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RESEARCH PAPER · Chemical Society Reviews · 2011

Framework-structured weak ferromagnets

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Framework-structured weak ferromagnetsOriginalColonic Perforation Following Neurosurgical Procedures and Corticosteroid Therapy in Four Dogs42Coordination assemblies of Coii/Niii/Mnii/Znii with 1,1′-biphenyl-2,2′-dicarboxylic acid and three positional isomeric ligands: structural diversity and properties20Isomorphous tetrazolate MnII and CoII compounds built on Δ-chain showing different magnetic behaviors23Structural diversity and fluorescent properties of Zn(ii)/Cd(ii) coordination polymers with a versatile tecton 2-(carboxymethoxy)benzoic acid and N-donor co-ligands49Syntheses, structures and photoluminescent properties of a series of Ag(i) coordination architectures based on 2,4-diamino-6-methyl-1,3,5-triazine and dicarboxylates: from a 0D discrete molecule to a 3D infinite network58Bitriazole bridged manganese(II) framework with weak ferromagnet behavior7Spin Canting and Metamagnetism in 2D and 3D Cobalt(II) Coordination Networks with Alternating Double End-On and Double End-to-End Azido Bridges72Assembly of coordination networks: Role of the different M(II)–cysteate chain in structural diversification8ChemInform Abstract: Framework‐Structured Weak Ferromagnets0Metal‐Organic Niccolite: Synthesis, Structures, Phase Transition, and Magnetic Properties of [CH3NH2(CH2)2NH2CH3][M2(HCOO)6] (M=divalent Mn, Fe, Co, Ni, Cu and Zn)56Azide‐Bridged Copper(II) and Manganese(II) Compounds with a Zwitterionic Tetrazolate Ligand: Structures and Magnetic Properties31Magnetic and Mechanical Anisotropy in a Manganese 2‐Methylsuccinate Framework Structure27Tricomponent Azide, Tetrazolate, and Carboxylate Cobridging Magnetic Systems: Ferromagnetic Coupling, Metamagnetism, and Single‐Chain Magnetism69Synthesis, Crystal Structure and Luminescent Properties of a 1D Cd(II) Complex with a Bent Connector: 1H-3-(3-pyridyl)-5-(4-pyridyl)-1,2,4-triazole1Canted antiferromagnetism and spin reorientation transition in layered inorganic–organic perovskite (C 6 H 5 CH 2 CH 2 NH 3 ) 2 MnCl 475Constructing Single‐Chain Magnets by Supramolecular π–π Stacking and Spin Canting: A Case Study on Manganese(III) Corroles69Templated Synthesis, Postsynthetic Metal Exchange, and Properties of a Porphyrin-Encapsulating Metal–Organic Material250Heterometallic cubane-like {M 2 Ln 2 } (M = Ni, Zn; Ln =, Gd, Dy) and {Ni 2 Y 2 } aggregates. Synthesis, structures and magnetic properties68New photoluminescence acylhydrazidate-coordinated complexes37A unique substituted Co(ii)-formate coordination framework exhibits weak ferromagnetic single-chain-magnet like behavior92Co(ii)/Ni(ii) coordination polymers incorporated with a bent connector: crystal structures and magnetic properties27Highly-connected, porous coordination polymers based on [M4(μ3-OH)2] (M = CoII and NiII) clusters: different networks, adsorption and magnetic properties72Mixed azide and carboxylate bridged trinuclear Mn(ii) and Co(ii) motifs in coordination ladders: structures and magnetism14New metal complexes with di(mono)acylhydrazidate molecules18New monoacylhydrazidate-coordinated Mn2+ and Pb2+ compounds26New thiocyanatocadmates with bidentate N-heterocyclic molecules as the templating agents: synthesis and structural characterization24One pot synthesis of heterometallic 3d–3d azido architectures: assembling strategy and magnetic properties21Polyrotaxane metal–organic frameworks (PMOFs)170Self-assembly, crystal structures, and properties of metal-2-sulfoterephthalate frameworks based on [M4(μ3-OH)2]6+ clusters (M = Co, Mn, Zn and Cd)31Stabilization of O–Mn–O clusters (Mn5) in three dimensionally extended MOF structures: synthesis, structure and properties18Structures and properties of lanthanide metal–organic frameworks based on a 1,2,3-triazole-containing tetracarboxylate ligand49Synthesis, structural characterization and photoluminescence property of four di(mono)acylhydrazidate-coordinated Cd2+ and Zn2+ compounds20Systematic investigations on magneto-structural correlations of copper(ii) coordination polymers based on organic ligands with mixed carboxylic and nitrogen-based moieties40Three-dimensional networks based on trinuclear motifs with tricomponent azide-carboxylate-tetrazolate cobridges: synthesis, structure and magnetic properties16Two azido-bridged cobalt(ii) coordination polymers with nicotinate co-ligand: synthesis, structures and magnetic properties28Two solvent-dependent zinc(ii) supramolecular isomers: structure analysis, reversible and nonreversible crystal-to-crystal transformation, highly selective CO2 gas adsorption, and photoluminescence behaviors47Weak ferromagnetism in chiral diamond-like neutral networks: Mn(2-pymS)2 and Co(2-pymS)2 (2-pymSH = 2-mercaptopyrimidine)14Co4(OH)2(C10H16O4)3 Metal–Organic Framework: Slow Magnetic Relaxation in the Ordered Phase of Magnetic Chains41Coordination Assemblies of CoII/NiII/ ZnII/CdII with Succinic Acid and Bent Connectors: Structural Diversity and Spin-Canted Antiferromagnetism41Detailed magnetic study on the formato-bridged MOFs with anion-tunable magnetic properties10Zinc‐Diluted Magnetic Metal Formate Perovskites: Synthesis, Structures, and Magnetism of [CH3NH3][MnxZn1−x(HCOO)3] (x=0–1)32Synthesis, structure, and magnetic properties of a cyanidebridged Fe(III)-Cu(II) bimetallic double-zigzag chain with slow relaxation of the magnetization6A three-dimensional heterometallic MnIICuII azide-bridged coordination polymer: Synthesis, structure, and magnetic properties4Detailed magnetic study on the formato-bridged MOFs with anion-tunable magnetic properties0Synthesis and Crystal Structure of [(μ-Biphenyl-3,3'-Dicarboxylato)Manganese(II)]0Synthesis, structures and single chain magnet behavior of a cyano-bridged {Fe2Cu} chain7Two 3D Supramolecular Isomeric Mixed‐Ligand CoII Frameworks – Guest‐Induced Structural Variation, Magnetism, and Selective Gas Adsorption9A Series of New Three-Dimensional d–f Heterometallic Coordination Polymers with Rare 10-ConnectedbctNet Topology Based on Planar Hexanuclear Heterometallic Second Building Units68Ligand-to-metal ratio dependent assembly of two distinct 1D and 3D copper(II)-dicyanamide magnetic coordination polymers with a tripyridyltriazole co-tecton25Solvent-regulated assemblies of silver(I) and cadmium(II) supramolecular complexes with versatile tripyridyltriazole multidentate ligands12Highly Selective CO2 Uptake in Uninodal 6-Connected “mmo” Nets Based upon MO42– (M = Cr, Mo) Pillars124A New Series of Chiral Metal Formate Frameworks of [HONH3][MII(HCOO)3] (M = Mn, Co, Ni, Zn, and Mg): Synthesis, Structures, and Properties86Single-chain magnets: beyond the Glauber model241Experimental and Theoretical Charge Densities of a Zinc-Containing Coordination Polymer, Zn(HCOO)2(H2O)225Auxiliary ligand-directed and counter anion-templated effects on coordination networks based on semirigid 2-aminodiacetic terephthalic acid ligand30Ligand Geometry Directed Polar Cobalt(II) Phosphonate Displaying Weak Ferromagnetism23Syntheses, structures and magnetic properties of two neutral coordination polymers of cobalt(II) containing a tailored aromatic diamine and pseudohalides as bridging units: Control of dimensionality by varying pseudohalide13Systematic studies of the structures and magnetic properties for a family of cubane complexes with the formula: [M2Ln2] (Ln = Dy, Gd; M = Ni, Zn) and [Ni2Y2]34Synthesis, Ab Initio X-ray Powder Diffraction Crystal Structure, and Magnetic Properties of Mn3(OH)2(C6H2O4S)2 Metal–Organic Framework14A chiral 2p–3d heterometallic azido complex with 2,6-pyridinedicarboxylate as the co-ligand showing magnetic order20A homospin cobalt(ii) topological ferrimagnet41A novel (3,3,6)-connected luminescent metal–organic framework for sensing of nitroaromatic explosives123A series of novel zinc(ii) entangled coordination polymers based on carboxyphenyl-terpyridine ligands79Diverse manganese(ii) coordination polymers derived from achiral/chiral imidazolium-carboxylate zwitterions and azide: structure and magnetic properties39Employing tripodal carboxylate ligand to construct Co(ii) coordination networks modulated by N-donor ligands: syntheses, structures and magnetic properties24Heterometallic Co(ii)–Ru2(ii,iii) carbonates: from discrete ionic crystals to three-dimensional network16New Cd2+, Pb2+ complexes with acylhydrazidate molecules from in situ acylation reactions23New halo(pseudohalo)cadmates templated by protonatated N-heterocyclic/diamine molecules16New thiocyanatocadmates templated by multi-dentate N-heterocyclic/diamine molecules29New two-dimensional Mn(ii) metal–organic framework featured spin canting24Oxalate-extended Cd2+–acylhydrazidate coordination polymers: synthesis, structure and fluorescence property21Pressure induced transition from spin glass-like behavior to a metamagnet exhibiting weak ferromagnetism observed for decamethylferrocenium hexacyanobutadienide, [FeCp*2]˙+[HCBD]˙−5Structural and magnetic characterization of the tridimensional network [Fe(HCO2)3]n·nHCO2H5Structural and magnetic investigation of CoII/MnII-based MIL-53 analogues with mixed ligands of neutral N-oxides and organic carboxylates6Structural diversity and fluorescent properties of CdII coordination polymers with 5-halonicotinates regulated by solvent and ligand halogen-substituting effect32Structural diversity in the complexes based on a hetero-trimetallic Cu2Cd node and dicyanamide spacer: a hexanuclear cluster, a 1D stair polymer and a 1D zigzag chain as supramolecular isomers, and a 3D network54Structures and magnetic properties of copper(ii) and manganese(ii) polymers derived from pseudohalides and a flexible zwitterionic dicarboxylate ligand22Syntheses, crystal structures and luminescent properties of four Zn(ii) coordination polymers with pyrazolone derivatives and 4,4′-bipyridine39The construction of Cu(i)/Cu(ii) coordination polymers based on pyrazine–carboxylate: Structural diversity tuned by in situ hydrolysis reaction27Theoretical Study on a Metal-Organic Framework Based on ${\rm \mu}$4-Oxo Tetrazinc Clusters: The Sorption Mechanism for Small Molecule6Syntheses, structural diversities and magnetic properties of four new Co(II) coordination polymers with phthalic acid derivatives16Synthesis, structural diversities and properties of a series of transition metal-organic frameworks based on asymmetric dicarboxylic acid and N-donor auxiliary ligand7Syntheses, structures and magnetic properties of two one-dimensional coordination polymers of cobalt(II) and nickel(II) dicyanamide containing a tridentate N-donor Schiff base19Crystal Structures and Luminescent Properties of Two Lanthanide(III) Complexes Featuring Double-Stranded Helical Chains of Based on 2-Sulfoterephthalate6Long-Range Magnetic Ordering at 5.5 K for Cobalt(II)–Hydroxide Diamond Chains Isolated by 17 Å with α-Phenylcinnamate20(H2mela)2[FeCl5]Cl (mela=melamine): A Cl-bridged single-chain magnet based on weak ferromagnetism18Transition-Metal Supramolecular Complexes with 2-Phenylacetate and a Bent Dipyridyl Ligand: In Situ Hydrothermal Syntheses, Crystal Structures, and Photoluminescent Properties2Absorption of CO2 and CS2 into the Hofmann-Type Porous Coordination Polymer: Electrostatic versus Dispersion Interactions86Decametallic CoII‐Cluster‐Based Microporous Magnetic Framework with a Semirigid Multicoordinating Ligand29Syntheses, structures, and magnetic properties of terephthalato bridged dinuclear copper(II) and manganese(II) complexes with a tetradentate N-donor Schiff base33Structural diversity and properties of four complexes with 4-acyl pyrazolone derivative17Structures and Magnetic Properties of Nickel Thiocyanato Coordination Compounds with 2‐Chloropyrazine as a Neutral Coligand14Syntheses, structures and magnetic properties of two isostructural metal-phosphonate frameworks14Manganese(II)-promoted ligand oxidation during the formation of a coordination polymer5Constructing a Series of Azide‐Bridged CuII Magnetic Low‐Dimensional Coordination Polymers by using Pybox Ligands25Two cobalt monophosphonates: Syntheses, structures and magnetic properties4Tracking the Formation of a Polynuclear Co 16 Complex and Its Elimination and Substitution Reactions by Mass Spectroscopy and Crystallography176Anion-directed assembly of cadmium(II)–dicyanamide coordination polymers based on a tripyridyltriazole ligand7Synthesis, Crystal Structures and Polymorphism of New Cadmium and Zinc Thio- and Selenocyanato Coordination Compounds with 4-Acetylpyridine as N-Donor Ligand3Synthesis, molecular and crystalline architectures, and properties of a mononuclear complex [Co II (benzidine) 2 (NCS) 2 (OH 2 ) 2 ]8Co5/Co8–Cluster-Based Coordination Polymers Showing High-Connected Self-Penetrating Networks: Syntheses, Crystal Structures, and Magnetic Properties219A Chain‐Based 2 D Cobalt(II) Coordination Polymer with a “Crab‐Like” Flexible Dicarboxylate Ligand: A Weak Ferromagnetic Single‐Chain Magnet30Dzyaloshinski–Moriya (D–M) oriented weak ferromagnets in isomorphic coordination architectures constructed by flexible 1,2,4-triazole-1-acetate ligands with the assistance of halogen or pseudohalogen anions5Three Series of 3d–4f Heterometallic Polymers Based on [LnCu6] or [Ln6Cu24] Clusters and Formate Bridges: Displaying Significant Magnetocaloric Effect532D LnIII(Nd/La)‐AgI Heterometallic and TmIII Homometallic Coordination Polymers Based on Pyridine Dicarboxylate Ligands4Two Extended 5‐Methyltetrazolate‐Based Magnetic Complexes: Synthesis, Structure, and Magnetic Properties5A Rational Route to Coordination Polymers with Condensed Networks and Cooperative Magnetic Properties81Construction of Ag(I)–Ln(III) Heterometallic Coordination Polymers Based on Binuclear Ag2(DSPT)2 (H2DSPT = 4′-(2,4-Disulfophenyl)-2,2′:6′2″-terpyridine) Rings and Ln(III) Dimeric Molecular Building Blocks45A symbol approach for classification of molecule-based magnetic materials exemplified by coordination polymers of metal carboxylates209Pressure Induced Crossover between a Ferromagnetic and a Canted Antiferromagnetic State for [Bis(pentamethylcyclopentadienyl)-iron(III)][Tetracyanoethenide], [FeCp2*][TCNE]6Bifunctional Co(II)–Ag(I) and Ni(II)–Ag(I) Frameworks: Modulation of Magnetic Property and CO2 Uptake Based on Organic Pillars12Four Coordination Polymers Based on Identical Eight-Connected Heptanuclear Clusters: Spin Canting, Spin Glass, Antiferromagnetism, and Gas Adsorption46Structures and photoluminescence properties of two cadmium(II) coordination polymers synthesized by flexible and rigid ligands7A high-connected self-penetrating network supported by pentanuclear cobalt(II) secondary building units15Syntheses, structures, and photoluminescent properties of a series of metal–organic frameworks constructed by 5,5′-bis(1H-imidazol-1-yl)-2,2′-bithiophene and various carboxylate ligands21Electric control of magnetism in a multiferroic metal–organic framework57A thermally stable pcu network based on ferromagnetic dinuclear Ni(II) units0Cobalt(II)–Lanthanide(III) Heterometallic Metal–Organic Frameworks with Unique (6,6)‐Connected Nia Topologies with 1H‐1,2,3‐Triazole‐4,5‐dicarboxylic Acid: Syntheses, Structures and Magnetic Properties24A Spin-Canted Polynuclear Manganese Complex Comprised of Alternating Linkage of Cyclic Tetra-and Mononuclear Fragments30Solvothermal syntheses and structures of four indium–phosphite coordination polymers8Assembly of Co(ii)/Cu(ii)–azido polynuclear polymers: structural diversity and magnetic behavior13The synthesis, structure, and magnetic properties of two novel manganese(ii) azido/formate coordination polymers with isonicotinic acid N-oxide as a coligand29Synthesis, Crystal Structures, Magnetic, and Thermal Properties of Divalent Metal Formate–Formamide Layered Compounds.17[NH 2 NH 3 ][M(HCOO) 3 ] (M = Mn 2+ , Zn 2+ , Co 2+ and Mg 2+ ): structural phase transitions, prominent dielectric anomalies and negative thermal expansion, and magnetic ordering187Metal-directed assembly of coordination polymers with the versatile ligand 2-(1 H -benzotriazol-1-yl) acetic acid: from discrete structures to two-dimensional networks46A perception of ferro- and antiferromagnetic interactions in a two dimensional Ni( ii ) heterochiral coordination polymer showing unusual CO 2 uptake behavior7An alternative strategy to construct Fe( ii )-based MOFs with multifarious structures and magnetic behaviors32An unusual water-bridged homospin Co II single-chain magnet44Discrete 0D and polymeric 2D and 3D derivatives assembled from [(CuL)2Zn]2+ and dicyanamide blocks (H2L = salen type Schiff bases): Genuine supramolecular isomers with distinct topologies47Doping cobalt into a [Zn 7 ] cluster-based MOF to tune magnetic behaviour and induce fluorescence signal mutation36Effect of phenylacetic acid coligands on the structures and magnetic properties of azido-bridged copper( ii )-chain compounds14Four-connected metal–organic frameworks constructed by tetracarboxylate acid-based ligands14Lanthanides in the frame of Molecular Magnetism3Ligand design for long-range magnetic order in metal–organic frameworks58Metal-ion controlled solid-state reactivity and photoluminescence in two isomorphous coordination polymers17New Zn2+ coordination polymers with mixed triazolate/tetrazolate and acylhydrazidate as linkers19Solid-state principles applied to organic–inorganic perovskites: new tricks for an old dog1030Structural diversity of 5-methylnicotinate coordination assemblies regulated by metal-ligating tendency and metal-dependent anion effect18Structural modulation in two Cu II -based MOFs by synergistic assembly involving the mixed-ligand synthetic strategy and the solvent effect31Syntheses, crystal structures, and optical properties of five metal complexes constructed from a V-shaped thiophene-containing ligand and different dicarboxylate ligands15Syntheses, crystal structures, photoluminescent/magnetic properties of four new coordination polymers based on 2,3′,4,5′-biphenyltetracarboxylic acid25Three Mn( ii ) coordination polymers with a bispyridyl-based quinolinate ligand: the anion-controlled tunable structural and magnetic properties17Quantum Tunneling of Magnetization in a Metal-Organic Framework85Synthesis, characterization and magnetic property of a succinate bridged 1D coordination polymer of cobalt(II) containing benzidine as end-capping ligand16Synthesis and properties of a new (3,8)-connected pillar-layered Co(II)-based coordination polymer supported by tetranuclear secondary building units (SBUs)6Chirality Transfer in Magnetic Coordination Complexes Monitored by Vibrational and Electronic Circular Dichroism16Crystal structures and electrochemical properties of two Mn(II) 2-sulfoterephthalate complexes with N-donor ligands5Nanoporous Cobalt(II) MOF Exhibiting Four Magnetic Ground States and Changes in Gas Sorption upon Post-Synthetic Modification440A Manganese(II) Coordination Polymer with the Ligands Azide and Picolinate: Synthesis, Structure, and Magnetic Properties3Self-assembled microporous lanthanide coordination polymers built by 2-hydroxynicotinic acid and oxalate ligands1

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  3. Isomorphous tetrazolate MnII and CoII compounds built on Δ-chain showing different magnetic behaviors

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  4. Structural diversity and fluorescent properties of Zn(ii)/Cd(ii) coordination polymers with a versatile tecton 2-(carboxymethoxy)benzoic acid and N-donor co-ligands

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  10. Metal‐Organic Niccolite: Synthesis, Structures, Phase Transition, and Magnetic Properties of [CH3NH2(CH2)2NH2CH3][M2(HCOO)6] (M=divalent Mn, Fe, Co, Ni, Cu and Zn)

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  15. Canted antiferromagnetism and spin reorientation transition in layered inorganic–organic perovskite (C 6 H 5 CH 2 CH 2 NH 3 ) 2 MnCl 4

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  22. Highly-connected, porous coordination polymers based on [M4(μ3-OH)2] (M = CoII and NiII) clusters: different networks, adsorption and magnetic properties

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  31. Structures and properties of lanthanide metal–organic frameworks based on a 1,2,3-triazole-containing tetracarboxylate ligand

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  32. Synthesis, structural characterization and photoluminescence property of four di(mono)acylhydrazidate-coordinated Cd2+ and Zn2+ compounds

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