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RESEARCH PAPER · Inorganic Chemistry · 2008

Metal Tetraphosphonate “Wires” and Their Corrosion Inhibiting Passive Films

Konstantinos D. Demadis, Eleni Barouda, Raphael G. Raptis, Hong Lin Zhao

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Metal Tetraphosphonate “Wires” and Their Corrosion Inhibiting Passive FilmsOriginal“Breathing” in Adsorbate‐Responsive Metal Tetraphosphonate Hybrid Materials43Structural architectures of charge-assisted, hydrogen-bonded, 2D layered amine⋯tetraphosphonate and zinc⋯tetraphosphonate ionic materials20STRUCTURAL MAPPING OF HYBRID METAL PHOSPHONATE CORROSION INHIBITING THIN FILMS41Cation effect on the inorganic–organic layered structure of pyrazole-4-sulfonate networks and inhibitory effects on copper corrosion23Novel polydentate phosphonic acids: Protonation and stability constants of complexes with Fe(III) and Cu(II) in aqueous medium14Two new layer structures of zinc(II) or strontium(II) diphosphonates based on N,N-dimethylaminomethane-1,1-diphosphonate ligand4Controlled Release of Bis(phosphonate) Pharmaceuticals from Cationic Biodegradable Polymeric Matrices91Strontium and barium 4-carboxylphenylphosphonates: Hybrid anti-corrosion coatings for magnesium alloy24Divalent Metal Vinylphosphonate Layered Materials: Compositional Variability, Structural Peculiarities, Dehydration Behavior, and Photoluminescent Properties27Mapping the supramolecular chemistry of pyrazole-4-sulfonate: layered inorganic–organic networks with Zn 2+ , Cd 2+ , Ag + , Na + and NH 4 + , and their use in copper anticorrosion protective films14Multifunctional lanthanum tetraphosphonates: Flexible, ultramicroporous and proton-conducting hybrid frameworks96Surface Modification Using Phosphonic Acids and Esters868Structural similarities in 1D coordination polymers of alkaline earth diphosphinates6High Proton Conductivity in a Flexible, Cross-Linked, Ultramicroporous Magnesium Tetraphosphonate Hybrid Framework124Linking 31P Magnetic Shielding Tensors to Crystal Structures: Experimental and Theoretical Studies on Metal(II) Aminotris(methylenephosphonates)21Synthesis, breathing, and gas sorption study of the first isoreticular mixed-linker phosphonate based metal–organic frameworks91Alkaline-earth metal phosphonocarboxylates: synthesis, structures, chirality, and luminescence properties3A Water-Stable Metal–Organic Framework with Highly Acidic Pores for Proton-Conducting Applications440Structural Variability in Multifunctional Metal Xylenediaminetetraphosphonate Hybrids55Intercalates of Strontium Phenylphosphonate with Alcohols – Structure Analysis by Experimental and Molecular Modeling Methods6Hybrid Materials Based on Multifunctional Phosphonic Acids4Phosphonates in Matrices11Light guided chemoselective olefin metathesis reactions13Photoluminescent Lanthanide-Organic Framework Based on a Tetraphosphonic Acid Linker23From light to heavy alkali metal tetraphosphonates (M = Li, Na, K, Rb, Cs): cation size-induced structural diversity and water-facilitated proton conductivity20Synthesis, spectral properties and corrosion inhibition efficiency of new ethyl hydrogen [(methoxyphenyl) (methylamino) methyl] phosphonate derivatives: Experimental and theoretical investigation70Corrosion protection of carbon steel by tetraphosphonates of systematically different molecular size81Fonctionnalisation du chitosane : vers un nouveau revêtement biosourcé pour la protection des métaux contre la corrosion0Supramolecular concepts and approaches in corrosion and biofouling prevention65Researching Advances of Chemically Modified Metal Surfaces by Organophosphonates0Chemical Methods for Scaling Control21Corrosion Control Using Inhibitor Systems Based on Phosphonates and Metal Phosphonate Materials1Zinc and Cadmium Nitrilotris(methylenephosphonate)s: A Comparative Study of Different Coordination Structures for Corrosion Inhibition of Steels in Neutral Aqueous Media25Synergistic effect of potassium iodide on corrosion inhibition of copper by tetraphosphonic acid in hydrochloric acid solution24Electrochemical investigation of di-phosphonic acid on corrosion inhibition behavior of copper in hydrochloric acid medium4Layered Inorganic–Organic 3,5-Dimethylpyrazole-4-Sulfonate Films for Protection of Copper Surfaces against Corrosion3Investigation of sorptive interaction between phosphonate inhibitor and barium sulfate for oilfield scale control22Chemical and Physical Properties of Nano-Hybrid Smart Coatings8Breathing Effect in a Tetrapodal Lanthanide‐Phosphonate Organic Framework1Corrosion Management with a Homologous Series of Phosphonate-Functionalized Linear Amino Acids as Environmentally Acceptable Corrosion Inhibitors4

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  1. “Breathing” in Adsorbate‐Responsive Metal Tetraphosphonate Hybrid Materials

    Chemistry - A European Journal · 2009-05-28

    Rosario M. P. Colodrero, Aurelio Cabeza, Pascual Olivera‐Pastor, Antonia Infantes‐Molina, Eleni Barouda, Konstantinos D. Demadis, Miguel Á. G. Aranda

    Read original paper ↗ ·

  2. Structural architectures of charge-assisted, hydrogen-bonded, 2D layered amine⋯tetraphosphonate and zinc⋯tetraphosphonate ionic materials

    Polyhedron · 2009-05-30

    Konstantinos D. Demadis, Eleni Barouda, Hong Lin Zhao, Raphael G. Raptis

    Read original paper ↗ ·

  3. STRUCTURAL MAPPING OF HYBRID METAL PHOSPHONATE CORROSION INHIBITING THIN FILMS

    Comments on Inorganic Chemistry · 2009-07-31

    Maria I. Papadaki, Konstantinos D. Demadis

    Read original paper ↗ ·

  4. Cation effect on the inorganic–organic layered structure of pyrazole-4-sulfonate networks and inhibitory effects on copper corrosion

    New Journal of Chemistry · 2010-01-01

    Isurika R. Fernando, Nikos Daskalakis, Konstantinos D. Demadis, Gellert Mezei

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  5. Novel polydentate phosphonic acids: Protonation and stability constants of complexes with Fe(III) and Cu(II) in aqueous medium

    Heteroatom Chemistry · 2010-01-01

    Nabila Aliouane, Salah Chafaa, Tahar Douadi, Jean‐Jacques Hélesbeux, Mustayeen A. Khan, Olivier Duval, Gilles Bouet

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  6. Two new layer structures of zinc(II) or strontium(II) diphosphonates based on N,N-dimethylaminomethane-1,1-diphosphonate ligand

    Journal of Molecular Structure · 2011-03-13

    Yu-Hui Sun, Zi‐Yi Du, Zhonggao Zhou, Shi‐Yong Zhang, Guohai Xu, Yong‐Rong Xie

    Read original paper ↗ ·

  7. Controlled Release of Bis(phosphonate) Pharmaceuticals from Cationic Biodegradable Polymeric Matrices

    Industrial & Engineering Chemistry Research · 2011-03-22

    Konstantinos D. Demadis, Maria Paspalaki, Ioanna Théodorou

    Read original paper ↗ ·

  8. Strontium and barium 4-carboxylphenylphosphonates: Hybrid anti-corrosion coatings for magnesium alloy

    Inorganic Chemistry Communications · 2011-09-15

    Dongmian Zang, Deng‐Ke Cao, Li‐Min Zheng

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  9. Divalent Metal Vinylphosphonate Layered Materials: Compositional Variability, Structural Peculiarities, Dehydration Behavior, and Photoluminescent Properties

    Inorganic Chemistry · 2011-09-27

    Rosario M. P. Colodrero, Aurelio Cabeza, Pascual Olivera‐Pastor, Duane Choquesillo‐Lazarte, Juan Manuel Garcı́a-Ruiz, Adele Turner, Gheorghe Ilia, Bianca Maranescu, Konstantinos E. Papathanasiou, Gary B. Hix, Konstantinos D. Demadis, Miguel Á. G. Aranda

    Read original paper ↗ ·

  10. Mapping the supramolecular chemistry of pyrazole-4-sulfonate: layered inorganic–organic networks with Zn 2+ , Cd 2+ , Ag + , Na + and NH 4 + , and their use in copper anticorrosion protective films

    CrystEngComm · 2011-11-11

    Isurika R. Fernando, Sarut Jianrattanasawat, Nikos Daskalakis, Konstantinos D. Demadis, Gellert Mezei

    Read original paper ↗ ·

  11. Multifunctional lanthanum tetraphosphonates: Flexible, ultramicroporous and proton-conducting hybrid frameworks

    Dalton Transactions · 2012-01-01

    Rosario M. P. Colodrero, Pascual Olivera‐Pastor, Enrique R. Losilla, Miguel Á. G. Aranda, Laura León‐Reina, Maria I. Papadaki, Alistair C. McKinlay, Russell E. Morris, Konstantinos D. Demadis, Aurelio Cabeza

    Read original paper ↗ ·

  12. Surface Modification Using Phosphonic Acids and Esters

    Chemical Reviews · 2012-04-24

    Clémence Queffélec, Marc Petit, Pascal Janvier, D. Andrew Knight, Bruno Bujoli

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  13. Structural similarities in 1D coordination polymers of alkaline earth diphosphinates

    Inorganica Chimica Acta · 2012-06-01

    Ferdinando Costantino, Pier Luigi Gentili, Annalisa Guerri, Andrea Ienco, Stefano Midollini, Werner Oberhauser

    Read original paper ↗ ·

  14. High Proton Conductivity in a Flexible, Cross-Linked, Ultramicroporous Magnesium Tetraphosphonate Hybrid Framework

    Inorganic Chemistry · 2012-07-03

    Rosario M. P. Colodrero, Pascual Olivera‐Pastor, Enrique R. Losilla, Daniel Hernández‐Alonso, Miguel Á. G. Aranda, Laura León‐Reina, Jordi Rius, Konstantinos D. Demadis, Bernard Moreau, Didier Villemin, Miguel Palomino, Fernando Rey, Aurelio Cabeza

    Read original paper ↗ ·

  15. Linking 31P Magnetic Shielding Tensors to Crystal Structures: Experimental and Theoretical Studies on Metal(II) Aminotris(methylenephosphonates)

    Inorganic Chemistry · 2012-10-05

    Johannes Weber, Gisbert Großmann, Konstantinos D. Demadis, Nikos Daskalakis, Erica Brendler, Martin Mangstl, Jörn Schmedt auf der Günne

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  16. Synthesis, breathing, and gas sorption study of the first isoreticular mixed-linker phosphonate based metal–organic frameworks

    Chemical Communications · 2012-12-21

    Marco Taddei, Ferdinando Costantino, Andrea Ienco, Angiolina Comotti, P.V. Dau, Seth M. Cohen

    Read original paper ↗ ·

  17. Alkaline-earth metal phosphonocarboxylates: synthesis, structures, chirality, and luminescence properties

    Dalton Transactions · 2013-01-01

    Vı́tězslav Zima, Duraisamy Senthil Raja, Yu-Shan Lee, Ting-Guang Chang, Cheng-You Wu, Chien‐Chieh Hu, Kueir‐Rarn Lee, Juin‐Yih Lai, Jui‐Ming Yeh, Chia‐Her Lin

    Read original paper ↗ ·

  18. A Water-Stable Metal–Organic Framework with Highly Acidic Pores for Proton-Conducting Applications

    Journal of the American Chemical Society · 2013-01-10

    Jared M. Taylor, Karl W. Dawson, George K. H. Shimizu

    Read original paper ↗ ·

  19. Structural Variability in Multifunctional Metal Xylenediaminetetraphosphonate Hybrids

    Inorganic Chemistry · 2013-07-24

    Rosario M. P. Colodrero, Giasemi K. Angeli, Montse Bazaga-García, Pascual Olivera‐Pastor, Didier Villemin, Enrique R. Losilla, Estefania Q. Martos, Gary B. Hix, Miguel Á. G. Aranda, Konstantinos D. Demadis, Aurelio Cabeza

    Read original paper ↗ ·

  20. Intercalates of Strontium Phenylphosphonate with Alcohols – Structure Analysis by Experimental and Molecular Modeling Methods

    European Journal of Inorganic Chemistry · 2015-02-11

    Vı́tězslav Zima, Klára Melánová, Petr Kovář, Ludvı́k Beneš, Jan Svoboda, Miroslav Pospı́šil, Aleš Růžička

    Read original paper ↗ ·

  21. Hybrid Materials Based on Multifunctional Phosphonic Acids

    Unknown journal · 2015-02-27

    Aurelio Cabeza, Pascual Olivera‐Pastor, Rosario M. P. Colodrero

    Read original paper ↗ ·

  22. Phosphonates in Matrices

    Unknown journal · 2015-02-27

    Konstantinos E. Papathanasiou, Konstantinos D. Demadis

    Read original paper ↗ ·

  23. Light guided chemoselective olefin metathesis reactions

    Pure and Applied Chemistry · 2017-03-17

    Ofer Reany, Norberto Gabriel Lemcoff

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  24. Photoluminescent Lanthanide-Organic Framework Based on a Tetraphosphonic Acid Linker

    Crystal Growth & Design · 2017-08-25

    Ricardo F. Mendes, Duarte Ananias, Luís D. Carlos, João Rocha, Filipe A. Almeida Paz

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  25. From light to heavy alkali metal tetraphosphonates (M = Li, Na, K, Rb, Cs): cation size-induced structural diversity and water-facilitated proton conductivity

    CrystEngComm · 2018-01-01

    Inés R. Salcedo, Rosario M. P. Colodrero, Montse Bazaga-García, Antonia Vasileiou, Maria I. Papadaki, Pascual Olivera‐Pastor, Antonia Infantes‐Molina, Enrique R. Losilla, Gellert Mezei, Aurelio Cabeza, Konstantinos D. Demadis

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  26. Synthesis, spectral properties and corrosion inhibition efficiency of new ethyl hydrogen [(methoxyphenyl) (methylamino) methyl] phosphonate derivatives: Experimental and theoretical investigation

    Journal of Molecular Structure · 2018-07-26

    Meriem Djenane, Salah Chafaa, Nadjib Chafai, Rachida Kerkour, Abdelkader Hellal

    Read original paper ↗ ·

  27. Corrosion protection of carbon steel by tetraphosphonates of systematically different molecular size

    Corrosion Science · 2018-10-03

    Argyri Moschona, Nicoleta Pleşu, Gellert Mezei, Andrew Guy Thomas, Konstantinos D. Demadis

    Read original paper ↗ ·

  28. Fonctionnalisation du chitosane : vers un nouveau revêtement biosourcé pour la protection des métaux contre la corrosion

    Unknown journal · 2018-10-04

    Clément Coquery

    Read original paper ↗ ·

  29. Supramolecular concepts and approaches in corrosion and biofouling prevention

    Corrosion Reviews · 2019-03-16

    Viswanathan S. Saji

    Read original paper ↗ ·

  30. Researching Advances of Chemically Modified Metal Surfaces by Organophosphonates

    IOP Conference Series Earth and Environmental Science · 2019-07-08

    Mei Ji

    Read original paper ↗ ·

  31. Chemical Methods for Scaling Control

    Springer eBooks · 2020-01-01

    Argyro Spinthaki, Konstantinos D. Demadis

    Read original paper ↗ ·

  32. Corrosion Control Using Inhibitor Systems Based on Phosphonates and Metal Phosphonate Materials

    NACE CORROSION Conference · 2020-03-15

    Konstantinos D. Demadis, Argyri Moschona, Nicoleta Pleşu, Andrew Guy Thomas

    Read original paper ↗ ·

  33. Zinc and Cadmium Nitrilotris(methylenephosphonate)s: A Comparative Study of Different Coordination Structures for Corrosion Inhibition of Steels in Neutral Aqueous Media

    ChemistrySelect · 2020-11-19

    Feodor Feodorovich Chausov, Irina S. Kazantseva, Sergey M. Reshetnikov, Natalya V. Lomova, Alyona Nikolaevna Maratkanova, Н. В. Сомов

    Read original paper ↗ ·

  34. Synergistic effect of potassium iodide on corrosion inhibition of copper by tetraphosphonic acid in hydrochloric acid solution

    Journal of Adhesion Science and Technology · 2021-05-12

    Naima Sait, Nabila Aliouane, Nadia Ait Ahmed, Linda Toukal, Mousa Z. Al-Noaimi

    Read original paper ↗ ·

  35. Electrochemical investigation of di-phosphonic acid on corrosion inhibition behavior of copper in hydrochloric acid medium

    Journal of the Iranian Chemical Society · 2021-06-26

    Naima Sait, Nabila Aliouane, Nadia Ait Ahmed, Mousa Z. Al-Noaimi

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  36. Layered Inorganic–Organic 3,5-Dimethylpyrazole-4-Sulfonate Films for Protection of Copper Surfaces against Corrosion

    Crystal Growth & Design · 2021-08-05

    Wisam A. Al Isawi, Sarut Jianrattanasawat, Eleftherios Tripodianos, Konstantinos D. Demadis, Alexander M. Kirillov, Mat­thias Zeller, Gellert Mezei

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  37. Investigation of sorptive interaction between phosphonate inhibitor and barium sulfate for oilfield scale control

    Journal of Petroleum Science and Engineering · 2021-08-26

    Yuan Liu, Zhaoyi Joey Dai, Amy T. Kan, Mason B. Tomson, Ping Zhang

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  38. Chemical and Physical Properties of Nano-Hybrid Smart Coatings

    ACS symposium series · 2024-06-18

    Abhinay Thakur, Ashish Kumar

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  39. Breathing Effect in a Tetrapodal Lanthanide‐Phosphonate Organic Framework

    European Journal of Inorganic Chemistry · 2024-11-06

    Ricardo F. Mendes, Filipe A. Almeida Paz

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  40. Corrosion Management with a Homologous Series of Phosphonate-Functionalized Linear Amino Acids as Environmentally Acceptable Corrosion Inhibitors

    ACS ES&T Water · 2025-08-28

    Adilla A. Pires, Georgios P. Apladas, Alankaa Al-Harbi, Saeed Al‐Meer, Mazen M. Khaled, Apostolos Fanourgiakis, Ibnelwaleed A. Hussein, Safwat Abdel‐Azeim, Konstantinos D. Demadis, Mohamed F. Mady

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