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RESEARCH PAPER · Inorganic Chemistry · 1977

Metal-metal bonding in reduced scandium halides. Synthesis and characterization of heptascandium decachloride (Sc7Cl10). A novel metal-chain structure

Kenneth Reinhard Poeppelmeier, John D. Corbett

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Metal-metal bonding in reduced scandium halides. Synthesis and characterization of heptascandium decachloride (Sc7Cl10). A novel metal-chain structureOriginalChemInform Abstract: METAL‐METAL BONDING IN REDUCED SCANDIUM HALIDES. SYNTHESIS AND CHARACTERIZATION OF HEPTASCANDIUM DECACHLORIDE (SC7CL10). A NOVEL METAL‐CHAIN STRUCTURE0Structure and bonding in metal-rich compounds: Pnictides, chalcides and halides140Was wissen wir über die Metall-Metall-Bindung?60What Do We Know about the Metal‐Metal Bond?108Metallreiche Verbindungen der Seltenen Erden Gd2Cl3, Gd2Br3 und Tb2Cl370Mixed-Valency in Discrete and Condensed Transition Metal Cluster Species with Classical Ligands0Monohalogenide der Lanthanoide [1]58Neue metallreiche erbiumjodide mit kondensierten clustern: Er7I10 und Er4I521Condensed Metal Clusters194Kondensierte Metall‐Cluster141Correlation of metal-metal bonding in halides and chalcides of the early transition elements with that in the metals66Extended metal-metal bonding in halides of the early transition metals82A Novel Kind of Metal-Rich Lanthanide Compound2Synthesis and structures of Sc7Cl12 and Zr6Cl1520Multiple metal-metal bonding and A-chain integrity in superconducting A3B (β-tungsten) alloy2Bond-alternating H�ckel-M�bius and related, twisted linear, cyclic and helical systems?their molecular orbitals, energies and phase correlation upon dissociation8Kinetics of the F,F2/Gd(s,v) reactions1Interstitial atoms in metal-metal bonded arrays: The synthesis and characterization of heptascandium decachlorodicarbide, Sc7Cl10C2, and comparison with the interstitial-free Sc7Cl1028Scandium2From Three-Dimensional to One-Dimensional Cluster Mo6 Chalcogenides17New Transition Metal Halides and Oxides with Extended Metal—Metal Bonding16Metal-metal-bonded scandium cluster (Sc7Cl12Z) and infinite chain (Sc4Cl6Z) phases stabilized by interstitial boron or nitrogen (Z)73Metal-metal bonding and interstitials in reduced rare earth metal halides4Bonding in clusters and condensed cluster compounds that extend in one, two and three dimensions91Chapter 100 Metal-rich halides120Discrete and Condensed Transition Metal Clusters in Solids28Sc2Te: ein neuartiges Beispiel für kondensierte Metallpolyeder in einer metallreichen, aber elektronenarmen Verbindung4Sc2Te: A Novel Example of Condensed Metal Polyhedra in a Metal‐Rich but Relatively Electron‐Poor Compound31Sc9Te2: A Two-Dimensional Distortion Wave in the Scandium-Richest Telluride30Two-Dimensional Metallic Chain Compounds Y5M2Te2 (M = Fe, Co, Ni) That Are Related to Gd3MnI3. The Hydride Derivative Y5Ni2Te2D0.415Exploratory synthesis of reduced rare-earth-metal halides, chalcogenides, intermetallics36Halogenide der Seltenerdmetalle Ln4X5Z. Teil 2: Eine orthorhombische Verknüpfungsvariante o‐Ln4X5Z10Eight‐Coordinate Endohedral Rhenium, Osmium and Iridium Atoms in Rare‐Earth Halide Cluster Complexes19Lanthanides: Metal Cluster Complexes0Clusters and Cluster Assemblies30Oligomeric rare-earth metal cluster complexes with endohedral transition metal atoms6Structural properties of scandium inorganic salts17Identifying quasi-2D and 1D electrides in yttrium and scandium chlorides via geometrical identification52Metal–Metal (MM) Bond Distances and Bond Orders in Binuclear Metal Complexes of the First Row Transition Metals Titanium Through Zinc170Ferromagnetic two-dimensional metal-chlorides MCl (M = Sc, Y, and La): Candidates for Weyl nodal line semimetals with small spin-orbit coupling gaps47

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  1. ChemInform Abstract: METAL‐METAL BONDING IN REDUCED SCANDIUM HALIDES. SYNTHESIS AND CHARACTERIZATION OF HEPTASCANDIUM DECACHLORIDE (SC7CL10). A NOVEL METAL‐CHAIN STRUCTURE

    ChemInform · 1977-07-26

    Kenneth Reinhard Poeppelmeier, John D. Corbett

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  2. Structure and bonding in metal-rich compounds: Pnictides, chalcides and halides

    Progress in Solid State Chemistry · 1978-01-01

    Hugo Frits Franzen

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  3. Was wissen wir über die Metall-Metall-Bindung?

    Angewandte Chemie · 1978-06-01

    Heinrich Vahrenkamp

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  4. What Do We Know about the Metal‐Metal Bond?

    Angewandte Chemie International Edition in English · 1978-06-01

    Heinrich Vahrenkamp

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  5. Metallreiche Verbindungen der Seltenen Erden Gd2Cl3, Gd2Br3 und Tb2Cl3

    Zeitschrift für anorganische und allgemeine Chemie · 1979-01-01

    Arndt Simon, Norbert Holzer, H. Mattusch

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  6. Mixed-Valency in Discrete and Condensed Transition Metal Cluster Species with Classical Ligands

    Springer eBooks · 1980-01-01

    Robert E. McCarley

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  7. Monohalogenide der Lanthanoide [1]

    Zeitschrift für anorganische und allgemeine Chemie · 1980-07-01

    Hj. Mattausch, Arndt Simon, Norbert Holzer, Roland Eger

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  8. Neue metallreiche erbiumjodide mit kondensierten clustern: Er7I10 und Er4I5

    Journal of the Less Common Metals · 1980-12-01

    Karl E. Berroth, Arndt Simon

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  9. Condensed Metal Clusters

    Angewandte Chemie International Edition in English · 1981-01-01

    Arndt Simon

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  10. Kondensierte Metall‐Cluster

    Angewandte Chemie · 1981-01-01

    Arndt Simon

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  11. Correlation of metal-metal bonding in halides and chalcides of the early transition elements with that in the metals

    Journal of Solid State Chemistry · 1981-05-01

    John D. Corbett

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  12. Extended metal-metal bonding in halides of the early transition metals

    Accounts of Chemical Research · 1981-08-01

    John D. Corbett

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  13. A Novel Kind of Metal-Rich Lanthanide Compound

    Springer eBooks · 1982-01-01

    Arndt Simon

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  14. Synthesis and structures of Sc7Cl12 and Zr6Cl15

    Zeitschrift für anorganische und allgemeine Chemie · 1982-08-01

    John D. Corbett, Kenneth Reinhard Poeppelmeier, Richard Lynn Daake

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  15. Multiple metal-metal bonding and A-chain integrity in superconducting A3B (β-tungsten) alloy

    Journal of Solid State Chemistry · 1982-12-01

    Ying‐Nan Chiu, Frederick E. Wang

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  16. Bond-alternating H�ckel-M�bius and related, twisted linear, cyclic and helical systems?their molecular orbitals, energies and phase correlation upon dissociation

    Theoretical Chemistry Accounts · 1983-01-01

    Ying‐Nan Chiu

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  17. Kinetics of the F,F2/Gd(s,v) reactions

    Metallurgical Transactions A · 1983-01-01

    Paul C. Nordine, Robert M. Atkins, Atilla M.öner

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  18. Interstitial atoms in metal-metal bonded arrays: The synthesis and characterization of heptascandium decachlorodicarbide, Sc7Cl10C2, and comparison with the interstitial-free Sc7Cl10

    Journal of Solid State Chemistry · 1985-03-01

    Shiou Jyh Hwu, John D. Corbett, Kenneth Reinhard Poeppelmeier

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  19. Scandium

    Coordination Chemistry Reviews · 1985-03-01

    Edwin C. Constable

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  20. From Three-Dimensional to One-Dimensional Cluster Mo6 Chalcogenides

    Springer eBooks · 1986-01-01

    Roger Chevrel, MARCEL SERGENT

    Read original paper ↗ ·

  21. New Transition Metal Halides and Oxides with Extended Metal—Metal Bonding

    Springer eBooks · 1986-01-01

    John D. Corbett, Robert E. McCarley

    Read original paper ↗ ·

  22. Metal-metal-bonded scandium cluster (Sc7Cl12Z) and infinite chain (Sc4Cl6Z) phases stabilized by interstitial boron or nitrogen (Z)

    Journal of Solid State Chemistry · 1986-10-01

    Shiou‐Jyh Hwu, John D. Corbett

    Read original paper ↗ ·

  23. Metal-metal bonding and interstitials in reduced rare earth metal halides

    Journal of the Less Common Metals · 1987-01-01

    John D. Corbett, Douglas S. Dudis, Jeff E. Ford, Shiou‐Jyh Hwu, Gerd Meyer, Sunil D. Wijeyesekera

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  24. Bonding in clusters and condensed cluster compounds that extend in one, two and three dimensions

    Progress in Solid State Chemistry · 1989-01-01

    Timothy R. Hughbanks

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  25. Chapter 100 Metal-rich halides

    Elsevier eBooks · 1991-01-01

    Arndt Simon, H. MATTAUSCH, Gordon J. Miller, W. Bauhofer, Reinhard Karl Kremer

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  26. Discrete and Condensed Transition Metal Clusters in Solids

    Unknown journal · 1994-02-24

    Arndt Simon

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  27. Sc2Te: ein neuartiges Beispiel für kondensierte Metallpolyeder in einer metallreichen, aber elektronenarmen Verbindung

    Angewandte Chemie · 1997-09-15

    Paul A. Maggard, John D. Corbett

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  28. Sc2Te: A Novel Example of Condensed Metal Polyhedra in a Metal‐Rich but Relatively Electron‐Poor Compound

    Angewandte Chemie International Edition in English · 1997-10-02

    Paul A. Maggard, John D. Corbett

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  29. Sc9Te2: A Two-Dimensional Distortion Wave in the Scandium-Richest Telluride

    Journal of the American Chemical Society · 2000-01-21

    Paul A. Maggard, John D. Corbett

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  30. Two-Dimensional Metallic Chain Compounds Y5M2Te2 (M = Fe, Co, Ni) That Are Related to Gd3MnI3. The Hydride Derivative Y5Ni2Te2D0.4

    Inorganic Chemistry · 2004-03-26

    Paul A. Maggard, John D. Corbett

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  31. Exploratory synthesis of reduced rare-earth-metal halides, chalcogenides, intermetallics

    Journal of Alloys and Compounds · 2006-01-20

    John D. Corbett

    Read original paper ↗ ·

  32. Halogenide der Seltenerdmetalle Ln4X5Z. Teil 2: Eine orthorhombische Verknüpfungsvariante o‐Ln4X5Z

    Zeitschrift für anorganische und allgemeine Chemie · 2008-01-21

    Hansjürgen Mattausch, M.C. Schaloske, Constantin Hoch, Arndt Simon

    Read original paper ↗ ·

  33. Eight‐Coordinate Endohedral Rhenium, Osmium and Iridium Atoms in Rare‐Earth Halide Cluster Complexes

    European Journal of Inorganic Chemistry · 2010-05-05

    Sina Zimmermann, Matthias Bruehmann, Frederick Casper, Oliver Heyer, T. Lorenz, Claudia Felser, Anja‐Verena Mudring, Gerd Meyer

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  34. Lanthanides: Metal Cluster Complexes

    Encyclopedia of Inorganic and Bioinorganic Chemistry · 2012-12-17

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  35. Clusters and Cluster Assemblies

    Elsevier eBooks · 2013-01-01

    Maxim N. Sokolov⧫, Н.Г. Наумов, P.P. Samoylov, Vladimir P. Fedin

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  36. Oligomeric rare-earth metal cluster complexes with endohedral transition metal atoms

    Journal of Solid State Chemistry · 2014-07-27

    Simon Steinberg, Sina Zimmermann, Matthias Bruehmann, Eva Meyer, Christian Rustige, Marike Wolberg, Kathrin Daub, Thomas Bell, Gerd Meyer

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  37. Structural properties of scandium inorganic salts

    Coordination Chemistry Reviews · 2016-12-16

    Jeremiah M. Sears, Timothy J. Boyle

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  38. Identifying quasi-2D and 1D electrides in yttrium and scandium chlorides via geometrical identification

    npj Computational Materials · 2018-12-10

    Biao Wan, Yangfan Lu, Zewen Xiao, Yoshinori Muraba, Junghwan Kim, Dajian Huang, Lailei Wu, Huiyang Gou, Jingwu Zhang, Faming Gao, Ho‐kwang Mao, Hideo Hosono

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  39. Metal–Metal (MM) Bond Distances and Bond Orders in Binuclear Metal Complexes of the First Row Transition Metals Titanium Through Zinc

    Chemical Reviews · 2018-12-13

    Richard H. Duncan Lyngdoh, Henry F. Schaefer, Robert Bruce King

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  40. Ferromagnetic two-dimensional metal-chlorides MCl (M = Sc, Y, and La): Candidates for Weyl nodal line semimetals with small spin-orbit coupling gaps

    Applied Surface Science · 2020-04-18

    Lei Jin, Xiaoming Zhang, Tingli He, Weizhen Meng, Xuefang Dai, Guodong Liu

    Read original paper ↗ ·
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