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RESEARCH PAPER · Journal of the American Chemical Society · 2009

Strong H···F Hydrogen Bonds as Synthons in Polymeric Quantum Magnets: Structural, Magnetic, and Theoretical Characterization of [Cu(HF2)(pyrazine)2]SbF6, [Cu2F(HF)(HF2)(pyrazine)4](SbF6)2, and [CuAg(H3F4)(pyrazine)5](SbF6)2

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Strong H···F Hydrogen Bonds as Synthons in Polymeric Quantum Magnets: Structural, Magnetic, and Theoretical Characterization of [Cu(HF2)(pyrazine)2]SbF6, [Cu2F(HF)(HF2)(pyrazine)4](SbF6)2, and [CuAg(H3F4)(pyrazine)5](SbF6)2OriginalCrystal structures of three new copper(II) halide layered perovskites: structural, crystallographic, and magnetic correlations215HF molecules and poly(hydrogen fluoride) anions as ligands to metal centers13Spin fluctuations and orbital ordering in quasi-one-dimensional α-Cu(dca)2(pyz) {dca=dicyanamide=N(CN)2−; pyz=pyrazine}, a molecular analogue of KCuF37Hydrogen-Bond Directed Cyanide-Bridged Molecular Magnets Derived from Polycyanidemetalates and Schiff Base Manganese(III) Compounds: Synthesis, Structures, and Magnetic Properties116High-Field Magnetization Study of [Cu(pyz)2(HF2)]PF6: An $S=\frac{1}{2}$ Quasi-two-dimensional Heisenberg Magnet0Crystal Structure and Antiferromagnetic Ordering of Quasi-2D [Cu(HF2)(pyz)2]TaF6 (pyz=pyrazine)13Magnetic properties of the quasi-two-dimensional S=12 Heisenberg antiferromagnet [Cu(pyz)2(HF2)]PF634Dinuclear Mesogens with Antiferromagnetic Properties3Experimental and theoretical investigations of magnetic properties for two low-dimensional spin systems based on bis(2-thioxo-1,3-dithiole-4,5-dithiolato)nickelate monoanion building blocks3Crystal‐to‐Crystal Transformation from a Mononuclear Compound in a Hydrogen‐Bonded Three‐Dimensional Framework to a Layered Coordination Polymer40Muon spin relaxation investigation of magnetic ordering in the hybrid organic-inorganic perovskites [(CH3)2NH2]M(HCOO)3 (M=Ni,Co,Mn,Cu)54[Cu(HF2)2(pyrazine)]n: A Rectangular Antiferromagnetic Lattice with a Spin Exchange Path Made Up of Two Different FHF− Bridges17[Cu(HF2)2(pyrazine)]n: A Rectangular Antiferromagnetic Lattice with a Spin Exchange Path Made Up of Two Different FHF− Bridges1Synthesis, Characterization and Property Studies on a Dinuclear Copper(II) Complex with Dipyridine Derivate and Acetylacetone0π–π Stacking, hydrogen bonding and anti-ferromagnetic coupling mechanism on a mononuclear Cu(II) complex17Mixed metalII–metalIV hybrid fluorides11Crystal‐to‐Crystal Transformation from a Chain Compound to a Layered Coordination Polymer17Structural, Electronic, and Magnetic Properties of Quasi-1D Quantum Magnets [Ni(HF2)(pyz)2]X (pyz = pyrazine; X = PF6–, SbF6–) Exhibiting Ni-FHF-Ni and Ni-pyz-Ni Spin Interactions35Pressure-Induced Local Structure Distortions in Cu(pyz)F2(H2O)213Magnetic order in quasi-two-dimensional molecular magnets investigated with muon-spin relaxation39Field-induced XY and Ising ground states in a quasi-two-dimensional S=12 Heisenberg antiferromagnet32Influence of HF2− geometry on magnetic interactions elucidated from polymorphs of the metal–organic framework [Ni(HF2)(pyz)2]PF6 (pyz = pyrazine)16Observation of metal ion dependent packing structures and magnetic behaviors of metal-bis-1, 2-dithiolene complexes17Ag(nic)2 (nic = Nicotinate): A Spin-Canted Quasi-2D Antiferromagnet Composed of Square-Planar S = 1/2 AgII Ions8Dimensionality Selection in a Molecule-Based Magnet51Magnetic couplings mediated through the non-covalent interactions16Intermolecular interaction and magnetic coupling mechanism between adjacent mononuclear NiII complexes6[Ni(HF2)(3-Clpy)4]BF4 (py = pyridine): Evidence for Spin Exchange Along Strongly Distorted F···H···F– Bridges in a One-Dimensional Polymeric Chain21Hydrogen-bond directed 2D cyanide-bridged coordination polymer assembled from a new pentacyanidecobalt(III) building block and a bicompartimental Schiff-base manganese(III) compound: Synthesis, structures and magnetic properties4Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template5X-ray Absorption Spectroscopy Study of Novel Inorganic–organic Hybrid Ferromagnetic Cu–pyz–[M(CN)8]3– Assemblies6Metal–Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal–Organic Materials2950Highlights on contemporary recognition and sensing of fluoride anion in solution and in the solid state284Mechanical properties of a metal–organic framework containing hydrogen-bonded bifluoride linkers38π–π Stacking, spin density and magnetic coupling strength35Recent Developments in Low‐Dimensional Copper(II) Molecular Magnets76Intermolecular interaction and magnetic coupling mechanism of a 2-D mixed-valence CuIICuI coordination polymer containing μ 1,1,3-SCN bridge7An ion-pair complex [TTF][Pd(mnt)2]: synthesis, crystal structure, magnetic property, and electrical conductivity2Intermolecular interaction and magnetic coupling mechanism of a mixed-valence CuIICuI tetranuclear complex with iodide bridge3An Overlooked yet Ubiquitous Fluoride Congenitor: Binding Bifluoride in Triazolophanes Using Computer-Aided Design54Synthesis, Structures and Magnetic Properties of Hydrogen-bond Directed 2D Heterobimetallic Cyanide-bridged Coordination Polymers2Syntheses, crystal structures and magnetic properties of two halogen bridged dinuclear copper(II) complexes [(4,4′-diethylester-2,2′-biquinoline)2Cu2(μ-X)2X2] (X−=Cl−, Br−)7A novel Cu 12 (pz) 12 loop-based coordination polymer templated by double-Keggin anions12Modified approach to the Arduengo carbene complexes of silver1Magnetic ground state of the two isostructual polymeric quantum magnets [Cu(HF2)(pyrazine)2]SbF6 and [Co(HF2)(pyrazine)2]SbF6 investigated with neutron powder diffraction12Crystal-to-crystal transformation from a chain compound to a layered coordination polymer12Bimetallic MOFs (H 3 O) x [Cu(MF 6 )(pyrazine) 2 ]·(4 − x)H 2 O (M = V 4+ , x = 0; M = Ga 3+ , x = 1): co-existence of ordered and disordered quantum spins in the V 4+ system6Experimental and Theoretical Electron Density Analysis of Copper Pyrazine Nitrate Quasi-Low-Dimensional Quantum Magnets50Antiferromagnetism in a Family of S = 1 Square Lattice Coordination Polymers NiX2(pyz)2 (X = Cl, Br, I, NCS; pyz = Pyrazine)33Spin–Lattice Coupling in [Ni(HF2)(pyrazine)2]SbF6 Involving the HF2– Superexchange Pathway7Adiabatic physics of an exchange-coupled spin-dimer system: Magnetocaloric effect, zero-point fluctuations, and possible two-dimensional universal behavior30(N2H6)3TaF8TaF7HF2 and Na7TaF8(TaF7)2: Novel fluoride tantalates with different isolated anionic polyhedra8Magnetic phase transitions and magnetoelastic coupling in S=12 Heisenberg antiferromagnets5(BEDT‐TTF)2Cu2(HCOO)5: An Organic–Inorganic Hybrid Conducting Magnet3Combining microscopic and macroscopic probes to untangle the single-ion anisotropy and exchange energies in an S=1 quantum antiferromagnet23Competing magnetostructural phases in a semiclassical system6A new 3D POMOF with two channels consisting of Wells–Dawson arsenotungstate and {Cl 4 Cu 10 (pz) 11 } complexes: synthesis, crystal structure, and properties15Quasi-2D Heisenberg Antiferromagnets [CuX(pyz)2](BF4) with X = Cl and Br25Implications of bond disorder in a S=1 kagome lattice6Cr(pyrazine)2(OSO2CH3)2: A two-dimensional coordination polymer with an antiferromagnetic ground state19Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO 3 ) 2 (pyz) 314A survey of interactions in crystal structures of pyrazine-based compounds20Field-induced anisotropy in the quasi-two-dimensional weakly anisotropic antiferromagnet [CuCl(pyz)2]BF43Halide-bridged Cu(pyrazine)2 perchlorate layers: Structure and magnetism3Determining the anisotropy and exchange parameters of polycrystalline spin-1 magnets13Pyrazine-bridged Cu( ii ) chains: diaquabis( n -methyl-2-pyridone)copper( ii ) perchlorate complexes15Enhancing easy-plane anisotropy in bespoke Ni(II) quantum magnets30Spin–Lattice Coupling Across the Magnetic Quantum-Phase Transition in Copper-Containing Coordination Polymers13Copper(II) Halide Salts with 1-(4′-Pyridyl)-Pyridinediium8The 3D POMOFs based two AsIII-capped Keggin arsenomolybdates with four VIV substituted: Synthesis, structures and properties4Structure and EPR investigation of Cu(II) bifluoride complexes with zwitterionic N-hydroxyimidazole ligands10Reentrance of spin-driven ferroelectricity through rotational tunneling of ammonium1Weak interactions in conducting metal–organic frameworks52CoMOF5(pyrazine)(H2O)2 (M = Nb, Ta): Two-Layered Cobalt Oxyfluoride Antiferromagnets with Spin Flop Transitions22Anomalous magnetic exchange in a dimerized quantum magnet composed of unlike spin species3Copper(II) Complexes with 4,4′-Bipyridine: From 1D to 3D Lattices1

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  4. Hydrogen-Bond Directed Cyanide-Bridged Molecular Magnets Derived from Polycyanidemetalates and Schiff Base Manganese(III) Compounds: Synthesis, Structures, and Magnetic Properties

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  5. High-Field Magnetization Study of [Cu(pyz)2(HF2)]PF6: An $S=\frac{1}{2}$ Quasi-two-dimensional Heisenberg Magnet

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  7. Magnetic properties of the quasi-two-dimensional S=12 Heisenberg antiferromagnet [Cu(pyz)2(HF2)]PF6

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  10. Crystal‐to‐Crystal Transformation from a Mononuclear Compound in a Hydrogen‐Bonded Three‐Dimensional Framework to a Layered Coordination Polymer

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  11. Muon spin relaxation investigation of magnetic ordering in the hybrid organic-inorganic perovskites [(CH3)2NH2]M(HCOO)3 (M=Ni,Co,Mn,Cu)

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  12. [Cu(HF2)2(pyrazine)]n: A Rectangular Antiferromagnetic Lattice with a Spin Exchange Path Made Up of Two Different FHF− Bridges

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  13. [Cu(HF2)2(pyrazine)]n: A Rectangular Antiferromagnetic Lattice with a Spin Exchange Path Made Up of Two Different FHF− Bridges

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  14. Synthesis, Characterization and Property Studies on a Dinuclear Copper(II) Complex with Dipyridine Derivate and Acetylacetone

    Bulletin of the Korean Chemical Society · 2011-01-20

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  15. π–π Stacking, hydrogen bonding and anti-ferromagnetic coupling mechanism on a mononuclear Cu(II) complex

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  16. Mixed metalII–metalIV hybrid fluorides

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  17. Crystal‐to‐Crystal Transformation from a Chain Compound to a Layered Coordination Polymer

    Chemistry - An Asian Journal · 2011-05-19

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  18. Structural, Electronic, and Magnetic Properties of Quasi-1D Quantum Magnets [Ni(HF2)(pyz)2]X (pyz = pyrazine; X = PF6–, SbF6–) Exhibiting Ni-FHF-Ni and Ni-pyz-Ni Spin Interactions

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  19. Pressure-Induced Local Structure Distortions in Cu(pyz)F2(H2O)2

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  21. Field-induced XY and Ising ground states in a quasi-two-dimensional S=12 Heisenberg antiferromagnet

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  22. Influence of HF2− geometry on magnetic interactions elucidated from polymorphs of the metal–organic framework [Ni(HF2)(pyz)2]PF6 (pyz = pyrazine)

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  26. Magnetic couplings mediated through the non-covalent interactions

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  28. [Ni(HF2)(3-Clpy)4]BF4 (py = pyridine): Evidence for Spin Exchange Along Strongly Distorted F···H···F– Bridges in a One-Dimensional Polymeric Chain

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  30. Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template

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  37. Intermolecular interaction and magnetic coupling mechanism of a 2-D mixed-valence CuIICuI coordination polymer containing μ 1,1,3-SCN bridge

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  42. Syntheses, crystal structures and magnetic properties of two halogen bridged dinuclear copper(II) complexes [(4,4′-diethylester-2,2′-biquinoline)2Cu2(μ-X)2X2] (X−=Cl−, Br−)

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  45. Magnetic ground state of the two isostructual polymeric quantum magnets [Cu(HF2)(pyrazine)2]SbF6 and [Co(HF2)(pyrazine)2]SbF6 investigated with neutron powder diffraction

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  47. Bimetallic MOFs (H 3 O) x [Cu(MF 6 )(pyrazine) 2 ]·(4 − x)H 2 O (M = V 4+ , x = 0; M = Ga 3+ , x = 1): co-existence of ordered and disordered quantum spins in the V 4+ system

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  48. Experimental and Theoretical Electron Density Analysis of Copper Pyrazine Nitrate Quasi-Low-Dimensional Quantum Magnets

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    Junjie Liu, Paul Goddard, John Singleton, Jamie Brambleby, Francesca R. Foronda, Johannes S. Möller, Yoshimitsu Kohama, Saman Ghannadzadeh, Arzhang Ardavan, Stephen J. Blundell, Tom Lancaster, Fan Xiao, Robert C. Williams, Francis Laurence Pratt, Peter J. Baker, Keola Wierschem, Saul H. Lapidus, Kevin H. Stone, Peter W. Stephens, Jesper Bendix, Toby J. Woods, Kimberly E. Carreiro, Hope E. Tran, Cecelia J. Villa, Jamie L. Manson

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  50. Spin–Lattice Coupling in [Ni(HF2)(pyrazine)2]SbF6 Involving the HF2– Superexchange Pathway

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    Kenneth R. O’Neal, Brian S. Holinsworth, Zhiguo Chen, Peter K. Peterson, Kimberly E. Carreiro, C. Lee, Jamie L. Manson, Myung‐Hwan Whangbo, Zhiqiang Li, Zhenxian Liu, Janice L. Musfeldt

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