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RESEARCH PAPER · Inorganica Chimica Acta · 2004

Organic–inorganic hybrid materials constructed from copper-organoimine subunits and molybdoarsonate clusters

T. Soumahoro, Eric M. Burkholder, W. Ouellette, Jon A. Zubieta

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Organic–inorganic hybrid materials constructed from copper-organoimine subunits and molybdoarsonate clustersOriginalNovel charge transfer supramolecular assemblies with Keggin anions and 2-amino-5-nitropyridine28Anion-Dependent Assembly of Cyclic Structure136Influence of Steric Hindrance of Organic Ligand on the Structure of Keggin-Based Coordination Polymer238Two novel inorganic–organic hybrids based on saturated Wells–Dawson polyoxoanion and copper–organonitrogen coordination polymer32Syntheses and characterizations of two novel networks formed by Keggin clusters and copper–organonitrogen complexes8Wells–Dawson anion, a useful building block to construct one-dimensional chain as a chelate ligand coordinating with transition metal cations17Tetrahydroxy-p-benzoquinone as a Source of Polydentate O-Donor Ligands. Synthesis, Crystal Structure, and Magnetic Properties of the [Cu(bpy)(dhmal)]2Dimer and the Two-Dimensional [{SiW12O40}{Cu2(bpy)2(H2O)(ox)}2]·16H2O Inorganic−Metalorganic Hybrid52Solvent-induced supramolecular isomers: Two dimensional coordination polymers constructed by Cu(II) and fluconazole22An Unprecedented Fivefold Interpenetrating Network Based on Polyoxometalate Building Blocks52Two-dimensional layer architecture assembled by Keggin polyoxotungstate, Cu(II)–EDTA complex and sodium linker: Synthesis, crystal structures, and magnetic properties25Hybrid organic–inorganic assemblies built up from saturated heteropolyoxoanions and copper coordination polymers with mixed 4,4′-bipyridine and 2,2′-bipyridine ligands30A novel wavelike chain constructed from Wells–Dawson type polyoxoanions and mixed-ligand decorated transition metal complex cations [Ni(phen)(bbi)2]2+17The Anhydride Route to Group 15/16 Ligands in Oligomeric and Polymeric Environments: From Metal Complexes to Supraionic Chemistry17High-Dimensional Assembly Depending on Polyoxoanion Templates, Metal Ion Coordination Geometries, and a Flexible Bis(imidazole) Ligand168[Cu(4,4′-bipy)]2[H4P2W18O62] · 2H2O: The first three-dimensional framework based on saturated Wells–Dawson POMs modified by multi-track Cu–N coordination polymeric chains36Hydrothermal syntheses and crystal structures of two hybrid materials constructed from polyoxometalate clusters and metal–dipyridine complexes24Hydrothermal synthesis and structural characterization of two 1-D and 2-D Dawson-based phosphotungstates22A new [As3Mo3O15]3− fragment decorated with Cu(I)-imi (imi = imidazole) complexes: Synthesis, structure and electrochemical properties21Assembly of the Highest Connectivity Wells-Dawson Polyoxometalate Coordination Polymer: the Use of Organic Ligand Flexibility227pH-Dependent Assembly of Hybrids Based on Wells-Dawson POM/Ag Chemistry159Assembly of a new Wells–Dawson polyoxometalate-templated compound based on Fe-btb complex21Two new supramolecular assemblies based on Keggin-type polyoxometalates through Ag...O and π...π stacking interactions19Extended Organic—Inorganic Hybrids Based on Dawson and Double-Dawson-Type Polyoxometalates56A 3D architecture constructed by saturated Dawson polyoxoanions and transition-metal coordination complexes [CuI7(Bpy)6(BpyEt)2]0Hydrothermal synthesis, crystal structure and electrochemical properties of a novel 3D Dawson-type polyoxometalate supramolecular network0The Hydrothermal and Structural Chemistry of Oxovanadium−Arylphosphonate Networks and Frameworks72An extended architecture built upon the double-Dawson-type polyoxoanion27Synthesis, structures and electrochemical properties of four organic–inorganic hybrid polyoxometalates constructed from polyoxotungstate clusters and transition metal complexes4Organic-Inorganic Hybrids Constructed from Dawson Anions and Copper Complexes of Imidazole and Triethylenetetramine3A series of POM-based hybrid materials with different copper/aminotriazole motifs31A new extended structural compound based on saturated Wells–Dawson polyoxoanions3Synthesis, structure, and electrochemical behavior of a novel copper compound Cu(2,2′-Bipy)3]3(P2W18O62) · 2H2O0Hydrothermal Synthesis and Characterization of Three Cationic Inorganic−Organic Hybrid Materials Based on Lead Fluoride21Syntheses, structures, and properties of two new hybrid Dawson-based polyoxotungstates [Mn(2,2′-bipy)3]H2 [Mn(2,2′-bipy)2][P2W18O62] and [Co(H2biim)3)]2H2[P2W18O62] · 8H2O5Synthesis and crystal structure of a new coordination polymer constructed from Dawson-type polyoxotungstate and transition metal complexes [Cu(H2Biim)2]2H2P2W18O62 · 2C2H5OH · 2H2O1Silver Linked Polyoxometalate Open Frameworks (Ag-POMOFs) for the Directed Fabrication of Silver Nanomaterials45Syntheses, Characterization, and Magnetic Studies of Copper(II) Complexes with the Ligand N,N,N′,N′-Tetrakis(2-pyridylmethyl)-1,3-benzenediamine (1,3-tpbd) and its Phenol Derivative 2,6-Bis[bis(2-pyridylmethyl)amino]-p-cresol] (2,6-Htpcd)10Novel building units in the construction of materials of the oxomolybdate–organodiphosphonate/copper(II)–dipodal-organonitrogen ligand system: Structural influences of dipodal ligand tether length and flexibility11One polyoxometalate-based hybrid 3-D network: synthesis, structure, photo- and electro-catalytic properties7A new inorganic 2D network polyoxometalate constructed from Wells–Dawson phosphomolybdate linked through Cu(II) ions6Hydrothermal syntheses and structures of bimetallic organoarsonate compounds of the M(II)–imine/Mo O /RAsO32− family (M = Ni, Cu, Zn)12Hydrothermal syntheses and structures of bimetallic organoarsonate compounds of the Cu(II)-imine/V O /RAsO3− family5Two-Dimensional Bicapped Supramolecular Hybrid Semiconductor Material Constructed from the Insulators α-Keggin Polyoxomolybdate and 4,4′-Bipyridine34pH and Ligand Dependent Assembly of Well–Dawson Arsenomolybdate Capped Architectures50Design and synthesis of purely inorganic 3D frameworks composed of reduced vanadium clusters and manganese linkers15Two new inorganic-organic hybrid materials based on inorganic cluster, [X2Mo18O62]6− (X=P, As)9Organic–inorganic hybrid supramolecular assembly through the highest connectivity of a Wells–Dawson molybdoarsenate12The Hybrid Organic–Inorganic Assemblies Based on Monocapped Trivacant Keggin Arsenatomolybdate and CuI-Organic Units4Linking PO43− and HAsO42− anions with a dinuclear [ZnII2] complex: Formation and stabilization of novel decanuclear metallomacrocyclic [ZnII10] and tetranuclear [ZnII4] clusters8A novel 3D POMOF based on Wells–Dawson arsenomolybdates with excellent photocatalytic and lithium-ion battery performance36Two extended Wells–Dawson arsenomolybdate architectures directed by Na( i ) and/or Cu( i ) organic complex linkers20Two unusual 3D honeycomb networks based on Wells–Dawson arsenomolybdates with d 10 transition-metal-pyrazole connectors20A novel 2, 6-connected inorganic-organic 3-D open framework based on {As2Mo18} with photocatalytic property and anticancer activity9Inorganic Phosphate and Arsenate within New Tetranuclear Copper and Zinc Complexes: Syntheses, Crystal Structures, Magnetic, Electrochemical, and Thermal Studies31An Unusual Bi-arsenic Capped Well-Dawson Arsenomolybdate Hybrid Supramolecular Material with Photocatalytic Property and Anticancer Activity4Self-assembly of a new building block of {BMo12O40} with excellent catalytic activity for methylene blue6Different coordination abilities of 1,7- and 4,7-phenanthroline in the reactions with copper(II) salts: Structural characterization and biological evaluation of the reaction products7A 3D supramolecular photo-/ electro-catalytic material based on 2D monoarsenate capped Dawson layer and metal-organic sheets with rich π–π interactions9Two arsenic capped Dawson-type supramolecular hybrid assemblies induced by benzimidazole for photo-/electro-catalytic performance3Two functional hybrids based on polyoxometalate coordination polymers: Synthesis, electrochemical and photocatalytic properties11

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  1. Novel charge transfer supramolecular assemblies with Keggin anions and 2-amino-5-nitropyridine

    Dalton Transactions · 2005-11-16

    José A. F. Gamelas, Filipe M. Santos, Vítor M. S. Félix, Ana M. V. Cavaleiro, Etelvina de Matos Gomes, Michael Scott Belsley, Michael G. B. Drew

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  2. Anion-Dependent Assembly of Cyclic Structure

    Crystal Growth & Design · 2005-12-24

    Yan‐Ping Ren, Xiang‐Jian Kong, La‐Sheng Long, Rong‐Bin Huang, Lan‐Sun Zheng

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  3. Influence of Steric Hindrance of Organic Ligand on the Structure of Keggin-Based Coordination Polymer

    Inorganic Chemistry · 2006-04-13

    Yan‐Ping Ren, Xiang‐Jian Kong, Xiang-Yang Hu, Meng Sun, La‐Sheng Long, Rong‐Bin Huang, Lan‐Sun Zheng

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  4. Two novel inorganic–organic hybrids based on saturated Wells–Dawson polyoxoanion and copper–organonitrogen coordination polymer

    Journal of Molecular Structure · 2006-11-08

    Hua Jin, Yanfei Qi, Dong‐Rong Xiao, Xinlong Wang, Song Chang, Enbo Wang

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  5. Syntheses and characterizations of two novel networks formed by Keggin clusters and copper–organonitrogen complexes

    Journal of Molecular Structure · 2007-01-15

    Yu Wang, Dong‐Rong Xiao, Linlin Fan, Enbo Wang, Jia Liu

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  6. Wells–Dawson anion, a useful building block to construct one-dimensional chain as a chelate ligand coordinating with transition metal cations

    Journal of Molecular Structure · 2007-01-17

    Linlin Fan, Enbo Wang, Yangguang Li, Haiyan An, Dong‐Rong Xiao, Xinlong Wang

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  7. Tetrahydroxy-p-benzoquinone as a Source of Polydentate O-Donor Ligands. Synthesis, Crystal Structure, and Magnetic Properties of the [Cu(bpy)(dhmal)]2Dimer and the Two-Dimensional [{SiW12O40}{Cu2(bpy)2(H2O)(ox)}2]·16H2O Inorganic−Metalorganic Hybrid

    Inorganic Chemistry · 2007-01-23

    Santiago Reinoso, Pablo Vitoria, Leire San Felices, Ainara Montero, Luis M. Lezama, Juan Manuel Gutierrez-Zorrilla

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  8. Solvent-induced supramolecular isomers: Two dimensional coordination polymers constructed by Cu(II) and fluconazole

    Inorganic Chemistry Communications · 2007-02-16

    Yun Gong, Jinzhi Liu, Changwen Hu, Wenliang Gao

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  9. An Unprecedented Fivefold Interpenetrating Network Based on Polyoxometalate Building Blocks

    Crystal Growth & Design · 2007-03-07

    Linlin Fan, Dong‐Rong Xiao, Enbo Wang, Yangguang Li, Zhongming Su, Xinlong Wang, Jia Liu

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  10. Two-dimensional layer architecture assembled by Keggin polyoxotungstate, Cu(II)–EDTA complex and sodium linker: Synthesis, crystal structures, and magnetic properties

    Journal of Solid State Chemistry · 2007-03-19

    Hong Liu, Lin Xu, Guang‐Gang Gao, Fengyan Li, Yanyan Yang, Zhi-Kui Li, Yu Sun

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  11. Hybrid organic–inorganic assemblies built up from saturated heteropolyoxoanions and copper coordination polymers with mixed 4,4′-bipyridine and 2,2′-bipyridine ligands

    Inorganica Chimica Acta · 2007-04-15

    Hua Jin, Xinlong Wang, Yanfei Qi, Enbo Wang

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  12. A novel wavelike chain constructed from Wells–Dawson type polyoxoanions and mixed-ligand decorated transition metal complex cations [Ni(phen)(bbi)2]2+

    Journal of Molecular Structure · 2007-04-17

    Bao‐Xia Dong, Jun Peng, Yanhui Chen, Pengpeng Zhang, Aixiang Tian, Jing Chen

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  13. The Anhydride Route to Group 15/16 Ligands in Oligomeric and Polymeric Environments: From Metal Complexes to Supraionic Chemistry

    Chemistry - A European Journal · 2007-05-18

    A. Rothenberger, Weifeng Shi, M. Shafaei-Fallah

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  14. High-Dimensional Assembly Depending on Polyoxoanion Templates, Metal Ion Coordination Geometries, and a Flexible Bis(imidazole) Ligand

    Inorganic Chemistry · 2007-06-26

    Bao‐Xia Dong, Jun Peng, Carlos J. Gómez‐García, Samia Benmansour, Heng‐Qing Jia, Ninghai Hu

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  15. [Cu(4,4′-bipy)]2[H4P2W18O62] · 2H2O: The first three-dimensional framework based on saturated Wells–Dawson POMs modified by multi-track Cu–N coordination polymeric chains

    Inorganic Chemistry Communications · 2007-08-22

    Jing‐Quan Sha, Cheng Wang, Jun Peng, Jing Chen, Ai‐Xiang Tian, Pengpeng Zhang

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  16. Hydrothermal syntheses and crystal structures of two hybrid materials constructed from polyoxometalate clusters and metal–dipyridine complexes

    Solid State Sciences · 2007-09-05

    Guangzhe Li, Chris Salim, Hirofumi Hinode

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  17. Hydrothermal synthesis and structural characterization of two 1-D and 2-D Dawson-based phosphotungstates

    Journal of Solid State Chemistry · 2008-01-11

    Junwei Zhao, Shou‐Tian Zheng, Wei Liu, Guo‐Yu Yang

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  18. A new [As3Mo3O15]3− fragment decorated with Cu(I)-imi (imi = imidazole) complexes: Synthesis, structure and electrochemical properties

    Inorganic Chemistry Communications · 2008-03-05

    Zhifeng Zhao, Baibin Zhou, Zhanhua Su, Huiyuan Ma, Chunxiang Li

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  19. Assembly of the Highest Connectivity Wells-Dawson Polyoxometalate Coordination Polymer: the Use of Organic Ligand Flexibility

    Inorganic Chemistry · 2008-03-11

    Aixiang Tian, Jun Ying, Jun Peng, Jing‐Quan Sha, Zhangang Han, Jian‐Fang Ma, Zhong‐Min Su, Ninghai Hu, Heng‐Qing Jia

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  20. pH-Dependent Assembly of Hybrids Based on Wells-Dawson POM/Ag Chemistry

    Inorganic Chemistry · 2008-05-16

    Jingquan Sha, Jun Peng, Yaqan Lan, Zhong‐Min Su, Haijun Pang, Aixiang Tian, Pengpeng Zhang, Min Zhu

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  21. Assembly of a new Wells–Dawson polyoxometalate-templated compound based on Fe-btb complex

    Inorganic Chemistry Communications · 2008-06-27

    Aixiang Tian, Jun Ying, Jun Peng, Jingquan Sha, Dongxia Zhu, Haijun Pang, Pengpeng Zhang, Yuan Chen, Min Zhu

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  22. Two new supramolecular assemblies based on Keggin-type polyoxometalates through Ag...O and π...π stacking interactions

    Journal of Molecular Structure · 2008-06-29

    Jing Chen, Jingquan Sha, Jun Peng, Zhenyu Shi, Aixiang Tian, Pengpeng Zhang

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  23. Extended Organic—Inorganic Hybrids Based on Dawson and Double-Dawson-Type Polyoxometalates

    Inorganic Chemistry · 2008-08-05

    Zhiming Zhang, Yangguang Li, Yonghui Wang, Yanfei Qi, Enbo Wang

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  24. A 3D architecture constructed by saturated Dawson polyoxoanions and transition-metal coordination complexes [CuI7(Bpy)6(BpyEt)2]

    Journal of Molecular Structure · 2008-09-21

    Xinyu Zhao, Shuxia Liu, Yuanhang Ren, Chao‐Ying Gao, Ruige Cao, Chaojie Yu

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  25. Hydrothermal synthesis, crystal structure and electrochemical properties of a novel 3D Dawson-type polyoxometalate supramolecular network

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  26. The Hydrothermal and Structural Chemistry of Oxovanadium−Arylphosphonate Networks and Frameworks

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  27. An extended architecture built upon the double-Dawson-type polyoxoanion

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  28. Synthesis, structures and electrochemical properties of four organic–inorganic hybrid polyoxometalates constructed from polyoxotungstate clusters and transition metal complexes

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  29. Organic-Inorganic Hybrids Constructed from Dawson Anions and Copper Complexes of Imidazole and Triethylenetetramine

    Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry · 2009-06-08

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  30. A series of POM-based hybrid materials with different copper/aminotriazole motifs

    Inorganica Chimica Acta · 2009-08-20

    Xiao‐Yuan Wu, Xiaofei Kuang, Zhen‐Guo Zhao, Shan‐Ci Chen, Yiming Xie, Rongmin Yu, Can‐Zhong Lu

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  31. A new extended structural compound based on saturated Wells–Dawson polyoxoanions

    Chinese Chemical Letters · 2009-09-02

    Min Xu, Jia Liu, Enbo Wang

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  32. Synthesis, structure, and electrochemical behavior of a novel copper compound Cu(2,2′-Bipy)3]3(P2W18O62) · 2H2O

    Russian Journal of Coordination Chemistry · 2009-11-01

    Jianghan Wang, Xuhai Tang, Fang Wang, Shuang Cheng

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  33. Hydrothermal Synthesis and Characterization of Three Cationic Inorganic−Organic Hybrid Materials Based on Lead Fluoride

    Crystal Growth & Design · 2010-01-14

    David L. Rogow, Matthew P. Russell, Lora M. Wayman, Claudia H. Swanson, Allen G. Oliver, Scott R. J. Oliver

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  34. Syntheses, structures, and properties of two new hybrid Dawson-based polyoxotungstates [Mn(2,2′-bipy)3]H2 [Mn(2,2′-bipy)2][P2W18O62] and [Co(H2biim)3)]2H2[P2W18O62] · 8H2O

    Journal of Coordination Chemistry · 2010-06-10

    Qiang Jin Wu, Xiao Fu, Junwei Zhao, Suzhi Li, Jingping Wang, Jingyang Niu

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  35. Synthesis and crystal structure of a new coordination polymer constructed from Dawson-type polyoxotungstate and transition metal complexes [Cu(H2Biim)2]2H2P2W18O62 · 2C2H5OH · 2H2O

    Russian Journal of Coordination Chemistry · 2010-08-01

    Xian-Lei Fu, P. T. Ma, J. S. Wang, Jingyang Niu

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  36. Silver Linked Polyoxometalate Open Frameworks (Ag-POMOFs) for the Directed Fabrication of Silver Nanomaterials

    Crystal Growth & Design · 2011-04-12

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  37. Syntheses, Characterization, and Magnetic Studies of Copper(II) Complexes with the Ligand N,N,N′,N′-Tetrakis(2-pyridylmethyl)-1,3-benzenediamine (1,3-tpbd) and its Phenol Derivative 2,6-Bis[bis(2-pyridylmethyl)amino]-p-cresol] (2,6-Htpcd)

    Inorganic Chemistry · 2011-12-06

    S. Turba, S.P. Foxon, A. Beitat, Frank W. Heinemann, K. Petukhov, Paul Müller, Olaf Walter, Francesc Lloret, Miguel Julve, Siegfried Schindler

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  38. Novel building units in the construction of materials of the oxomolybdate–organodiphosphonate/copper(II)–dipodal-organonitrogen ligand system: Structural influences of dipodal ligand tether length and flexibility

    Inorganica Chimica Acta · 2012-01-28

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  39. One polyoxometalate-based hybrid 3-D network: synthesis, structure, photo- and electro-catalytic properties

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  40. A new inorganic 2D network polyoxometalate constructed from Wells–Dawson phosphomolybdate linked through Cu(II) ions

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  41. Hydrothermal syntheses and structures of bimetallic organoarsonate compounds of the M(II)–imine/Mo O /RAsO32− family (M = Ni, Cu, Zn)

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  42. Hydrothermal syntheses and structures of bimetallic organoarsonate compounds of the Cu(II)-imine/V O /RAsO3− family

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  43. Two-Dimensional Bicapped Supramolecular Hybrid Semiconductor Material Constructed from the Insulators α-Keggin Polyoxomolybdate and 4,4′-Bipyridine

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  44. pH and Ligand Dependent Assembly of Well–Dawson Arsenomolybdate Capped Architectures

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  45. Design and synthesis of purely inorganic 3D frameworks composed of reduced vanadium clusters and manganese linkers

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  46. Two new inorganic-organic hybrid materials based on inorganic cluster, [X2Mo18O62]6− (X=P, As)

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  47. Organic–inorganic hybrid supramolecular assembly through the highest connectivity of a Wells–Dawson molybdoarsenate

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  48. The Hybrid Organic–Inorganic Assemblies Based on Monocapped Trivacant Keggin Arsenatomolybdate and CuI-Organic Units

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  49. Linking PO43− and HAsO42− anions with a dinuclear [ZnII2] complex: Formation and stabilization of novel decanuclear metallomacrocyclic [ZnII10] and tetranuclear [ZnII4] clusters

    Polyhedron · 2016-10-11

    Shobhraj Haldar, Gonela Vijaykumar, Aloke Kumar Ghosh, Luca M. Carrella, Manindranath Bera

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  50. A novel 3D POMOF based on Wells–Dawson arsenomolybdates with excellent photocatalytic and lithium-ion battery performance

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