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RESEARCH PAPER · Inorganic Chemistry · 2007

Interchain-Solvent-Induced Chirality Change of 1D Helical Chains: From Achiral to Chiral Crystallization

Long Jiang, Xiao‐Long Feng, Cheng‐Yong Su, Xiao‐Ming Chen, Tong‐Bu Lu

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Interchain-Solvent-Induced Chirality Change of 1D Helical Chains: From Achiral to Chiral CrystallizationOriginalSupramolecular coordination chemistry11Chiral Symmetry Breaking by Chemically Manipulating Statistical Fluctuation in Crystallization178Chiral Symmetry Breaking by Chemically Manipulating Statistical Fluctuation in Crystallization13Three coordination polymers with helical chains based on methylenediisophthalic acid (H4MDIP)57Spontaneous Resolution of a Racemic Nickel(II) Complex and Helicity Induction via Hydrogen Bonding: The Effect of Chiral Building Blocks on the Helicity of One-Dimensional Chains64Solvent-Assisted Spontaneous Resolution of a 16-Membered Ring Containing Gold(I) Showing Short Au···Au Aurophilic Interaction and a Figure-Eight Conformation34Two bimetallic tetranuclear three-blade propeller shaped complexes with helical water chains: Crystal structures, second-order nonlinear optical (NLO) properties and thermal decomposition mechanisms12Concomitant and Controllable Chiral/Racemic Polymorphs: From Achirality to Isotactic, Syndiotactic, and Heterotactic Chirality100Concomitant and Controllable Chiral/Racemic Polymorphs: From Achirality to Isotactic, Syndiotactic, and Heterotactic Chirality7Polymorphism and Pseudopolymorphism of an Aromatic Amide: Spontaneous Resolution and Crystal-to-Crystal phase Transition14Synthesis, Structure, and Solvent‐Induced Spontaneous Homochiral Assembly of Bidentate Bis(N,N′‐diaryl‐N‐heterocyclic carbene)‐Palladium Complexes15The Supramolecular Isomerism Based on Argentophilic Interactions: The Construction of Helical Chains with Defined Right-Handed and Left-Handed Helicity63Controlling the dimensionalities and structures of homochiral Zn( ii ) and Cd( ii ) compounds of N-(p-tosyl)-S-carboxymethyl- l -cysteinevia tuning the connecting modes of metal ions and chiral linkers by different kinds of ancillary ligands45Vanadium polyoxoanion-bridged macrocyclic metal complexes: from one-dimensional to three-dimensional structures44Constructions of 1D helical chains with left-handed/right-handed helicity: a correlation between the helicity of 1D chains and the chirality of building blocks27Solvent‐Induced Pseudopolymorphism of a New Dinuclear Oxovanadium(V) Compound Based on 2,6‐Di(hydroxymethyl)‐4‐methylphenol3Synthesis, spectroscopic, thermal Studies, antimicrobial activities and crystal structures of Co(II), Ni(II), Cu(II) and Zn(II)-orotate complexes with 2-methylimidazole41Diaqua(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)nickel(II) tetracyanidonickelate(II)2Constructions of helical coordination compounds153One-dimensional coordination polymers of Co(II) and Cd(II)-squarate with 2-methylimidazole and 4(5)-methylimidazole ligands14Chiral resolution of a racemic macrocyclic complex by recognition of one enantiomer over the other: structures and DFT calculations21Syntheses and Crystal Structures of a Series of Coordination Polymers Constructed From C2‐Symmetric Ligand 1,3‐Adamantanedicarboxylic Acid36Synthesis, Crystal Structure and Luminescence Property of a Chiral Magnesium (II) Mixed-ligand Complex [Mg(H2O)2(phen)(HBDC)2](phen)3One-Dimensional Coordination Polymers: Complexity and Diversity in Structures, Properties, and Applications1113From Infinite One-Dimensional Helix to Discrete CuII15 Cluster along with in Situ SN2 Ring-Cleavage of cis-Epoxysuccinic Acid: pH-Controlled Assemblies, Crystal Structures, and Properties72Molecular structures of nickel(II) monochelates of a racemic tridentate ligand and co-ligand induced structural variations17Cyano-Bridged Homochiral Heterometallic Helical Complexes: Synthesis, Structures, Magnetic and Dielectric Properties38Coordination polymers and metallomacrocycles based on bis(pyridylcarbamate) ligands with flexible glycol spacers20Structure, adsorption and magnetic properties of chiral metal–organic frameworks bearing linear trinuclear secondary building blocks48Synthesis and crystal structures of terephthalato-bridged macrocyclic nickel(II) complexes with cis configurations8pH Values Dependent Helicity of 1D Homochiral Helical Chains37A cyanide-bridged 1-D helical chain involving both four- and six-coordinate nickel(II)12Chiral Moieties-Oriented Single-Stranded Helical Assembly of Calix[4]azacrown Derivatives6Solvent-Controlled Rare Case of a Triple Helical Molecular Braid Assembled from Proton-Transferred Sebacic Acid57Inducing Effect of Additive Agents on Coordination Assembly of Silver(I) Nitrate with 3,5-Bis(2-pyridyl)-4-amino-1,2,4-triazole: Supramolecular Isomerism and Interconversion75Syntheses, Structures, and Magnetic Properties of Five Novel Octacyanometallate-Based Lanthanide Complexes with Helical Chains44Position of substituent dependent dimensionality in Ln–Cu heterometallic coordination polymers14Synthesis, Crystal Structure, Magnetic Properties of a Manganese(II) Coordination Polymer with Double-Helix Chains2A pair of 3D homochiral metal–organic frameworks: spontaneous resolution, single-crystal-to-single-crystal transformation and selective adsorption properties47Spontaneous resolution through helical association of a Cu–azamacrocyclic complex with Lindqvist-type isopolyanion22Three 2D complexes with helical chains constructed from pimelic acid and rigid bis (imidazole) ligand: Syntheses, structures, thermal and photoluminescent properties6Helicity controlled by the chirality of amino acid: two novel enantiopure chiral 3D architectures containing fivefold interwoven helices49Self‐Assembly of Coordination Chains and Helices0A novel 3D homochiral helical coordination polymer based on a flexible tripodal ligand3Solvent-induced supramolecular chirality switching of bis-(trisalkoxy)-hexavanadates25Crystal structure of a nickel(II) complex with the macrocyclic ligand 4-methyl-1,3,5,8,11,14-hexaazatricyclooctadecane0Synthesis, crystal structures and properties of two Cd(II) complexes based on Zaltoprofen3A novel porous material constructed from linear helical cadmium(II) coordination polymer based on in-situ ligand reaction2Synthesis, Crystal Structure, and Properties of Two Novel Complexes Based on Zaltoprofen Ligand0Concentration-controlled Zn(II) compounds constructed from N-tosyl-L-glutamic acid and 1,10-phenanthroline4Diastereoselective self-assembly of heterochiral Zn( ii ) complexes of racemic Schiff bases in a chiral self-discriminating process: effect of non-covalent interactions on solid state structural self-assembly22Construction of one-dimensional homochiral helical supramolecular stereoismers using chiral macrocyclic nickel(II) complexes as building blocks3A novel 3D self-catenated coordination polymer with multiform helical chains84,2′:6′,4′′-Terpyridines: diverging and diverse building blocks in coordination polymers and metallomacrocycles95A Three‐dimensional Homochiral Camphorate Coordination Polymer Based on Two Types of Dinuclear Cadmium Clusters and a Flexible Bis(benzimidazole)‐based Ligand2Metals in supramolecular chemistry34Syntheses, structures and properties of a series of bis(benzimidazole)-based coordination polymers tuned by camphorate and divalent transition metal ions3Effect of steric congestion and non-covalent interaction on the self-organization of two isostructural 1D chiral coordination polymers5Two-level hierarchical entangled framework in a novel copper(I) coordination polymer with multiform helical features and unprecedented self-penetrated subnet7Concomitant Crystallization of Genuine Supramolecular Isomeric Rhombus Grid and Ribbon21Synthesis and magnetic properties of a 1-D helical chain derived from a Nickel-Sodium Schiff base complex6Crystal disassembly and reassembly of heterometallic Ni II –Ta V oxalate compounds16From isolated 1H-pyrazole cryptand anion receptors to hybrid inorganic–organic 1D helical polymeric anion receptors10Racemic and conglomerate 1-(4-haloaryl)ethylammonium tetrachlorocobaltate salts: formation of helical structures8Circular dichroism enhancement by the coordination of different metal ions with a pair of chiral tripodal ligands14A pair of novel helical Zn(II) enantiomers constructed from - and -threonine Schiff bases: Synthesis, crystal structures and properties4Chirality at metal and helical ligand folding in optical isomers of chiral bis(naphthaldiminato)nickel( ii ) complexes54An unprecedented self-penetrating Cu(I)-MOF based on a new 1D-ladder+ 2D-layer→ 3D polycatenation subnet showing luminescent sensing for nitrobenzene7Metal cation-dependent helicity of two 1-D heterometal chains constructed from pyridine-2,6-dicarboxylate3Crystal structure and magnetic properties of two manganese (ii) homometallic coordination polymers9π–π interaction leading to an inversion-symmetric complex pair of Λ- and Δ-bis[N-2-(R-pyridyl)-2-oxo-1-naphthaldiminato-κ2N,O]zinc(II)17Solvent‐Ratio Dependency of Polymorphism of Silver(I) Complexes Containing 1,2,3‐Tris(Isoniconitoyloxy)Benzene4Homochiral and heterochiral associations observed in crystals of ArSO 2 -(Aib) 5 -OMe4Chiral induction in boron imidazolate frameworks: the construction of cage-based absolute helices14Synthesis, Structures, and Magnetism of Four One-Dimensional Complexes Using [Ni(CN)4]2− and Macrocyclic Metal Complexes4

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  1. Supramolecular coordination chemistry

    Annual Reports Section A (Inorganic Chemistry) · 2007-01-01

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  2. Chiral Symmetry Breaking by Chemically Manipulating Statistical Fluctuation in Crystallization

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  3. Chiral Symmetry Breaking by Chemically Manipulating Statistical Fluctuation in Crystallization

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  4. Three coordination polymers with helical chains based on methylenediisophthalic acid (H4MDIP)

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  5. Spontaneous Resolution of a Racemic Nickel(II) Complex and Helicity Induction via Hydrogen Bonding: The Effect of Chiral Building Blocks on the Helicity of One-Dimensional Chains

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  6. Solvent-Assisted Spontaneous Resolution of a 16-Membered Ring Containing Gold(I) Showing Short Au···Au Aurophilic Interaction and a Figure-Eight Conformation

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    Tünde Tunyogi, Andrea Deák, Gábor Tárkányi, Peter Kiraly, G. Pálinkás

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  7. Two bimetallic tetranuclear three-blade propeller shaped complexes with helical water chains: Crystal structures, second-order nonlinear optical (NLO) properties and thermal decomposition mechanisms

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  8. Concomitant and Controllable Chiral/Racemic Polymorphs: From Achirality to Isotactic, Syndiotactic, and Heterotactic Chirality

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  9. Concomitant and Controllable Chiral/Racemic Polymorphs: From Achirality to Isotactic, Syndiotactic, and Heterotactic Chirality

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  10. Polymorphism and Pseudopolymorphism of an Aromatic Amide: Spontaneous Resolution and Crystal-to-Crystal phase Transition

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  11. Synthesis, Structure, and Solvent‐Induced Spontaneous Homochiral Assembly of Bidentate Bis(N,N′‐diaryl‐N‐heterocyclic carbene)‐Palladium Complexes

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  12. The Supramolecular Isomerism Based on Argentophilic Interactions: The Construction of Helical Chains with Defined Right-Handed and Left-Handed Helicity

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  13. Controlling the dimensionalities and structures of homochiral Zn( ii ) and Cd( ii ) compounds of N-(p-tosyl)-S-carboxymethyl- l -cysteinevia tuning the connecting modes of metal ions and chiral linkers by different kinds of ancillary ligands

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    Zilu Chen, Yan Qing Su, Wei Xiong, Lixia Wang, Fupei Liang, Min Shao

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  14. Vanadium polyoxoanion-bridged macrocyclic metal complexes: from one-dimensional to three-dimensional structures

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  15. Constructions of 1D helical chains with left-handed/right-handed helicity: a correlation between the helicity of 1D chains and the chirality of building blocks

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  16. Solvent‐Induced Pseudopolymorphism of a New Dinuclear Oxovanadium(V) Compound Based on 2,6‐Di(hydroxymethyl)‐4‐methylphenol

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  17. Synthesis, spectroscopic, thermal Studies, antimicrobial activities and crystal structures of Co(II), Ni(II), Cu(II) and Zn(II)-orotate complexes with 2-methylimidazole

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  18. Diaqua(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)nickel(II) tetracyanidonickelate(II)

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  19. Constructions of helical coordination compounds

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  20. One-dimensional coordination polymers of Co(II) and Cd(II)-squarate with 2-methylimidazole and 4(5)-methylimidazole ligands

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  21. Chiral resolution of a racemic macrocyclic complex by recognition of one enantiomer over the other: structures and DFT calculations

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  22. Syntheses and Crystal Structures of a Series of Coordination Polymers Constructed From C2‐Symmetric Ligand 1,3‐Adamantanedicarboxylic Acid

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  24. One-Dimensional Coordination Polymers: Complexity and Diversity in Structures, Properties, and Applications

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  25. From Infinite One-Dimensional Helix to Discrete CuII15 Cluster along with in Situ SN2 Ring-Cleavage of cis-Epoxysuccinic Acid: pH-Controlled Assemblies, Crystal Structures, and Properties

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  26. Molecular structures of nickel(II) monochelates of a racemic tridentate ligand and co-ligand induced structural variations

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  27. Cyano-Bridged Homochiral Heterometallic Helical Complexes: Synthesis, Structures, Magnetic and Dielectric Properties

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  28. Coordination polymers and metallomacrocycles based on bis(pyridylcarbamate) ligands with flexible glycol spacers

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  29. Structure, adsorption and magnetic properties of chiral metal–organic frameworks bearing linear trinuclear secondary building blocks

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  30. Synthesis and crystal structures of terephthalato-bridged macrocyclic nickel(II) complexes with cis configurations

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  31. pH Values Dependent Helicity of 1D Homochiral Helical Chains

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  32. A cyanide-bridged 1-D helical chain involving both four- and six-coordinate nickel(II)

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  33. Chiral Moieties-Oriented Single-Stranded Helical Assembly of Calix[4]azacrown Derivatives

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  34. Solvent-Controlled Rare Case of a Triple Helical Molecular Braid Assembled from Proton-Transferred Sebacic Acid

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  35. Inducing Effect of Additive Agents on Coordination Assembly of Silver(I) Nitrate with 3,5-Bis(2-pyridyl)-4-amino-1,2,4-triazole: Supramolecular Isomerism and Interconversion

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  36. Syntheses, Structures, and Magnetic Properties of Five Novel Octacyanometallate-Based Lanthanide Complexes with Helical Chains

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  37. Position of substituent dependent dimensionality in Ln–Cu heterometallic coordination polymers

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  38. Synthesis, Crystal Structure, Magnetic Properties of a Manganese(II) Coordination Polymer with Double-Helix Chains

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  39. A pair of 3D homochiral metal–organic frameworks: spontaneous resolution, single-crystal-to-single-crystal transformation and selective adsorption properties

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  40. Spontaneous resolution through helical association of a Cu–azamacrocyclic complex with Lindqvist-type isopolyanion

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  41. Three 2D complexes with helical chains constructed from pimelic acid and rigid bis (imidazole) ligand: Syntheses, structures, thermal and photoluminescent properties

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  42. Helicity controlled by the chirality of amino acid: two novel enantiopure chiral 3D architectures containing fivefold interwoven helices

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  43. Self‐Assembly of Coordination Chains and Helices

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  44. A novel 3D homochiral helical coordination polymer based on a flexible tripodal ligand

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  45. Solvent-induced supramolecular chirality switching of bis-(trisalkoxy)-hexavanadates

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  46. Crystal structure of a nickel(II) complex with the macrocyclic ligand 4-methyl-1,3,5,8,11,14-hexaazatricyclooctadecane

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  47. Synthesis, crystal structures and properties of two Cd(II) complexes based on Zaltoprofen

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  48. A novel porous material constructed from linear helical cadmium(II) coordination polymer based on in-situ ligand reaction

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  49. Synthesis, Crystal Structure, and Properties of Two Novel Complexes Based on Zaltoprofen Ligand

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  50. Concentration-controlled Zn(II) compounds constructed from N-tosyl-L-glutamic acid and 1,10-phenanthroline

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