenyl Sulfide42Theoretical Investigation on the Chiral Diamine-Catalyzed Epoxidation of Cyclic Enones: Mechanism and Effects of Cocatalyst14New insights into the mechanism of oxodiperoxomolybdenum catalysed olefin epoxidation and the crystal structures of several oxo–peroxo molybdenum complexes47Insights on the mechanistic features of catalytic oxidations of simple and conjugated olefins promoted by VO(acac)2/H2O2 system, in acetonitrile: A computational study19Dioxomolybdenum(VI) Complexes with Pyrazole Based Aryloxide Ligands: Synthesis, Characterization and Application in Epoxidation of Olefins55Mechanism of the MeReO3-Catalyzed Deoxygenation of Epoxides38Hydroxamic Acids in Asymmetric Synthesis105Oxido-peroxido molybdenum(VI) complexes in catalytic and stoichiometric oxidations132Mechanistic Studies on the Roles of the Oxidant and Hydrogen Bonding in Determining the Selectivity in Alkene Oxidation in the Presence of Molybdenum Catalysts15Activation of Hydrogen Peroxide by Ionic Liquids: Mechanistic Studies and Application in the Epoxidation of Olefins58Dioxidomolybdenum(VI) Complexes Containing Ligands with the Bipyrrolidine Backbone as Efficient Catalysts for Olefin Epoxidation24Non‐covalent Activation of a Titanium(IV) Oxygen‐Transfer Catalyst16Determination of Thermodynamic Affinities of Various Polar Olefins as Hydride, Hydrogen Atom, and Electron Acceptors in Acetonitrile19Historical landmarks of the application of molecular transition metal catalysts for olefin epoxidation93Water-Catalyzed Activation of H2O2 by Methyltrioxorhenium: A Combined Computational–Experimental Study21Preparation of γ-Fe2O3@C@MoO3 core/shell nanocomposites as magnetically recyclable catalysts for efficient and selective epoxidation of olefins38Selective oxidation passing through η 3 -ozone intermediates: applications to direct propene epoxidation using molecular oxygen oxidant14Organometallic Mo complex anchored to magnetic iron oxide nanoparticles as highly recyclable epoxidation catalyst42Reactions of Metal Complexes with Singlet Oxygen4Oxygen Atom Transfer Reactions from Mimoun Complexes to Sulfides and Sulfoxides. A Bonding Evolution Theory Analysis18Theoretical Mechanistic Studies on Methyltrioxorhenium-Catalyzed Olefin Cyclopropanation: Stepwise Transfer of a Terminal Methylene Group7Niobium Peroxide‐Catalyzed Selective Epoxidation of Allylic Alcohols20Catalytic oxygen activation versus autoxidation for industrial applications: a physicochemical approach45Rutile Surface Reactivity Provides Insight into the Structure-Directing Role of Peroxide in TiO 2 Polymorph Control17Hafnium catalysts for direct alkene epoxidation using molecular oxygen as oxidant8Silica microspheres containing high density surface hydroxyl groups as efficient epoxidation catalysts14Dioxomolybdenum(VI) and ‐tungsten(VI) Complexes with Multidentate Aminobisphenol Ligands as Catalysts for Olefin Epoxidation48The enantioselectivity of the manganese-salen complex in the epoxidation of unfunctionalized olefins and the influence of grafting8Assessment of DFT Methods for Computing Activation Energies of Mo/W-Mediated Reactions60Highly Efficient Epoxidation of Allylic Alcohols with Hydrogen Peroxide Catalyzed by Peroxoniobate-Based Ionic Liquids44Mechanistic Investigation into Olefin Epoxidation with H2O2 Catalyzed by Aqua‐Coordinated Sandwich‐Type Polyoxometalates: Role of the Noble Metal and Active Oxygen Position9Selective epoxidation of cyclohexene with molecular oxygen on catalyst of nanoporous Au integrated with MoO3 nanoparticles31Rational Design of a Polyoxometalate Intercalated Layered Double Hydroxide: Highly Efficient Catalytic Epoxidation of Allylic Alcohols under Mild and Solvent‐Free Conditions49Evaluation of density functionals for elementary steps of selective oxidation reactions14Oxidodiperoxidomolybdenum Complexes: Properties and Their Use as Catalysts in Green Oxidations2Philipps‐Universität Marburg1Peroxotantalate‐Based Ionic Liquid Catalyzed Epoxidation of Allylic Alcohols with Hydrogen Peroxide22Increased selectivity for allylic oxidation of cyclohexene using TiO2 modified V2O5/MoO3 catalysts15Mixed-valence dimolybdenum complexes containing hard oxo and soft carbonyl ligands: synthesis, structure, and electrochemistry of Mo 2 (O)(CO) 2 (μ-κ 2 -S(CH 2 ) n S) 2 (κ 2 -diphosphine)3Identifying Catalytically Active Mononuclear Peroxoniobate Anion of Ionic Liquids in the Epoxidation of Olefins50Relevance of Protons in Heterolytic Activation of H2O2 over Nb(V): Insights from Model Studies on Nb-Substituted Polyoxometalates77Polymer immobilized tantalum( v )–amino acid complexes as selective and recyclable heterogeneous catalysts for oxidation of olefins and sulfides with aqueous H 2 O 222Ionic Liquid Stabilized Niobium Oxoclusters Catalyzing Oxidation of Sulfides with Exceptional Activity25Polymer‐anchored mononuclear and binuclear CuII Schiff‐base complexes: Impact of heterogenization on liquid phase catalytic oxidation of a series of alkenes10Recent Advances in Facile Liquid Phase Epoxidation of Light Olefins over Heterogeneous Molybdenum Catalysts11Remarkable binuclear Schiff‐based complex catalyze the epoxidation of alkenes: effects of substituent group7Ionic Liquids Based on Oxidoperoxido-Molybdenum(VI) Complexes with a Chelating Picolinate Ligand for Catalytic Epoxidation3Oxide-Supported Titanium Catalysts: Structure–Activity Relationship in Heterogeneous Catalysis, with the Choice of Support as a Key Step6Reaction Pathway Discrimination in Alkene Oxidation Reactions by Designed Ti‐Siloxy‐Polyoxometalates19Dioxomolybdenum(VI) complexes of hydrazone phenolate ligands - syntheses and activities in catalytic oxidation reactions18Enhanced oxygen transfer over bifunctional Mo-based oxametallacycle catalyst for epoxidation of propylene33Characterization of peroxo-Mo and superoxo-Mo intermediate adducts in Photo-Oxygen Atom Transfer with O217High selective epoxidation of 2-methylpropene over a Mo-based oxametallacycle reinforced nano composite15Group 6 carbonyl complexes of N,O,P-ligands as precursors of high-valent metal-oxo catalysts for olefin epoxidation13Photo-epoxidation of α-pinene catalyzed by a MoVI oxo-diperoxo complex modified Ti-based metal-organic framework3Reaction induced self-separating metal catalysts – Wonder systems in 21st century catalysis950 Years of Passion for Organometallic Chemistry4Relay Catalysis for Epoxidation of Cyclohexene by Mg–Mo Bimetallic Oxides and O2 under Solvent-Free Conditions8Schiff Base-Based Molybdenum Complexes as Green Catalyst in the Epoxidation Reaction: A Minireview4Oxidorhenium( v ) complexes of apigenin: a rare example of catalysis with O , O -bidentate ligands obtained from a naturally renewable resource2Research Progress in Epoxidation of Light Small-Molecule Olefins10

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  1. 2 Synthetic methods : Part (ii) Oxidation and reduction methods

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  2. Gas phase oxidation of alkoxo ligands in bis(peroxo)[MO(O2)2(OR)]? and trisoxo [MO3(OR)]? anions (M = Cr, Mo, W)

    Dalton Transactions · 2004-01-01

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  3. Olefin Epoxidation with Inorganic Peroxides. Solutions to Four Long‐Standing Controversies on the Mechanism of Oxygen Transfer

    ChemInform · 2004-11-15

    Dirk V. Deubel, Gernot Frenking, Philip Gisdakis, Wolfgang Anton Herrmann, Notker Rösch, Joerg Sundermeyer

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  4. 2 Synthetic methods : Part (ii) Oxidation and reduction methods

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  5. Grafting of [CpMo(CO)3]−Na+ on 3,6-dichloro-pyridazine modified mesoporous MCM-41 and MCM-48 molecular sieves

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  6. Loss of Ammine from Platinum( II ) Complexes: Implications for Cisplatin Inactivation, Storage, and Resistance

    Chemistry - A European Journal · 2005-03-03

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  7. Siloxane functionalized cyclopentadienyl-molybdenum complexes: Synthesis, characterization and catalytic application

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  8. Why Do Peroxomolybdenum Complexes Chemoselectively Oxidize the Sulfur Centers of Unsaturated Sulfides and Sulfoxides? A DFT Analysis

    European Journal of Organic Chemistry · 2005-05-25

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  9. Epoxidation of Simple Alkenes with O2and Isobutyraldehyde Catalyzed by Ni Catalysts Deposited on Nanoporous Carbon

    Bulletin of the Korean Chemical Society · 2005-06-20

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  10. In situ grafting of cyclopentadienyl-molybdenum complexes on mesoporous materials: The reaction of [η5-CpMo(CO)3]−Na+ with surface fixed iodo-benzyl siloxane

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  11. Grafting of the η5-CpMo(CO)3 moiety on pure and surface modified SBA-15 molecular sieves

    Microporous and Mesoporous Materials · 2005-09-10

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  12. Rhenium, Aquamethyloxodiperoxy

    Encyclopedia of Reagents for Organic Synthesis · 2005-10-15

    Roberto Rinaldi, Ulf Friedrich Schuchardt

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  13. Olefin Oxygenation by the Hydroperoxide Adduct of a Nonheme Manganese(IV) Complex: Epoxidations by a Metallo−Peracid Produces Gentle Selective Oxidations

    Journal of the American Chemical Society · 2005-11-17

    Guochuan Yin, Maria Buchalova, Andrew M. Danby, Chris M. Perkins, David J. Kitko, John D. Carter, William M. Scheper, Daryle H. Busch

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  14. Grafting of η5-Cp(COOMe)MoCl(CO)3 on the surface of mesoporous MCM-41 and MCM-48 materials

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  15. Preparation and Catalytic Performances of Ultralarge-Pore TiSBA-15 Mesoporous Molecular Sieves with Very High Ti Content

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  16. Olefin epoxidation with tert-butyl hydroperoxide catalyzed by MoO2X2L complexes: a DFT mechanistic study

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  17. The Literature of Heterocyclic Chemistry, Part IX, 2002–2004

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  18. Synthesis, characterisation and reactivity of oxodiperoxo-[2-(1-pyrazolyl)-6-menthylpyridine]molybdenum(VI): The first chiral 2-(1-pyrazole)pyridineoxodiperoxomolybdenum(VI) complex

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  19. Olefin Epoxidation by the Hydrogen Peroxide Adduct of a Novel Non-heme Mangangese(IV) Complex: Demonstration of Oxygen Transfer by Multiple Mechanisms

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  20. The chemical reactivity of some terpenes investigated by alumina catalyzed epoxidation with hydrogen peroxide and by DFT calculations

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  21. Enantioselective Oxidation of Olefins Catalyzed by a Chiral Bishydroxamic Acid Complex of Molybdenum

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  22. Enantioselective Oxidation of Olefins Catalyzed by a Chiral Bishydroxamic Acid Complex of Molybdenum

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  23. Trimanganese Complexes Bearing Bidentate Nitrogen Ligands as a Highly Efficient Catalyst Precursor in the Epoxidation of Alkenes

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  24. Catalysis and Organometallic Chemistry of Rhodium and Iridium in the Oxidation of Organic Substrates

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  25. Olefin Epoxidation with Hydrogen Peroxide Catalyzed by Lacunary Polyoxometalate [γ‐SiW10O34(H2O)2]4−

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  26. Tuning the acidic properties of aluminas via sol-gel synthesis: New findings on the active site of alumina-catalyzed epoxidation with hydrogen peroxide

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  27. Mechanism of olefin epoxidation with transition metal peroxo complexes: DFT study

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  28. Three-membered ring systems (2004)

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  29. Mechanism of [γ-H2SiV2W10O40]4--Catalyzed Epoxidation of Alkenes with Hydrogen Peroxide

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  30. Understanding the Selectivity of a Moderate Oxidation Catalyst: Hydrogen Abstraction by a Fully Characterized, Activated Catalyst, the Robust Dihydroxo Manganese(IV) Complex of a Bridged Cyclam

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  31. Development and application of versatile bis-hydroxamic acids for catalytic asymmetric oxidation

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  32. Synthesis, characterization and catalytic activity of a new peroxomolybdenum(VI) complex-based coordination polymer

    Applied Catalysis A General · 2007-05-11

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  33. Chiral oxoperoxomolybdenum(VI) complexes for enantioselective olefin epoxidation: Some mechanistic and stereochemical reflections

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  34. Mechanism of Cis-Dihydroxylation and Epoxidation of Alkenes by Highly H2O2 Efficient Dinuclear Manganese Catalysts

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  35. Quantum Chemical Modeling of Ethene Epoxidation with Hydrogen Peroxide: The Effect of Microsolvation with Water

    The Journal of Physical Chemistry A · 2007-08-24

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  36. Lewis Acid Catalyzed Epoxidation of Olefins Using Hydrogen Peroxide

    Elsevier eBooks · 2008-01-01

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  37. Oxiranes and Oxirenes: Monocyclic

    Elsevier eBooks · 2008-01-01

    Gregory R. Dake

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  38. Rates, Kinetics, and Mechanisms of Epoxidation

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  39. From Olefins to Ketones via a 2‐Rhodaoxetane Complex

    Angewandte Chemie International Edition · 2008-02-22

    M. Pilar del Rı́o, Miguel A. Ciriano, Cristina Tejel

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  40. From Olefins to Ketones via a 2‐Rhodaoxetane Complex

    Angewandte Chemie · 2008-02-22

    M. Pilar del Rı́o, Miguel A. Ciriano, Cristina Tejel

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  41. Alumina-catalyzed Baeyer–Villiger oxidation of cyclohexanone with hydrogen peroxide

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  42. Dioxobis(2,4-pentanedionato)molybdenum, MoO2(acac)2

    Encyclopedia of Reagents for Organic Synthesis · 2008-03-14

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  43. Computational Modeling of a Stereoselective Epoxidation: Reaction of Carene with Peroxyformic Acid

    The Journal of Organic Chemistry · 2008-03-26

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  44. Enantioselective Epoxidation of Electrophilic Olefins by Using Glycosyl Hydroperoxides

    Chemistry - A European Journal · 2008-05-26

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  45. Theoretical study on selective oxidation of olefin and alcohol with Mo–peroxo amine complex using “paired interacting orbitals (PIOs)” analysis

    Journal of Molecular Catalysis A Chemical · 2008-06-01

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  46. Gel derived niobium–silicon mixed oxides: Characterization and catalytic activity for cyclooctene epoxidation

    Applied Catalysis A General · 2008-06-18

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  47. ((2-Hydroxynapthalen-1-yl)methylene)aniline derived Schiff base adducts of MTO: Synthesis and catalytic application

    Journal of Organometallic Chemistry · 2008-07-23

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  48. Radical Formation in the [MeReO3]-Catalyzed Aqueous Peroxidative Oxidation of Alkanes: A Theoretical Mechanistic Study

    Inorganic Chemistry · 2008-12-02

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  49. (N‐Salicylidene)aniline Derived Schiff Base Complexes of Methyltrioxorhenium(VII): Ligand Influence and Catalytic Performance

    Chemistry - An Asian Journal · 2008-12-15

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  50. Kinetic Studies on the Oxidation of η5-Cyclopentadienyl Methyl Tricarbonyl Molybdenum(II) and the Use of Its Oxidation Products as Olefin Epoxidation Catalysts

    Organometallics · 2008-12-29

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