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RESEARCH PAPER · Advanced Functional Materials · 2012

Lone‐Pair‐Induced Covalency as the Cause of Temperature‐ and Field‐Induced Instabilities in Bismuth Sodium Titanate

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Lone‐Pair‐Induced Covalency as the Cause of Temperature‐ and Field‐Induced Instabilities in Bismuth Sodium TitanateOriginalSynthesis, dielectric and relaxation behavior of lead free NBT–BT ceramics59A High‐Temperature‐Capacitor Dielectric Based on K 0.5 Na 0.5 NbO 3 ‐Modified Bi 1/2 Na 1/2 TiO 3 – Bi 1/2 K 1/2 TiO 3130Remarkably high-temperature stable piezoelectric properties of Bi(Mg0.5Ti0.5)O3 modified BiFeO3–BaTiO3 ceramics112Bifurcated Polarization Rotation in Bismuth‐Based Piezoelectrics182Structural, microstructural and electrical properties of BiFeO3–BaTiO3 ceramics with high thermal stability94The Composition and Temperature‐Dependent Structure Evolution and Large Strain Response in (1− x )( Bi 0.5 Na 0.5 ) TiO 3 − x Ba ( Al 0.5 Ta 0.5 ) O 3 Ceramics140Piezoelectric properties and temperature stabilities of Mn- and Cu-modified BiFeO3–BaTiO3 high temperature ceramics180Structure–property relationships in BaTiO3–BiFeO3–BiYbO3 ceramics61Temperature‐Insensitive (K,Na)NbO3‐Based Lead‐Free Piezoactuator Ceramics574Giant electrostrains accompanying the evolution of a relaxor behavior in Bi(Mg,Ti)O3–PbZrO3–PbTiO3 ferroelectric ceramics176Switching of morphotropic phase boundary and large strain response in lead-free ternary (Bi0.5Na0.5)TiO3–(K0.5Bi0.5)TiO3–(K0.5Na0.5)NbO3 system158A New Phase Boundary in (Bi1/2Na1/2)TiO3−BaTiO3 Revealed via a Novel Method of Electron Diffraction Analysis144Tailoring the Piezoelectric and Relaxor Properties of ( Bi 1/2 Na 1/2 ) TiO 3 – BaTiO 3 via Zirconium Doping54Dielectric relaxation, lattice dynamics and polarization mechanisms in Bi0.5Na0.5TiO3-based lead-free ceramics178Phase transitions, relaxor behavior, and large strain response in LiNbO3-modified Bi0.5(Na0.80K0.20)0.5TiO3 lead-free piezoceramics122A family of oxide ion conductors based on the ferroelectric perovskite Na0.5Bi0.5TiO3929Large Electrostrictive Strain in ( Bi 0.5 Na 0.5 ) TiO 3 – BaTiO 3 –( Sr 0.7 Bi 0.2 ) TiO 3 Solid Solutions192Effect of neodymium substitution on structural and ferroelectric properties of BNT ceramics57Phase transitional behavior and electric field-induced large strain in alkali niobate-modified Bi0.5(Na0.80K0.20)0.5TiO3 lead-free piezoceramics66Effect of BiMeO 3 on the Phase Structure, Ferroelectric Stability, and Properties of Lead‐Free Bi 0.5 (Na 0.80 K 0.20 ) 0.5 TiO 3 Ceramics64Large strains accompanying field-induced ergodic phase-polar ordered phase transformations in Bi(Mg0.5Ti0.5)O3–PbTiO3–(Bi0.5Na0.5)TiO3 ternary system56Enhanced electric field-induced strain and ferroelectric behavior of (Bi0.5Na0.5)TiO3–BaTiO3–SrZrO3 lead-free ceramics105Electromechanical and electrical properties of Bi0.5Na0.5Ti1−xMnxO3−δ ceramics with high remnant polarization67High Strain in (K,Na)NbO3-Based Lead-Free Piezoelectric Fibers82Giant strain response and structure evolution in (Bi0.5Na0.5)0.945−x(Bi0.2Sr0.7□0.1)xBa0.055TiO3 ceramics135Effect of poling on nanodomains and nanoscale structure in A-site disordered lead-free piezoelectric Na 0.5 Bi 0.5 TiO 3 –BaTiO 390Atomistic origin of huge response functions at the morphotropic phase boundary of (1−x)Na0.5Bi0.5TiO3−xBaTiO369Composition‐ and Temperature‐Dependent Large Strain in (1− x )(0.8Bi 0.5 Na 0.5 TiO 3 –0.2Bi 0.5 K 0.5 TiO 3 )– x NaNbO 3 Ceramics142Dramatic Influence of A-Site Nonstoichiometry on the Electrical Conductivity and Conduction Mechanisms in the Perovskite Oxide Na 0.5 Bi 0.5 TiO 3251Crystal structure, defect chemistry and oxygen ion transport of the ferroelectric perovskite, Na 0.5 Bi 0.5 TiO 3 : insights from first-principles calculations96Evolution of phase structure and giant strain at low driving fields in Bi-based lead-free incipient piezoelectrics77Ultra‐Wide Temperature Stable Dielectrics Based on Bi 0.5 Na 0.5 TiO 3 –NaNbO 3 System118Origin of anomalous giant dielectric performance in novel perovskite: Bi0.5−xLaxNa0.5−xLixTi1−yMyO3 (M = Mg2+, Ga3+)67Core–Shell Lead–Free Piezoelectric Ceramics: Current Status and Advanced Characterization of the Bi 1/2 Na 1/2 TiO 3 –SrTiO 3 System150Effect of different templates and texture on structure evolution and strain behavior of <001>-textured lead-free piezoelectric BNT-based ceramics50Lead-Free Piezoceramics: Revealing the Role of the Rhombohedral–Tetragonal Phase Coexistence in Enhancement of the Piezoelectric Properties150Bismuth Sodium Titanate Based Materials for Piezoelectric Actuators156Phase evolution and correlation between tolerance factor and electromechanical properties in BNT-based ternary perovskite compounds with calculated end-member Bi(Me 0.5 Ti 0.5 )O 3 (Me = Zn, Mg, Ni, Co)53Phase transition behavior, dielectric and ferroelectric properties of (1 −x)(Bi0.5Na0.5)TiO3-xBa0.85Ca0.15Ti0.9Zr0.1O3 ceramics189The phase diagram of K0.5Na0.5NbO3–Bi1/2Na1/2TiO375Defect dipole induced large recoverable strain and high energy-storage density in lead-free Na0.5Bi0.5TiO3-based systems176Structure evolution and electrostrictive properties in (Bi0.5Na0.5)0.94Ba0.06TiO3–M2O5 (M = Nb, Ta, Sb) lead-free piezoceramics114Morphotropic NaNbO3-BaTiO3-CaZrO3 lead-free ceramics with temperature-insensitive piezoelectric properties55Quenching effects for piezoelectric properties on lead-free (Bi 1/2 Na 1/2 )TiO 3 ceramics105Grain-orientated lead-free BNT-based piezoceramics with giant electrostrictive effect57Electric-field-temperature phase diagram and electromechanical properties in lead-free (Na0.5Bi0.5)TiO3-based incipient piezoelectric ceramics62Influence of phase transitions and defect associates on the oxygen migration in the ion conductor Na 1/2 Bi 1/2 TiO 354Optimisation of oxide-ion conductivity in acceptor-doped Na 0.5 Bi 0.5 TiO 3 perovskite: approaching the limit?97Suppression of electrical conductivity and switching of conduction mechanisms in ‘stoichiometric’ (Na 0.5 Bi 0.5 TiO 3 ) 1−x (BiAlO 3 ) x (0 ≤ x ≤ 0.08) solid solutions75External-field-induced crystal structure and domain texture in (1−x)Na0.5Bi0.5TiO3–xK0.5Bi0.5TiO3 piezoceramics47Influence of structural evolution on energy storage properties in Bi0.5Na0.5TiO3-SrTiO3-NaNbO3 lead-free ferroelectric ceramics229Thermal evolution of polar nanoregions identified by the relaxation time of electric modulus in the Bi 1/2 Na 1/2 TiO 3 system66Tuning the ferroelectric-relaxor transition temperature in NBT-based lead-free ceramics by Bi nonstoichiometry79Phase–composition and temperature dependence of electrocaloric effect in lead–free Bi0.5Na0.5TiO3–BaTiO3–(Sr0.7Bi0.2□0.1)TiO3 ceramics109Electric field-induced phase transitions and composition-driven nanodomains in rhombohedral-tetragonal potassium-sodium niobate-based ceramics47Ferroelectric‐quasiferroelectric‐ergodic relaxor transition and multifunctional electrical properties in Bi 0.5 Na 0.5 TiO 3 ‐based ceramics72Defect chemistry and electrical properties of sodium bismuth titanate perovskite227Giant electrostrain accompanying structural evolution in lead-free NBT-based piezoceramics108Giant energy-storage density and high efficiency achieved in (Bi 0.5 Na 0.5 )TiO 3 –Bi(Ni 0.5 Zr 0.5 )O 3 thick films with polar nanoregions160Preparation and Characterization80Simultaneous enhancement of piezoelectricity and temperature stability in (K,Na)NbO 3 -based lead-free piezoceramics by incorporating perovskite zirconates67Ultrahigh strain in site engineering-independent Bi0.5Na0.5TiO3-based relaxor-ferroelectrics130Relaxor behaviour and phase transition of perovskite ferroelectrics-type complex oxides (1–x)Na0.5Bi0.5TiO3–xCaTiO3 system65Temperature stability and electrical properties in La‐doped KNN ‐based ceramics48Local phenomena in bismuth sodium titanate perovskite studied by Raman spectroscopy55Electric-field-induced local distortion and large electrostrictive effects in lead-free NBT-based relaxor ferroelectrics67Relaxor-ferroelectric transitions: Sodium bismuth titanate derivatives141Thermal depolarization regulation by oxides selection in lead-free BNT/oxides piezoelectric composites96High thermal stability of electric field-induced strain in (1−x)(Bi0.5Na0.5)TiO3-xBa0.85Ca0.15Ti0.9Zr0.1O3 lead-free ferroelectrics78Progress in high-strain perovskite piezoelectric ceramics840Grain size dependent physical properties in lead-free multifunctional piezoceramics: A case study of NBT-xST system149Influence of structural evolution on electrocaloric effect in Bi0.5Na0.5TiO3-SrTiO3 ferroelectric ceramics55Enhanced piezoelectric properties and temperature stability of Bi4Ti3O12-based Aurivillius ceramics via W/Nb substitution76Excellent energy storage density and charge–discharge performance of a novel Bi 0.2 Sr 0.7 TiO 3 –BiFeO 3 thin film55Fine-grain induced outstanding energy storage performance in novel Bi 0.5 K 0.5 TiO 3 –Ba(Mg 1/3 Nb 2/3 )O 3 ceramics via a hot-pressing strategy155Linear-like lead-free relaxor antiferroelectric (Bi 0.5 Na 0.5 )TiO 3 –NaNbO 3 with giant energy-storage density/efficiency and super stability against temperature and frequency555Perovskite Na 0.5 Bi 0.5 TiO 3 : a potential family of peculiar lead-free electrostrictors87Review of chemical modification on potassium sodium niobate lead-free piezoelectrics213Superior and anti-fatigue electro-strain in Bi 0.5 Na 0.5 TiO 3 -based polycrystalline relaxor ferroelectrics68Tailoring frequency-insensitive large field-induced strain and energy storage properties in (Ba 0.85 Ca 0.15 )(Zr 0.1 Ti 0.9 )O 3 -modified (Bi 0.5 Na 0.5 )TiO 3 lead-free ceramics74The effect of Fe‐acceptor doping on the electrical properties of Na 1/2 Bi 1/2 TiO 3 and 0.94 (Na 1/2 Bi 1/2 )TiO 3 –0.06 BaTiO 375Structure-design strategy of 0–3 type (Bi0.32Sr0.42Na0.20)TiO3/MgO composite to boost energy storage density, efficiency and charge-discharge performance132Improvement of dielectric and ferroelectric properties in bismuth sodium titanate based relaxors through Bi non-stoichiometry91Large energy density with excellent stability in fine-grained (Bi0.5Na0.5)TiO3-based lead-free ceramics110Enhanced energy density and thermal stability in relaxor ferroelectric Bi0.5Na0.5TiO3-Sr0.7Bi0.2TiO3 ceramics305Practical high-performance lead-free piezoelectrics: structural flexibility beyond utilizing multiphase coexistence123High temperature lead-free BNT-based ceramics with stable energy storage and dielectric properties245A CO2‐Tolerant Perovskite Oxide with High Oxide Ion and Electronic Conductivity57Advances in tuning the “ d 33 ∝ 1/ T d ” bottleneck: simultaneously realizing large d 33 and high T d in Bi 0.5 Na 0.5 TiO 3 -based relaxor ferroelectrics63Emerging new phase boundary in potassium sodium-niobate based ceramics393Giant electrostrictive strain in (Bi 0.5 Na 0.5 )TiO 3 –NaNbO 3 lead-free relaxor antiferroelectrics featuring temperature and frequency stability72Optimization of polarization behavior in (1 − x )BSBNT– x NN ceramics for pulsed power capacitors85Complex impedance and Raman spectroscopy of Na0.5(Bi1-xDyx)0.5TiO3 ceramics80Effects of rare-earth dopants on phase structure and electrical properties of lead-free bismuth sodium titanate-based ceramics56B-site vacancy induced Raman scattering in BaTiO3-based ferroelectric ceramics152Superior Electrostrictive Effect in Relaxor Potassium Sodium Niobate Based Ferroelectrics70Expanded linear polarization response and excellent energy-storage properties in (Bi0.5Na0.5)TiO3-KNbO3 relaxor antiferroelectrics with medium permittivity110Ultrahigh field-induced strain in lead-free ceramics157Large electrostrictive coefficient with high electro‐strain dominated by modified ergodic state in BNT‐based solid solutions50Remarkably enhanced energy-storage density and excellent thermal stability under low electric fields of (Na0.5Bi0.5)TiO3-based ceramics via composition optimization strategy75Large electrostrain in Bi1/2Na1/2TiO3-based relaxor ferroelectrics: A case study of Bi1/2Na1/2TiO3-Bi1/2K1/2TiO3-Bi(Ni2/3Nb1/3)O3 ceramics67Strategies to Improve the Energy Storage Properties of Perovskite Lead-Free Relaxor Ferroelectrics: A Review191Energy storage performance of Bi0.5Na0.5TiO3-based relaxor ferroelectric ceramics with superior temperature stability under low electric fields191Critical state to achieve a giant electric field-induced strain with a low hysteresis in relaxor piezoelectric ceramics54Emerging antiferroelectric phases with fascinating dielectric, polarization and strain response in NaNbO3-(Bi0.5Na0.5)TiO3 lead-free binary system168Excellent catalytic performance of molten-salt-synthesized Bi0.5Na0.5TiO3 nanorods by the piezo-phototronic coupling effect159Optimized strain properties with small hysteresis in BNT-based ceramics with ergodic relaxor state81Enhanced energy storage density of Sr0.7BixTiO3 lead-free relaxor ceramics via A-site defect and grain size tuning108Effect of oxygen vacancy and A-site-deficiency on the dielectric performance of BNT-BT-BST relaxors93Domain Engineered Lead-Free Ceramics with Large Energy Storage Density and Ultra-High Efficiency under Low Electric Fields143Energy storage performance of Na0.5Bi0.5TiO3 based lead-free ferroelectric ceramics prepared via non-uniform phase structure modification and rolling process191High capacitive performance at moderate operating field in (Bi0.5Na0.5)TiO3-based dielectric ceramics via synergistic effect of site engineering strategy79Electric field-induced transformations in bismuth sodium titanate-based materials95Phase structure and properties of sodium bismuth titanate lead-free piezoelectric ceramics363(Bi0.5Na0.5)TiO3-based relaxor ferroelectrics with medium permittivity featuring enhanced energy-storage density and excellent thermal stability112Oxygen vacancy migration and its lattice structural origin in A-site non-stoichiometric bismuth sodium titanate perovskites98Achieving synergistic electromechanical and electrocaloric responses by local structural evolution in lead-free BNT-based relaxor ferroelectrics53Grain size modulated (Na0.5Bi0.5)0.65Sr0.35TiO3-based ceramics with enhanced energy storage properties91Evolution from Lead‐Based to Lead‐Free Piezoelectrics: Engineering of Lattices, Domains, Boundaries, and Defects Leading to Giant Response227Simultaneously achieving high energy-storage efficiency and density in Bi-modified SrTiO3-based relaxor ferroelectrics by ion selective engineering94Local structure engineered lead-free ferroic dielectrics for superior energy-storage capacitors: A review324Remarkably enhanced dielectric stability and energy storage properties in BNT—BST relaxor ceramics by A-site defect engineering for pulsed power applications145Intelligent self-actuating lead-free cooling ceramics based on A-site defect engineering55A strategy to achieve high energy storage performance under a relatively low electric field in NBT-based ceramics50Ultrahigh energy storage density in (Bi0.5Na0.5)0.65Sr0.35TiO3-based lead-free relaxor ceramics with excellent temperature stability268Enhanced energy storage performance in Sr0.7La0.2Zr0.15Ti0.85O3-modified Bi0.5Na0.5TiO3 ceramics via constructing local phase coexistence106A Review on Lead-Free-Bi0.5Na0.5TiO3 Based Ceramics and Films: Dielectric, Piezoelectric, Ferroelectric and Energy Storage Performance109Enhanced Piezocatalytic Activity in Bi1/2Na1/2TiO3for Water Splitting by Oxygen Vacancy Engineering51Optimized strain performance in <001>-textured Bi0.5Na0.5TiO3-based ceramics with ergodic relaxor state and core—shell microstructure65Superior Energy-Storage Properties in Bi0.5Na0.5TiO3-Based Lead-Free Ceramics via Simultaneously Manipulating Multiscale Structure and Field-Induced Structure Transition51A critical review on crystal structure mechanisms, microstructural and electrical performances of Bi0.5Na0.5TiO3—SrTiO3 perovskites49High Energy Storage Performance and Large Electrocaloric Response in Bi0.5Na0.5TiO3–Ba(Zr0.2Ti0.8)O3 Thin Films70Enhanced energy storage performance of Bi0.5Na0.5TiO3-based ceramics via grain tuning and relaxor construction67High energy-storage performance in X9R-type Na0.5Bi0.5TiO3-based lead-free ceramics45Insight into the large electro-strain in bismuth sodium titanate-based relaxor ferroelectrics: From fundamentals to regulation methods49Superior Energy Storage Properties and Optical Transparency in K 0.5 Na 0.5 NbO 3 ‐Based Dielectric Ceramics via Multiple Synergistic Strategies115Excellent energy-storage performance in Bi0.5Na0.5TiO3-based lead-free composite ceramics via introducing pyrochlore phase Sm2Ti2O794Enhanced piezo-catalytic H2O2 production over Bi0.5Na0.5TiO3 via piezoelectricity enhancement and surface engineering58Hierarchically polar structures induced superb energy storage properties for relaxor Bi0.5Na0.5TiO3-based ceramics97Superb Energy Storage Capability for NaNbO 3 ‐Based Ceramics Featuring Labyrinthine Submicro‐Domains with Clustered Lattice Distortions123Broad-high operating temperature range and enhanced energy storage performances in lead-free ferroelectrics159Research progress, doping strategies and dielectric-ferroelectric anomalies of rare earth-based Bi0.5Na0.5TiO3 perovskites62High-performance energy storage in BaTiO3-based oxide ceramics achieved by high-entropy engineering74Temperature stability lock of high-performance lead-free relaxor ferroelectric ceramics57Enhanced energy storage properties in BNST-based lead-free relaxor ferroelectric ceramics achieved via a high-entropy strategy45Remarkable energy storage properties in (Bi0.5Na0.5)TiO3-based quasilinear relaxor ferroelectrics via superparaelectric regulation67Domain engineered lead-free Bi0.5Na0.5TiO3-Bi(Ni0.5Hf0.5)O3 relaxor ferroelectric ceramics for energy storage with low electric field applications57Origin of Polarization in Bismuth Sodium Titanate-Based Ceramics56Lead-free ferroelectrics with giant unipolar strain for high-precision actuators62Polar Vortices in Relaxor Ferroelectric Ceramics for High-Efficiency Capacitive Energy Storage85

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