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RESEARCH PAPER · CrystEngComm · 2005

New trends in crystal engineering

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New trends in crystal engineeringOriginal(HO2C(CH2)3NH3)2(CH3NH3)Pb2I7: a predicted non-centrosymmetrical structure built up from carboxylic acid supramolecular synthons and bilayer perovskite sheets127Concomitant crystallization of two polymorphs—a ring and a helix: concentration effect on supramolecular isomerism111Crystal engineering of porphyrin framework solids256Crystal engineering or crystal mysticism? A case study26Crystal engineering with hydrogen bonds and halogen bonds191Introduction and a short dictionary of network terminology0Making crystals from crystals: a green route to crystal engineering and polymorphism211Microporous organic crystals: an unusual case for l-leucyl–l-serine97One-dimensional fluorescent stacking structure based on zinc mixed-complex salt encapsulated within an ‘ice-like’ three-dimensional hydrogen-bonded water network89Sorting of polymorphs based on mechanical properties. Trimorphs of 6-chloro-2,4-dinitroaniline95Why bother with nets ?04‘-Bromo-2‘,3‘,5‘,6‘-tetrafluorostilbazole: Donor and Acceptor Site for Halogen Bonding and π-Stacking in One Rigid-Rod-Type Molecule40Second-sphere coordination complexes via hydrogen bonding: Synthesis, spectroscopic characterization, crystal structures and packing of cis-diazidobis(ethylenediamine)cobalt(III) cations with complex fluoroanions22What do we know about three-periodic nets?268Guest‐Induced Supramolecular Isomerism in Inclusion Complexes of T‐Shaped Host 4,4‐Bis(4′‐hydroxyphenyl)cyclohexanone95Triple Hydrogen Bonds Direct Crystal Engineering of Metal‐Assembled Complexes: The Effect of a Novel Organic–Inorganic Module on Supramolecular Structure40One‐Dimensional Oxalato‐Bridged Metal( II ) Complexes with 4‐Amino‐1,2,4‐triazole as Apical Ligand49Metal complexes from 1,1′-di(pyrazinyl)ferrocene: coordination polymers and bridged diferrocenes41Formation and X-ray crystal structures of neutral 3D networks by charge-assisted hydrogen bonds between tetrakis(thiourea)platinum(II) complexes and dicarboxylates9Directed supramolecular assembly of Cu( ii )-based “paddlewheels” into infinite 1-D chains using structurally bifunctional ligands33‘Rings and rectangles’ mediated through weak interactions in ionic solids: Synthesis and packing analysis of [Co(NH3)6]Cl2SeCN and [Co(NH3)6]3Cl4(N3)5 in the crystalline state16A molecular ‘back-flip’: the structural consequences of the crystal-to-crystal phase transition between [(phen) 2 CuCO 3 ]·11H 2 O and [(phen) 2 CuCO 3 ]·7H 2 O4Face-selective decoration of an organic single crystal toward photochemical devices6Hierarchical regulated assembly of new metallosupramolecular networks based on metal thiocyanate and trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene (bpe)via multiple interactions34Ligands and complexes with supramolecular aromatic–aromatic interactions: iron( ii ) and ruthenium( ii ) complexes of 2,2′:6′,2″-terpyridines with pendant naphthalene groups36Mechanochemical preparation of molecular and supramolecular organometallic materials and coordination networks289New coordination polymer networks based on copper( ii ) hexafluoroacetylacetonate and pyridine containing building blocks: synthesis and structural study42Solid-state preparation of hybrid organometallic–organic macrocyclic adducts with long chain dicarboxylic acids32Solvent-directed layered Co(ii) coordination polymers with unusual solid-state properties: from a nanoporous framework to the dense polythreading 3-D aggregation90Supramolecular architectures of neutral and cationic complexes of transition metals with lactate and 1,10-phenanthroline20Design, synthesis, characterization and utilization of hydrogen bonded networks based on functionalized organometallic sandwich compounds and the occurrence of crystal polymorphism75Noncovalent Syntheses of Supramolecular Organo Gelators23Hydrogen bond network structures based on sulfonated phosphine ligands: The effects of complex geometry, cation substituents and phosphine oxidation on guanidinium sulfonate sheet formation17Solvent Exchange in Thermally Stable Resorcinarene Nanotubes50Second-sphere coordination complex via hydrogen bonding: Synthesis, characterization, X-ray crystal structure determination and packing of hexaamminecobalt(III) chloride di(para-nitrobenzoate)14New N,N,N-Heteroscorpionates Based on 2,2‘-Bis(pyrazolyl)ethanamine and Its Derivatives. Ligands Designed for Probing Supramolecular Interactions28M−X···X‘−C Halogen-Bonded Network Formation in MX2(4-halopyridine)2 Complexes (M = Pd, Pt; X = Cl, I; X‘ = Cl, Br, I)77Self-assembly of extended structures through non-coordination intermolecular forces: Synthesis, crystal structures, and properties of metal complexes with 5-methyl-2-pyrazinecarboxylate23Anisotropic Decoration of Gold Nanoparticles onto Specific Crystal Faces of Organic Single Crystals48Anisotropic Decoration of Gold Nanoparticles onto Specific Crystal Faces of Organic Single Crystals5Packing Modes in Some Mono‐ and Disubstituted Phenylpropiolic Acids: Repeated Occurrence of the Rare syn,anti Catemer80Synthesis and structure of the two-dimensional coordination networks [Ln(PDC)(N-HPDC)]∞ (PDC=pyridine-3,4-dicarboxylate, Ln=La, Ce, Pr)29Linking Chiral Clusters with Molybdate Building Blocks: From Homochiral Helical Supramolecular Arrays to Coordination Helices57The Nature of Halogen⋅⋅⋅Halogen Synthons: Crystallographic and Theoretical Studies427Growth of Six Different Crystals of the Versatile Host Compound 1,1‘-Binaphthyl-2,2‘-dicarboxylic Acid from Solutions in 1,4-Dioxane16Syntheses and crystal structures of four silver(I) complexes based on 2-(4-pyridyl)benzimidazole18Extremely Long Axial Cu−N Bonds in Chiral One-Dimensional Zigzag Cyanide-Bridged CuII-NiII and CuII-PtII Bimetallic Assemblies381,8-Naphthalimide Synthon in Silver Coordination Chemistry: Control of Supramolecular Arrangement43Iron( ii ) complexes with a terpyridine embrace packing motif show remarkably consistent cooperative spin-transitions96Self-Assembly of Sticky TABs: Inclusion Complexes and Hydrates from 1,3,5-Tris(4-hydroxybenzoyl)benzene14Making crystals from crystals: three solvent-free routes to the hydrogen bonded co-crystal between 1,1′-di-pyridyl-ferrocene and anthranilic acid66Hexagonal Supramolecular Architectures from Ferrocenium Cations Incorporating [Ni(mnt)2]− Columns: Structures and Properties of [Alkylferrocene][Ni(mnt)2]− Charge‐Transfer Complexes (mnt=maleonitriledithiolate)25Construction of macrocycle-based molecular stairs having pendant 4-aminopyridine, 4-dimethylaminopyridine and isonicotinonitrile groups22Hydrogen storage in metal–organic frameworks290Interplay of coordinative and supramolecular interactions in engineering unusual crystalline architectures of low-dimensional metal–pamoate complexes under co-ligand intervention76Intra- and intermolecular interactions and water pincer in the crystal structure of a 3-P(O)Ph 2 substituted 1,2,3,6-tetrahydrophosphinine oxide hydrate8Investigation into the reactivity of the coordinatively unsaturated phosphonodithioato [Ni(MeOpdt)2] towards 2,4,6-tris(2-pyridyl)-1,3,5-triazine: goals and achievements22Metallotectons: using enantiopure tris(dipyrrinato)cobalt(iii) complexes to build chiral molecular materials66Predictable and unpredictable reactions between 4,4′-dipyridyldisulfide and phosphonodithioato/dithiophosphato NiII complexes: novel coordination polymers and the unique example of 4,4′-dipyridyltrisulfide50Pyridine complexes of mercury(ii)halides: Implications of a soft metal center for crystal engineering.68Rational design of 1-D metal–organic frameworks based on the novel pyrimidine-4,6-dicarboxylate ligand. New insights into pyrimidine through magnetic interaction41Rectangular architectures formed by acyclic diamido-metal-N-heterocyclic carbenes with skewed conformation36Self-assembly of 3-D 4d–4f coordination frameworks based on 1-D inorganic heterometallic chains and linear organic linkers120Syntheses, crystal structures, optical limiting properties, and DFT calculations of three thiophene-2-aldazine Schiff base derivatives13Unusual hydrogen bonded (OH)4 tetrahedral nests organize zinc(ii) coordination complexes in a non covalent diamondoid network14Self‐Assembly of Halogenated Cobaltacarborane Compounds: Boron‐Assisted CH⋅⋅⋅XB Hydrogen Bonds?21Structural diversity of copper complexes with angular and linear dipyridyl ligands24Metal–Organic Hybrids of 1,3,5‐Tris(4‐pyridylsulfanylmethyl)‐2,4,6‐trimethylbenzene with Mercuric Halides15The potential of intermolecular N⋯O interactions of nitro groups in crystal engineering, as revealed by structures of hexakis(4-nitrophenyl)benzene42Solution and Solid‐State Preparation of 18‐Crown[6] Complexes with M[HSO4]n Salts (M = NH4+, K+, Sr2+ and n = 1, 2) and an Investigation of Solvation/Desolvation Processes and Crystal Polymorphism35Solution and Solid-State Preparation of 18-Crown-6 and 15-Crown-5 Adducts of Hydrogen Sulfate Salts and an Investigation of the Reversible Dehydration Processes36Highly Interpenetrated Supramolecular Networks Supported by N⋅⋅⋅I Halogen Bonding128Synthesis, Crystal Structure and Supramolecular Organization of the 1D Coordination Polymer [Cu(HCOO)2(4‐bpytm)], (4‐bpytm = Bis(4‐pyridylthio)methane)21Three crystalline forms of 1,3,5-benzene-tri(3-pyridinyl)carboxamide from the same solvent system17Incorporating Metal Clusters into Three-Dimensional Ln(III)−Cu(I) Coordination Frameworks through Linear Ligands98Coordination polymers of manganese(II) and cobalt(II) of a flexible tetradentate pyridine amide ligand: 1D zigzag network and non-covalent interactions23Rational Design of MOFs Constructed from Modified Aromatic Amino Acids53Crystalline Complexes of 2,2′-Bis(9-hydroxy-9-fluorenyl)biphenyl Host with Oligofunctional and Conjugate Functional Group Guests7Crystal engineering with urea and thiourea hydrogen-bonding groups331Hydrogen bonding patterns in a series of 1-arylcycloalkanecarboxamides5Mechanical mixing of molecular crystals27Solid State Synthesis and Hierarchical Supramolecular Self-assembly of Organic Salt Cocrystals18Engineering of Pharmaceutical Materials: An Industrial Perspective142Heterotapes: A Persistent, Dual‐Synthon Hydrogen‐Bonding Motif26A guest-templated (6,3)-sheet constructed using asymmetric hydrogen-bonding anions26Polymorphism-dependent fluorescence of 9,10-bis(pentafluorobenzoyloxy)anthracene30Dimension Increase via Hydrogen Bonding and Weak Coordination Interactions from Simple Complexes of 2-(Pyridyl)benzimidazole Ligands51Supramolecular Bimetallic Systems Constructed through π‐π Stacking and Hydrogen Bond Interactions3Crystal Structures of N-Aryl-N′-4-Nitrophenyl Ureas: Molecular Conformation and Weak Interactions Direct the Strong Hydrogen Bond Synthon83A one-dimensional ladder-like coordination polymer: poly[[hexaaquabis(μ-5-nitrobenzene-1,3-dicarboxylato-κ3O,O′,O′′)(μ-oxalato-κ4O,O′:O′′,O′′′)diyttrium(III)] trihydrate]0Crystal Structures of Spiroborates Derived from 2,2′-Dihydroxybiphenyl15Crystal engineering of lanthanide–transition-metal coordination polymers17Cd(II)-sulfonyldibenzoilate coordination polymers based on mono-, bi-, tri- and tetranuclear cores as nodes63Crucial role of Ru⋯H interactions in the crystal packing of ruthenocene and its derivatives44Crystalline packings of diketoarylhydrazones controlled by a methyl for trifluoromethyl structural change22Flexible and versatile anionic modules in the direction of 1-D, 2-D, and 3-D coordination frameworks by metal–ligand synergistic interactions23Hydrogen bonded networks in N–alkyl substituted thiourea platinum (II) oxocarbodianion and carboxylate salts25Hydrogen-bonding tectons for the construction of bimolecular framework materials23Inorganic–organic hybrid salts of diaminobenzenes and related cations55Mechanochemical assembly of hybrid organic–organometallic materials. Solid–solid reactions of 1,1′-di-pyridyl-ferrocene with organic acids33Metal-organic framework materials for hydrogen storage11Molecular networks. Design and serendipity6Remarkable structural similarities between organic co-crystals and a metal–organic coordination network—insights into hydrogen bonded aliphatic ammonium chlorides13Supramolecular networks of silver(i) and iron(ii) complexes of the third generation tris(pyrazolyl)methane ligand Ph2(O)POCH2C(pz)3 (pz = pyrazolyl ring)21Towards tuning the packing and entanglement of zigzag coordination chains by terminal ligands49Two-Dimensional Crystal Engineering at the Liquid–Solid Interface61Mononuclear, trinuclear, and hetero-trinuclear supramolecular complexes containing a new tri-sulfonate ligand and cobalt(II)/copper(II)-(1,10-phenanthroline)2 building blocks4A New Supramolecular Assembly Formed by Melamine and Sulfuric Acid13Structural Versatility in Copper(II) α-Hydroxycarboxylate Complexes with the Twisted Ligands 4,4′-Dipyridyldisulfide and Bis(4-pyridylthio)methane: From Molecular Compounds to Two-Dimensional Coordination Polymers44Novel Metal−Organic Frameworks Derived from Group II Metal Cations and Aryldicarboxylate Anionic Ligands135Estimation of the energy of coordination K-O bonds in a potassium hydrophthalate crystal on the basis of electron-density distribution analysis9Engineering Hydrogen-Bonded Molecular Crystals Built from 1,3,5-Substituted Derivatives of Benzene: 6,6′,6′′-(1,3,5-Phenylene)tris-1,3,5-triazine-2,4-diamines27Crystal Structures of Spiroborates Derived from [1,1′-Binaphthalene]-2,2′-diol (BINOL)20Synthesis and Structure of Spirocyclic Tetraethers Derived from [1,1′-Binaphthalene]-2,2′-diol and Pentaerythritol10Solid state coordination chemistry of copper(II) lactate complexes with the twisted ligands 4,4′-dipyridyldisulfide and bis(4-pyridylthio)methane25Influence of Fluorine Substitution on the Crystal Packing of N-Phenylmaleimides and Corresponding Phthalimides73Growth of Copper Pyrazole Complex Templated Phosphomolybdates: Supramolecular Interactions Dictate Nucleation of a Crystal99The role of charge assisted arylhalogen–halide ion interactions in the structures of the dibromopyridinium halide salts25Structural Equivalence of Br and I Halogen Bonds: A Route to Isostructural Materials with Controllable Properties105Destabilisation of a dual-synthon hydrogen bonding motif by packing effects and competing hydrogen bond donors17Self-Assembly of Electroactive Thiacrown Ruthenium(II) Complexes into Hydrogen-Bonded Chain and Tape Networks16The synthesis and X-ray crystal structures of rare earth(III) perfluoroadipate complexes — Novel coordination polymers2“Click” synthesis of isomeric compounds for assessing the efficiency of the bifurcated Br⋯NO 2 synthon16In situ synthesis of 5-substituted-tetrazoles and metallosupramolecular co-ordination polymers39Caesium 18-crown[6] complexes with aromatic polycarboxylate anions: preparation, solid-state characterization and thermal behaviour17CH/π hydrogen bonds in organic and organometallic chemistry556Competitive interactions in crystalline 9-pyridyl-9-fluorenols: crossover from O–H⋯O to O–H⋯N hydrogen bonding to construct intra- and intermolecular, helical and linear contact modes5From copper(II) carboxylate to copper(II) 4-pyridylsulfonate coordination polymers as a consequence of the copper(II)-assisted oxidative cleavage of the 4,4′-dipyridyldisulfide ligand34Hydrogen, Methane and Carbon Dioxide Adsorption in Metal-Organic Framework Materials127Investigation on the reactivity of dithiophosphonato/dithiophosphato NiII complexes towards 2,4,6-tris-2-pyridyl-1,3,5-triazine: developments and new perspectives16Second-sphere hydrogen-bonding in heteroditopic mercaptopyridinium copper(I) frameworks12Synthesis and X-ray Crystal Structures of New Tetrahedral Arylethynyl Substituted Silanes10Hydrogenoxalate and squarate salts of (E)-4-(hydroxyiminomethyl)-pyridine – Crystal structures, spectroscopic and theoretical elucidation13Metallotectons: Comparison of Molecular Networks Built from Racemic and Enantiomerically Pure Tris(dipyrrinato)cobalt(III) Complexes52Solid‐State NMR Investigation of Ligand Mobility and Reactivity in Transition Metal Complexes19Mixed-ligand complexes with trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene terminal and different aromatic polycarboxyl linkers: Synergistic modulation of metallosupramolecular architectures via coordinative and secondary interactions6Structural architectures of charge-assisted, hydrogen-bonded, 2D layered amine⋯tetraphosphonate and zinc⋯tetraphosphonate ionic materials20Design, structure, and properties of functional metal–ligand inorganic modules9Metal complexes of new scorpionate ligands: 2,2′-Bis(pyrazolyl)ethylamine and its derivatives12Structural and magnetic characterization of one-dimensional oxalato-bridged metal(II) complexes with 4-amino-3,5-bis(2-pyridyl)-1,2,4-triazole ligand: A supramolecular open-framework15Structural evidence for metalloaromaticity in a new molecular complex with the divergent ligand 4,4′-dipyridyldisulfide14Supramolecular Rhombic Grids Formed from Bimolecular Building Blocks26A Novel Bi-Metal NiIICdII Supramolecular Structure with 4-Hydroxypyridine Ligands, [{CdII(4-OHpy)2}{NiII(CN)4}], and Deprotonated 3-Hydroxypyridine Ligands, [{CdII3(3-O−py)2(mea)2}{NiII(CN)4}2]2Highly Organized Structures and Unusual Magnetic Properties of Paddlewheel Copper(II) Carboxylate Dimers Containing the π−π Stacking, 1,8-Naphthalimide Synthon97对羧基苯氧乙酸-稀土系列配位聚合物的合成、结构及性质2Thickness Control of Highly Efficient Organic Electro-Optic Phenolic Polyene Crystals by Metal Acetates12Easy obtainment of three-dimensional coordination polymer of zinc 1,2,4,5-benzenetetracarboxylate with para-amino-pyridinium cations2Halogen bonding in metal–organic–supramolecular networks364Supramolecular Architectures of Metal Complexes Controlled by a Strong π···π Stacking, 1,8-Naphthalimide Functionalized Third Generation Tris(pyrazolyl)methane Ligand36Monofluoride Bridged, Binuclear Metallacycles of First Row Transition Metals Supported by Third Generation Bis(1-pyrazolyl)methane Ligands: Unusual Magnetic Properties44

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  4. Crystal engineering or crystal mysticism? A case study

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  5. Crystal engineering with hydrogen bonds and halogen bonds

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  6. Introduction and a short dictionary of network terminology

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  46. Syntheses and crystal structures of four silver(I) complexes based on 2-(4-pyridyl)benzimidazole

    Polyhedron · 2006-10-15

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  49. Iron( ii ) complexes with a terpyridine embrace packing motif show remarkably consistent cooperative spin-transitions

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