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RESEARCH PAPER · Inorganic Chemistry · 2014

Triazolyl–Based Copper–Molybdate Hybrids: From Composition Space Diagram to Magnetism and Catalytic Performance

Ganna A. Senchyk, A.B. Lysenko, Artem A. Babaryk, Eduard B. Rusanov, Harald Krautscheid, Patrícia Neves, Anabela A. Valente, Isabel S. Gonçalves, Karl W. Krämer, Shi‐Xia Liu, Silvio Decurtins, K.V. Domasevitch

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Triazolyl–Based Copper–Molybdate Hybrids: From Composition Space Diagram to Magnetism and Catalytic PerformanceOriginalTriazolate-based 3D frameworks and a 2D layer with centrosymmetric Cu II 7 , Cu II 5 , Cu II 4 clusters and tunable interlayer/interchain compactness: hydrothermal syntheses, crystal structures and magnetic properties19Hydrothermal synthesis and structural characterization of an organically-templated open-framework trimolybdates1Composition Space Analysis in the Development of Copper Molybdate Hybrids Decorated by a Bifunctional Pyrazolyl/1,2,4-Triazole Ligand31Direct synthesis of heterometallic Cu/Mo complexes with aromatic chelating N,N-donating ligands10A series of organic–inorganic hybrid materials consisting of flexible organic amine modified polyoxomolybdates: synthesis, structures and properties64pH-Dependent assembly of three novel inorganic–organic hybrids based on different isopolymolybdates and Cu I/II (bbx) n units8General Assembly of Twisted Trigonal‐Prismatic Nonanuclear Silver(I) Clusters56Molybdenum-oxygen anionic chain grafted by Cu-phen complex. Synthesis, crystal structure and properties2Ribbon and Self‐Penetrated Hybrid Copper Molybdates with Ancillary Bis(4‐pyridylmethyl)piperazine Ligands1Effective parameter study for the facile and controlled growth of silver molybdate nano/micro rods5Aromaticity introduced by antiferromagnetic ligand mediated metal–metal interactions. Insights from the induced magnetic response in [Cu 6 (dmPz) 6 (OH) 6 ]8Hybrid compounds assembled from copper-triazole complexes and phosphomolybdic acid as advanced catalysts for the oxidation of olefins with oxygen21Constructions and properties of zinc coordination polymers based on 3,5-di(4H-1,2,4-triazol-4-yl) benzoic acid with different polycarboxylic acids as a secondary ligand63D hierarchical flower of copper molybdate Cu3Mo2O9: Synthesis, nanostructure and lithium storage properties37Three Organic–Inorganic Hybrids Based on [MoxOy]n– Chains Decorated with Organic Ligands and Transition‐Metal Coordination Complexes9Evans–Showell-Type Polyoxometalates Constructing High-Dimensional Inorganic–Organic Hybrid Compounds with Copper–Organic Coordination Complexes: Synthesis and Oxidation Catalysis58Exploration of a Variety of Copper Molybdate Coordination Hybrids Based on a Flexible Bis(1,2,4-triazole) Ligand: A Look through the Composition-Space Diagram16Three inorganic-organic hybrid complexes based on isopolymolybdate and derivatives of 1H-4-nitroimidazole4Hydrothermal synthesis and polarized micro-Raman spectroscopy of copper molybdates12On the Border between Low-Nuclearity and One-Dimensional Solids: A Unique Interplay of 1,2,4-Triazolyl-Based {CuII5(OH)2} Clusters and MoVI-Oxide Matrix7A series of oxyfluoride chains containing asymmetric basic building units of both early- and late-transition metal cations5Metal–organic frameworks in Germany: From synthesis to function125Evans–Showell-type polyoxometalate-based metal–organic complexes with novel 3D structures constructed from flexible bis-pyrazine–bis-amide ligands and copper metals: syntheses, structures, and fluorescence and catalytic properties27Syntheses, structures and catalytic properties of Evans–Showell-type polyoxometalate-based 3D metal–organic complexes constructed from the semi-rigid bis(pyridylformyl)piperazine ligand and transition metals15Applications of inorganic‐organic hybrid architectures based on polyoxometalates in catalyzed and photocatalyzed chemical transformations57Mixed Transition Metal (Oxy)fluoride Paramagnet Chains: Synthesis, Structure, and Characterization11Rare example of chiral and achiral polymorphs of a metal-oxide/organic hybrid compound2Microstructure and optical vibration features of complex cobalt molybdates synthesized by the microwave and conventional hydrothermal processes2New Coordination Polymers of Zinc(II), Copper(II) and Cadmium(II) with 1,3-Bis(1,2,4-triazol-4-yl)adamantane7Polyoxometalate-based metal–organic frameworks for heterogeneous catalysis163In-situ fabrication of Cu3(MoO4)2(OH)2 films decorated with MO (M=Zn, Cu, and Ni) for CO2 photoconversion into value-added compounds14Synthesis, Crystal Structure, and Luminescence of Cadmium(II) and Silver(I) Coordination Polymers Based on 1,3-Bis(1,2,4-triazol-1-yl)adamantane141,2,4-Triazolyl-4-acetate: a ditopic ligand combining soft and hard donor sites in homometallic (Ag I ) and heterometallic (Ag I /U VI ) coordination polymers8MOF/POM hybrids as catalysts for organic transformations57Preparation and Characterization of Cu 3 (MoO 4 ) 2 (OH) 2 Nanosheets with Solar Photocatalytic Activity5High-Temperature Behavior of the CuMo3O10⋅H2O Compound0Copper-substituted polyoxometalate-soldered interpenetrating polymeric networks membranes for water remediation20Polyoxometalate-based porphyrinic metal-organic frameworks as heterogeneous catalysts82The crystal structure of {hexakis(1-methyl-1H-imidazole-κ 1 N)cobalt(II)}(μ 2-oxido)-hexaoxido-dimolybdenum(VI)— 1-methyl-1H-imidazole (1/2), C32H48CoMo2N16O71The crystal structure of {hexakis(1-methyl-1H-imidazole-κ 1N)nickel(II)} (μ 2-oxo)-hexaoxido-di-molybdenum(VI)─1-methyl-1H-imidazole (1/2), C32H48NiMo2N16O70Fabrication of cost-effective biogenic assisted synthesis of ultrafine copper Molybdate (α-CuMoO₄) nanoparticles: Characterisation and exploration of their optical, and Photocatalysis applications2

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    Dalton Transactions · 2015-01-01

    Yuanyuan Zhang, Hong Zhao, En‐Cui Yang, Zhong‐Yi Liu, Qiu Shang, Xiao‐Jun Zhao

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  2. Hydrothermal synthesis and structural characterization of an organically-templated open-framework trimolybdates

    International Journal of the Physical Sciences · 2015-10-16

    Chinyere A. Anyama, E Iniama Grace, Ottong Joseph, Ayi A. Ayi

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  3. Composition Space Analysis in the Development of Copper Molybdate Hybrids Decorated by a Bifunctional Pyrazolyl/1,2,4-Triazole Ligand

    Inorganic Chemistry · 2015-12-16

    A.B. Lysenko, Ganna A. Senchyk, Liliana Lukashuk, K.V. Domasevitch, Marcel Handke, Jörg Lincke, Harald Krautscheid, Eduard B. Rusanov, Karl W. Krämer, Silvio Decurtins, Shi‐Xia Liu

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  4. Direct synthesis of heterometallic Cu/Mo complexes with aromatic chelating N,N-donating ligands

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  5. A series of organic–inorganic hybrid materials consisting of flexible organic amine modified polyoxomolybdates: synthesis, structures and properties

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    Chunhua Gong, Xianghua Zeng, Chengfeng Zhu, Jiahui Shu, Pingxiu Xiao, Hao Xu, Lichun Liu, Junyong Zhang, Qingdao Zeng, Jingli Xie

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  6. pH-Dependent assembly of three novel inorganic–organic hybrids based on different isopolymolybdates and Cu I/II (bbx) n units

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    Panfeng Wu, Qi Xue, Xinbo Dong, Yanjie Zhang, Bin Liu, Huai‐Ming Hu, Ganglin Xue

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  7. General Assembly of Twisted Trigonal‐Prismatic Nonanuclear Silver(I) Clusters

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    Xiao‐Yu Li, Hai‐Feng Su, Rui‐Qi Zhou, Sheng Feng, Yuan‐Zhi Tan, Xing‐Po Wang, Jiong Jia, Mohamedally Kurmoo, Di Sun, Lan‐Sun Zheng

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  8. Molybdenum-oxygen anionic chain grafted by Cu-phen complex. Synthesis, crystal structure and properties

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  9. Ribbon and Self‐Penetrated Hybrid Copper Molybdates with Ancillary Bis(4‐pyridylmethyl)piperazine Ligands

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  10. Effective parameter study for the facile and controlled growth of silver molybdate nano/micro rods

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  11. Aromaticity introduced by antiferromagnetic ligand mediated metal–metal interactions. Insights from the induced magnetic response in [Cu 6 (dmPz) 6 (OH) 6 ]

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    V. Molina, Markus Rauhalahti, John Hurtado, Heike Fliegl, D. Sundholm, Alvaro Rafael Muñoz-Castro

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  12. Hybrid compounds assembled from copper-triazole complexes and phosphomolybdic acid as advanced catalysts for the oxidation of olefins with oxygen

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    Xiaojing Song, Yan Yan, Yan‐Ning Wang, Dianwen Hu, Li‐Na Xiao, Jie‐Hui Yu, Wenxiang Zhang, Mingjun Jia

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  13. Constructions and properties of zinc coordination polymers based on 3,5-di(4H-1,2,4-triazol-4-yl) benzoic acid with different polycarboxylic acids as a secondary ligand

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    Wen‐Hong Jiang, Ji-Long Liu, Li-Zhong Niu, Bin Liu, Ying‐Hui Yu, Guang‐Feng Hou, Dong‐Sheng Ma

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  14. 3D hierarchical flower of copper molybdate Cu3Mo2O9: Synthesis, nanostructure and lithium storage properties

    Journal of Alloys and Compounds · 2017-06-19

    Lifeng Zhang, Wenjie He, Yi Liu, Min Ling, Peng Zheng, Shouwu Guo

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  15. Three Organic–Inorganic Hybrids Based on [MoxOy]n– Chains Decorated with Organic Ligands and Transition‐Metal Coordination Complexes

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  16. Evans–Showell-Type Polyoxometalates Constructing High-Dimensional Inorganic–Organic Hybrid Compounds with Copper–Organic Coordination Complexes: Synthesis and Oxidation Catalysis

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  17. Exploration of a Variety of Copper Molybdate Coordination Hybrids Based on a Flexible Bis(1,2,4-triazole) Ligand: A Look through the Composition-Space Diagram

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  18. Three inorganic-organic hybrid complexes based on isopolymolybdate and derivatives of 1H-4-nitroimidazole

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  19. Hydrothermal synthesis and polarized micro-Raman spectroscopy of copper molybdates

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  20. On the Border between Low-Nuclearity and One-Dimensional Solids: A Unique Interplay of 1,2,4-Triazolyl-Based {CuII5(OH)2} Clusters and MoVI-Oxide Matrix

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  21. A series of oxyfluoride chains containing asymmetric basic building units of both early- and late-transition metal cations

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  22. Metal–organic frameworks in Germany: From synthesis to function

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  23. Evans–Showell-type polyoxometalate-based metal–organic complexes with novel 3D structures constructed from flexible bis-pyrazine–bis-amide ligands and copper metals: syntheses, structures, and fluorescence and catalytic properties

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  24. Syntheses, structures and catalytic properties of Evans–Showell-type polyoxometalate-based 3D metal–organic complexes constructed from the semi-rigid bis(pyridylformyl)piperazine ligand and transition metals

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  25. Applications of inorganic‐organic hybrid architectures based on polyoxometalates in catalyzed and photocatalyzed chemical transformations

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  26. Mixed Transition Metal (Oxy)fluoride Paramagnet Chains: Synthesis, Structure, and Characterization

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  27. Rare example of chiral and achiral polymorphs of a metal-oxide/organic hybrid compound

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  28. Microstructure and optical vibration features of complex cobalt molybdates synthesized by the microwave and conventional hydrothermal processes

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  29. New Coordination Polymers of Zinc(II), Copper(II) and Cadmium(II) with 1,3-Bis(1,2,4-triazol-4-yl)adamantane

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  30. Polyoxometalate-based metal–organic frameworks for heterogeneous catalysis

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  31. In-situ fabrication of Cu3(MoO4)2(OH)2 films decorated with MO (M=Zn, Cu, and Ni) for CO2 photoconversion into value-added compounds

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  32. Synthesis, Crystal Structure, and Luminescence of Cadmium(II) and Silver(I) Coordination Polymers Based on 1,3-Bis(1,2,4-triazol-1-yl)adamantane

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  33. 1,2,4-Triazolyl-4-acetate: a ditopic ligand combining soft and hard donor sites in homometallic (Ag I ) and heterometallic (Ag I /U VI ) coordination polymers

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  35. Preparation and Characterization of Cu 3 (MoO 4 ) 2 (OH) 2 Nanosheets with Solar Photocatalytic Activity

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  36. High-Temperature Behavior of the CuMo3O10⋅H2O Compound

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  39. The crystal structure of {hexakis(1-methyl-1H-imidazole-κ 1 N)cobalt(II)}(μ 2-oxido)-hexaoxido-dimolybdenum(VI)— 1-methyl-1H-imidazole (1/2), C32H48CoMo2N16O7

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