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RESEARCH PAPER · Organometallics · 2008

A Dichromium(II) Bis(η 8 -pentalene) Double-Sandwich Complex with a Spin Equilibrium: Synthetic, Structural, Magnetic, and Theoretical Studies

Gábor Balázs, F. Geoffrey N. Cloke, Laura Gagliardi, Jennifer C. Green, Andrew Harrison, Peter B. Hitchcock, Abdul Rehaman Moughal Shahi, Owen T. Summerscales

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A Dichromium(II) Bis(η 8 -pentalene) Double-Sandwich Complex with a Spin Equilibrium: Synthetic, Structural, Magnetic, and Theoretical StudiesOriginalAb initio and Semiempirical Methods0Homoleptic Permethylpentalene Complexes: “Double Metallocenes” of the First-Row Transition Metals98Density functional theory for transition metals and transition metal chemistry1648Double Metallocene Nanowires62Electronic Communication through Unsaturated Hydrocarbon Bridges in Homobimetallic Organometallic Complexes332Synthesis and Reactions of Dibenzo[a,e]pentalenes103Structure:function relationships in molecular spin-crossover complexes953Ab initio and Semiempirical Methods1The occurrence and representation of three-centre two-electron bonds in covalent inorganic compounds293Bis(heptalene) “submarine” metal dimer sandwich compounds (C12H10)2M2 (M = Ti, V, Cr, Mn, Fe, Co, Ni)9A new heterobimetallic manganese–rhodium carbonyl complex derived from partially alkylated s-indacene13Double-Sandwich Pentalene Complexes M2(pent†)2(M = Rh, Pd; pent†= 1,4-Bis(triisopropylsilyl)pentalene): Synthesis, Structure, and Bonding19Bis(pentalene)di-titanium: a bent double-sandwich complex with a very short Ti–Ti bond30Can a linear metal–metal bonded array of tetravanadium be stabilized between two dicyclopenta[a,e]pentalene ligands? A theoretical investigation5Reductive deoxygenation of CO 2 by a bimetallic titanium bis(pentalene) complex37Coordination diversity of the phenazine ligand in binuclear transition metal sandwich complexes: Theoretical investigation30The Reductive Activation of CO2 Across a Ti═Ti Double Bond: Synthetic, Structural, and Mechanistic Studies41Bonding in Complexes of Bis(pentalene)dititanium, Ti2(C8H6)219Pushing the Limits of Delta Bonding in Metal–Chromium Complexes with Redox Changes and Metal Swapping53Bis(azulene) “submarine” metal dimer sandwich compounds (C10H8)2M2 (M = Ti, V, Cr, Mn, Fe, Co, Ni): Parallel and opposed orientations7Dinuclear first-row transition metal–(C 8 Me 6 ) 2 complexes: metal–metal and metal–ligand bonds determined by the d electron configuration of the metal atom10The Covalent Bond Classification Method and Its Application to Compounds That Feature 3-Center 2-Electron Bonds20Transition Metal Complexes of Cross‐Conjugated π Systems0Ten‐Electron Donor Indenyl Anion in Binuclear Transition‐Metal Sandwich Complexes: Electronic Structure and Bonding Analysis12Coordination capabilities of anthracene ligand in binuclear sandwich complexes: DFT investigation19Reactivity of a Dititanium Bis(pentalene) Complex toward Heteroallenes and Main-Group Element–Element Bonds16Bonding in pentalene complexes and their recent applications51A new access route to dimetal sandwich complexes, including a radical anion6Metal–metal bonded compounds with uncommon low oxidation state54Metal–Metal (MM) Bond Distances and Bond Orders in Binuclear Metal Complexes of the First Row Transition Metals Titanium Through Zinc170Chromium(II) Complexes2Cyclic and Non-cyclic Pi Complexes of Chromium3Twinned versus linked organometallics - bimetallic “half-baguette” pentalenide complexes of Rh( i )3Synthesis, characterisation, and magnetic properties of a permethylindenyl manganocene0

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  1. Ab initio and Semiempirical Methods

    Encyclopedia of Inorganic Chemistry · 2005-09-07

    Serge I. Gorelsky

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  2. Homoleptic Permethylpentalene Complexes: “Double Metallocenes” of the First-Row Transition Metals

    Journal of the American Chemical Society · 2008-10-22

    Andrew E. Ashley, Robert T. Cooper, Gregory G. Wildgoose, Jennifer C. Green, Dermot M. O'Hare

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  3. Density functional theory for transition metals and transition metal chemistry

    Physical Chemistry Chemical Physics · 2009-01-01

    Christopher J. Cramer, Donald G. Truhlar

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  4. Double Metallocene Nanowires

    Journal of the American Chemical Society · 2009-09-16

    Xiaojun Wu, Xiao Cheng Zeng

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  5. Electronic Communication through Unsaturated Hydrocarbon Bridges in Homobimetallic Organometallic Complexes

    Chemical Reviews · 2010-04-19

    Paulina Aguirre-Etcheverry, Dermot M. O'Hare

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  6. Synthesis and Reactions of Dibenzo[a,e]pentalenes

    Symmetry · 2010-04-21

    Masaichi Saito

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  7. Structure:function relationships in molecular spin-crossover complexes

    Chemical Society Reviews · 2011-01-01

    Malcolm A. Halcrow

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  8. Ab initio and Semiempirical Methods

    Encyclopedia of Inorganic and Bioinorganic Chemistry · 2011-12-09

    Serge I. Gorelsky

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  9. The occurrence and representation of three-centre two-electron bonds in covalent inorganic compounds

    Chemical Communications · 2012-01-01

    Jennifer C. Green, Malcolm L. H. Green, Gerard Parkin

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  10. Bis(heptalene) “submarine” metal dimer sandwich compounds (C12H10)2M2 (M = Ti, V, Cr, Mn, Fe, Co, Ni)

    Journal of Molecular Modeling · 2012-08-13

    Huidong Li, Hao Feng, Weiguo Sun, Qunchao Fan, Yaoming Xie, Robert Bruce King, Henry F. Schaefer

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  11. A new heterobimetallic manganese–rhodium carbonyl complex derived from partially alkylated s-indacene

    Inorganica Chimica Acta · 2012-08-30

    Cesar A. Morales-Verdejo, Luciano Oehninger, Iván Martínez, Desmond MacLeod‐Carey, Ramiro Arratia‐Pérez, I. Chávez, Juan Manuel Manriquez

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  12. Double-Sandwich Pentalene Complexes M2(pent†)2(M = Rh, Pd; pent†= 1,4-Bis(triisopropylsilyl)pentalene): Synthesis, Structure, and Bonding

    Organometallics · 2012-12-06

    Owen T. Summerscales, Christopher J. Rivers, Morgan Taylor, Peter B. Hitchcock, Jennifer C. Green, F. Geoffrey N. Cloke

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  13. Bis(pentalene)di-titanium: a bent double-sandwich complex with a very short Ti–Ti bond

    Chemical Communications · 2013-01-01

    Alexander F. R. Kilpatrick, Jennifer C. Green, F. Geoffrey N. Cloke, Nikolaos Tsoureas

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  14. Can a linear metal–metal bonded array of tetravanadium be stabilized between two dicyclopenta[a,e]pentalene ligands? A theoretical investigation

    New Journal of Chemistry · 2013-11-22

    Yanchun Liu, Shui‐Xing Wu, Zhong‐Min Su, Houyu Zhang

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  15. Reductive deoxygenation of CO 2 by a bimetallic titanium bis(pentalene) complex

    Chemical Communications · 2014-01-01

    Alexander F. R. Kilpatrick, F. Geoffrey N. Cloke

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  16. Coordination diversity of the phenazine ligand in binuclear transition metal sandwich complexes: Theoretical investigation

    Journal of Organometallic Chemistry · 2014-08-19

    Meriem Merzoug, Bachir Zouchoune

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  17. The Reductive Activation of CO2 Across a Ti═Ti Double Bond: Synthetic, Structural, and Mechanistic Studies

    Organometallics · 2015-07-04

    Alexander F. R. Kilpatrick, Jennifer C. Green, F. Geoffrey N. Cloke

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  18. Bonding in Complexes of Bis(pentalene)dititanium, Ti2(C8H6)2

    Organometallics · 2015-07-05

    Alexander F. R. Kilpatrick, Jennifer C. Green, F. Geoffrey N. Cloke

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  19. Pushing the Limits of Delta Bonding in Metal–Chromium Complexes with Redox Changes and Metal Swapping

    Inorganic Chemistry · 2015-07-13

    Reed J. Eisenhart, P. Alex Rudd, Nora Planas, David W. Boyce, Rebecca K. Carlson, William B. Tolman, Eckhard Bill, Laura Gagliardi, Connie C. Lu

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  20. Bis(azulene) “submarine” metal dimer sandwich compounds (C10H8)2M2 (M = Ti, V, Cr, Mn, Fe, Co, Ni): Parallel and opposed orientations

    Journal of Computational Chemistry · 2015-07-27

    Hongyan Wang, Hongyan Wang, Hui Wang, Hui Wang, Robert Bruce King, Henry F. Schaefer

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  21. Dinuclear first-row transition metal–(C 8 Me 6 ) 2 complexes: metal–metal and metal–ligand bonds determined by the d electron configuration of the metal atom

    New Journal of Chemistry · 2015-11-10

    Xiuli Yan, Xiaoyan Li, Zheng Sun, Qingzhong Li, Lingpeng Meng

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  22. The Covalent Bond Classification Method and Its Application to Compounds That Feature 3-Center 2-Electron Bonds

    Structure and bonding · 2016-01-01

    Malcolm L. H. Green, Gerard Parkin

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  23. Transition Metal Complexes of Cross‐Conjugated π Systems

    Unknown journal · 2016-04-08

    Holger Butenschön

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  24. Ten‐Electron Donor Indenyl Anion in Binuclear Transition‐Metal Sandwich Complexes: Electronic Structure and Bonding Analysis

    ChemistrySelect · 2016-04-16

    Saber‐Mustapha Zendaoui, Jean‐Yves Saillard, Bachir Zouchoune

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  25. Coordination capabilities of anthracene ligand in binuclear sandwich complexes: DFT investigation

    Structural Chemistry · 2016-07-18

    Narimene Bensalem, Bachir Zouchoune

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  26. Reactivity of a Dititanium Bis(pentalene) Complex toward Heteroallenes and Main-Group Element–Element Bonds

    Organometallics · 2016-12-20

    Alexander F. R. Kilpatrick, Jennifer C. Green, F. Geoffrey N. Cloke

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  27. Bonding in pentalene complexes and their recent applications

    Coordination Chemistry Reviews · 2016-12-23

    F. Geoffrey N. Cloke, Jennifer C. Green, Alexander F. R. Kilpatrick, Dermot M. O'Hare

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  28. A new access route to dimetal sandwich complexes, including a radical anion

    Chemical Communications · 2018-01-01

    Nicholas S. Labrum, Yaroslav B. Losovyj, Kenneth George Caulton

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  29. Metal–metal bonded compounds with uncommon low oxidation state

    Coordination Chemistry Reviews · 2018-03-31

    Chun‐Shuai Cao, Ying Shi, Hang Xu, Bin Zhao

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  30. Metal–Metal (MM) Bond Distances and Bond Orders in Binuclear Metal Complexes of the First Row Transition Metals Titanium Through Zinc

    Chemical Reviews · 2018-12-13

    Richard H. Duncan Lyngdoh, Henry F. Schaefer, Robert Bruce King

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  31. Chromium(II) Complexes

    Elsevier eBooks · 2020-08-27

    Anders Reinholdt, Orion Staples, Daniel J. Mindiola

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  32. Cyclic and Non-cyclic Pi Complexes of Chromium

    Elsevier eBooks · 2021-10-30

    Tingting Song, Ying Mu

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  33. Twinned versus linked organometallics - bimetallic “half-baguette” pentalenide complexes of Rh( i )

    Dalton Transactions · 2024-01-01

    Hugh J. Sanderson, Gabriele I. Kociok-Köhn, Claire Louise McMullin, Ulrich Hintermair

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  34. Synthesis, characterisation, and magnetic properties of a permethylindenyl manganocene

    Dalton Transactions · 2025-01-01

    Alexander Evans, Thomas Arnold, Paul Ransom, Samantha C. Binding, William K. Myers, Agamemnon E. Crumpton, Zoë R. Turner, Jean‐Charles Buffet, Dermot M. O'Hare

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