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RESEARCH PAPER · Materials Research Bulletin · 2006

Displacive disorder in three high-k bismuth oxide pyrochlores

Brent C. Melot, Efrain E. Rodriguez, Thomas E. Proffen, Michael A. Hayward, Ram Seshadri

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Displacive disorder in three high-k bismuth oxide pyrochloresOriginalPyrochlore phases in the system ZnOBi2O3Sb2O5: II. Crystal structures of Zn2Bi3.08Sb2.92O14+δ and Zn2+xBi2.96−(x−y)Sb3.04−yO14.04+δ10Local Structure of Displacively Disordered Pyrochlore Dielectrics50Structural Variations in Pyrochlore-Structured Bi2Hf2O7, Bi2Ti2O7 and Bi2Hf2-xTixO7 Solid Solutions as a Function of Composition and Temperature by Neutron and X-ray Diffraction and Raman Spectroscopy72The disordered structures and low temperature dielectric relaxation properties of two misplaced-displacive cubic pyrochlores found in the Bi2O3–MIIO–Nb2O5 (M=Mg, Ni) systems59Microstructure and dielectric properties of pyrochlore Bi2Ti2O7 thin films34Polymorphism in Bismuth Stannate: A First-Principles Study57Structure, dielectric and optical properties of Bi1.5+xZnNb1.5O7+1.5x pyrochlores17Bismuth-based pyrochlore dielectric ceramics for microwave applications5Crystal structure, stoichiometry, and dielectric relaxation in Bi3.32Nb7.09O22.7 and structurally related ternary phases5Diffuse scattering in the cesium pyrochlore CsTi0.5W1.5O612Pyrochlore formation, phase relations, and properties in the CaO–TiO2–(Nb,Ta)2O5 systems48First-principles study of cubic Bi pyrochlores73Preparation and Crystal Structures of Bismuth Technetates: A New Metal Oxide System30Anomalous lattice parameter increase in alkali earth aluminium substituted tungsten defect pyrochlores9Synthesis and structural studies of lanthanide substituted bismuth–titanium pyrochlores7Large low-temperature specific heat in pyrochlore Bi2Ti2O760Displacive disorder and dielectric relaxation in the stoichiometric bismuth-containing pyrochlores, Bi2MIIINbO7 (M=In and Sc)42Structures and solid solution mechanisms of pyrochlore phases in the systems Bi2O3–ZnO–(Nb, Ta)2O520First-principles calculation of the structure and dielectric properties of Bi2Ti2O723Cation disorder in NaW2O6+δ·nH2−zO post-ion exchange with K, Rb, Sr, and Cs3New (Bi1.88Fe0.12)(Fe1.42Te0.58)O6.87 Pyrochlore with Spin-Glass Transition37Reverse Monte Carlo neutron scattering study of the ‘ordered-ice’ oxide pyrochlore Pb2Ru2O6.510Incoherent Bi off-centering in Bi 2 Ti 2 O 6 O ′ and Bi 2 Ru 2 O 6 O ′ : Insulator versus metal44Raman spectroscopy evidence of inhomogeneous disorder in the bismuth-oxygen framework of Bi 25 InO 39 and other sillenites21Energy landscape in frustrated systems: Cation hopping in pyrochlores10Design of Medium Band Gap Ag–Bi–Nb–O and Ag–Bi–Ta–O Semiconductors for Driving Direct Water Splitting with Visible Light9Structural, hyperfine and Raman properties of RE2FeSbO7 compounds8Atomic Displacive Disorder in Bi2Ti2O723Metastable (Bi, M) 2 (Fe, Mn, Bi) 2 O 6+ x (M = Na or K) Pyrochlores from Hydrothermal Synthesis23Structure Refinement and Dielectric Properties of Bismuth-Based Pyrochlores Containing Titanium1Structures and Phase Transitions in Pertechnetates30Emerging scenario on displacive cubic bismuth pyrochlores (Bi,M)MNO7-δ (M = transition metal, N = Nb, Ta, Sb) in context of their fascinating structural, dielectric and magnetic properties28Structure, thermal stability, optoelectronic and electrophysical properties of Mg- and Na-codoped bismuth niobate pyrochlores: Experimental and theoretical study21Disordered Structures and Dielectric Properties of Ni-Doped Bismuth Magnesium Niobate Pyrochlores10Compositional influence of local and long-range polarity in the frustrated pyrochlore system Bi 2− x RE x Ti 2 O 7 (RE = Y 3+ ,Ho 3+ )5Chemistry, Structure, and Function of Lone Pairs in Extended Solids117Effect of Co2+ substitutions on microstructure and dielectric properties of Bi1.5MgNb1.5O7 cubic pyrochlore5Microstructure of the spark-plasma sintered pyrochlore ceramics based on Bi 2 O 3 -ZnO-Nb 2 O 5 system0Technological Ways of Reducing the Sintering Temperature of Ceramics Based on Cubic Pyrochlore1Technological methods for reducing the sintering temperature of ceramics based on the BZN cubic pyrochlore system0Covalency and Lone Pair-Driven Distortions in Sulfur-Doped Tin Niobate2Pyrochlore oxides: Redefining dielectric materials prospective towards fresh energy storage capacitors6

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  1. Pyrochlore phases in the system ZnOBi2O3Sb2O5: II. Crystal structures of Zn2Bi3.08Sb2.92O14+δ and Zn2+xBi2.96−(x−y)Sb3.04−yO14.04+δ

    Solid State Sciences · 2006-11-30

    Gabrielle C. Miles, Anthony R. West

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  2. Local Structure of Displacively Disordered Pyrochlore Dielectrics

    Chemistry of Materials · 2007-01-20

    Victor Krayzman, Igor Levin, JOSEPH C. WOICIK

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  3. Structural Variations in Pyrochlore-Structured Bi2Hf2O7, Bi2Ti2O7 and Bi2Hf2-xTixO7 Solid Solutions as a Function of Composition and Temperature by Neutron and X-ray Diffraction and Raman Spectroscopy

    Chemistry of Materials · 2007-03-13

    Stuart J. Henderson, Olga N. Shebanova, Andrew L. Hector, Paul Francis McMillan, Mark T. Weller

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  4. The disordered structures and low temperature dielectric relaxation properties of two misplaced-displacive cubic pyrochlores found in the Bi2O3–MIIO–Nb2O5 (M=Mg, Ni) systems

    Journal of Solid State Chemistry · 2007-07-14

    Hai Binh Nguyen, Lasse Norén, Yun Liu, Ray Leslie Withers, Xiaoyong Wei, Margaret M. Elcombe

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  5. Microstructure and dielectric properties of pyrochlore Bi2Ti2O7 thin films

    Journal of Applied Physics · 2007-08-15

    Joël Cagnon, Damien S. Boesch, Nicholas H. Finstrom, Saide Z. Nergiz, Sean P. Keane, Susanne Stemmer

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  6. Polymorphism in Bismuth Stannate: A First-Principles Study

    Chemistry of Materials · 2007-09-27

    Aron Walsh, Graeme W. Watson

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  7. Structure, dielectric and optical properties of Bi1.5+xZnNb1.5O7+1.5x pyrochlores

    Ceramics International · 2007-12-28

    Qian Wang, Hong Wang, Xi Yao

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  8. Bismuth-based pyrochlore dielectric ceramics for microwave applications

    Elsevier eBooks · 2008-01-01

    Hong Wang, X. Yao

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  9. Crystal structure, stoichiometry, and dielectric relaxation in Bi3.32Nb7.09O22.7 and structurally related ternary phases

    Journal of Solid State Chemistry · 2008-01-02

    Ian Edward Grey, Terrell A. Vanderah, William Gus Mumme, R. S. Roth, J. Guzman, Juan C. Nino, Igor Levin

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  10. Diffuse scattering in the cesium pyrochlore CsTi0.5W1.5O6

    Materials Research Bulletin · 2008-01-11

    Gordon James Thorogood, Paul J. Saines, Brendan J. Kennedy, Ray Leslie Withers, Margaret M. Elcombe

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  11. Pyrochlore formation, phase relations, and properties in the CaO–TiO2–(Nb,Ta)2O5 systems

    Journal of Solid State Chemistry · 2008-01-30

    R. S. Roth, Terrell A. Vanderah, P. Bordet, Ian Edward Grey, William Gus Mumme, Lu Cai, Juan C. Nino

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  12. First-principles study of cubic Bi pyrochlores

    Physical Review B · 2008-03-31

    Beverly Brooks Hinojosa, Juan C. Nino, Aravind Asthagiri

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  13. Preparation and Crystal Structures of Bismuth Technetates: A New Metal Oxide System

    Inorganic Chemistry · 2008-06-24

    Efrain E. Rodriguez, Frédéric Poineau, Anna Llobet, Ken Czerwinski, Ram Seshadri, Anthony Kevin Cheetham

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  14. Anomalous lattice parameter increase in alkali earth aluminium substituted tungsten defect pyrochlores

    Journal of Solid State Chemistry · 2008-11-21

    Gordon James Thorogood, Brendan J. Kennedy, Vanessa Kate Peterson, Margaret M. Elcombe, Gordon J. Kearley, John V. Hanna, Vittorio Luca

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  15. Synthesis and structural studies of lanthanide substituted bismuth–titanium pyrochlores

    Journal of Solid State Chemistry · 2009-01-20

    Jimmy Ting, Brendan J. Kennedy, Ray Leslie Withers, Maxim Avdeev

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  16. Large low-temperature specific heat in pyrochlore Bi2Ti2O7

    Physical Review B · 2009-06-12

    Brent C. Melot, Ronald J. Tackett, J. R. O’Brien, Andrew L. Hector, G. Lawes, Ram Seshadri, Arthur P. Ramirez

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  17. Displacive disorder and dielectric relaxation in the stoichiometric bismuth-containing pyrochlores, Bi2MIIINbO7 (M=In and Sc)

    Journal of Solid State Chemistry · 2009-07-12

    Yun Liu, Ray Leslie Withers, Hai Binh Nguyen, K. Wilson Elliott, Qijun Ren, Zhanghai Chen

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  18. Structures and solid solution mechanisms of pyrochlore phases in the systems Bi2O3–ZnO–(Nb, Ta)2O5

    Journal of Alloys and Compounds · 2010-09-03

    Kar Ban Tan, C.C. Khaw, C.K. Lee, Zulkarnain Zainal, Gabrielle C. Miles

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  19. First-principles calculation of the structure and dielectric properties of Bi2Ti2O7

    Physical Review B · 2010-10-04

    Charles H. Patterson

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  20. Cation disorder in NaW2O6+δ·nH2−zO post-ion exchange with K, Rb, Sr, and Cs

    Journal of Physics and Chemistry of Solids · 2011-03-07

    Gordon James Thorogood, Brendan J. Kennedy, Maxim Avdeev, Vanessa Kate Peterson, John V. Hanna, Vittorio Luca

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  21. New (Bi1.88Fe0.12)(Fe1.42Te0.58)O6.87 Pyrochlore with Spin-Glass Transition

    Chemistry of Materials · 2011-04-18

    Gunda Santosh Babu, Matjaž Valant, Katharine Lynn Page, Anna Llobet, Taras V. Kolodiazhnyi, Anna‐Karin Axelsson

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  22. Reverse Monte Carlo neutron scattering study of the ‘ordered-ice’ oxide pyrochlore Pb2Ru2O6.5

    Journal of Physics Condensed Matter · 2011-07-21

    Daniel P Shoemaker, Anna Llobet, Makoto Tachibana, Ram Seshadri

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  23. Incoherent Bi off-centering in Bi 2 Ti 2 O 6 O ′ and Bi 2 Ru 2 O 6 O ′ : Insulator versus metal

    Physical Review B · 2011-08-24

    Daniel P. Shoemaker, Ram Seshadri, Makoto Tachibana, Andrew L. Hector

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  24. Raman spectroscopy evidence of inhomogeneous disorder in the bismuth-oxygen framework of Bi 25 InO 39 and other sillenites

    Physical Review B · 2012-10-26

    Daniel J. Arenas, Theo Jegorel, Chris Knab, L. V. Gasparov, Catalin Martin, Daniel M. Pajerowski, Hideo Kohno, Michael W. Lufaso

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  25. Energy landscape in frustrated systems: Cation hopping in pyrochlores

    Applied Physics Letters · 2013-07-08

    Beverly Brooks Hinojosa, Aravind Asthagiri, Juan C. Nino

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  26. Design of Medium Band Gap Ag–Bi–Nb–O and Ag–Bi–Ta–O Semiconductors for Driving Direct Water Splitting with Visible Light

    Inorganic Chemistry · 2013-07-31

    Limin Wang, Bingfei Cao, Wei Kang, Mark S. Hybertsen, Kazuhiko Maeda, Kazunari Domen, Peter G. Khalifah

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  27. Structural, hyperfine and Raman properties of RE2FeSbO7 compounds

    Journal of Alloys and Compounds · 2014-09-03

    Graciele Berndt, Klebson Lucenildo Da Silva, Flávio F. Ivashita, Andrea Paesano, M. Cecilia Blanco, Elisa V. Pannunzio Miner, Raúl E. Carbonio, S.M.C. Dantas, Alejandro Pedro Ayala, O. Isnard

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  28. Atomic Displacive Disorder in Bi2Ti2O7

    The Journal of Physical Chemistry C · 2014-11-11

    Christopher Turner, Paul M. Johns, Evan M. Thatcher, David B. Tanner, Juan C. Nino

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  29. Metastable (Bi, M) 2 (Fe, Mn, Bi) 2 O 6+ x (M = Na or K) Pyrochlores from Hydrothermal Synthesis

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    Luke M. Daniels, Helen Y. Playford, Jean−Marc Grenèche, Alex C. Hannon, Richard I. Walton

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  30. Structure Refinement and Dielectric Properties of Bismuth-Based Pyrochlores Containing Titanium

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  31. Structures and Phase Transitions in Pertechnetates

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  32. Emerging scenario on displacive cubic bismuth pyrochlores (Bi,M)MNO7-δ (M = transition metal, N = Nb, Ta, Sb) in context of their fascinating structural, dielectric and magnetic properties

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  33. Structure, thermal stability, optoelectronic and electrophysical properties of Mg- and Na-codoped bismuth niobate pyrochlores: Experimental and theoretical study

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  34. Disordered Structures and Dielectric Properties of Ni-Doped Bismuth Magnesium Niobate Pyrochlores

    The Journal of Physical Chemistry C · 2021-12-13

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  35. Compositional influence of local and long-range polarity in the frustrated pyrochlore system Bi 2− x RE x Ti 2 O 7 (RE = Y 3+ ,Ho 3+ )

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  36. Chemistry, Structure, and Function of Lone Pairs in Extended Solids

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  37. Effect of Co2+ substitutions on microstructure and dielectric properties of Bi1.5MgNb1.5O7 cubic pyrochlore

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  38. Microstructure of the spark-plasma sintered pyrochlore ceramics based on Bi 2 O 3 -ZnO-Nb 2 O 5 system

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  39. Technological Ways of Reducing the Sintering Temperature of Ceramics Based on Cubic Pyrochlore

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  40. Technological methods for reducing the sintering temperature of ceramics based on the BZN cubic pyrochlore system

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  41. Covalency and Lone Pair-Driven Distortions in Sulfur-Doped Tin Niobate

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  42. Pyrochlore oxides: Redefining dielectric materials prospective towards fresh energy storage capacitors

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