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RESEARCH PAPER · Crystal Growth & Design · 2006

A Novel Chiral Cd(II) Coordination Polymer Based on Achiral Unsymmetrical 3-Amino-1,2,4-triazole with an Unprecedented μ4-Bridging Mode

Wei Li, Hongpeng Jia, Zhanfeng Ju, Jie Zhang

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A Novel Chiral Cd(II) Coordination Polymer Based on Achiral Unsymmetrical 3-Amino-1,2,4-triazole with an Unprecedented μ4-Bridging ModeOriginalThe first 1D twofold interpenetrating metal–organic network generated by 1D triple helical chains with nanosized cages30Novel material for second harmonic generation: 3-Amino-1,2,4-triazolinium(1+) hydrogen l-tartrate26Synthesis and Structural Determination of Four Novel Metal−Organic Frameworks in a Zn−3-Amino-1,2,4-Triazole System51Chiral Symmetry Breaking by Chemically Manipulating Statistical Fluctuation in Crystallization178Chiral Symmetry Breaking by Chemically Manipulating Statistical Fluctuation in Crystallization13Nonlinear optical and ferroelectric properties of a 3-D Cd(ii) triazolate complex with a novel (63)2(610·85) topology82Syntheses, structures, luminescence, and magnetism of four 3D lanthanide 5-sulfosalicylates31Thermal behavior of some new triazole derivative complexes13Coordination Polymers with the Angular Dipyridyl Ligand 1,3,4-Thiadiazole-2,5-di-3-pyridyl: Influence of Analogue Dipyridyl Ligands and Bridging Anions on Structural Diversity56A new 3D supramolecular architecture constructed from the overlapping of ladder-like 1,2,4-triazole-bridging Ag(I) chains2Four Zn(II)/Cd(II)-3-amino-1,2,4-triazolate frameworks constructed by in situ metal/ligand reactions: Structures and fluorescent properties41Synthesis, structure and fluorescence of a new 1,2,4-triazole-bridging manganese(II) 2D layered framework12Two cadmium(II) 1-D coordination polymers, {[Cd2(μ-Cl)4Cl2(CH3OH)(H2O)] · (H-aql)2} n and [Cd(μ-Cl)2(aql)] n : synthesis, crystal structures and fluorescent properties9Syntheses, structures and fluorescence studies of two new cadmium(II) pyridyl-diphosphonates28Inclusion cages constructed from trinuclear linear ZnII/CoII building blocks3Two new d10 2D layered frameworks based on 1,2,4-triazole bridge: Syntheses, structures, and fluorescence18Pillaring Zn-Triazolate Layers with Flexible Aliphatic Dicarboxylates into Three-Dimensional Metal−Organic Frameworks109Solid chemistry of the ZnII/1,2,4-triazolate/anion system: Separation of 2D isoreticular layers tuned by the terminal counteranions X (X=Cl−, Br−, I−, SCN−)19A novel 3D coordination polymer [Cd15(μ4-Mtta)12(μ3-Mtta)6(μ3-SO4)4(μ3-OH)4]: Synthesis, structure and solid properties11Synthesis, X-ray Structures, and Fluorescent Properties of Coordination Networks Constructed from 2-(2-Pyridinyl-benzimidazolyl) Acetic Anion73Hydrothermal Synthesis, Structure and Fluorescence of a New Triazole-bridging Zinc(II) 2D Layered Framework3An amine-functionalized metal organic framework for preferential CO2 adsorption at low pressures433Structural variability of Cd(II) and Co(II) mixed-ligand coordination polymers: effect of ligand isomerism and metal-to-ligand ratio46Theoretical and matrix isolation FTIR studies of 3-amino-1,2,4-triazole and its isomers47Thermal behaviour of new Ni(II) and Cu(II) complexes with macrocyclic ligands functionalised with 1,2,4-triazole5Design and construction of two new polymers featuring macrocyclic subunits based on a rigid clamp-like ligand15In-Situ X-ray Diffraction Studies of Host−Guest Properties in Nanoporous Zinc-Triazolate-Based Framework Materials14Syntheses of Metal−2-(Pyridin-4-yl)-1H-imidazole-4,5-dicarboxylate Networks with Topological Diversity: Gas Adsorption, Thermal Stability and Fluorescent Emission Properties172Experimental and DFT computational studies on 5-benzyl-4-(3,4-dimethoxyphenethyl)-2H-1,2,4-triazol-3(4H)-one21Four novel Zn(II)/Cd(II) metal–organic frameworks constructed from 4′-(4-pyridyl)-4,2′:6′,4″-terpyridine: hydrothermal synthesis, crystal structures, and luminescent properties71Ag(I)-Mediated In situ Dehydrogenative Coupling of 3-Amino-1,2,4-triazole into 3,3′-Azobis(1,2,4-triazole) in Cd(II) Coordination Polymers20Capturing in situ generated NHCH–NNH molecule via the templating synthesis of a 4-connected open Cd(ii) framework15Triazole based cadmium(II) anionic framework with 2-dimensional helical channels: Ionic liquid induced synthesis10Anion assisted self-assembly of a Ni(II) complex into metallo-supramolecular network involving H-bonded synthons as nodes20Metal–organic coordination architectures of bis(1,2,4-triazole) ligands bearing different spacers: syntheses, structures and luminescent properties19Synthesis and structures of helical and meso-helical coordination polymers directed by the conformation restriction of flexible/angular pyridine-containing ligands17An experimental and DFT computational study on 4-(3-(1H-imidazol-1-yl)propyl)-5-methyl-2H-1,2,4-triazol-3(4H)-one monohydrate47One Cadmium(II) Complex of a New Polydentate Double Schiff Base Ligand Derived from 1,10-phenanthroline: Syntheses, Structures, and Fluorescent Property3Two di-nuclear Cd(II) and Mn(II) complexes with one new poly-dentate double Schiff base ligand derived from 1,10-phenanthroline: Syntheses, structures, and physical properties6Novel Structural Diversity of Triazolate-Based Coordination Polymers Generated Solvothermally with Anions42Metal–organic frameworks constructed with 1,2,4-triazol-1-ylacrylic acid ligand: syntheses and crystal structures2Two Cd(II) Complexes with One New Polydentate Double Schiff Base Ligand Derived from 1,10-phenanthroline and Two Anionic Ligands: Syntheses, Structures, and Fluorescent Properties1Syntheses, Structures, and Photoluminescence of a Series of Three-Dimensional Cd(II) Frameworks with a Flexible Ligand, 1,5-Bis(5-tetrazolo)-3-oxapentane118Inorganic–organic hybrid compounds based on molybdenum oxide chains and tetrazolate-bridged polymeric silver cations52A 2D homochiral inorganic–organic framework exhibiting a spin–flop transition20Detailed investigations of phase transitions and magnetic structure in Fe(iii), Mn(ii), Co(ii) and Ni(ii) 3,4,5-trihydroxybenzoate (gallate) dihydrates by neutron and X-ray diffraction55Role of molar-ratio, temperature and solvent on the Zn/Cd 1,2,4-triazolate system with novel topological architectures97The coordination chemistry of Zn(ii), Cd(ii) and Hg(ii) complexes with 1,2,4-triazole derivatives147Molecular self-assembly of cadmium-triazolate complexes via hydrogen bonding: Synthesis, structures and photoluminescent properties22Bitriazole bridged manganese(II) framework with weak ferromagnet behavior7Three new complexes synthesized from an imidazole-based dicarboxylate ligand containing hydroxymethyl group31Two novel Zn(II) coordination polymers based on a carboxylate functionalized imidazophenanthroline derivative ligand17Axially chiral metal–organic frameworks produced from spontaneous resolution with an achiral pyridyl dicarboxylate ligand52A Novel Twofold Interpenetrating 2D (3,5)-Connected Cd(II) Coordination Framework with (52.6)(55.64.7) Topology9Rational Synthesis of Noncentrosymmetric Metal–Organic Frameworks for Second-Order Nonlinear Optics1005Competition and Cooperativity in Carbon Dioxide Sorption by Amine‐Functionalized Metal–Organic Frameworks135Competition and Cooperativity in Carbon Dioxide Sorption by Amine‐Functionalized Metal–Organic Frameworks27Keggin POM-based 3D framework tuned by silver polymeric motifs: structural influences of tetrazolate functional groups41Polyoxoanion-enveloped Ag/ptz inorganic–organic hybrid system: From a single to a double template59Secondary ligand-directed assembly of metal–organic coordination polymers based on a 2-(pyridin-4-yl)-1H-imidazole-4,5-dicarboxylic acid ligand: Syntheses, structures and photoluminescent properties51Crystal structure, spectroscopic investigations and density functional studies of 4-(4-methoxyphenethyl)-5-benzyl-2H-1,2,4-triazol-3(4H)-one monohydrate34One-Dimensional Zinc and Cadmium Coordination Polymers Constructed by Dicyanamide Anions: Synthesis, Crystal Structure, and Fluorescent Property1Chiral Supramolecular Frameworks Based on Chiral Metallocycles: Crystal Structures and Photophysical Properties32One- and two-dimensional coordination polymers of substituted tetrazoles with cadmium(II)14Complexes of unsymmetric bis-hydrazide ligands: crystal structures and properties6Assembly of Two 3D Porous Metal–Organic Frameworks Based on 1,2,3-Triazole-4,5-dicarboxylate Exhibiting Novel Coordination Modes31Spectroscopy studies, X-ray diffraction and DFT, HF calculations of 4-allyl-5-(thiophen-2-ylmethyl)-2H-1,2,4-triazol-3(4H)-one13Effect of pH/metal ion on the structure of metal–organic frameworks based on novel bifunctionalized ligand 4′-carboxy-4,2′:6′,4′′-terpyridine74Alkyl substituents introduced into novel d 10 -metalimidazole-4,5-dicarboxylate frameworks: synthesis, structure diversities and photoluminescence properties23Design of microporous mixed zinc–nickel triazolate metal–organic frameworks with functional ligands11Hydrothermal syntheses and characterization of a series of luminescent Cd(ii) frameworks with pyridine-based and benzene-based bis-triazole ligands46Hydrothermal synthesis and characterization of a series of luminescent Zn(ii) and Cd(ii) coordination polymers with the new versatile multidentate ligand 1,3-di-(1,2,4-triazol-4-yl)benzene34Four manganese(II) 3-amino-1,2,4-triazole complexes incorporated with different polycarboxylate coligands: Synthesis, structures and magnetism16A 3D Zn(II) coordination polymer with a new semi-rigid tripodal ligand tecton showing 4-connected three-fold interpenetrating diamond network and helical character17A Series of Coordination Polymers Exhibiting Dual Chiral Features and Diverse Interhelical Interactions18Syntheses, structures and luminescence of a series of 4d–4f heterometallic coordination polymers constructed by 4,4′-oxybis(benzoicacid)2A novel 2D chiral silver(I) coordination polymer assembled from 5-sulfosalicylic acid and (2S,4R)-4-hydroxyproline: Synthesis, crystal structure, HOMO–LUMO and NBO analysis20Metal–organic coordination polymers based on imidazolyl- and benzimidazolyl-containing 4,4′-bipy type ligands6Hydrothermal Synthesis, Crystal Structures, and Characterization of Two Copper Complexes With 3-Amino-1,2,4-Triazole4Tuning the dimension of POM-based inorganic–organic hybrids from 3D self-penetrating framework to 1D poly-pendant chain via changing POM clusters and introducing secondary spacers34Structural variability, topological analysis and photocatalytic properties of neoteric Cd( ii ) coordination polymers based on semirigid bis(thiazolylbenzimidazole) and different types of carboxylic acid linkers82Solvothermal Synthesis of Four Polyoxometalate-Based Coordination Polymers Including Diverse Ag(I)···π Interactions61Construction of 1D to 3D cadmium(II) coordination polymers from 4-(imidazol-1-yl)-benzoic acid: Effect of bridging anions14Four metal–organic frameworks constructed with hydroxylphenyl imidazole dicarboxylate: Syntheses, crystal structures and properties14Effect of Polycarboxylate Coligands from Linear to V‐shaped CuII Coordination Polymers Based on a Rigid Tripodal Ligand3Unusual solvent influence of formamide on the structural variations of chiral and achiral Mn(II) complexes based on tetrachlorophthalate5A three-dimensional metal–organic framework with a pcu net constructed by zinc(II)/3-amino-1,2,4-triazole layer and an inorganic sulfate pillar4A Zn-oxalate helix linked by a water helix: spontaneous chiral resolution of a Zn helical coordination polymer8Chiral crystallization and optical properties of three metal complexes based on two non-centrosymmetric tripodal ligands16Manipulating connecting nodes through remote alkoxy chain variation in coordination networks with 4′-alkoxy-4,2′:6′,4′′-terpyridine linkers16Tuning the topology structures of polymolybdate-based hybrids from interpenetrated framework to interdigitated architecture via changing polymolybdate clusters14Two novel metal–organic coordination polymers based on diphosphonate and oxalate: Synthesis, structures and properties11A molecular crown analogue templated by Keggin polyanions: synthesis, structure, and electrochemical and luminescent properties3Synthesis, Structure, and Magnetic Characterization of a Series of Iron(II) Coordination Frameworks with 2, 6‐Bis(1, 2,4‐triazole‐4‐yl)pyridine2Hydrothermal synthesis and characterization of a series of luminescent Ag( i ) coordination polymers with two new multidentate bis-(1,2,3-triazole) ligands: structural diversity, polymorphism and photoluminescent sensing39The factors affecting the assembly of Keggin–metal–bimb systems: charge/polarity of Keggin polyanions and coordination modes of metal cations20Synthesis, Structures, Magnetic and Luminescent Properties of a Series of Iron(II) and Zinc(II) Coordination Frameworks with Versatile 4‐Substitued 1, 2,4‐Triazole Ligands10A new POMOF consisting of [VW12]4− clusters and metal-organic nanotubes: Synthesis, structure, electrocatalytic and luminescent properties17Two novel two-dimensional copper(II) coordination polymers with 1-(4-aminobenzyl)-1,2,4-triazole: Synthesis, crystal structure, magnetic characterization and absorption of anion pollutants7Self-assembly of new M( ii ) coordination polymers based on asymmetric 1,3,4-oxadiazole-containing ligands: effect of counterions and magnetic properties17Micropore Formation of [Zn2(Oxac) (Taz)2]·(H2O)2.5 via CO2 Adsorption3Three pyridyl modified Cu(II)/Cd(II)-diphosphonates: Syntheses, crystal structures and properties9Molecular structures and fluorescence property of Zn(II), Cd(II) complexes of 3-pyridyl-5-aryl-(1 H )-1,2,4-triazoles14Stabilizing volatile azido in a 3D nitrogen-rich energetic metal–organic framework with excellent energetic performance27Resolution of chiral nitrogen atoms in 1D helical coordination polymers5Synthesis of Porous Coordination Polymers Comprising Mixed Ligands of Triazole and Amino Triazole under Magnetic Fields and Its Effects in Enhance CO2 Adsorptivity1Synthesis, Structure, and Properties of Cadmium(II) Centered Chiral Coordination Polymer based on (R)‐6‐(1‐Carboxyethoxy)‐2‐naphthoic Acid13Cu-Enabled [3 + 2] Annulation of In Situ Formed Nitrile Ylides with Aryldiazonium Salts: Access to 5-Cyano-1,2,4-Triazoles37Synthesis and Structural Analysis of a Semi-Rigid Cd(II) Coordination Polymer1Amine-Functionalized Metal-Organic Frameworks: from Synthetic Design to Scrutiny in Application144Supramolecular architectures of three monomer Zn(II)/Ni(II)/Co(II) complexes with sulfonate functionalized dipyrazinylpyridine derivative ligand: Hirshfeld surface analyses, luminescent and magnetic properties2Crystal growth, hirshfeld surfaces and quantum chemical investigations of 3-amino-1,2,4-triazolinium (1 +) hydrogen l-tartrate single crystal for nonlinear optical applications6Investigation of growth, optical, thermal, mechanical, electrical, laser damage threshold properties of 3-amino-1,2,4-triazolium benzoate (3ATB) single crystals for nonlinear optical applications22A two-fold interpenetrated mixed-ligands acentric 3D coordination polymer Zn(OBA)(DIB)·0.5H2O: Topological analysis, fluorescent and second-order NLO properties7An engineered POSS drug delivery system for copper( ii ) anticancer metallodrugs in a selective application toward melanoma cells2Adsorption Properties of Hydrophobic Porous Coordination Polymers of Zinc-Oxalic Acid with Triazole and Amino Triazole Mixture Ligands0Breaking the SHG-stability trade-off in UV nonlinear optical materials by polar-layer-dense-locking4

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  2. Novel material for second harmonic generation: 3-Amino-1,2,4-triazolinium(1+) hydrogen l-tartrate

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  6. Nonlinear optical and ferroelectric properties of a 3-D Cd(ii) triazolate complex with a novel (63)2(610·85) topology

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  10. A new 3D supramolecular architecture constructed from the overlapping of ladder-like 1,2,4-triazole-bridging Ag(I) chains

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  11. Four Zn(II)/Cd(II)-3-amino-1,2,4-triazolate frameworks constructed by in situ metal/ligand reactions: Structures and fluorescent properties

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  12. Synthesis, structure and fluorescence of a new 1,2,4-triazole-bridging manganese(II) 2D layered framework

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  13. Two cadmium(II) 1-D coordination polymers, {[Cd2(μ-Cl)4Cl2(CH3OH)(H2O)] · (H-aql)2} n and [Cd(μ-Cl)2(aql)] n : synthesis, crystal structures and fluorescent properties

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  17. Pillaring Zn-Triazolate Layers with Flexible Aliphatic Dicarboxylates into Three-Dimensional Metal−Organic Frameworks

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  19. A novel 3D coordination polymer [Cd15(μ4-Mtta)12(μ3-Mtta)6(μ3-SO4)4(μ3-OH)4]: Synthesis, structure and solid properties

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  24. Theoretical and matrix isolation FTIR studies of 3-amino-1,2,4-triazole and its isomers

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  25. Thermal behaviour of new Ni(II) and Cu(II) complexes with macrocyclic ligands functionalised with 1,2,4-triazole

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  27. In-Situ X-ray Diffraction Studies of Host−Guest Properties in Nanoporous Zinc-Triazolate-Based Framework Materials

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  29. Experimental and DFT computational studies on 5-benzyl-4-(3,4-dimethoxyphenethyl)-2H-1,2,4-triazol-3(4H)-one

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  31. Ag(I)-Mediated In situ Dehydrogenative Coupling of 3-Amino-1,2,4-triazole into 3,3′-Azobis(1,2,4-triazole) in Cd(II) Coordination Polymers

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  32. Capturing in situ generated NHCH–NNH molecule via the templating synthesis of a 4-connected open Cd(ii) framework

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  33. Triazole based cadmium(II) anionic framework with 2-dimensional helical channels: Ionic liquid induced synthesis

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  34. Anion assisted self-assembly of a Ni(II) complex into metallo-supramolecular network involving H-bonded synthons as nodes

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  35. Metal–organic coordination architectures of bis(1,2,4-triazole) ligands bearing different spacers: syntheses, structures and luminescent properties

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  36. Synthesis and structures of helical and meso-helical coordination polymers directed by the conformation restriction of flexible/angular pyridine-containing ligands

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  37. An experimental and DFT computational study on 4-(3-(1H-imidazol-1-yl)propyl)-5-methyl-2H-1,2,4-triazol-3(4H)-one monohydrate

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  38. One Cadmium(II) Complex of a New Polydentate Double Schiff Base Ligand Derived from 1,10-phenanthroline: Syntheses, Structures, and Fluorescent Property

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  39. Two di-nuclear Cd(II) and Mn(II) complexes with one new poly-dentate double Schiff base ligand derived from 1,10-phenanthroline: Syntheses, structures, and physical properties

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  40. Novel Structural Diversity of Triazolate-Based Coordination Polymers Generated Solvothermally with Anions

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  42. Two Cd(II) Complexes with One New Polydentate Double Schiff Base Ligand Derived from 1,10-phenanthroline and Two Anionic Ligands: Syntheses, Structures, and Fluorescent Properties

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  43. Syntheses, Structures, and Photoluminescence of a Series of Three-Dimensional Cd(II) Frameworks with a Flexible Ligand, 1,5-Bis(5-tetrazolo)-3-oxapentane

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  44. Inorganic–organic hybrid compounds based on molybdenum oxide chains and tetrazolate-bridged polymeric silver cations

    Dalton Transactions · 2010-12-01

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  45. A 2D homochiral inorganic–organic framework exhibiting a spin–flop transition

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  46. Detailed investigations of phase transitions and magnetic structure in Fe(iii), Mn(ii), Co(ii) and Ni(ii) 3,4,5-trihydroxybenzoate (gallate) dihydrates by neutron and X-ray diffraction

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  47. Role of molar-ratio, temperature and solvent on the Zn/Cd 1,2,4-triazolate system with novel topological architectures

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  48. The coordination chemistry of Zn(ii), Cd(ii) and Hg(ii) complexes with 1,2,4-triazole derivatives

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  49. Molecular self-assembly of cadmium-triazolate complexes via hydrogen bonding: Synthesis, structures and photoluminescent properties

    Inorganic Chemistry Communications · 2011-02-23

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  50. Bitriazole bridged manganese(II) framework with weak ferromagnet behavior

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