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RESEARCH PAPER · The Journal of Physical Chemistry B · 2010

Layer-by-Layer Ultrathin Films of Azobenzene-Containing Polymer/Layered Double Hydroxides with Reversible Photoresponsive Behavior

Jingbin Han, Dongpeng Yan, Wenying Shi, Jing Ma, Hong Juan Yan, Min Wei, David G. Evans, Xue Duan

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Layer-by-Layer Ultrathin Films of Azobenzene-Containing Polymer/Layered Double Hydroxides with Reversible Photoresponsive BehaviorOriginalAssembling Exfoliated Layered Double Hydroxide (LDH) Nanosheet/Carbon Nanotube (CNT) Hybrids via Electrostatic Force and Fabricating Nylon Nanocomposites109Fabrication of pyrenetetrasulfonate/layered double hydroxide ultrathin films and their application in fluorescence chemosensors32Preparation and functionality of clay-containing films127Recent advances in photofunctional guest/layered double hydroxide host composite systems and their applications: experimental and theoretical perspectives92Helical Chirality of Azobenzenes Induced by an Intramolecular Chiral Axis and Potential as Chiroptical Switches48Photo-triggered assembly/disassembly of macroscopically ordered monodomain lamellar structure in side-chain liquid crystalline polymer containing strong polar azobenzene mesogens11Synthesis and Conformation of Substituted Chiral Binaphthyl-Azobenzene Cyclic Dyads with Chiroptical Switching Capabilities28Facile synthesis via a solvothermal route and characterization of Mg–Al layered double hydroxide (LDH) 3D micro–nano structures28Fluorescence Chemosensory Ultrathin Films for Cd2+Based on the Assembly of Benzothiazole and Layered Double Hydroxide29Enhanced high-current capacitive behavior of graphene/CoAl-layered double hydroxide composites as electrode material for supercapacitors215Développement de couches polymères nanométriques pour l'immobilisation de récepteurs naturels et le design de récepteurs synthétiques sur des transducteurs optiques0Solid state photochromism of pyrano[3,2-c]chromen-5-one moiety with the assistance of localized surface plasmons8Hierarchical Nanocomposites Derived from Nanocarbons and Layered Double Hydroxides ‐ Properties, Synthesis, and Applications590Preparation of Layered Double Hydroxides Nanomaterails via the Anionic Surfactant3Directional Photofluidization Lithography: Micro/Nanostructural Evolution by Photofluidic Motions of Azobenzene Materials277Resettable Fluorescence Logic Gate Based on Calcein/Layered Double Hydroxide Ultrathin Films14Photoresponsive molecular switches for biotechnology94CdTe Quantum Dots/Layered Double Hydroxide Ultrathin Films with Multicolor Light Emission via Layer‐by‐Layer Assembly86Two-photon induced data storage in hydrogen bonded supramolecular azopolymers25First principle evaluation of the chiroptical activity of the di-phenyl-diazene derivatives6Optical storage in azobenzene-containing epoxy polymers processed as Langmuir Blodgett films15LDH in Physical, Chemical, Biochemical, and Life Sciences40Photophysical pore control in an azobenzene-containing metal–organic framework273Recent Advances in Stimuli‐Responsive Photofunctional Materials Based on Accommodation of Chromophore into Layered Double Hydroxide Nanogallery21Stimuli-responsive layer-by-layer nanocomposites34Villain's fractal growth of poly[1-[4-(3-carboxy-4-hydroxyphenylazo) benzenesulfonamido]-1,2-ethanediyl, sodium salt] J-aggregates onto layer-by-layer films and its effect on film absorbance spectrum12Multilayer films of layered double hydroxide/polyaniline and their ammonia sensing behavior53Exciton Transfer of Azobenzene Derivatives in Self-Assembled Monolayers16Reversible Actuation of Polyelectrolyte Films: Expansion-Induced Mechanical Force Enables cis–trans Isomerization of Azobenzenes26Mass Spectrometry Characterization of Novel Synthetic Materials0Photoresponsive superhydrophobic surfaces from one-pot solution spin coating mediated by polydopamine23Laser inscription of surface structures and induction of optical anisotropy in azo-benzene substituted photochromic polymers and other systems1Photo‐Switching in a Hybrid Material Made of Magnetic Layered Double Hydroxides Intercalated with Azobenzene Molecules57Synthesis and morphological modification of semiconducting Mg(Zn)Al(Ga)–LDH/ITO thin films8Layer‐by‐Layer Assembly of Light‐Responsive Polymeric Multilayer Systems130Direct growth of layered double hydroxides in an aqueous suspension of carbon nanotubes and their application as fillers in polypropylene11Quenching of the Photoisomerization of Azobenzene Self-Assembled Monolayers by the Metal Substrate15Work Function Changes of Azo-Derivatives Adsorbed on a Gold Surface10Fabrication of high-performance poly(vinyl alcohol)/MgAl-layered double hydroxide nanocomposites28Exfoliation-restacking synthesis of coal-layered double hydroxide nanosheets/reduced graphene oxide composite for high performance supercapacitors88Stimuli-responsive hybrid materials: breathing in magnetic layered double hydroxides induced by a thermoresponsive molecule43A supramolecular assembly of cross-linked azobenzene/polymers for a high-performance light-driven actuator78Layered Double Hydroxide Materials: Assembly and Photofunctionality21Layered double hydroxides toward electrochemical energy storage and conversion: design, synthesis and applications451Photochromic Intercalation Compounds26Solution‐Grown Zn/Al Layered Double Hydroxide Nanoplatelets onto Al Thin Films: Fine Control of Position and Lateral Thickness29Can Azobenzene Photoisomerize When Chemisorbed on a Gold Surface? An Analysis of Steric Effects Based on Nonadiabatic Dynamics Simulations23A facile method for the construction of covalently cross-linked layered double hydroxides layer-by-layer films: Enhanced stability and delayed release of guests10Film deposition mechanisms and properties of optically active chelating polymer and composites13Universal dispersing agent for electrophoretic deposition of inorganic materials with improved adsorption, triggered by chelating monomers19Azobenzene – functionalized polyelectrolyte nanolayers as ultrafast optoacoustic transducers9Graphene/layered double hydroxide nanocomposite: Properties, synthesis, and applications203Intercalation of Varied Sulfonates into a Layered MOC: Confinement‐Caused Tunable Luminescence and Novel Properties20Synthesis and Applications164A Luminescent Inorganic/Organic Composite Ultrathin Film Based on a 2D Cascade FRET Process and Its Potential VOC Selective Sensing Properties35A switchable electrochromism and electrochemiluminescence bifunctional sensor based on the electro-triggered isomerization of spiropyran/layered double hydroxides34Adsorbents Derived from Layered Solids3Organoclay Hybrid Films With Improved Functionality13Photoinduced structural changes of cationic azo dyes confined in a two dimensional nanospace by two different mechanisms17Tailoring Hybrid Layered Double Hydroxides for the Development of Innovative Applications320Preparation and application of clay mineral films2Three-dimensional layered double hydroxide membranes: fabrication technique, growth mechanism, and enhanced photocatalytic activity15Effect of Adding UV Absorbers Embedded in Carbonate Calcium Templates Covered with Light Responsive Polymer into a Clear Wood Coating13Reversible Photoswitching Function in Atomic/Molecular-Layer-Deposited ZnO:Azobenzene Superlattice Thin Films35Comparison of two encapsulation systems of UV stabilizers on the UV protection efficiency of wood clear coats16Recovery of cesium using NiHCF/NiAl-LDHs/CCFs composite by two-stage membrane-free ESIX process19Recent developments in stimuli-responsive luminescent films133Optical anisotropy induced at five different wavelengths in azopolymer thin films: Kinetics and spectral dependence26Functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings10An overview of semiconductors/layered double hydroxides composites: Properties, synthesis, photocatalytic and photoelectrochemical applications130Surface modification of fluorescent Tb3+-doped layered double hydroxides with hyperbranched polymers through host-guest interaction9Atomic/Molecular Layer Deposited Iron–Azobenzene Framework Thin Films for Stimuli‐Induced Gas Molecule Capture/Release40Atomic/Molecular Layer Deposited Iron–Azobenzene Framework Thin Films for Stimuli‐Induced Gas Molecule Capture/Release12The preparation and recent research progress of LDHs-based film fluorescent nanosensors0Fabrication, assembly, and optoelectric properties of layered double hydroxide/conjugated polymer nanocomposites2Composition-tuned metal–organic thin-film structures based on photoswitchable azobenzene by ALD/MLD11Preparation of multifunctional poly(l-lactic acid) film using heparin-mimetic polysaccharide multilayers: Hemocompatibility, cytotoxicity, antibacterial and drug loading/releasing properties30Layer-by-Layer Assembly of Two-Dimensional Materials: Meticulous Control on the Nanoscale227Thermocapillary Marangoni Flows in Azopolymers18Structural insight into the photoinduced E→Z isomerisation of cinnamate embedded in ZnAl and MgAl layered double hydroxides3Supramolecular dendrimer-containing layer-by-layer nanoassemblies for bioapplications: current status and future prospects14Hybrid Dispersion Model Characterization of PAZO Azopolymer Thin Films over the Entire Transmittance Spectrum Measured in the UV/VIS/NIR Spectral Region5Layered Double Hydroxides for Regulating Phosphate in Water to Achieve Long-Term Nutritional Management33Light Sensitive Liposomes: A Novel Strategy for Targeted Drug Delivery6Advancements in Polymer-Assisted Layer-by-Layer Fabrication of Wearable Sensors for Health Monitoring33Liquid-crystal-based diffractive optical elements with high Pancharatnam-Berry phase accuracy for holographic displays fabricated using an optimized liquid crystal on silicon device11Biopolymer-inorganic hybrid composites: The expanding role of cellulose/layered double hydroxides (LDHs) in advanced applications5Controllable removal/release of phosphate by light-responsive layered double hydroxide composite electrode0

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  2. Fabrication of pyrenetetrasulfonate/layered double hydroxide ultrathin films and their application in fluorescence chemosensors

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  3. Preparation and functionality of clay-containing films

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  4. Recent advances in photofunctional guest/layered double hydroxide host composite systems and their applications: experimental and theoretical perspectives

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  5. Helical Chirality of Azobenzenes Induced by an Intramolecular Chiral Axis and Potential as Chiroptical Switches

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  6. Photo-triggered assembly/disassembly of macroscopically ordered monodomain lamellar structure in side-chain liquid crystalline polymer containing strong polar azobenzene mesogens

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  7. Synthesis and Conformation of Substituted Chiral Binaphthyl-Azobenzene Cyclic Dyads with Chiroptical Switching Capabilities

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  8. Facile synthesis via a solvothermal route and characterization of Mg–Al layered double hydroxide (LDH) 3D micro–nano structures

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  9. Fluorescence Chemosensory Ultrathin Films for Cd2+Based on the Assembly of Benzothiazole and Layered Double Hydroxide

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  14. Preparation of Layered Double Hydroxides Nanomaterails via the Anionic Surfactant

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  15. Directional Photofluidization Lithography: Micro/Nanostructural Evolution by Photofluidic Motions of Azobenzene Materials

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  16. Resettable Fluorescence Logic Gate Based on Calcein/Layered Double Hydroxide Ultrathin Films

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  17. Photoresponsive molecular switches for biotechnology

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  18. CdTe Quantum Dots/Layered Double Hydroxide Ultrathin Films with Multicolor Light Emission via Layer‐by‐Layer Assembly

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  20. First principle evaluation of the chiroptical activity of the di-phenyl-diazene derivatives

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  21. Optical storage in azobenzene-containing epoxy polymers processed as Langmuir Blodgett films

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  23. Photophysical pore control in an azobenzene-containing metal–organic framework

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  42. A supramolecular assembly of cross-linked azobenzene/polymers for a high-performance light-driven actuator

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