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RESEARCH PAPER · Dalton Transactions · 2010

Self-assembly of polyoxoselenitopalladate nanostars [Pd15(μ3-SeO3)10(μ3-O)10Na]9− and their supramolecular pairing in the solid state

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Self-assembly of polyoxoselenitopalladate nanostars [Pd15(μ3-SeO3)10(μ3-O)10Na]9− and their supramolecular pairing in the solid stateOriginalPolyoxopalladates Encapsulating Yttrium and Lanthanide Ions, [XIIIPdII12(AsPh)8O32]5− (X=Y, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu)87A Noble‐Metalate Bowl: The Polyoxo‐6‐vanado(V)‐7‐palladate(II) [Pd7V6O24(OH)2]6−67Edelmetallatschale: Das Polyoxo‐6‐vanado(V)‐7‐palladat(II) [Pd7V6O24(OH)2]6−23Synthese und Charakterisierung des Dikupfer(II)‐haltigen 22‐Palladats(II) [CuII2PdII22PV12O60(OH)8]20−20Synthesis and Characterization of the Dicopper(II)‐Containing 22‐Palladate(II)[CuII2PdII22PV12O60(OH)8]20−66A Supramolecular Heteropolyoxopalladate {Pd15} Cluster Host Encapsulating a {Pd2} Dinuclear Guest: [PdII2⊂{H7PdII15O10(PO4)10}]9−60Synthesis, Structural Characterization, and Magnetic Properties of the Heteroleptic Dinuclear Nickel Selenite Complex [{Ni(TMEDA)SeO3}2]6Polyoxométallates et chimie verte : molécules et matériaux nanostructurés pour la conversion de l’énergie et l’environnement0Bis(triphenylphosphanylidene)iminium dichloridotriphenylstannate(IV)3Engineering polyoxometalates with emergent properties969The selenite-capped polyoxo-4-aurate(iii), [AuIII4O4(SeIVO3)4]4−35Cation-Induced Synthesis of New Polyoxopalladates47Edelmetalle in Polyoxometallaten72Noble Metals in Polyoxometalates404Controlling the Self‐Assembly of a Mixed‐Metal Mo/V–Selenite Family of Polyoxometalates34Polyoxopalladates Encapsulating 8-Coordinated Metal Ions, [MO8PdII12L8]n−(M = Sc3+, Mn2+, Fe3+, Co2+, Ni2+, Cu2+, Zn2+, Lu3+; L = PhAsO32–, PhPO32–, SeO32–)63New Chemistry of Noble Metals3Polyoxometalates: Synthesis and Structure – From Building Blocks to Emergent Materials67Controlled Synthesis of Polyoxopalladates, and Their Gas‐Phase Fragmentation Study by Electrospray Ionization Tandem Mass Spectrometry34Self-assembly and structural transformations of high-nuclearity palladium-rich polyoxometalates56The Mixed Gold–Palladium Polyoxo‐Noble‐Metalate [NaAuIII4PdII8O8(AsO4)8]11−42Alkaline Earth Guests in Polyoxopalladate Chemistry: From Nanocube to Nanostar via an Open‐Shell Structure67Erdalkalimetalle als Gastionen in der Polyoxopalladatchemie: vom Nanowürfel über eine offenschalige Struktur zum Nanostern18Exploring the electronic properties and cation complexation of polyoxoaurates [Au III 4 X 4 O m ] n− (X = Si IV , P V , Ge IV , As V , and Se IV ) using quantum chemical calculations2The polyoxo-22-palladate( ii ), [Na 2 PdII22O 12 (As V O 4 ) 15 (As V O 3 OH)] 25−18Classical/Non‐classical Polyoxometalate Hybrids12Discrete Silver(I)‐Palladium(II)‐Oxo Nanoclusters, {Ag4Pd13} and {Ag5Pd15}, and the Role of Metal–Metal Bonding Induced by Cation Confinement36Diskrete Silber(I)‐Palladium(II)‐Oxo‐Nanocluster, {Ag4Pd13} und {Ag5Pd15}, sowie die Rolle der Metall‐Metall‐Bindung induziert durch Kationen‐Einschluss8Alkali earth MO x ( x = 6, 7, 9, 12) polyhedra tuned cadmium selenites with different dimensions and diverse SeO 3 2− coordinations1Size and charge effect of guest cations in the formation of polyoxopalladates: a theoretical and experimental study28Structural motifs in heteroleptic copper and cadmium selenites7Rational Design of Organically Functionalized Polyoxopalladates and Their Supramolecular Properties33Role of Bis(triphenylphosphine)iminium Cation [PNP]+ on the Crystal Packing of [PNP]+[HSeO3]− Solvate Salt2Mild Synthesis and Structural Characterization of a Novel Vanadyl Selenite-Hydrogen Selenite Phase, Na[VO(SeO3)(HSeO3)]·1,5H2O2Discovery and Evolution of Polyoxopalladates126Exploring High-Symmetry Lanthanide-Functionalized Polyoxopalladates as Building Blocks for Quantum Computing10Synthèse de polyoxométallates hybrides et étude de leurs propriétés en biologie et en optique0Discovery of Polyoxo-Noble-Metalate-Based Metal–Organic Frameworks59Discrete Polyoxopalladates as Molecular Precursors for Supported Palladium Metal Nanoparticles as Hydrogenation Catalysts32Tetravalent Metal Ion Guests in Polyoxopalladate Chemistry: Synthesis and Anticancer Activity of [MO8Pd12(PO4)8]12– (M = SnIV, PbIV)24Organically templated zinc selenite compounds: synthesis, structural chemistry and DFT calculations5Polyoxopalladate-Loaded Metal–Organic Framework (POP@MOF): Synthesis and Heterogeneous Catalysis39Noble metals in polyoxometalates20Using topological analysis of the electron density to study a geometry-electronic structure relationship in M (d5–10)…O and E…O (E = Se,Te) compounds6Host–Guest Chemistry in Discrete Polyoxo-12-Palladate(II) Cubes [MO8Pd12L8]n− (M = ScIII, CoII, CuII, L = AsO43 –; M = CdII, HgII, L = PhAsO32–): Structure, Magnetism, and Catalytic Hydrogenation11Gallium(III)- and Thallium(III)-Encapsulated Polyoxopalladates: Synthesis, Structure, Multinuclear NMR, and Biological Activity Studies9Binary Heterogroup-Templated Scaffolds of Polyoxopalladates as Precatalysts for Plasma-Assisted Ammonia Synthesis13Electron‐Sponge Nature of Polyoxometalates for Next‐Generation Electrocatalytic Water Splitting and Nonvolatile Neuromorphic Devices58Lanthanoid-, Yttrium-, and Thorium-Centered Polyoxopalladates3Speciation‐Dependent Solvent Extraction of Polyoxopalladates Toward Separation of Critical Materials0Speciation‐Dependent Solvent Extraction of Polyoxopalladates Toward Separation of Critical Materials1Assembly modelling of cyclic and prismatic polyoxoaurates0

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  1. Polyoxopalladates Encapsulating Yttrium and Lanthanide Ions, [XIIIPdII12(AsPh)8O32]5− (X=Y, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu)

    Chemistry - A European Journal · 2010-06-29

    Maria Barsukova, Natalya V. Izarova, Rosa Ngo Biboum Bimbong, Bineta Keita, Louis Nadjo, V. Ramachandran, Naresh S. Dalal, Nadya S. Antonova, Jorge Juan Carbó, Josep Maria Poblet, Ulrich Kortz

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  2. A Noble‐Metalate Bowl: The Polyoxo‐6‐vanado(V)‐7‐palladate(II) [Pd7V6O24(OH)2]6−

    Angewandte Chemie International Edition · 2010-09-13

    Natalya V. Izarova, Nina Vankova, Abhishek Banerjee, Geoffrey B. Jameson, Thomas Heine, Florian Schinle, Oliver Hampe, Ulrich Kortz

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  3. Edelmetallatschale: Das Polyoxo‐6‐vanado(V)‐7‐palladat(II) [Pd7V6O24(OH)2]6−

    Angewandte Chemie · 2010-09-13

    Natalya V. Izarova, Nina Vankova, Abhishek Banerjee, Geoffrey B. Jameson, Thomas Heine, Florian Schinle, Oliver Hampe, Ulrich Kortz

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  4. Synthese und Charakterisierung des Dikupfer(II)‐haltigen 22‐Palladats(II) [CuII2PdII22PV12O60(OH)8]20−

    Angewandte Chemie · 2011-02-10

    Maria Barsukova-Stuckart, Natalya V. Izarova, Geoffrey B. Jameson, V. Ramachandran, Zhenxing Wang, Johan van Tol, Naresh S. Dalal, Rosa Ngo Biboum Bimbong, Bineta Keita, Louis Nadjo, Ulrich Kortz

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  5. Synthesis and Characterization of the Dicopper(II)‐Containing 22‐Palladate(II)[CuII2PdII22PV12O60(OH)8]20−

    Angewandte Chemie International Edition · 2011-02-10

    Maria Barsukova-Stuckart, Natalya V. Izarova, Geoffrey B. Jameson, V. Ramachandran, Zhenxing Wang, Johan van Tol, Naresh S. Dalal, Rosa Ngo Biboum Bimbong, Bineta Keita, Louis Nadjo, Ulrich Kortz

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  6. A Supramolecular Heteropolyoxopalladate {Pd15} Cluster Host Encapsulating a {Pd2} Dinuclear Guest: [PdII2⊂{H7PdII15O10(PO4)10}]9−

    Journal of the American Chemical Society · 2011-03-16

    Feng Xu, Rachel A. Scullion, Jun Yan, Haralampos N. Miras, Christoph Busche, Antonino Scandurra, Bruno Pignataro, De‐Liang Long, Leroy Cronin

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  7. Synthesis, Structural Characterization, and Magnetic Properties of the Heteroleptic Dinuclear Nickel Selenite Complex [{Ni(TMEDA)SeO3}2]

    European Journal of Inorganic Chemistry · 2011-06-22

    Massimiliano Delferro, Claudia Graiff, Luciano Marchiò, Lisa Elviri, Marcello Mazzani, Mauro Riccò, Giovanni Predieri

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  8. Polyoxométallates et chimie verte : molécules et matériaux nanostructurés pour la conversion de l’énergie et l’environnement

    Unknown journal · 2011-06-27

    Rosa Ngo Biboum

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  9. Bis(triphenylphosphanylidene)iminium dichloridotriphenylstannate(IV)

    Acta Crystallographica Section E Structure Reports Online · 2011-09-14

    Lucio De Lorentiis, Claudia Graiff, Giovanni Predieri

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  10. Engineering polyoxometalates with emergent properties

    Chemical Society Reviews · 2012-01-01

    Haralampos N. Miras, Jun Yan, De‐Liang Long, Leroy Cronin

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  11. The selenite-capped polyoxo-4-aurate(iii), [AuIII4O4(SeIVO3)4]4−

    Chemical Communications · 2012-01-01

    Yixian Xiang, Natalya V. Izarova, Florian Schinle, Oliver Hampe, Bineta Keita, Ulrich Kortz

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  12. Cation-Induced Synthesis of New Polyoxopalladates

    Inorganic Chemistry · 2012-04-02

    Zhengguo Lin, Bo Wang, Jie Cao, Baokuan Chen, Yuanzhe Gao, Yingnan Chi, Chong Xu, Xianqiang Huang, Ruodan Han, Shuangyue Su, Changwen Hu

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  13. Edelmetalle in Polyoxometallaten

    Angewandte Chemie · 2012-08-21

    Natalya V. Izarova, Michael T. Pope, Ulrich Kortz

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  14. Noble Metals in Polyoxometalates

    Angewandte Chemie International Edition · 2012-08-21

    Natalya V. Izarova, Michael T. Pope, Ulrich Kortz

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  15. Controlling the Self‐Assembly of a Mixed‐Metal Mo/V–Selenite Family of Polyoxometalates

    Chemistry - A European Journal · 2012-09-20

    M. Nieves Corella‐Ochoa, Haralampos N. Miras, De‐Liang Long, Leroy Cronin

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  16. Polyoxopalladates Encapsulating 8-Coordinated Metal Ions, [MO8PdII12L8]n−(M = Sc3+, Mn2+, Fe3+, Co2+, Ni2+, Cu2+, Zn2+, Lu3+; L = PhAsO32–, PhPO32–, SeO32–)

    Inorganic Chemistry · 2012-11-29

    Maria Barsukova-Stuckart, Natalya V. Izarova, Ryan Barrett, Zhenxing Wang, Johan van Tol, Harold Walter Kroto, Naresh S. Dalal, P. Jimenez-Lozano, Jorge Juan Carbó, Josep Maria Poblet, Marc von Gernler, Thomas Drewello, Pedro de Oliveira, Bineta Keita, Ulrich Kortz

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  17. New Chemistry of Noble Metals

    Elsevier eBooks · 2013-01-01

    Mathias Siegfried Wickleder, Christian Logemann

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  18. Polyoxometalates: Synthesis and Structure – From Building Blocks to Emergent Materials

    Elsevier eBooks · 2013-01-01

    Marie Hutin, Mali H. Rosnes, De‐Liang Long, Leroy Cronin

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  19. Controlled Synthesis of Polyoxopalladates, and Their Gas‐Phase Fragmentation Study by Electrospray Ionization Tandem Mass Spectrometry

    European Journal of Inorganic Chemistry · 2013-05-21

    Zhengguo Lin, Bo Wang, Jie Cao, Baokuan Chen, Chong Xu, Xianqiang Huang, Yanxuan Fan, Changwen Hu

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  20. Self-assembly and structural transformations of high-nuclearity palladium-rich polyoxometalates

    Inorganic Chemistry Frontiers · 2014-01-01

    Jamie M. Cameron, Jing Gao, De-Liang Long, Leroy Cronin

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  21. The Mixed Gold–Palladium Polyoxo‐Noble‐Metalate [NaAuIII4PdII8O8(AsO4)8]11−

    Chemistry - A European Journal · 2014-06-04

    Natalya V. Izarova, Aleksandar Kondinski, Nina Vankova, Thomas Heine, Patrick Jäger, Florian Schinle, Oliver Hampe, Ulrich Kortz

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  22. Alkaline Earth Guests in Polyoxopalladate Chemistry: From Nanocube to Nanostar via an Open‐Shell Structure

    Angewandte Chemie International Edition · 2014-09-12

    Peng Yang, Yixian Xiang, Zhengguo Lin, Bassem S. Bassil, Jie Cao, Linyuan Fan, Yanxuan Fan, Ming‐Xing Li, P. Jimenez-Lozano, Jorge Juan Carbó, Josep Maria Poblet, Ulrich Kortz

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  23. Erdalkalimetalle als Gastionen in der Polyoxopalladatchemie: vom Nanowürfel über eine offenschalige Struktur zum Nanostern

    Angewandte Chemie · 2014-09-12

    Peng Yang, Yixian Xiang, Zhengguo Lin, Bassem S. Bassil, Jie Cao, Linyuan Fan, Yanxuan Fan, Ming‐Xing Li, P. Jimenez-Lozano, Jorge Juan Carbó, Josep Maria Poblet, Ulrich Kortz

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  24. Exploring the electronic properties and cation complexation of polyoxoaurates [Au III 4 X 4 O m ] n− (X = Si IV , P V , Ge IV , As V , and Se IV ) using quantum chemical calculations

    Physical Chemistry Chemical Physics · 2015-01-01

    Caixia Wu, Tengying Ma, Li‐Kai Yan, Ting Zhang, Zhong‐Min Su

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  25. The polyoxo-22-palladate( ii ), [Na 2 PdII22O 12 (As V O 4 ) 15 (As V O 3 OH)] 25−

    Dalton Transactions · 2016-01-01

    Natalya V. Izarova, Zhengguo Lin, Peng Yang, Aleksandar Kondinski, Nina Vankova, Thomas Heine, Ulrich Kortz

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  26. Classical/Non‐classical Polyoxometalate Hybrids

    Chemistry - A European Journal · 2016-09-12

    Natalya V. Izarova, Beatrix Santiago‐Schübel, Sabine Willbold, Volkmar Heß, Paul Kögerler

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  27. Discrete Silver(I)‐Palladium(II)‐Oxo Nanoclusters, {Ag4Pd13} and {Ag5Pd15}, and the Role of Metal–Metal Bonding Induced by Cation Confinement

    Angewandte Chemie International Edition · 2016-11-29

    Peng Yang, Yixian Xiang, Zhengguo Lin, Zhongling Lang, P. Jimenez-Lozano, Jorge Juan Carbó, Josep Maria Poblet, Linyuan Fan, Changwen Hu, Ulrich Kortz

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  28. Diskrete Silber(I)‐Palladium(II)‐Oxo‐Nanocluster, {Ag4Pd13} und {Ag5Pd15}, sowie die Rolle der Metall‐Metall‐Bindung induziert durch Kationen‐Einschluss

    Angewandte Chemie · 2016-11-29

    Peng Yang, Yixian Xiang, Zhengguo Lin, Zhongling Lang, P. Jimenez-Lozano, Jorge Juan Carbó, Josep Maria Poblet, Linyuan Fan, Changwen Hu, Ulrich Kortz

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  29. Alkali earth MO x ( x = 6, 7, 9, 12) polyhedra tuned cadmium selenites with different dimensions and diverse SeO 3 2− coordinations

    CrystEngComm · 2017-01-01

    Ying‐Jie Jia, Yi-Gang Chen, Xiao-Ni Yao, Xian‐Ming Zhang

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  30. Size and charge effect of guest cations in the formation of polyoxopalladates: a theoretical and experimental study

    Chemical Science · 2017-01-01

    Zhongling Lang, Peng Yang, Zhengguo Lin, Li‐Kai Yan, Ming‐Xing Li, Jorge Juan Carbó, Ulrich Kortz, Josep Maria Poblet

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  31. Structural motifs in heteroleptic copper and cadmium selenites

    Inorganica Chimica Acta · 2017-06-03

    Stefano Canossa, Enrico Bellè, Massimiliano Delferro, Giovanni Predieri, Claudia Graiff

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  32. Rational Design of Organically Functionalized Polyoxopalladates and Their Supramolecular Properties

    Chemistry - A European Journal · 2017-12-05

    Peng Yang, Hui Li, Tian Ma, Fadi Haso, Tianbo Liu, Linyuan Fan, Zhengguo Lin, Changwen Hu, Ulrich Kortz

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  33. Role of Bis(triphenylphosphine)iminium Cation [PNP]+ on the Crystal Packing of [PNP]+[HSeO3]− Solvate Salt

    Crystals · 2018-03-29

    Stefano Canossa, Claudia Graiff

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  34. Mild Synthesis and Structural Characterization of a Novel Vanadyl Selenite-Hydrogen Selenite Phase, Na[VO(SeO3)(HSeO3)]·1,5H2O

    Crystals · 2018-05-15

    Stefano Canossa, Giovanni Predieri, Claudia Graiff

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  35. Discovery and Evolution of Polyoxopalladates

    Accounts of Chemical Research · 2018-06-18

    Peng Yang, Ulrich Kortz

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  36. Exploring High-Symmetry Lanthanide-Functionalized Polyoxopalladates as Building Blocks for Quantum Computing

    Inorganics · 2018-09-21

    José J. Baldoví, Aleksandar Kondinski

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  37. Synthèse de polyoxométallates hybrides et étude de leurs propriétés en biologie et en optique

    Unknown journal · 2018-11-05

    Amandine Boulmier

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  38. Discovery of Polyoxo-Noble-Metalate-Based Metal–Organic Frameworks

    Journal of the American Chemical Society · 2019-02-02

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  39. Discrete Polyoxopalladates as Molecular Precursors for Supported Palladium Metal Nanoparticles as Hydrogenation Catalysts

    Inorganic Chemistry · 2019-04-05

    Wassim W. Ayass, Juan Francisco Miñambres, Peng Yang, Tian Ma, Zhengguo Lin, Randall J. Meyer, Helge Jaensch, Anton‐Jan Bons, Ulrich Kortz

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  40. Tetravalent Metal Ion Guests in Polyoxopalladate Chemistry: Synthesis and Anticancer Activity of [MO8Pd12(PO4)8]12– (M = SnIV, PbIV)

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  41. Organically templated zinc selenite compounds: synthesis, structural chemistry and DFT calculations

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  42. Polyoxopalladate-Loaded Metal–Organic Framework (POP@MOF): Synthesis and Heterogeneous Catalysis

    Inorganic Chemistry · 2020-07-15

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  43. Noble metals in polyoxometalates

    Inorganica Chimica Acta · 2021-04-14

    Morteza Tahmasebi, Masoud Mirzaei, Antonio Frontera

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  44. Using topological analysis of the electron density to study a geometry-electronic structure relationship in M (d5–10)…O and E…O (E = Se,Te) compounds

    Computational and Theoretical Chemistry · 2021-05-03

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  45. Host–Guest Chemistry in Discrete Polyoxo-12-Palladate(II) Cubes [MO8Pd12L8]n− (M = ScIII, CoII, CuII, L = AsO43 –; M = CdII, HgII, L = PhAsO32–): Structure, Magnetism, and Catalytic Hydrogenation

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  46. Gallium(III)- and Thallium(III)-Encapsulated Polyoxopalladates: Synthesis, Structure, Multinuclear NMR, and Biological Activity Studies

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  47. Binary Heterogroup-Templated Scaffolds of Polyoxopalladates as Precatalysts for Plasma-Assisted Ammonia Synthesis

    ACS Applied Materials & Interfaces · 2023-09-10

    Yue Yu Zhao, Kelin Li, Jing Hong Du, Chao‐Qin Chen, She Chen, Peng Yang

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  48. Electron‐Sponge Nature of Polyoxometalates for Next‐Generation Electrocatalytic Water Splitting and Nonvolatile Neuromorphic Devices

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  49. Lanthanoid-, Yttrium-, and Thorium-Centered Polyoxopalladates

    Inorganic Chemistry · 2025-06-12

    Doctor Stephen, Alexander Roseborough, Dhruba R. Paudel, Pere Miró, May Nyman

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  50. Speciation‐Dependent Solvent Extraction of Polyoxopalladates Toward Separation of Critical Materials

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