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RESEARCH PAPER · Journal of Materials Chemistry · 2012

Kinetics and mechanism of ionic intercalation/de-intercalation during the formation of α-cobalt hydroxide and its polymorphic transition to β-cobalt hydroxide: reaction–diffusion framework

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Kinetics and mechanism of ionic intercalation/de-intercalation during the formation of α-cobalt hydroxide and its polymorphic transition to β-cobalt hydroxide: reaction–diffusion frameworkOriginalA novel co-precipitation method for one-pot fabrication of a Co–Ni multiphase composite electrode and its application in high energy-density pseudocapacitors23Reaction-Diffusion Framework: The Mechanism of the Polymorphic Transition of α- to β-Cobalt Hydroxide13Large scale selective synthesis of α-Co(OH)2 and β-Co(OH)2 nanosheets through a fluoride ions mediated phase transformation process56Influences of anion exchange and phase transformation on the supercapacitive properties of α-Co(OH)2115Co3O4 nanosheets: synthesis and catalytic application for CO oxidation at room temperature18Alternating Metastable/Stable Pattern in the Mercuric Iodide Crystal Formation Outside the Ostwald Rule of Stages13Mesoscopic architectures of Co(OH) 2 spheres with an extended array of microporous threads as pseudocapacitor electrode materials17α-Co(OH) 2 /carbon nanofoam composite as electrochemical capacitor electrode operating at 2 V in aqueous medium44Preparation of α-Co(OH)2 monolayer nanosheets by an intercalation agent-free exfoliation process13Electrochemical etching of α-cobalt hydroxide for improvement of oxygen evolution reaction140Cadmium–Aluminum Layered Double Hydroxide Microspheres for Photocatalytic CO2 Reduction39Synergistic Assembly of Peptide‐Metal Hydroxide Hybrid Nanostructures for Electrochemical Capacitors8Dynamics and Mechanism of Intercalation/De-Intercalation of Rhodamine B during the Polymorphic Transformation of the CdAl Layered Double Hydroxide to the Brucite-like Cadmium Hydroxide17Kinetics of intercalation of fluorescent probes in magnesium–aluminium layered double hydroxide within a multiscale reaction–diffusion framework11Facile Synthesis of Co3O4 with Different Morphologies via Oxidation Kinetic Control and Its Application in Hydrogen Peroxide Decomposition14Pd Nanoparticle/CoP Nanosheet Hybrids: Highly Electroactive and Durable Catalysts for Ethanol Electrooxidation94A new concept of charging supercapacitors based on the photovoltaic effect70Trash to Treasure: Waste Eggshells as Chemical Reactors for the Synthesis of Amorphous Co(OH)2 Nanorod Arrays on Various Substrates for Applications in Rechargeable Alkaline Batteries and Electrocatalysis35Porous cobalt chalcogenide nanostructures as high performance pseudo-capacitor electrodes64Observation of ferromagnetic ordering in a stable α−Co(OH)2 phase grown on a MoS2 surface15Novel Hybrid Energy Conversion and Storage Cell with Photovoltaic and Supercapacitor Effects in Ionic Liquid Electrolyte39Fabrication of Hierarchical Co/MgO Catalyst for Enhanced CO2 Reforming of CH4 in a Fluidized‐Bed Reactor22Low-temperature synthesized self-supported single-crystalline LiCoO 2 nanoflake arrays as advanced 3D cathodes for flexible lithium-ion batteries64Kinetics and Mechanism of the Hydrolysis and Rearrangement Processes within the Assembly–Disassembly–Organization–Reassembly Synthesis of Zeolites34Electrochemical Instability of Metal–Organic Frameworks: In Situ Spectroelectrochemical Investigation of the Real Active Sites499Metal–organic framework-derived hierarchical ultrathin CoP nanosheets for overall water splitting144Facile synthesis of hexagonal α-Co(OH) 2 nanosheets and their superior activity in the selective reduction of nitro compounds13Conception, développement et mise au point d'un procédé hydrométallurgique de récupération du cobalt (II) issu de mines secondaires par précipitation0Reducing the Energy Band Gap of Cobalt Hydroxide Nanosheets with Silver Atoms and Enhancing Their Electrical Conductivity with Silver Nanoparticles60Operando mechanistic studies of selective oxidation of glycerol to dihydroxyacetone over amorphous cobalt oxide126Electrochemical Production of 2,5-Furandicarboxylic from 5-Hydroxymethylfurfural Using Ultrathin Co(OH) 2 on ZIF-6728Colorimetric Nanosensor for the Determination of Glyphosate Herbicide in Aqueous Solutions3Polygonal boundary gaps in multiple diffusion source precipitation systems in gel media6Facile coating of Co3O4 on open-cell metallic foam for N2O catalytic decomposition9The Structure, Preparation, Characterization, and Intercalation Mechanism of Layered Hydroxides Intercalated with Guest Anions43Impact of Sulfate Adsorption on Particle Morphology during the Precipitation of Ni-Rich Hydroxide Precursors for Li-Ion Battery Cathode Active Materials15Hydroxide-Source-Dependent Polymorphism and Phase Stability of Cobalt(II) Hydroxides in Diffusion-Driven Systems16Identifying the dynamic behaviors in complete reconstruction of Co-based complex precatalysts during electrocatalytic oxygen evolution34Deciphering the Synergistic Effect in Strong Metal–Support Interaction toward Surface Reconstruction of Prussian Blue Analogue-Based Pre-Catalysts for Boosted Bifunctional Oxygen Electrocatalysis via Operando Raman Spectroscopy7Hydrolysing agent-mediated synthesis of α- cobalt hydroxide: Impact on crystal structure, morphology and electrochemical performance4Transformation Cascades in Iron Oxides: Quantitative Resolution of Sequential Precipitation Using the Reaction-Diffusion Framework0Synergistic surface reconstruction and Mg doping for upcycling high-voltage LiCoO2 cathodes from spent batteries0Pd nanoparticle-decorated cobalt aminoclay for enzyme-free electrochemical detection of uric acid3Mechanistic Insights into Moisture-Assisted Low-Temperature Synthesis of LiCoO2 Revealed by In Situ X-ray Absorption Spectroscopy0

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  2. Reaction-Diffusion Framework: The Mechanism of the Polymorphic Transition of α- to β-Cobalt Hydroxide

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  3. Large scale selective synthesis of α-Co(OH)2 and β-Co(OH)2 nanosheets through a fluoride ions mediated phase transformation process

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  4. Influences of anion exchange and phase transformation on the supercapacitive properties of α-Co(OH)2

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  5. Co3O4 nanosheets: synthesis and catalytic application for CO oxidation at room temperature

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  6. Alternating Metastable/Stable Pattern in the Mercuric Iodide Crystal Formation Outside the Ostwald Rule of Stages

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  7. Mesoscopic architectures of Co(OH) 2 spheres with an extended array of microporous threads as pseudocapacitor electrode materials

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  8. α-Co(OH) 2 /carbon nanofoam composite as electrochemical capacitor electrode operating at 2 V in aqueous medium

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  10. Electrochemical etching of α-cobalt hydroxide for improvement of oxygen evolution reaction

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  14. Kinetics of intercalation of fluorescent probes in magnesium–aluminium layered double hydroxide within a multiscale reaction–diffusion framework

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  15. Facile Synthesis of Co3O4 with Different Morphologies via Oxidation Kinetic Control and Its Application in Hydrogen Peroxide Decomposition

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  16. Pd Nanoparticle/CoP Nanosheet Hybrids: Highly Electroactive and Durable Catalysts for Ethanol Electrooxidation

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  17. A new concept of charging supercapacitors based on the photovoltaic effect

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  18. Trash to Treasure: Waste Eggshells as Chemical Reactors for the Synthesis of Amorphous Co(OH)2 Nanorod Arrays on Various Substrates for Applications in Rechargeable Alkaline Batteries and Electrocatalysis

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  19. Porous cobalt chalcogenide nanostructures as high performance pseudo-capacitor electrodes

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  20. Observation of ferromagnetic ordering in a stable α−Co(OH)2 phase grown on a MoS2 surface

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  21. Novel Hybrid Energy Conversion and Storage Cell with Photovoltaic and Supercapacitor Effects in Ionic Liquid Electrolyte

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  23. Low-temperature synthesized self-supported single-crystalline LiCoO 2 nanoflake arrays as advanced 3D cathodes for flexible lithium-ion batteries

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  24. Kinetics and Mechanism of the Hydrolysis and Rearrangement Processes within the Assembly–Disassembly–Organization–Reassembly Synthesis of Zeolites

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