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RESEARCH PAPER · Inorganic Chemistry · 2005

A Second-Order Nonlinear Optical Material Prepared through In Situ Hydrothermal Ligand Synthesis

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A Second-Order Nonlinear Optical Material Prepared through In Situ Hydrothermal Ligand SynthesisOriginalTwo Homochiral Copper(I) Complexes with Strong Luminescence Based on Chiral Phase Transfer Catalysts (PTCs) as Building Blocks114-(4′-Hydroxy-3′-methoxystyryl)-1-methylpyridinium 4-chlorobenzenesulfonate9Syntheses, Crystal Structures, and Luminescent Properties of Three Novel Zinc Coordination Polymers with Tetrazolyl Ligands2712-[(E)-2-(3-Hydroxy-4-methoxyphenyl)ethenyl]-1-methylquinolinium 4-methylbenzenesulfonate14A new Co(ii) coordination solid with mixed oxygen, carboxylate, pyridine and thiolate donors exhibiting canted antiferromagnetism with TC≈ 68 K462-(4-Hydroxystyryl)-1-methylpyridiniump-toluenesulfonate5In situ ligands syntheses involving malic acid in hydrothermal condition26Homochiral 1D Zinc−Quitenine Coordination Polymer with a High Dielectric Constant83Synthesis and characterization of a novel 3D copper(I) coordination polymer with a ligand generated in situ18Synthesis and characterization of two new coordination supramolecular structures from a versatile unsymmetric 5-(4-pyridyl)-1,3,4-oxadiazole-2-thione (Hpot) ligand33One new nickel coordination polymer with an unsymmetric 5-(4-pyridyl)-1,3,4-oxadiazole-2-thione: Synthesis, structure and characterization18SHG Active Crystals of a Remote Functionalized Achiral NLO-phore Assembled through Zinc(II) Complexation21catena-Poly[silver(I)-μ3-5-phenyl-1,2,3,4-tetrazolato-κ3N1:N2:N3]1A new one-dimensional Mn(ii) complex containing two enantiomeric subunits with mixed carboxylate, pyridine and sulfinate bridges11A pcu-type metal–organic framework with spindle [Zn 7 (OH) 8 ] 6+ cluster as secondary building units170Hydro(solvo)thermal synthesis, structures, luminescence of 2-D zinc(ii) and 1-D copper(ii) complexes constructed from pyridine-2,6-dicarboxylic acid N-oxide and decarboxylation of the ligand51Unusual Magnetic Behavior of a 2D Citrate‐Bridged Dysprosium(III) Coordination Polymer24Growth and characterization of a novel nonlinear optical crystal zinc succinate, Zn(C4H4O4)28Radius-dependent assembly of complexes with the rigid unsymmetric ligand 5-(2-pyridyl)-1,3,4-oxadiazole-2-thione: Syntheses, structures and luminescence properties42Synthesis, structures and characterization of two new supramolecular coordination complexes with the ambidentate ligand 5-(4-pyridyl)-1,3,4-oxadiazole-2-thione (Hpot)8Syntheses, structures and properties of a series of organic–inorganic complexes based on methylenediisophthalic acid (H 4 MDIP)45Huge Deuterated Effect on Permittivity in a Metal–Organic Framework42Poly[bis(μ2-5-n-butyltetrazolato-κ2N1:N4)zinc(II)]1Carboxylic acid-dependent assembly of neodymium–organic frameworks with attractive topologies and second-order nonlinear optical and/or magnetic properties28Coordination compounds of bis(5-tetrazolyl)amine with manganese(ii), zinc(ii) and cadmium(ii): synthesis, structure and magnetic properties50Dielectric anisotropy of a homochiral rare-earth metal complex10Tetrazoles126Multiferroic Homochiral Metal−Organic Framework103Hybrid inorganic–organic materials: a new family in condensed matter physics327A tricobalt(II) coordination polymer incorporating in situ generated 5-methyltetrazolate ligands25Preparation, Crystal Structure and Thermal Analyses of 1,5‐Diamino‐4‐hydro‐1,2,3,4‐tetrazolium 3,5‐Dihydroxy‐2,4,6‐trinitrophenolate11Hybrid inorganic-organic materials: a new family in condensed matter physics83Copper(I) Bromide-Mediated Coupling of Imidazoles. Trapping and X-Ray Crystal Structures of the Reaction Intermediates20A 3D-diamond-like tetrazole-based Zn(II) coordination polymer: Crystal structure, nonlinear optical effect and luminescent property56Molecular Packing Variation of Crimpled 2D Layers and 3D Uncommon 65.8 Topology: Effect of Ligand on the Construction of Metal−Quinoline-6-carboxylate Polymers43Two copper(II) coordination polymers containing atza ligand [atza = 5-aminotetrazole-1-acetato]28Assembly of a Chiral Bikitaite Zeolite Metal−Organic Framework Based on the Asymmetrical Tetrahedral Building Blocks38Isotope Effect on SHG Response and Ferroelectric Properties of a Homochiral Zinc Coordination Compound Containing Tetrazole Ligand98Topology Analysis and Nonlinear-Optical-Active Properties of Luminescent Metal−Organic Framework Materials Based on Zinc/Lead Isophthalates139Synthesis and structural characterization of heavier group 1 methyl tetrazolate complexes: New bridging coordination modes of the tetrazolate ligand21Novel 3-D PtS-like Tetrazolate-Bridged Manganese(II) Complex Exhibiting Spin-Canted Antiferromagnetism and Field-Induced Spin-Flop Transition96Manganese(II) coordination polymers with bis(5-tetrazolyl)methane: Synthesis, structure and magnetic properties14Unusual hydrothermal synthesis of a heteroaromatic macrocyclic complex5In situ synthesis of 5-substituted-tetrazoles and metallosupramolecular co-ordination polymers39One novel and unprecedented one-dimensional zinc coordination polymer with a N,O-donor chelating phenolic ligand, 3-n-butyl-2-(2-hydroxyphenyl)-3H-benzimidazole: synthesis, structure, characterization, photoluminescence and theoretical calculations9A novel 3D Mn(II) coordination polymer involving 4,4′-dipyridylsulfide and 4,4′-dipyridyltrisulfide obtained by in situ ligand formation from 4,4′-dipyridyldisulfide56In situ cyclodehydration of iminodiacetic acid into 2,5-diketopiperazine-1,4-diacetate in lanthanide-based coordination polymers21New (3,4)-connected intrinsically chiral topology observed in a homochiral coordination polymer from achiral precursors30Entangled zinc–ditetrazolate frameworks involving in situ ligand synthesis and topological modulation by various secondary N-donor ligands34U(VI) and Zn(II) coordination complexes with 5-[N-acetato(4-pyridyl)]tetrazolate anions14In situ syntheses of two tetrazole coordination polymers14Synthesis, structure and fluorescence of novel cadmium(II) and silver(I) complexes with in situ ligand formation of 1-(5-tetrazolyl)-4-(imidazol-1-ylmethyl)benzene16Solvent-dependent luminescent Cu(I) framework based on 5-(4-pyridyl)tetrazole31Bis[5-(2-amino-3-pyridyl)tetrazolato]copper(II)0Hydrothermal syntheses, crystal structures and luminescent properties of zinc(II) coordination polymers constructed by bifunctional tetrazolate-5-carboxylate ligands63In situ solvothermal syntheses of a heteronuclear copper(I)-alkaline metallic tetrazole-based coordination polymer48Synthesis and structures of two novel non-centrosymmetric metal–organic polymers containing 2-(pyridin-4-yl)-1H-imidazole-4,5-dicarboxylic acid ligands47Construction and photoluminescence properties of two novel zinc(II) and cadmium(II) benzyl-tetrazole coordination polymers36A Series of Cation-Templated, Polycarboxylate-Based Cd(II) or Cd(II)/Li(I) Frameworks with Second-Order Nonlinear Optical and Ferroelectric Properties118Synthesis and characterization of a novel 2D zinc(II) coordination polymer5Three Coordination Polymers Based on 1H-Tetrazole (HTz) Generated via in Situ Decarboxylation: Synthesis, Structures, and Selective Gas Adsorption Properties85Five Metal(II) Coordination Polymers Constructed from Two Vanillin Derivatives: From Discrete Structure to 3D Diamondoid Network36A spontaneously resoluted zinc–organic framework with nonlinear optical and ferroelectric properties generated from tetrazolate-ethyl ester ligand33Syntheses, topological analyses, and NLO-active properties of new Cd(ii)/M(ii) (M = Ca, Sr) metal–organic frameworks based on R-isophthalic acids (R = H, OH, and t-Bu)63Synthesis, structure and hydrogen adsorption of a novel porous metal–organic framework, Mn9(btt)2(HCOO)12·0.7DMF·0.9H2O, where btt = 1,3,5-benzenetristetrazolate93D copper coordination polymers based on N-heterocyclic ligands with different topology9NaVO2(IO3)2(H2O): A Unique Layered Material Produces A Very Strong SHG Response143Syntheses, crystal structures and properties of a series of 3D cadmium coordination polymers with different topologies33Noncentrosymmetric and Homochiral Metal−Organic Frameworks of (S)-2-(1H-Imidazole1-yl) Propionic Acid24Construction of two mercury(II) coordination frameworks involving in situ tetrazole ligand synthesis22Syntheses, Structures, and Physical Properties of Camphorate Coordination Polymers Controlled by Semirigid Auxiliary Ligands with Variable Coordination Positions and Conformations59Antibacterial, spectral and thermal aspects of some novel first transition metal‐based heterochelates6Triazoles and tetrazoles: Prime ligands to generate remarkable coordination materials989Experimental and computational approach of understanding the gas adsorption in amino functionalized interpenetrated metal organic frameworks (MOFs)64In situ oxalate formation during hydrothermal synthesis of uranyl hybrid materials50Tetraaquabis[5-(3-pyridyl-κN)pyrimidine]zinc(II) bis(trifluoromethanesulfonate): a novel cationic complex and three-dimensional hydrogen-bonded network2Zinc(II) Complexes with a Versatile Multitopic Tetrazolate-Based Ligand Showing Various Structures: Impact of Reaction Conditions on the Final Product Structures47Metal–Organic Frameworks Based on Unprecedented Trinuclear and Pentanuclear Metal–Tetrazole Clusters as Secondary Building Units60Rational Synthesis of Noncentrosymmetric Metal–Organic Frameworks for Second-Order Nonlinear Optics1005Novel tetrazole-based metal–organic frameworks constructed from in situ synthesize bifunctional ligands: syntheses, structure and luminescent properties40Direct Synthesis and Characterization of New Copper(II) and Zinc(II) 5‐R‐Tetrazolato Complexes [R = Me, Ph, 4‐Py] with Ethylenediamine and DMSO as Coligands22Hydrothermal syntheses and crystal structures of a series of 3d–4f heterometallic tetrazole-based coordination polymers9A Novel Zinc(II)‐Organic Coordination Framework Involving in situ Tetrazole Ligand Synthesis: Crystal Structure and Luminescent Properties2Luminescent, second-order NLO and magnetic properties of the hydrogen-bond based network derived from 2,2′-bipyridine-6,6′-dicarboxylate16The three-dimensional coordination network in poly[di-μ3-cyanido-μ5-[5-(pyridin-4-yl)tetrazolato]-tricopper(I)]5Hydrothermal syntheses, crystal structures and properties of three new zinc(II) coordination polymers with in situ formed 5-(3-pyridyl)tetrazolate5Barium Carboxylate Metal–Organic Framework – Synthesis, X‐ray Crystal Structure, Photoluminescence and Catalytic Study47Cuprous Halide Coordination Polymers Based on Cationic [Cu4X2] and [Cu3X] Clusters and [Cu2Br]n Layers with Tetrazolates as Assembling Ligands: Highly Connected Networks and Halide‐Dependent Luminescence24A magnesium-based multifunctional metal–organic framework: synthesis, thermally induced structural variation, selective gas adsorption, photoluminescence and heterogeneous catalytic study51A series of coordination polymers based on a 5-(3′-amine-1′H-pyrazol-4′-yl)-1H-tetrazole ligand: synthesis, structure and properties9Coordination polymers of tetrazole-yl acylamide with octahedrally coordinated divalent transition metals: the effects of metal centers and side-groups on the structural topologies and symmetries9From achiral tetrazolate-based tectons to chiral coordination networks: effects of substituents on the structures and NLO properties18Investigation on the prime factors influencing the formation of entangled metal–organic frameworks144Metal–Organic Frameworks for Second-Order Nonlinear Optics12Mg(ii)-induced second-harmonic generation based on bis-monodentate coordination mode of thiobarbiturate14Zinc(ii) coordination compounds based on in situ generated 3-(5H-tetrazol)benzaldehyde with diverse modes: hydrothermal syntheses, crystal structures and photoluminescent properties18Hydrogen bonding and coordination bonding in the electronically excited states of Cu2(L)2 (L=5-(4-pyridyl)tetrazole)MeOH: A TDDFT study9Photoluminescent 3D Lanthanide–Organic Frameworks Based on 2,5-Dioxo-1,4-piperazinylbis(methylphosphonic) Acid Formed via in Situ Cyclodehydration of Glyphosates29Synthesis, structural characterization and luminescence studies of three novel complexes of asymmetric 5-(1-imidazolyl)pyrimidine ligand1A novel Ag(I) coordination polymers based on 2-(pyridin-4-yl)-1H-imidazole-4,5-dicarboxylic acid: Syntheses, structures, ferroelectric, dielectric and optical properties24A series of novel metal–organic coordination polymers constructed from the new 5-(4-imidazol-1-yl-phenyl)-2H-tetrazole spacer and aromatic carboxylates: Synthesis, crystal structures, and luminescence properties17Three new Zn(II) coordination polymers with tetrazole-1-carboxylate ligand: Crystal structures and luminescent properties7Nickel-catalyzed Decarbonylative and Decarboxylative Cycloaddition of Isatoic Anhydrides with Alkynes16Acentric and chiral heterometallic inorganic–organic hybrid frameworks mediated by alkali or alkaline earth ions: synthesis and NLO properties31A Coordination Polymer Involving Two Different Binuclear Co(II) Clusters Obtained by In Situ Ligand Formation From 4,4′-Dipyridyldisulfide1Rhodium Enalcarbenoids: Direct Synthesis of Indoles by Rhodium(II)‐Catalyzed [4+2] Benzannulation of Pyrroles109Rhodium Enalcarbenoids: Direct Synthesis of Indoles by Rhodium(II)‐Catalyzed [4+2] Benzannulation of Pyrroles25A Highly Stable 3D Acentric Zinc Metal–Organic Framework Based on Two Symmetrical Flexible Ligands: High Second-Harmonic-Generation Efficiency and Tunable Photoluminescence32Entangled Two-Dimensional Coordination Networks: A General Survey285Utilization of a ligand containing 2,2′-bipyridyl and tetrazolate groups to construct a 2D Co( ii ) coordination polymer: spin canting and metamagnetism20Assembly of Zn-metal organic frameworks based on a N-rich ligand: selective sorption for CO 2 and luminescence sensing of nitro explosives29A new three-dimensional Cd II supramolecular framework constructed from the 1-[(1 H -tetrazol-5-yl)methyl]-1,4-diazoniabicyclo[2.2.2]octane ligand5Two New Nonlinear Optical and Ferroelectric Zn(II) Compounds Based on Nicotinic Acid and Tetrazole Derivative Ligands84Crystal Structure, Cytotoxicity and Interaction with DNA of Zinc (II) Complexes with o-Vanillin Schiff Base Ligands31Crystal structure, spectroscopic studies and non‐linear optical properties of 2‐amino‐3‐nitropyridinium trichloroacetate15Azide Chemistry – An Inorganic Perspective, Part II[‡][3+2]‐Cycloaddition Reactions of Metal Azides and Related Systems76A novel Zn6Co3 cluster-based heterometallic coordination polymer with PMG3− linker formed via in situ decarboxylation from H4PMIDA5In situ synthesis, SHG and luminescent property of a novel acentric 3D-diamond-like zinc tetrazole polymer8Metal–organic frameworks for electronics: emerging second order nonlinear optical and dielectric materials59Gold‐Catalyzed CH Annulation of Anthranils with Alkynes: A Facile, Flexible, and Atom‐Economical Synthesis of Unprotected 7‐Acylindoles308Goldkatalysierte C‐H‐Anellierung von Anthranilen mit Alkinen: flexible, atomökonomische Synthese ungeschützter 7‐Acylindole75Azide-bridged Cu( ii ), Mn( ii ) and Co( ii ) coordination polymers constructed with a bifunctional ligand of 6-(1H-tetrazol-5-yl)-2,2′-bipyridine20Metal–organic frameworks as competitive materials for non-linear optics312Supramolecular Interactions Induced Chirality Transmission, Second Harmonic Generation Responses, and Photoluminescent Property of a Pair of Enantiomers from in Situ [2 + 3] Cycloaddition Synthesis18Synthesis, Characterization, and Density Functional Theory Analysis of Uranium and Thorium Complexes Containing Nitrogen-Rich 5-Methyltetrazolate Ligands40Expedient Synthesis of Substituted Benzoheterocycles using 2‐Butoxy‐2,3‐dihydrofurans as [4+2] Benzannulation Reagents40Synthesis, structure and properties of a 3D acentric coordination polymer with noninterpenetrated (10,3)-d topology3Three-Dimensional Non-Centrosymmetric Ba(II)/Li(I)–Imidazolecarboxylate Coordination Polymers: Second Harmonic Generation and Blue Fluorescence11A novel 3-D photoluminescent cuprous chloride polymer based on bifunctional imidazolate/tetrazolate bridges15pH-Switchability and Second-Order Nonlinear Optical Properties of Monocyclopentadienylruthenium(II)/iron(II) Tetrazoles/Tetrazolates: Synthesis, Characterization, and Time-Dependent Density Functional Theory Calculations11Structural Diversity and Vibrational Spectra of Nine Cu(I)-Cyanide Metal–Organic Frameworks with in Situ Generated N-Heterocyclic Ligands31An unusual cuprous iodide polymer incorporating I − , I 2 and I 3 − structural units13pH-Controlled Assembly of 3D and 2D Zinc-Based Metal-Organic Frameworks with Tetrazole Ligands31Temperature-dependent crystal structure and fluorescence properties of a tetranuclear copper(I) cluster from in situ [2 + 3] cycloaddition synthesis5A Nonlinear Optically Active Bismuth–Camphorate Coordination Polymer13Structural, elastic, electronic, phonon, dielectric and optical properties of Bi3TeBO9 from first-principles calculations26Silver(I) and Copper(I) Complexes from Homoleptic to Heteroleptic: Synthesis, Structure and Characterization0Impressive second harmonic generation response in a novel phase-matchable NLO-active MOF derived from achiral precursors38Controlled Growth of the Noncentrosymmetric Zn(3-ptz) 2 and Zn(OH)(3-ptz) Metal–Organic Frameworks13Hexanuclear manganese(III) single-molecule magnets based on oxime and azole-type ligands5In situ [2 + 3] cycloaddition synthesis, crystal structures, strong SHG responses and fluorescence properties of three novel Zn coordination polymers13Giant Enhancement of Second Harmonic Generation Accompanied by the Structural Transformation of 7‐Fold to 8‐Fold Interpenetrated Metal–Organic Frameworks (MOFs)94Giant Enhancement of Second Harmonic Generation Accompanied by the Structural Transformation of 7‐Fold to 8‐Fold Interpenetrated Metal–Organic Frameworks (MOFs)35Recent Progress in 2D Metal‐Organic Frameworks for Optical Applications149A nonlinear optical cadmium( ii )-based metal–organic framework with chiral helical chains derived from an achiral bent dicarboxylate ligand15Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications928Synthesis of Tetrazole Derivatives13Hybrid Metal‐Halide Infrared Nonlinear Optical Crystals of (TMEDA)MI5 (M = Sb, Bi) with High Stability36Distinct nonlinear optical responses in three pairs of 2D homochiral Ag( i ) enantiomers modulated by dicarboxylic acid ligands25Prediction of Large Second Harmonic Generation in the Metal-Oxide/Organic Hybrid Compound CuMoO3(p2c)2

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  2. 4-(4′-Hydroxy-3′-methoxystyryl)-1-methylpyridinium 4-chlorobenzenesulfonate

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  3. Syntheses, Crystal Structures, and Luminescent Properties of Three Novel Zinc Coordination Polymers with Tetrazolyl Ligands

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  4. 2-[(E)-2-(3-Hydroxy-4-methoxyphenyl)ethenyl]-1-methylquinolinium 4-methylbenzenesulfonate

    Acta Crystallographica Section E Structure Reports Online · 2005-09-14

    Boonwasana JINDAWONG, Suchada Chantrapromma, Hoong‐Kun Fun, Chatchanok Karalai B

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  5. A new Co(ii) coordination solid with mixed oxygen, carboxylate, pyridine and thiolate donors exhibiting canted antiferromagnetism with TC≈ 68 K

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  34. A 3D-diamond-like tetrazole-based Zn(II) coordination polymer: Crystal structure, nonlinear optical effect and luminescent property

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  35. Molecular Packing Variation of Crimpled 2D Layers and 3D Uncommon 65.8 Topology: Effect of Ligand on the Construction of Metal−Quinoline-6-carboxylate Polymers

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