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RESEARCH PAPER · CrystEngComm · 2008

Interpenetrated three-dimensional hydrogen-bonded networks from metal–organic molecular and one- or two-dimensional polymeric motifs

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Interpenetrated three-dimensional hydrogen-bonded networks from metal–organic molecular and one- or two-dimensional polymeric motifsOriginalA new 3-D two-fold interpenetrated framework with sqp net based on Cu6I6 and Cu8I8 cluster nodes45An unusual 3D polycatenane motif generated by the 2D → 2D parallel → 3D parallel interpenetration of (4,4) sheets45Construction of 3-fold interpenetrated pcu organic frameworks from methanetetrabenzoic acid with zigzag bipyridines13Supramolecular Borromean sheet consisting of threefold parallel interwoven 44-sql layers assembled by a flexible bipyridinium ligand24Rational Construction of 2D and 3D Borromean Arrayed Organic Crystals by Hydrogen‐Bond‐Directed Self‐Assembly79Rational Construction of 2D and 3D Borromean Arrayed Organic Crystals by Hydrogen‐Bond‐Directed Self‐Assembly12Synthesis, and characterization of 1- and 2-D coordination polymers derived from the pseudopeptidic ligand oxamide-N,N′-diacetate: Insights into the supramolecular architectures constructed through H-bonds13A new 3-fold interpenetration of diamond-like network constructed from polyoxometalate building blocks15Bottom‐Up Synthesis of Porous Coordination Frameworks: Apical Substitution of a Pentanuclear Tetrahedral Precursor191Bottom‐Up Synthesis of Porous Coordination Frameworks: Apical Substitution of a Pentanuclear Tetrahedral Precursor36An Unprecedentedly Huge Square-Grid Copper(II)−Organic Framework Material Built from a Bulky Pyrene-Derived Elongated Cross-Shaped Scaffold26A novel self-penetrating metal–organic open framework containing unusual triple-stranded molecular braid and septuple helices13Hydrothermal Synthesis and Structure of Coordination Polymers by Combination of Bipyrazole and Aromatic Dicarboxylate Ligands63Crystal structure, thermal stability and theoretical investigation on four 1,3-bis(1,2,4-triazol-1-yl)propane-based copper(II) complexes17Temperature and Concentration Control over Interpenetration in a Metal−Organic Material388Self‐Assembled Arrays of Single‐Walled Metal–Organic Nanotubes122Self‐Assembled Arrays of Single‐Walled Metal–Organic Nanotubes26[Mn(acac)2(HOCH3)2]3[Ce(NO3)6]—Icosahedral Anion Builds a Cubic Network3Recent advances in crystal engineering746Methods for topological analysis of atomic nets33Crystalline Self-Assembly of a Bowl-Like Cyclotriguaiacylene Derivative with Alcohol/Phenols by Hydrogen Bonding and C−H···π Interactions: The Self-Inclusion Extended Organic Frameworks20A chiral manganese–potassium heterometallic MOF with an unusual (3,7)-connected network14Design and construction of an organic crystal with a novel interpenetrated n-Borromean linked topology23Metal oxide-organic frameworks (MOOFs), a new series of coordination hybrids constructed from molybdenum(vi) oxide and bitopic 1,2,4-triazole linkers70MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)1185Self-assembly, thermal stability and photoluminescence of two mixed-ligand silver(i) networks via 2D → 2D and 2D → 3D parallel interpenetration of (4,4) nets59Transition metal dipicolinates as designer T-shaped building blocks17A >22 Å long metal-complex anion and a 1D cationic coordination polymer, both based on 4,4′-bipyridine-N,N′-dioxide, yielding a 3D and 2-fold interpenetrated fsc net of the hydrogen-bonded metal-organic 1D polymer19Three New Supramolecular Complexes Based on 2‐Propyl‐1H‐imidazole‐4,5‐dicarboxylate: Synthesis, Structures and Properties10Pyridineboronic Acids as Useful Building Blocks in Combination with Perchloroplatinate(II) and -(IV) Salts: 1D, 2D, and 3D Hydrogen-Bonded Networks Containing X-H···Cl2Pt− (X = C, N+), B(OH)2···Cl2Pt−, and B(OH)2···(HO)2B Synthons20Hydrogen-Bonding 3D Networks by Polyhedral Organosilanols: Selective Inclusion of Hydrocarbons in Open Frameworks35Crystal engineering: A brief overview226Two unusual (4,6)- and 8-connected metal–organic frameworks constructed from flexible 1,4-benzenebis(thioacetic acid) and pyridine-based ligands12Periodic‐Graph Approaches in Crystal Structure Prediction66An unprecedented (5,12)-connected 3D self-penetrating metal–organic framework based on dinuclear barium clusters as building blocks39Hydrogen-bonding self-assembly of two dimensional (2D) layer structures generating metal–organic nanotubes13Substituent effect of R-isophthalates (R = –H, –CH 3 , –OCH 3 , –tBu, –OH, and –NO 2 ) on the construction of Cd II coordination polymers incorporating a dipyridyl tecton 2,5-bis(3-pyridyl)-1,3,4-oxadiazole87Coordination Chemistry of Thiazole‐Based Ligands: New Complexes Generating 3D Hydrogen‐Bonded Architectures28A series of novel entangled coordination frameworks with inherent features of self-threading, polyrotaxane and polycatenane60An unprecedented 3-fold interpenetrated double-edged pseudo-diamondoid network containing exceptional 5-fold interlocking tri-flexure helices and 15-fold interwoven helices34Computational Studies of Crystal Structure and Bonding20Two novel isomeric organic anion-water aggregations: 1D tape and 3D 2-fold interpenetrated diamond network15Underlying nets in three-periodic coordination polymers: topology, taxonomy and prediction from a computer-aided analysis of the Cambridge Structural Database709Unusual self-threading and interdigitated architectures self-assembled from long flexible ligands and d10 metal salts35Topological systematization of the framework coordination polymers formed by iron, cobalt, or nickel complexes2Two new frameworks of potassium saccharate obtained from acidic and alkaline solution8Halogen Bonding in the Assembly of Coordination Polymers Based on 5-Iodo-Isophthalic Acid85A 3D interpenetrated rutile coordination framework formed by dinuclear cadmium clusters and 4,4′-sulfonyldibenzoate10Two Unprecedented Entangled Metal–Olsalazine Complexes with Coexistence of 2D → 3D Polycatenation and meso‐Helix10Crystal Engineering Using a “Turtlebug” Algorithm: A de Novo Approach to the Design of Binodal Metal–Organic Frameworks12Networks based on hydrogen-bonds containing phosphorus anions and tris(3,5-dimethylpyrazolyl)borate nickel(II) moieties5Two new Nickel(II) complexes constructed by 2-carboxymethylsulfanyl nicotinic acid with different N-containing auxiliary ligands6Syntheses, crystal structures and photoluminescent properties of two novel Ag( i ) coordination polymers with benzoguanamine and pyrazine-carboxylate ligands: From 1D helix to 1D → 2D interdigitation47Nucleobase assemblies supported by uranyl cation coordination and other non-covalent interactions3Highly interpenetrated diamondoid nets of Zn( ii ) and Cd( ii ) coordination networks from mixed ligands89Two new Cerium-Organic Frameworks with unusual network topologies constructed by racemic tartaric acid involving in situ reaction53D → 3D interpenetrated and 2D → 3D polycatenated Ag( i ) networks constructed from 1,4-bis(2-methylimidazol-1-ylmethyl)benzene and dicarboxylates34Two types of rare earth–organic frameworks constructed by racemic tartaric acid181,2,4-Triazole functionalized adamantanes: a new library of polydentate tectons for designing structures of coordination polymers54A 2D→3D net with coexistence of polycatenation and polythreading constructed by long rigid and flexible ligands17A novel dodecanuclear cadmium(ii) macrocycle with a 3D framework: synthesis, structure and properties6Catenation control in the two-dimensional coordination polymers based on tritopic carboxylate linkers and azamacrocyclic nickel(ii) complexes13Metal–ligand ratio-controlled assembly of two pairs of Co(ii) complexes: syntheses, structures and magnetic properties50Molecular braids in metal–organic frameworks170Phase transfer catalyst supported, room-temperature biphasic synthesis: a facile approach to the synthesis of coordination polymers10Synthesis, structure, topology and magnetic properties of cobalt(ii) coordination polymers with 2-nitrobiphenyl-4,4′-dicarboxylic acid and bis(pyridyl) ligands47Two novel entangled metal–organic networks constructed from 4,4′-bis(2-methylimidazol-1-ylmethyl)biphenyl and dicarboxylates: From polycatenated 2D + 2D → 3D framework to polyrotaxane-like 2D + 2D → 2D layer45Interpenetration0A new type of polythreaded network self-assembled from sidearm-containing 2D bilayer motifs based on tetracarboxylate and N-heterocyclic multipyridyl ligand16A 1D → 3D Two‐Fold Interpenetration Array Formed by Hydrogen‐Bonding Interactions1A topological method for the classification of entanglements in crystal networksA preliminary account of this work was presented at the workshop `Topological dynamics in physics and biology' held in Pisa, 12–13 July 2011.74Coordination chemistry beyond Werner: interplay between hydrogen bonding and coordination93Reactions of rhodium (II) acetate with non-lacunary Keggin and Dawson polyoxoanions and related catalytic studies20Construction of Metal–Organic Frameworks Based on Two Neutral Tetradentate Ligands25A novel luminescent 3D metal–organic framework possessing 3-fold interpenetrating (3,5)-connected net4Structural Diversity and Properties of Six 2D or 3D Metal–Organic Frameworks Based on Thiophene-Containing Ligand25Assembly of discrete linear (H2O)5 water cluster within an entangled two-dimensional coordination network7Improving the Solubility of 6-Mercaptopurine via Cocrystals and Salts55Syntheses, characterizations and properties of five new metal–organic complexes based on flexible ligand 4,4′-(phenylazanediyl)dibenzoic acid27Polycarboxylate anions effect on the structures of a series of transition metal-based coordination polymers: Syntheses, crystal structures and bioactivities19Synthesis and structure of coordination polymers of Mn2+, Cu2+, Ag+, Zn2+ and Cd2+ by combination of bipyrazole and diphenate ligands4Four New Cd(II) Coordination Polymers with Mixed Multidentate N-Donors and Biphenyl-Based Polycarboxylate Ligands: Syntheses, Structures, and Photoluminescent Properties208An unusual 3D 8-connected entangled coordination network with coexistence of self-threading, polythreading and interpenetration16Investigation on the prime factors influencing the formation of entangled metal–organic frameworks144Modular construction of 3D coordination frameworks incorporating SiF62− links: Accessing the significance of [M(pyrazole)4{SiF6}] synthon27Two ligand-length-tunable interpenetrating coordination networks with stable Zn2 unit as three-connected uninode and supramolecular topologies143D Ni(II)/Cu(II) Supermolecular Frameworks Based on Pyridylamine and Fumarate Co‐ligands Containing a Trinodal (4,5,6)‐Connected Network and a (H2O)16 Water Cluster5Interpenetration control in metal–organic frameworks for functional applications563Tuning the entanglement of coordination polymers by controlling the steric hindrance of organic linkers4An Unprecedented 3D Self-catenated Four-coordinated Dense Net of Silver-Organic Framework8Two 3D Supramolecular Architectures from Ag(I) Coordination Polymers Constructed by Flexible Bis(benzimidazolyl)butane Ligand13Hydrogen-bond directed 2D → 3D polythreading of a new luminescent Cd(II) coordination polymer12Three interdigitated metal–quinolone complexes from self-assembly of mixed ligands and cadmium salts17Giant Zn14 Molecular Building Block in Hydrogen-Bonded Network with Permanent Porosity for Gas Uptake50Construction of a series of coordination polymers based on 1,4-naphthalenedicarboxylic and flexible dipyridyl ligands38Heterometal–organic framework with pcu net constructed from mixed linear ligands9Mixed-ligand hydroxocopper( ii )/pyridazine clusters embedded into 3D framework lattices19Solvothermal synthesis, crystal structure and photoluminescence properties of four Cd( ii ) coordination polymers with different topological structures18Structural and functional studies on coordination polymers based on 5-tert-butylisophthalic acid and N,N′-bis-(4-pyridylmethyl) piperazine6Solution and Mechanochemical Syntheses of Two Novel Cocrystals: Ligand Length Modulated Interpenetration of Hydrogen-Bonded 2D 63-hcb Networks Based on a Robust Trimeric Heterosynthon31Entangled structures in polyoxometalate-based coordination polymers112Extended structures in copper(II) complexes with 4-hydroxypyridine-2,6-dicarboxylate and pyrimidine derivative ligands: X-ray crystal structure, solution and magnetic studies19Applied Topological Analysis of Crystal Structures with the Program Package ToposPro3167Topological Diversity of Supramolecular Networks Constructed from Copper(II) Aminoalcohol Blocks and 2,6-Naphthalenedicarboxylate Linkers: Self-Assembly Synthesis, Structural Features, and Magnetic Properties44Entangled Two-Dimensional Coordination Networks: A General Survey285Subtle C–H···Hal (Hal = Cl, Br) Bonding as Predominant Synthon in the Assembly of Supramolecular Architectures Based on Luminescent Tin(IV) Complexes. Crystallography, Hirshfeld Surfaces, DFT Calculations, and Fluorescence24A key route to designing huge eight-fold interpenetrated coordination networks with ths-type topology: Synthesis, structures, and topological characteristics5A High-connected Cobalt(II) Pyromellitate MOF Displaying An Uncommon Decadentate Coordination Mode7Interpenetration of three-periodic networks in crystal structures: Description and classification methods, geometrical-topological conditions of implementation10Metal‐Organic Frameworks: Interpenetration and Entanglement2A huge diamondoid metal–organic framework with a neo-mode of tenfold interpenetration12Hydrogen Bonding in Supramolecular Crystal Engineering11Luminescent silver( i ) coordination architectures containing 2-aminopyrimidyl ligands36New tricopper( ii ) cores self-assembled from aminoalcohol biobuffers and homophthalic acid: synthesis, structural and topological features, magnetic properties and mild catalytic oxidation of cyclic and linear C 5 –C 8 alkanes80Self-penetrating and interpenetrating 3D metal–organic frameworks constructed from 4-(4-carboxyphenoxy)-phthalic acid and N-donor auxiliary ligands1Synthesis, Structure, and Topological Studies of Solvates and Salts of a Chiral Zwitterionic Host N-(2-Imidazol-5-yl-1-carboxyethyl)-1,8-naphthalimide13In situ synthesis of amide-imidate-imidazolate ligand and formation of metal-organic frameworks: Application for gas storage11A new 2D → 3D network with the coexistence of inclined polycatenation and polythreading constructed by an N-centered tripodal linker11Synthesis, structure and adsorption properties of a three-dimensional 3-fold interpenetrated Cd(II) coordination network with the rare tfz topology5An unusual 2D nanoscaled quadruple-layer metal–organic framework based on octanuclear cobalt clusters2Syntheses, Structures, and Luminescence Properties of Two Copper( II ) Complexes Constructed by Rigid Bis(triazole) and Nitrogen‐containing Carboxylic Acid Ligands5A Complex Self‐Catenated Coordination Framework with a Rare (3,12)‐Connected Underlying Net Showing Selective Adsorption of CO24Modelling Gas Adsorption in Porous Solids: Roles of Surface Chemistry and Pore Architecture6Tuning different kinds of entangled metal–organic frameworks by modifying the spacer group of aliphatic dicarboxylate ligands and the reactant ratio24Hydrogen bonding-induced conformational change in a crystalline sugar derivative5Syntheses, structures and properties of five entangled coordination polymers constructed with trigonal N-donor ligands15Two-folded interpenetrated metal-organic framework constructed by zinc(ii) and mixed ligands0Structure–Property Relationships in Amorphous Microporous Polymers19Syntheses and structures of three entangled coordination polymers based on the bifunctional ligand 4-((3-(pyridin-4-yl)-1H-pyrazol-1-yl)methyl)benzoic acid2Assembly of Two Coordination Polymers Based on the Flexible Carboxylate and N‐Donor Ligands with Polycatenane Characterization: Syntheses, Crystal Structures, and Luminescent Properties2Coordination Behavior of Chelidamic Acid With V V , Ni II , Fe III , and Ca II : Syntheses, X‐ray Characterization and DFT Studies14Network Topology7Syntheses, structures and magnetism of four Ni(II)/Co(II) interpenetrating coordination polymers based on 1,4-bis(4-(imidazole-1-yl)benzyl)piperazine9A series of coordination polymers with 2D → 3D interdigitated structures self-assembled from 1,4-bis(4-(imidazole-1-yl)benzyl)piperazine6Three unique MOFs constructed by 1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene and dicarboxylates: From rhombic tetrameric zinc(II) 2D layer to 2D + 2D → 3D polycatenated frameworks9A series of coordination polymers constructed from R-isophthalic acid (R=–SO 3 H, –NO 2 , and –OH) and N-donor ligands: Syntheses, structures and fluorescence properties20How 2-periodic coordination networks are interweaved: entanglement isomerism and polymorphism58Borates A Novel Twofold Interpenetrating 3D Diamondoid Borate Framework Constructed from B 4 and B 5 Clusters15Topological identification of the first uninodal 8-connected lsz MOF built from 2,2′-difluorobiphenyl-4,4′-dicarboxylate pillars and cadmium(II)–triazolate layers7Lignin Based Molecular Materials – a Zinc Vanillate with a Hydrogen Bonded 4‐ and 8‐connected Net with a New Topology4Four interpenetrating hydrogen-bonded three-dimensional networks in divanillin0A survey on application of MOFs in chemistry2Recent Developments in Molecular Spin Gyroid Research23Self-assembly of square planar rhodium carbonyl complexes with 4,4-disubstituted-2,2′-bipyridine ligands5Syntheses, crystal structures, dye degradation and luminescence sensing properties of four coordination polymers26Polycarbonate Microchip Containing CuBTC-Monopol Monolith for Solid-Phase Extraction of Dyes3Adsorption of Polar Volatile Organic Compounds by a Crystalline Network Structure Based on a Bis(benzimidazole)NiCl2 Complex13Topology of Infinite Networks0MOFs assembled from C 3 symmetric ligands: structure, iodine capture and role as bifunctional catalysts towards the oxidation–Knoevenagel cascade reaction19Control of interpenetration and structural transformations in the interpenetrated MOFs166

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  2. An unusual 3D polycatenane motif generated by the 2D → 2D parallel → 3D parallel interpenetration of (4,4) sheets

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  4. Supramolecular Borromean sheet consisting of threefold parallel interwoven 44-sql layers assembled by a flexible bipyridinium ligand

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  5. Rational Construction of 2D and 3D Borromean Arrayed Organic Crystals by Hydrogen‐Bond‐Directed Self‐Assembly

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  6. Rational Construction of 2D and 3D Borromean Arrayed Organic Crystals by Hydrogen‐Bond‐Directed Self‐Assembly

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  7. Synthesis, and characterization of 1- and 2-D coordination polymers derived from the pseudopeptidic ligand oxamide-N,N′-diacetate: Insights into the supramolecular architectures constructed through H-bonds

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  11. An Unprecedentedly Huge Square-Grid Copper(II)−Organic Framework Material Built from a Bulky Pyrene-Derived Elongated Cross-Shaped Scaffold

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  12. A novel self-penetrating metal–organic open framework containing unusual triple-stranded molecular braid and septuple helices

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  13. Hydrothermal Synthesis and Structure of Coordination Polymers by Combination of Bipyrazole and Aromatic Dicarboxylate Ligands

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  14. Crystal structure, thermal stability and theoretical investigation on four 1,3-bis(1,2,4-triazol-1-yl)propane-based copper(II) complexes

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  15. Temperature and Concentration Control over Interpenetration in a Metal−Organic Material

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  20. Methods for topological analysis of atomic nets

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  22. A chiral manganese–potassium heterometallic MOF with an unusual (3,7)-connected network

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  24. Metal oxide-organic frameworks (MOOFs), a new series of coordination hybrids constructed from molybdenum(vi) oxide and bitopic 1,2,4-triazole linkers

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  30. Pyridineboronic Acids as Useful Building Blocks in Combination with Perchloroplatinate(II) and -(IV) Salts: 1D, 2D, and 3D Hydrogen-Bonded Networks Containing X-H···Cl2Pt− (X = C, N+), B(OH)2···Cl2Pt−, and B(OH)2···(HO)2B Synthons

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  31. Hydrogen-Bonding 3D Networks by Polyhedral Organosilanols: Selective Inclusion of Hydrocarbons in Open Frameworks

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  32. Crystal engineering: A brief overview

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  33. Two unusual (4,6)- and 8-connected metal–organic frameworks constructed from flexible 1,4-benzenebis(thioacetic acid) and pyridine-based ligands

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  34. Periodic‐Graph Approaches in Crystal Structure Prediction

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  35. An unprecedented (5,12)-connected 3D self-penetrating metal–organic framework based on dinuclear barium clusters as building blocks

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  36. Hydrogen-bonding self-assembly of two dimensional (2D) layer structures generating metal–organic nanotubes

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