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RESEARCH PAPER · Applied Clay Science · 2007

Clay minerals and layered double hydroxides for novel biological applications

Jin‐Ho Choy, S CHOI, J OH, Tae Gwan Park

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Clay minerals and layered double hydroxides for novel biological applicationsOriginalClays and health: An introduction51Molecular Dynamics Simulation of the Energetics and Structure of Layered Double Hydroxides Intercalated with Carboxylic Acids84Three Dimensionally Ordered Macroporous Layered Double Hydroxides: Preparation by Templated Impregnation/Coprecipitation and Pattern Stability upon Calcination100Interactions of pesticides with clays and layered double hydroxides: a review144Evidence for the formation of anhydrous zinc acetate and acetic anhydride during the thermal degradation of zinc hydroxy acetate, Zn5(OH)8(CH3CO2)2·4H2O to ZnO73Analysis of Oligonucleotide DNA Binding and Sedimentation Properties of Montmorillonite Clay Using Ultraviolet Light Spectroscopy52A novel core-shell structured magnetic organic-inorganic nanohybrid involving drug-intercalated layered double hydroxides coated on a magnesium ferrite core for magnetically controlled drug release152Sorption/desorption of arsenate on/from Mg–Al layered double hydroxides: Influence of phosphate110Structural characterization of arsenate ion exchanged MgAl-layered double hydroxide55Inorganic Drug‐Delivery Nanovehicle Conjugated with Cancer‐Cell‐Specific Ligand200Preparation and characterization of PVC/montmorillonite nanocomposites—A review64Synthesis, Characterization, and Magnetically Controlled Release Behavior of Novel Core−Shell Structural Magnetic Ibuprofen-Intercalated LDH Nanohybrids101Raman Scattering and Fourier Transform Infrared Spectroscopy of Me6Al2(OH)16Cl2·4H2O (Me = Mg, Ni, Zn, Co, and Mn) and Ca2Al(OH)6Cl·2H2O Hydrotalcites64Structure and Catalytic Behavior of Myoglobin Adsorbed onto Nanosized Hydrotalcites55Clay and non-clay minerals in the pharmaceutical industry346Bioinorganic Magnetic Core−Shell Nanocomposites Carrying Antiarthritic Agents: Intercalation of Ibuprofen and Glucuronic Acid into Mg−Al−Layered Double Hydroxides Supported on Magnesium Ferrite106Self-assembled 3D flower-like Ni2+–Fe3+layered double hydroxides and their calcined products68Hydrotalcite-type precursors of active catalysts for hydrogen production84Hybrid materials based on clays for environmental and biomedical applications324Intercalation chemistry in a LDH system: anion exchange process and staging phenomenon investigated by means of time-resolved, in situ X-ray diffraction54Emerging trends and challenges in synthetic clay-based materials and layered double hydroxides112Current challenges in clay minerals for drug delivery365Porphyrins Intercalated in Zn/Al and Mg/Al Layered Double Hydroxides: Properties and Structural Arrangement63Molecular dynamics computer simulations of the effects of hydrogen bonding on the properties of layered double hydroxides intercalated with organic acids62Synthesis of clay minerals328Synthesis and characterization of biomimetic hydroxyapatite/sepiolite nanocomposites76Rapid direct growth of Li–Al layered double hydroxide (LDH) film on glass, silicon wafer and carbon cloth and characterization of LDH film on substrates57Integrated bio-inorganic hybrid systems for nano-forensics57Layered double hydroxides with interlayer borate anions: A critical evaluation of synthesis methodology and pH-independent orientations in nano-galleries70Effect of physico-chemical parameters on the toxicity of inorganic nanoparticles62Hybrid materials based on montmorillonite and citostatic drugs: Preparation and characterization69Chemical and radiological characterization of clay minerals used in pharmaceutics and cosmetics54Near-infrared and mid-infrared investigations of Na-dodecylbenzenesulfate intercalated into hydrocalumite chloride (CaAl-LDH-Cl)57An overview on strategies towards clay-based designer catalysts for green and sustainable catalysis243Perspectives for nano-biotechnology enabled protection and nutrition of plants1184Layered Double Hydroxide Nanoparticles as Target-Specific Delivery Carriers: Uptake Mechanism and Toxicity194MCM-41 for furosemide dissolution improvement82Mechanism of interaction of hydrocalumites (Ca/Al-LDH) with methyl orange and acidic scarlet GR78Structural analysis of naproxen-intercalated bentonite (Unye)79Bending of Layered Silicates on the Nanometer Scale: Mechanism, Stored Energy, and Curvature Limits61Layered double hydroxides — multifunctional nanomaterials165Interaction of Biological Molecules with Clay Minerals: A Combined Spectroscopic and Sorption Study of Lysozyme on Saponite49Pickering emulsions stabilized by amphiphile covered clays56Hierarchical Nanocomposites Derived from Nanocarbons and Layered Double Hydroxides ‐ Properties, Synthesis, and Applications590A review of intercalation composite phase change material: Preparation, structure and properties112Modeling drug release from a layered double hydroxide–ibuprofen complex93Intracellular trafficking pathway of layered double hydroxide nanoparticles in human cells: Size-dependent cellular delivery60Adsorption Behaviors and Mechanisms of Methyl Orange on Heat-Treated Palygorskite Clays94The systems containing clays and clay minerals from modified drug release: A review205Aminoclay: a functional layered material with multifaceted applications153Layered Double Hydroxides (LDH)235Nanomaterials in Agricultural Production: Benefits and Possible Threats?57Size-Matching Effect on Inorganic Nanosheets: Control of Distance, Alignment, and Orientation of Molecular Adsorption as a Bottom-Up Methodology for Nanomaterials151Octadecenylsuccinic anhydride pickering emulsion stabilized by γ-methacryloxy propyl trimethoxysilane grafted montmorillonite59Advanced Analytical Techniques for the Measurement of Nanomaterials in Food and Agricultural Samples: A Review91In situ synthesis and antibacterial activity of copper nanoparticle loaded natural montmorillonite clay based on contact inhibition and ion release127Fibrous clays based bionanocomposites249Sorption of metal cations on layered double hydroxides304Polymer–inorganic supramolecular nanohybrids for red, white, green, and blue applications115Natural halloysite nanotubes as mesoporous carriers for the loading of ibuprofen154Toxicity Assessment of Cerium Oxide Nanoparticles in Cilantro (Coriandrum sativum L.) Plants Grown in Organic Soil187Adsorption of proteins and nucleic acids on clay minerals and their interactions: A review365Intercalation strategies in clay/polymer hybrids289The Use of Feed Additives to Reduce the Effects of Aflatoxin and Deoxynivalenol on Pig Growth, Organ Health and Immune Status during Chronic Exposure113Advances in layered double hydroxide (LDH)-based elastomer composites261Montmorillonite–alginate nanocomposite as a drug delivery system – incorporation and in vitro release of irinotecan173Layered Double Hydroxides57Pectin-coated chitosan–LDH bionanocomposite beads as potential systems for colon-targeted drug delivery225Intercalation of drugs in layered double hydroxides and their controlled release: A review403High-capacity loading of 5-fluorouracil on the methoxy-modified kaolinite49pH sensitive nanocomposite hydrogel beads based on carboxymethyl cellulose/layered double hydroxide as drug delivery systems163Integrative strategies to hybrid lamellar compounds: an integration challenge55Removal of Cu2+, Pb2+ and Cd2+ by layered double hydroxide–humate hybrid. Sorbate and sorbent comparative studies138Biomedical applications of cationic clay minerals259Layered double hydroxides toward electrochemical energy storage and conversion: design, synthesis and applications451Progress on layered hydrotalcite (HT) materials as potential support and catalytic materials129Effects of bentonite on different cell types: A brief review98Mammalian gastrointestinal tract parameters modulating the integrity, surface properties, and absorption of food‐relevant nanomaterials129Synthesis of Cu–Al layered double hydroxide nanofluid and characterization of its thermal properties83Cu(II), Pb(II) and Cd(II) sorption on different layered double hydroxides. A kinetic and thermodynamic study and competing factors152Multifaceted Role of Clay Minerals in Pharmaceuticals68Use of nanofillers in wood coatings: a scientific review149Layered double hydroxide nanoparticles for biomedical applications: Current status and recent prospects258Optimisation of the synthesis parameters of mechanochemically prepared CaAl-layered double hydroxide53Swelling, mechanical and mucoadhesion properties of Mt/starch-g-PMAA nanocomposite hydrogels61Mineralogical characterization of commercial clays used in cosmetics and possible risk for health61Biosensors Based on Two-Dimensional MoS 2357Clay nanocomposites as engineered drug delivery systems106Pancreatic cancer therapy using an injectable nanobiohybrid hydrogel60Stem cell secretome-rich nanoclay hydrogel: a dual action therapy for cardiovascular regeneration93Nanoencapsulation, Nano-guard for Pesticides: A New Window for Safe Application975Energy and structure of bonds in the interaction of organic anions with layered double hydroxide nanosheets: A molecular dynamics study61Drug–clay nanohybrids as sustained delivery systems129Emerging trends in eco-compliant, synergistic, and hybrid assembling of multifunctional polymeric bionanocomposites79Recent Advances in Solid Catalysts Obtained by Metalloporphyrins Immobilization on Layered Anionic Exchangers: A Short Review and Some New Catalytic Results58Review of Clay-Drug Hybrid Materials for Biomedical Applications: Administration Routes98Synthesis of hydrotalcite type layered double hydroxide with various Mg/Al ratio and surface charge under controlled reaction condition86Structural characterization of chlorine intercalated Mg-Al layered double hydroxides: A comparative study between mechanochemistry and hydrothermal methods108Layered Double Hydroxide Nanotransporter for Molecule Delivery to Intact Plant Cells121A review of materials used as carrier agents in pesticide formulations154Magnesium, zinc and calcium aluminium layered double hydroxide-drug nanohybrids: A comprehensive study80Clay-biosurfactant materials as functional drug delivery systems: Slowing down effect in the in vitro release of cinnamic acid59Ni Nanoparticles Decorated NiFe Layered Double Hydroxide as Bifunctional Electrochemical Catalyst72Application of nanoelements in plant nutrition and its impact in ecosystems240Unique fluorescence behavior of dyes on the clay minerals surface: Surface Fixation Induced Emission (S-FIE)61Hybrid nanocomposites of layered double hydroxides: an update of their biological applications and future prospects62Pectins functionalized biomaterials; a new viable approach for biomedical applications: A review330A comparative study of the amaranth azo dye adsorption/desorption from aqueous solutions by layered double hydroxides109Cellular uptake pathways of sepiolite nanofibers and DNA transfection improvement52Nanoparticles for pest control: current status and future perspectives454Kaolinite in pharmaceutics and biomedicine228Halloysite Tubes as Nanocontainers for Herbicide and Its Controlled Release in Biodegradable Poly(vinyl alcohol)/Starch Film82Tailoring Hybrid Layered Double Hydroxides for the Development of Innovative Applications320Antioxidant agents against trichothecenes: new hints for oxidative stress treatment72Opportunities to advance sustainable design of nano-enabled agriculture identified through a literature review86Intercalation of metformin into montmorillonite602D Nanostructured Metal Hydroxides with Gene Delivery and Theranostic Functions; A Comprehensive Review58Interactions between Biological Cells and Layered Double Hydroxides: Towards Functional Materials64Layered Double Hydroxide/Chitosan Nanocomposite Beads as Sorbents for Selenium Oxoanions58Effect of particle size and local disorder on specific surface area of layered double hydroxides upon calcination-reconstruction66Gemini surfactant modified clays: Effect of surfactant loading and spacer length63Bio-inspired nanomaterials in agriculture and food: Current status, foreseen applications and challenges103Recent advances in layered double hydroxides (LDHs) as two-dimensional membrane materials for gas and liquid separations155High and long-term antibacterial activity against Escherichia coli via synergy between the antibiotic penicillin G and its carrier ZnAl layered double hydroxide50A comparative study and optimization of corrosion resistance of ZnAl layered double hydroxides films intercalated with different anions on AZ31 Mg alloys102Evaluation of clay-ionene nanocomposite carriers for controlled drug delivery: Synthesis, in vitro drug release, and kinetics58Bionanocomposites based on cationic and anionic layered clays as controlled release devices of amoxicillin56Layered double hydroxide based bionanocomposites129Why Do Carbonate Anions Have Extremely High Stability in the Interlayer Space of Layered Double Hydroxides? Case Study of Layered Double Hydroxide Consisting of Mg and Al (Mg/Al = 2)76Comparison of adsorption mechanisms for cadmium removal by modified zeolites and sands coated with Zn-layered double hydroxides68Functionalized layered double hydroxides for innovative applications314Potential Risk to Pollinators from Nanotechnology-Based Pesticides54A Bioresponsive System Based on Mesoporous Organosilica Nanoparticles for Smart Delivery of Fungicide in Response to Pathogen Presence146New Insights on Unique Features and Role of Nanostructured Materials in Cosmetics135Curcumin encapsulated dual cross linked sodium alginate/montmorillonite polymeric composite beads for controlled drug delivery159Synthesis of a mesoporous Mg–Al–mixed metal oxide with P123 template for effective removal of Congo red via aggregation-driven adsorption57Layered double hydroxides: An advanced encapsulation and delivery system for cosmetic ingredients-an overview55Reviewing the recent advances in application of pectin for technical and health promotion purposes: From laboratory to market163Intelligent, Nano-fertilizers: A New Technology for Improvement Nutrient Use Efficiency (Article Review)112Recent Strategies for Strengthening and Stiffening Tough Hydrogels82Nanostructured layered double hydroxides based photocatalysts: Insight on synthesis methods, application in water decontamination/splitting and antibacterial activity59The New Challenge of Green Cosmetics: Natural Food Ingredients for Cosmetic Formulations215Nanopesticides: A Systematic Review of Their Prospects With Special Reference to Tea Pest Management166Encapsulation of volatile compounds in liquid media: Fragrances, flavors, and essential oils in commercial formulations99Adsorptive removal of heavy metal anions from water by layered double hydroxide: A review97Bioactive 2D nanomaterials for neural repair and regeneration84Nanocomposite-based smart fertilizers: A boon to agricultural and environmental sustainability118Halloysite Nanotubes and Sepiolite for Health Applications52Inorganic nanoparticles in dermopharmaceutical and cosmetic products: Properties, formulation development, toxicity, and regulatory issues115Design and development of the high-performance aqueous asymmetric supercapacitor based on the hydrothermally grown binder-less Ni-Co LDH nanosheets77

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  3. Characterization of surfactant/hydrotalcite-like clay/glassy carbon modified electrodes: Oxidation of phenol

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  4. Molecular Dynamics Simulation of the Energetics and Structure of Layered Double Hydroxides Intercalated with Carboxylic Acids

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  5. Nanohybrids of edible dyes intercalated in ZnAl layered double hydroxides

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  6. New hybrid nanostructures based on oxacillin–hydrotalcite-like anionic clays and their textural properties

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  7. Three Dimensionally Ordered Macroporous Layered Double Hydroxides: Preparation by Templated Impregnation/Coprecipitation and Pattern Stability upon Calcination

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  8. The application of focused microwave irradiation coupled with freeze drying to investigate the reaction of MgO and Al2O3 slurries in the formation of layered double hydroxides

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  12. Evidence for the formation of anhydrous zinc acetate and acetic anhydride during the thermal degradation of zinc hydroxy acetate, Zn5(OH)8(CH3CO2)2·4H2O to ZnO

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  14. Analysis of Oligonucleotide DNA Binding and Sedimentation Properties of Montmorillonite Clay Using Ultraviolet Light Spectroscopy

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  15. Successful transfer of plasmid DNA intoin vitrocells transfected with an inorganic plasmid–Mg/Al-LDH nanobiocomposite material as a vector for gene expression

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  16. A new route for local probing of inner interactions within a layered double hydroxide/benzene derivative hybrid material

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  17. A novel core-shell structured magnetic organic-inorganic nanohybrid involving drug-intercalated layered double hydroxides coated on a magnesium ferrite core for magnetically controlled drug release

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  18. ADSORPTION OF ARSENIC COMPONENTS ON LAYERED DOUBLE HYDROXIDES AND MIXED OXIDES FOR WATER PURIFICATION

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  20. Controlled synthesis of layered double hydroxide compounds with novel morphologies for biological applications

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  21. Sorption/desorption of arsenate on/from Mg–Al layered double hydroxides: Influence of phosphate

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  22. Electrochemical Study of Anionic Ferrocene Derivatives Intercalated in Layered Double Hydroxides: Application to Glucose Amperometric Biosensors

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  23. Structural characterization and thermal decomposition of layered double hydroxide/poly(p-dioxanone) nanocomposites

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  26. Intercalation of fatty acids in a layered double hydroxide

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  28. Detection of Biocompatibility between Nano-Layered Double Hydroxides and Hela Cells

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  35. Bioinorganic Magnetic Core−Shell Nanocomposites Carrying Antiarthritic Agents: Intercalation of Ibuprofen and Glucuronic Acid into Mg−Al−Layered Double Hydroxides Supported on Magnesium Ferrite

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  36. Selective Adsorption of Adenosine and Guanosine by a β‐Cyclodextrin/Layered Double Hydroxide Intercalation Compound

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  37. Self-assembled 3D flower-like Ni2+–Fe3+layered double hydroxides and their calcined products

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  38. Hydrotalcite-type precursors of active catalysts for hydrogen production

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  39. Paraquat release control using intercalated montmorillonite compounds

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  40. Synthesis and Characterization of Dual Radiolabeled Layered Double Hydroxide Nanoparticles for Use in In Vitro and In Vivo Nanotoxicology Studies

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  42. Hybrid materials based on clays for environmental and biomedical applications

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  46. Synthesis, characterization and activation of quaternary layered double hydroxides for the one-pot synthesis of methyl isobutyl ketone

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  47. Current challenges in clay minerals for drug delivery

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  49. ISOLATION OF CAFFEIC ACID FROM EUPATORIUM ADENOPHORUM SPRENG BY HIGH-SPEED COUNTERCURRENT CHROMATOGRAPHY AND SYNTHESIS OF CAFFEIC ACID-INTERCALATED LAYERED DOUBLE HYDROXIDE

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  50. Porphyrins Intercalated in Zn/Al and Mg/Al Layered Double Hydroxides: Properties and Structural Arrangement

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