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RESEARCH PAPER · Journal of the American Chemical Society · 2002

Monolayers as Models for Supported Catalysts: Zirconium Phosphonate Films Containing Manganese(III) Porphyrins

Isa O. Benítez, Bruno Bujoli, Laurent J. Camus, Christine M. Lee, Fabrice Odobel, Daniel R. Talham

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Monolayers as Models for Supported Catalysts: Zirconium Phosphonate Films Containing Manganese(III) PorphyrinsOriginalCoordination Chemistry of the Water-Soluble Ligand TPPTP and Formation of a [Mo(CO)5(m-TPPTP)] Monolayer on an Alumina Surface19Organic–inorganic hybrids of imidazole complexes of palladium( ii ), copper( ii ) and zinc( ii ). Crystals and liquid crystals43{M(C5H4N)CH(OH)PO3}(H2O) (M = Mn, Fe, Co): layered compounds based on [hydroxy(4-pyridyl)methyl]phosphonate15Hybrid Organic−Inorganic Langmuir−Blodgett Films Starting from Colloidal Prussian Blue Solution40Catalytic Reduction of Acetone by [(bpy)Rh]+: A Theoretical Mechanistic Investigation and Insight into Cooperativity Effects in This System19Porphyrins Bearing Arylphosphonic Acid Tethers for Attachment to Oxide Surfaces63New Approach to Oligonucleotide Microarrays Using Zirconium Phosphonate-Modified Surfaces131Enhancement of Molecular Properties in Thin Films by Controlled Orientation of Molecular Building Blocks69Surface density as a significant parameter for the enzymatic activity of two forms of alkaline phosphatase immobilized on phospholipid Langmuir?Blodgett films39Layered -Zirconium Phosphates and Phosphonates1Mixed Thin Films of a Cationic Amphiphilic Porphyrin and n-Alkanes2Organic Cross-Linked Electropolymers as Supported Oxidation Catalysts: Poly((tetrakis(9,9‘-spirobifluorenyl)porphyrin)manganese) Films47Layered α‐Zirconium Phosphates and Phosphonates6New polymers for catalytic carbene transfer: electropolymerization of tetrafluorenylporphyrinruthenium carbon monoxide40Hydrothermal synthesis, crystal structure, and magnetic property of a three-dimensional inorganic–organic hybrid material: Mn(H2O)[HO3PCH2NH(CH2CO2)2]17A Catalytic Langmuir Film as a Model for Heterogeneous and Homogeneous Catalytic Processes24A Catalytic Langmuir Film as a Model for Heterogeneous and Homogeneous Catalytic Processes10Preparation and catalytic property of the solid base supported on the mixed zirconium phosphate phosphonate for Knoevenagel condensation34Metal Phosphonates Applied to Biotechnologies: A Novel Approach to Oligonucleotide Microarrays98The Binding Energy of Two Nitrilotriacetate Groups Sharing a Nickel Ion19Hydrothermal syntheses, structures and characterizations of three one-dimensional polyoxomolybdates with 4,4′-dimethylenebiphenyl diphosphonic acid as bridge11Manganese porphyrin multilayer films assembled on ITO electrodes via zirconium phosphonate chemistry: chemical and electrochemical catalytic oxidation activity12Solvothermal synthesis, crystal structure, magnetic and luminescent properties of (H3O)6·[Co4(H2O)4(HPMIDA)2(PMIDA)2)]·2H2O14Monolayers of Salen Derivatives as Catalytic Planes for Alkene Oxidation in Water13Syntheses, Characterization, and Magnetic Properties of Four New Layered Transition-Metal Hydroxyl−Carboxylate−Phosphonates: [M(CH(OH)(CO2)(PO3H))(H2O)2] (M = Mn, Fe, Co, Zn)36A novel copper diphosphonate complex Cu4(aedp)2(4,4′-bpy)(H2O)4 with three-dimensional framework structure27Liquid/Liquid Interface Polymerized Porphyrin Membranes Displaying Size-Selective Molecular and Ionic Permeability11Novel phosphate–phosphonate hybrid nanomaterials applied to biology28Strategies for Electrooptic Film Fabrication. Influence of Pyrrole−Pyridine-Based Dibranched Chromophore Architecture on Covalent Self-Assembly, Thin-Film Microstructure, and Nonlinear Optical Response76Asymmetric heterogeneous catalysis by metalloporphyrins75Synthesis and catalytic application of zirconium-substituted aminoethyl phosphonate14Zirconium Phosphonate-Modified Porous Silicon for Highly Specific Capture of Phosphopeptides and MALDI-TOF MS Analysis163Activity boost of a biomimetic oxidation catalyst by immobilization onto a gold surface48Synthesis and characterization of a novel type of self-assembled chiral zirconium phosphonates and its application for heterogeneous asymmetric catalysis24XPS investigation of DNA binding to zirconium-phosphonate surfaces16Langmuir–Blodgett films of palladium(II)-imidazole liquid crystals8Synthesis, characterization, and applications in Heck and Suzuki coupling reactions of amphiphilic cyclopalladated ferrocenylimines67Monolayer-Based Selective Optical Recognition and Quantification of FeCl3 via Electron Transfer39Specific capture of phosphopeptides by Zr4+‐modified monolithic capillary column32Syntheses, Crystal Structures, Thermal Stabilities, and Magnetic and Luminescent Properties of 3D Heterometal Phosphonates: NaM[O3PCH(OH)CO2] (M = Mn, Fe, Co, Zn)19Synthesis, characterization and intercalation property of layered zirconium benzylamino-N,N-dimethylphosphonate phosphate materials16Towards Zirconium Phosphonate-Based Microarrays for Probing DNA−Protein Interactions: Critical Influence of the Location of the Probe Anchoring Groups85Poly(dG) Spacers Lead to Increased Surface Coverage of DNA Probes: An XPS Study of Oligonucleotide Binding to Zirconium Phosphonate Modified Surfaces24Palladium-catalysed aminocarbonylation of iodoarenes and iodoalkenes with aminophosphonate as N-nucleophile14Synthesis and characterization of a new kind of immobilized Mn(salen) and catalytic epoxidation of styrene on the catalyst13Langmuir–Blodgett films of cyclopalladated ferrocenylimine: preparation, characterization, and application in Suzuki coupling reaction31Synthesis of a new type of immobilized chiral salen Mn(III) complex as effective catalysts for asymmetric epoxidation of unfunctionalized olefins98Techniques for phosphopeptide enrichment prior to analysis by mass spectrometry213NO-Induced Reorganization of Porphyrin Arrays48Synthesis of meso-Polyphosphorylporphyrins and Example of Self-Assembling53Chemical Fingerprints of Large Organic Molecules in Scanning Tunneling Microscopy: Imaging Adsorbate−Substrate Coupling of Metalloporphyrins63Bisphosphonate Adaptors for Specific Protein Binding on Zirconium Phosphonate-based Microarrays37Porphyrin self-assembled monolayers and photodynamic oxidation of tryptophan4Vesicle Formation from an Amphiphilic Porphyrin Derivative at the Air–Water Interface10Electrochemical behavior of dopamine in the presence of phosphonate and the determination of dopamine at phosphonate modified zirconia films electrode with highly antifouling capability45How or not to calculate Ni(II) Werner-type complexes: evaluation of quantum chemical methods6Novel layered crystalline zinc poly(styrene-phenylvinyl phosphonate)-phosphate synthesized by a simple route in a THF–water medium28Synthesis of a Novel Zirconium Oligostyrenylphosphonate-Phosphate and its Application in Asymmetric Epoxidation0A New Strategy for Designing Conjugated Polymer-Based Fluorescence Sensing Films via Introduction of Conformation Controllable Side Chains31Comparative study of porphyrin derivatives in monolayers at the air–water interface and in Langmuir–Blodgett films28Mixed self-assembled monolayers of Co-porphyrin and n-alkane phosphonates on gold12Supported l-proline on zirconium phosphates methyl and/or phenyl phosphonates as heterogeneous organocatalysts for direct asymmetric aldol addition65Chiral Salen Mn(III) Complex Axial Coordination Immobilized on Diamine Modified Alspp and Highly Efficient Large-Scale Epoxidation of Olefins as a Recoverable Catalyst5Increased Catalytic Activity of Surface‐Immobilized Palladium Complexes in the Fluorogenic Deprotection of an Alloc‐Derivatized Coumarin15Self-assembled monolayers of metalloporphyrin phosphonates on electrochemically modified HOPG5Comparative electrochemical investigations on series of SH-terminated-functional porphyrins8Gold nanoparticles modified with coordination compounds of metals: synthesis and application41Surface Modification Using Phosphonic Acids and Esters868Cyclopalladated ferrocenylimine self-assembly films for Suzuki coupling reaction18Synthesis of layered crystalline AlSPP and its immobilized chiral salen Mn(III) catalysts applicated in the large scale asymmetric epoxidation of olefins4Removal of Pb(II) and Cu(II) Ions From Aqueous Solutions by Manganese Phosphonate11Cyclopalladated Arylimine Self‐Assembly Films for Suzuki Reaction31Preparation and photolithography of self-assembled monolayers of 10-mercaptodecanylphosphonic acid on glass mediated by zirconium for protein patterning17Performance of a biomimetic oxidation catalyst immobilized on silica particles9Preparation, characterization and catalytic activity of amphiphilic cyclopalladated aryl imines and their Langmuir-Blodgett films9Structure tuning of metal phosphonates: Syntheses, structures and characterizations of two new lead (II) trisphosphonates9Catalytic oxidation of ascorbic acid via copper–polypyridyl complex immobilized on glass18High density monolayer of diisocyanide on gold surface as a platform of supported Rh-catalyst for selective 1,4-hydrogenation of α,β-unsaturated carbonyl compounds24Immobilization of chiral Rh catalyst on glass and application to asymmetric transfer hydrogenation of aryl ketones in aqueous media6Synthesis of Zirconium Phosphonate Supported L ‐Proline as an Effective Organocatalyst for Direct Asymmetric Aldol Addition35Porphyrinic Materials: Self-Assembly on Surfaces0A series of crystalline organic polymer–inorganic hybrid material zinc-phosphonate-phosphates synthesized in the presence of templates for superior performance catalyst support3High‐Density Monolayers of Metal Complexes: Preparation and Catalysis2Functionalization of Zirconium Oxide Surfaces7Formation of Highly Stable Self-Assembled Alkyl Phosphonic Acid Monolayers for the Functionalization of Titanium Surfaces and Protein Patterning19An electrochemically polymerized and assembled cyclopalladated bi-thiophene imine for catalyzing coupling reactions: a modern strategy to enhance catalytic activity16Fine‐Tuning the Functionality of Inorganic Surfaces Using Phosphonate Chemistry3Molecular Orientation and Structural Transformations in Phthalic Anhydride Thin Films on MgO(100)/Ag(100)16Organic linkers on oxide surfaces: Adsorption and chemical bonding of phthalic anhydride on MgO(100)8A Double‐Cavity‐Containing Porphyrin Host as a Highly Stable Epoxidation Catalyst17Niobium phytate prepared from phytic acid and NbCl 5 : a highly efficient and heterogeneous acid catalyst22Fluorescence Detection of DNA Based on Non-covalent π-π Stacking Interaction between 1-Pyrenebutanoic Acid and Hypericin5Highly ordered amphiphilic cyclopalladated arylimine self‐assembly films for catalyzing Heck and Suzuki coupling reactions13Self-Assembly Mechanisms of Organosilanes and Porphyrins Investigated with Scanning Probe Microscopy0Interaction of free-base tetraphenylporphyrin with magnesium oxide: Influence of MgO morphology on metalation16Coverage-Dependent Anchoring of 4,4′-Biphenyl Dicarboxylic Acid to CoO(111) Thin Films17Geometry of Molecular Motions in Dye Monolayers at Various Coverages6Overcoming the crystallization and designability issues in the ultrastable zirconium phosphonate framework system454Self-Assembly Mechanisms of Organosilanes and Porphyrins Investigated with Scanning Probe Microscopy1Phosphonate‐Mediated Immobilization of Rhodium/Bipyridine Hydrogenation Catalysts8An ingenious one-dimensional zirconium phosphonate with efficient strontium exchange capability and moderate proton conductivity23Heterostuctures of 4-(chloromethyl)phenyltrichlorosilane and 5,10,15,20-tetra(4-pyridyl)-21 H ,23 H -porphine prepared on Si(111) using particle lithography: Nanoscale characterization of the main steps of nanopatterning3Hydrogen Peroxide and Metalloporphyrins in Oxidation Catalysis: Old Dogs with Some New Tricks62Manganese Fluorene Phosphonates: Formation of Isolated Chains4Exploring the Effect of Gold Support on the Oxygen Reduction Reaction Activity of Metal Porphycenes9Recent advances in the catalytic oxidation of alkene and alkane substrates using immobilized manganese complexes with nitrogen containing ligands70Self-Metalation of Porphyrins by Cobalt Oxide: Photoemission Spectroscopic Investigation14A rare potassium-rich zirconium fluorophosphonate with high Eu 3+ adsorption capacities from acidic solutions4Direct observation of narrow electronic energy band formation in 2D molecular self-assembly2Synthesis, characterization and investigation of photochemical and in vitro antiproliferative properties of novel Zn(II) phthalocyanine9Hybrid Materials Based on Imidazo[4,5-b]porphyrins for Catalytic Oxidation of Sulfides18Supramolecular assembly of phosphonate-substituted porphyrins in Langmuir layers and Langmuir–Schäfer films: structural studies and selective sensing of pyridine vapors4Synthesis and Functional Properties of Fluorinated Phosphonate‐Substituted Porphyrins: Excellent Photosensitizers and Robust Precursors for Photoactive Langmuir–Schaefer Films0

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  2. Organic–inorganic hybrids of imidazole complexes of palladium( ii ), copper( ii ) and zinc( ii ). Crystals and liquid crystals

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  3. {M(C5H4N)CH(OH)PO3}(H2O) (M = Mn, Fe, Co): layered compounds based on [hydroxy(4-pyridyl)methyl]phosphonate

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  4. Hybrid Organic−Inorganic Langmuir−Blodgett Films Starting from Colloidal Prussian Blue Solution

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  5. Catalytic Reduction of Acetone by [(bpy)Rh]+: A Theoretical Mechanistic Investigation and Insight into Cooperativity Effects in This System

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  6. Porphyrins Bearing Arylphosphonic Acid Tethers for Attachment to Oxide Surfaces

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  7. New Approach to Oligonucleotide Microarrays Using Zirconium Phosphonate-Modified Surfaces

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  8. Enhancement of Molecular Properties in Thin Films by Controlled Orientation of Molecular Building Blocks

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  31. Synthesis and catalytic application of zirconium-substituted aminoethyl phosphonate

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  32. Zirconium Phosphonate-Modified Porous Silicon for Highly Specific Capture of Phosphopeptides and MALDI-TOF MS Analysis

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  33. Activity boost of a biomimetic oxidation catalyst by immobilization onto a gold surface

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  35. XPS investigation of DNA binding to zirconium-phosphonate surfaces

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  39. Specific capture of phosphopeptides by Zr4+‐modified monolithic capillary column

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  41. Synthesis, characterization and intercalation property of layered zirconium benzylamino-N,N-dimethylphosphonate phosphate materials

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  43. Poly(dG) Spacers Lead to Increased Surface Coverage of DNA Probes: An XPS Study of Oligonucleotide Binding to Zirconium Phosphonate Modified Surfaces

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  44. Palladium-catalysed aminocarbonylation of iodoarenes and iodoalkenes with aminophosphonate as N-nucleophile

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  45. Synthesis and characterization of a new kind of immobilized Mn(salen) and catalytic epoxidation of styrene on the catalyst

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  46. Langmuir–Blodgett films of cyclopalladated ferrocenylimine: preparation, characterization, and application in Suzuki coupling reaction

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  47. Synthesis of a new type of immobilized chiral salen Mn(III) complex as effective catalysts for asymmetric epoxidation of unfunctionalized olefins

    Journal of Catalysis · 2009-01-08

    Biwei Gong, Xiangkai Fu, Junxian Chen, Yuedong Li, Xiaochuan Zou, Xiaobo Tu, Pingping Ding, Liping Ma

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  48. Techniques for phosphopeptide enrichment prior to analysis by mass spectrometry

    Mass Spectrometry Reviews · 2009-03-04

    Jamie D. Dunn, Gavin E. Reid, Merlin L. Bruening

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  49. NO-Induced Reorganization of Porphyrin Arrays

    ACS Nano · 2009-06-22

    Florian Buchner, Knud Seufert, Willi Auwärter, Daniel Heim, Johannes V. Barth, Ken Flechtner, J. Michael Gottfried, Hans‐Peter Steinrück, Hubertus Marbach

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  50. Synthesis of meso-Polyphosphorylporphyrins and Example of Self-Assembling

    Organic Letters · 2009-07-31

    Yulia Yu. Enakieva, Alla Bessmertnykh‐Lemeune, Yulia G. Gorbunova, Christine Stern, Yoann Rousselin, Aslan Yu. Tsivadze, Roger Guilard

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