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RESEARCH PAPER · Inorganic Chemistry · 2005

Non-Interpenetrating Transition Metal Diorganophosphate 2-Dimensional Rectangular Grids from Their 1-Dimensional Wires: Structural Transformations under Mild Conditions

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Non-Interpenetrating Transition Metal Diorganophosphate 2-Dimensional Rectangular Grids from Their 1-Dimensional Wires: Structural Transformations under Mild ConditionsOriginalMononuclear Metal Phosphinates with Ancillary Pyrazole Ligands. Synthesis and X‐ray Crystal Structures of [M(Ph2PO2)2(3,5‐DMPZ)2] (M = Co, Zn)7Chameleonic ligand in self-assembly and synthesis of polymeric manganese(II), and grid-type copper(I) and silver(I) complexes17Hydrothermal Syntheses, Architectures and Magnetic Properties of Six Novel MnII Coordination Polymers with Mixed Ligands70Hierarchical Structures Built from a Molecular Zinc Phosphate Core88Hierarchical Structures Built from a Molecular Zinc Phosphate Core15Octameric and Decameric Aluminophosphates62Octameric and Decameric Aluminophosphates11Novel Layered Copper Phosphoramidate, Which Contains Six-Membered Rings Made of Five Different Elements19From Hydrogen-Bonded Net-to-Net Framework to Twofold Interpenetrated (4,6) Net: Effect of Ligand Topology on the Supramolecular Structural Diversity64Seeking tetrameric transition metal phosphonate with a D4R core and organising it into a 3-D supramolecular assembly73Synthesis, magnetic behaviour, and X-ray structures of dinuclear copper complexes with multiple bridges. Efficient and selective catalysts for polymerization of 2,6-dimethylphenol26Hydrothermal synthesis and structural characterization of three new transition-metal coordination polymers with 2-carboxycinnamic acid13Different aliphatic dicarboxylates affected assemble of new coordination polymers constructed from flexible–rigid mixed ligands39Structural Diversity and Supramolecular Aggregation in Calcium, Strontium, and Barium Salicylates Incorporating 1,10-Phenanthroline and 4,4‘-Bipyridine: Probing the Softer Side of Group 2 Metal Ions with Pyridinic Ligands63Assembling metal phosphonates in the presence of monodentate-terminal and bidentate-bridging pyridine ligands. Use of non-covalent and covalent-coordinate interactions to build polymeric metal–phosphonate architectures53Facile one-pot synthesis of functionalized organophosphonate esters via ketone insertion into bulky arylphosphites8Structural Diversity in Zinc Phosphates and Phosphinates: Observation of a Lattice Water Dimer Sandwiched Between Phosphoryl Oxygen Atoms35Water in Organoaluminum Chemistry! Three‐in‐One Aluminophosphate Clusters That Incorporate Boehmite Repeating Units37Cooperative Binding of Phosphate Anion and a Neutral Nitrogen Donor to Alkaline-Earth Metal Ions. Investigation of Group 2 Metal−Organophosphate Interaction in the Absence and Presence of 1,10-Phenanthroline35Metal Complexes of Organophosphate Esters and Open-Framework Metal Phosphates: Synthesis, Structure, Transformations, and Applications370Organic-Soluble Tri-, Tetra-, and Pentanuclear Titanium(IV) Phosphates29Controlling the Structure of Manganese(II) Phosphates by the Choice and Ratio of Organophosphate and Auxiliary Ligands28Di-, Tri-, Tetra-, and Hexanuclear Copper(II) Mono-organophosphates: Structure and Nuclearity Dependence on the Choice of Phosphorus Substituents and Auxiliary N-Donor Ligands48Tetra- and Decanuclear Iron(III) Phosphonates: Observance of a Rare P−C Bond Cleavage in a Homogeneous Medium37Nuclearity Control in Molecular Iron Phosphates through Choice of Iron Precursors and Ancillary Ligands25Rings, chains and cages in metal phosphate chemistry: The interdependence and possible interconversion between various structural forms19Noncovalent Synthesis of Hierarchical Zinc Phosphates from a Single Zn4O12P4 Double‐Four‐Ring Building Block: Dimensionality Control through the Choice of Auxiliary Ligands47Assembling Discrete D4R Zeolite SBUs through Noncovalent Interactions. 3. Mediation by Butanols and 1,2-Bis(dimethylamino)ethane29Quantum chemical studies on chameleonic ligand and its grid-type copper(I) and zinc(II) complexes2Flexible Two-Dimensional Square-Grid Coordination Polymers: Structures and Functions135Pulsed corona plasma source characterization for film deposition on the inner surface of tubes28Thermally Induced Changes in a Porous Coordination Polymer {Cu2(pyrazine-2,3-dicarboxylate)2(4,4′-bipyridine)} Studied via in Situ X-ray Diffraction and 13C Cross-Polarization Magic Angle Spinning Nuclear Magnetic Resonance Spectroscopy17Copper phosphates and phosphinates with pyridine/pyrazole alcohol co-ligands: Synthesis and structure20Amorphous carbon film deposition on the inner surface of tubes using atmospheric pressure pulsed filamentary plasma source25Film deposition on the inner surface of tubes using atmospheric-pressure Ar–CH4, Ar–C2H2 and Ar–C2H2–H2 plasmas: interpretation of film properties from plasma-chemical kinetics14Iron phosphonate clusters: From magnetism to biological mimics12Organotitanium phosphates with free P–OH groups: Synthesis, spectroscopy and solid state structures11Auxiliary ligand-aided tuning of aggregation of transition metal benzoates: isolation of four different types of coordination polymers14Polymeric and cyclic manganese phosphates and phosphinates: Synthesis, spectral characterization and solid-state structures14Fluoride Ion Sensing and Caging by a Preformed Molecular D4R Zinc Phosphate Heterocubane42Development of Efficient Processes for the Preparation of Di-tert-butyl Potassium Phosphate and Di-tert-butyl (Chloromethyl) Phosphate13Role of 4,4′-bipyridine versus longer spacers 4,4′-azobipyridine, 1,2-bis(4-pyridyl)ethylene, and 1,2-bis(pyridin-3-ylmethylene)hydrazine in the formation of thermally labile metallophosphate coordination polymers10Synthetic strategies to achieve further-functionalised monoaryl phosphate primary building units: crystal structures and solid-state aggregation behavior21Discrete and polymeric cobalt organophosphates: isolation of a 3-D cobalt phosphate framework exhibiting selective CO 2 capture36The crystal structure, luminescence and nitrobenzene-sensing properties of a two-dimensional MnIIcoordination polymer based on 2,6-bis(imidazol-1-yl)pyridine3Dimensionality Alteration and Intra- versus Inter-SBU Void Encapsulation in Zinc Phosphate Frameworks29Intriguing structural chemistry of neutral and anionic layered monoalkylphosphates: single-source precursors for high-yield ceramic phosphates11m-Carboranylphosphinate as Versatile Building Blocks To Design all Inorganic Coordination Polymers25Dinuclear Manganese(II), Cobalt(II), and Nickel(II) Aryl Phosphates Incorporating 4′‐Chloro‐2,2′:6′,2′′‐Terpyridine Coligands – Efficient Catalysts for Alcohol Oxidation28Merging Icosahedral Boron Clusters and Magnetic Nanoparticles: Aiming toward Multifunctional Nanohybrid Materials35All inorganic coordination polymers have been made possible with the m -carboranylphosphinate ligand8[Bis(2,6-diisopropylphenyl) phosphato-κO]pentakis(methanol-κO)manganese bis(2,6-diisopropylphenyl) phosphate methanol trisolvate2Metallacarboranes on the Road to Anticancer Therapies: Cellular Uptake, DNA Interaction, and Biological Evaluation of Cobaltabisdicarbollide [COSAN] −120Ceramic and porous framework metal silicates and phosphates from molecular precursors: an ever-evolving ambient synthesis approach16ATMP derived cobalt-metaphosphate complex as highly active catalyst for oxygen reduction reaction42Discrete and Polymeric Cobalt Pyrophosphates Derived from Pyrophosphoric Acid Diester Ar2H2P2O75Dinuclear group 12 metal phosphates bridged by hexadentate 2,3,5,6-tetra(2-pyridyl)-pyrazine and their supramolecular organization5Di-tert-butylphosphate Derived Thermolabile Calcium Organophosphates: Precursors for Ca(H2PO4)2, Ca(HPO4), α-/β-Ca(PO3)2, and Nanocrystalline Ca10(PO4)6(OH)215Cyclopentadienyl Removal Assisted Nuclearity Expansion in Thermolabile Titanium and Zirconium Organophosphates Sourced from Metallocene Dichlorides3Transformations of Polymers of 4,4'-Dipyridyl and Cobalt(II) and Manganese(II) Cymantrenates in the Presence of N-Donors of Different Denticity7Alkali Metal Di-tert-butyl Phosphates: Single-Source Precursors for Homo- and Heterometallic Inorganic Phosphate Materials13Structure- and phase-transformable coordination polymers/metal complexes with fluorinated anions19Ligand-Field Directed Electronic Effects in Heterogenized Bifunctional Co(II) Molecular Clusters Accomplish Efficient Overall Water Splitting15Compelling DNA intercalation through ‘anion–anion’ anti-coulombic interactions: boron cluster self-vehicles as promising anticancer agents71D polymeric and 2D layered zinc monoalkyl phosphates bearing long alkyl chains: synthesis, structural transformations and thermal behaviour1Thermally labile mono-alkyl phosphates and their alkali metal derivatives: synthesis and solid-state supramolecular aggregation0A sulfoxide-functionalized graphitic carbon nitride–cobalt dialkyl phosphate bipyridine heterojunction for photocatalytic hydrogen production1Synergistic 2-D cobalt di-tert-butyl phosphate grid graphitic carbon nitride (gC3N4) hybrids for rapid photocatalytic hydrogen evolution2

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  1. Mononuclear Metal Phosphinates with Ancillary Pyrazole Ligands. Synthesis and X‐ray Crystal Structures of [M(Ph2PO2)2(3,5‐DMPZ)2] (M = Co, Zn)

    Zeitschrift für anorganische und allgemeine Chemie · 2005-10-01

    Vadapalli Chandrasekhar, Ramamoorthy Boomishankar, Palani Sasikumar, Nagarajan Loganathan, A. W. Cordes

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  2. Chameleonic ligand in self-assembly and synthesis of polymeric manganese(II), and grid-type copper(I) and silver(I) complexes

    Polyhedron · 2006-04-16

    Violetta Patroniak, Jean‐Maríe Lehn, Maciej Kubicki, Artur Ciesielski, Monika Wałęsa‐Chorab

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  3. Hydrothermal Syntheses, Architectures and Magnetic Properties of Six Novel MnII Coordination Polymers with Mixed Ligands

    European Journal of Inorganic Chemistry · 2006-04-18

    Changyan Sun, Song Wei Gao, Lin‐Pei Jin

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  4. Hierarchical Structures Built from a Molecular Zinc Phosphate Core

    Angewandte Chemie International Edition · 2006-07-18

    Ramaswamy Murugavel, Subramaniam Kuppuswamy, Ramamoorthy Boomishankar, Alexander Steiner

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  5. Hierarchical Structures Built from a Molecular Zinc Phosphate Core

    Angewandte Chemie · 2006-07-18

    Ramaswamy Murugavel, Subramaniam Kuppuswamy, Ramamoorthy Boomishankar, Alexander Steiner

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  6. Octameric and Decameric Aluminophosphates

    Angewandte Chemie International Edition · 2006-10-02

    Ramaswamy Murugavel, Subramaniam Kuppuswamy

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  7. Octameric and Decameric Aluminophosphates

    Angewandte Chemie · 2006-10-02

    Ramaswamy Murugavel, Subramaniam Kuppuswamy

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  8. Novel Layered Copper Phosphoramidate, Which Contains Six-Membered Rings Made of Five Different Elements

    Inorganic Chemistry · 2006-10-13

    Ramaswamy Murugavel, Mayank Pratap Singh

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  9. From Hydrogen-Bonded Net-to-Net Framework to Twofold Interpenetrated (4,6) Net: Effect of Ligand Topology on the Supramolecular Structural Diversity

    Crystal Growth & Design · 2006-12-29

    Lijun Zhou, YaoYu Wang, Caihua Zhou, Cui‐Juan Wang, Qi‐Zhen Shi, Shie‐Ming Peng

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  10. Seeking tetrameric transition metal phosphonate with a D4R core and organising it into a 3-D supramolecular assembly

    Chemical Communications · 2007-01-01

    Ramaswamy Murugavel, Swaminathan Shanmugan

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  11. Synthesis, magnetic behaviour, and X-ray structures of dinuclear copper complexes with multiple bridges. Efficient and selective catalysts for polymerization of 2,6-dimethylphenol

    Dalton Transactions · 2007-01-01

    Ramaswamy Murugavel, Ramasamy Pothiraja, Nayanmoni Gogoi, Rodolphe Clérac, Lollita Lecren, Ray John Butcher, Munirathinam Nethaji

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  12. Hydrothermal synthesis and structural characterization of three new transition-metal coordination polymers with 2-carboxycinnamic acid

    Journal of Molecular Structure · 2007-01-22

    Changyan Sun, Jie Zhou, Lin‐Pei Jin

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  13. Different aliphatic dicarboxylates affected assemble of new coordination polymers constructed from flexible–rigid mixed ligands

    Journal of Solid State Chemistry · 2007-06-23

    Xinxin Xu, Ying Ma, Enbo Wang

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  14. Structural Diversity and Supramolecular Aggregation in Calcium, Strontium, and Barium Salicylates Incorporating 1,10-Phenanthroline and 4,4‘-Bipyridine: Probing the Softer Side of Group 2 Metal Ions with Pyridinic Ligands

    Inorganic Chemistry · 2007-11-30

    Ramaswamy Murugavel, Remya Korah

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  15. Assembling metal phosphonates in the presence of monodentate-terminal and bidentate-bridging pyridine ligands. Use of non-covalent and covalent-coordinate interactions to build polymeric metal–phosphonate architectures

    Dalton Transactions · 2008-01-01

    Ramaswamy Murugavel, Swaminathan Shanmugan

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  16. Facile one-pot synthesis of functionalized organophosphonate esters via ketone insertion into bulky arylphosphites

    Journal of Chemical Sciences · 2008-01-01

    Ramaswamy Murugavel, Subramaniam Kuppuswamy

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  17. Structural Diversity in Zinc Phosphates and Phosphinates: Observation of a Lattice Water Dimer Sandwiched Between Phosphoryl Oxygen Atoms

    European Journal of Inorganic Chemistry · 2008-02-20

    Ramasamy Pothiraja, Swaminathan Shanmugan, Mrinalini Ganapati Walawalkar, Munirathinam Nethaji, Ray John Butcher, Ramaswamy Murugavel

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  18. Water in Organoaluminum Chemistry! Three‐in‐One Aluminophosphate Clusters That Incorporate Boehmite Repeating Units

    Chemistry - A European Journal · 2008-03-20

    Ramaswamy Murugavel, Subramaniam Kuppuswamy

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  19. Cooperative Binding of Phosphate Anion and a Neutral Nitrogen Donor to Alkaline-Earth Metal Ions. Investigation of Group 2 Metal−Organophosphate Interaction in the Absence and Presence of 1,10-Phenanthroline

    Inorganic Chemistry · 2008-05-24

    Ramaswamy Murugavel, Subramaniam Kuppuswamy, S. Randoll

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  20. Metal Complexes of Organophosphate Esters and Open-Framework Metal Phosphates: Synthesis, Structure, Transformations, and Applications

    Chemical Reviews · 2008-06-28

    Ramaswamy Murugavel, Amitava Choudhury, Mrinalini Ganapati Walawalkar, Ramasamy Pothiraja, C. N. R. Rao

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  21. Organic-Soluble Tri-, Tetra-, and Pentanuclear Titanium(IV) Phosphates

    Inorganic Chemistry · 2008-07-29

    Ramaswamy Murugavel, Subramaniam Kuppuswamy

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  22. Controlling the Structure of Manganese(II) Phosphates by the Choice and Ratio of Organophosphate and Auxiliary Ligands

    Chemistry - An Asian Journal · 2008-11-28

    Ramaswamy Murugavel, Subramaniam Kuppuswamy, Nayanmoni Gogoi, Alexander Steiner, John Bacsa, Ramamoorthy Boomishankar, К. Г. Суреш

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  23. Di-, Tri-, Tetra-, and Hexanuclear Copper(II) Mono-organophosphates: Structure and Nuclearity Dependence on the Choice of Phosphorus Substituents and Auxiliary N-Donor Ligands

    Inorganic Chemistry · 2008-12-02

    Ramaswamy Murugavel, Subramaniam Kuppuswamy, Amarendra Nath Maity, Mayank Pratap Singh

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  24. Tetra- and Decanuclear Iron(III) Phosphonates: Observance of a Rare P−C Bond Cleavage in a Homogeneous Medium

    Inorganic Chemistry · 2008-12-16

    Ramaswamy Murugavel, Nayanmoni Gogoi, Rodolphe Clérac

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  25. Nuclearity Control in Molecular Iron Phosphates through Choice of Iron Precursors and Ancillary Ligands

    Chemistry - An Asian Journal · 2009-05-06

    Ramaswamy Murugavel, Nayanmoni Gogoi, К. Г. Суреш, Samar Layek, Harish Chandra Verma

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  26. Rings, chains and cages in metal phosphate chemistry: The interdependence and possible interconversion between various structural forms

    Journal of Organometallic Chemistry · 2009-11-03

    Ramaswamy Murugavel, Nayanmoni Gogoi

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  27. Noncovalent Synthesis of Hierarchical Zinc Phosphates from a Single Zn4O12P4 Double‐Four‐Ring Building Block: Dimensionality Control through the Choice of Auxiliary Ligands

    Chemistry - A European Journal · 2009-11-10

    Ramaswamy Murugavel, Subramaniam Kuppuswamy, Nayanmoni Gogoi, Ramamoorthy Boomishankar, Alexander Steiner

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  28. Assembling Discrete D4R Zeolite SBUs through Noncovalent Interactions. 3. Mediation by Butanols and 1,2-Bis(dimethylamino)ethane

    Inorganic Chemistry · 2010-02-02

    Ramaswamy Murugavel, Subramaniam Kuppuswamy, Nayanmoni Gogoi, Alexander Steiner

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  29. Quantum chemical studies on chameleonic ligand and its grid-type copper(I) and zinc(II) complexes

    Journal of Molecular Structure THEOCHEM · 2010-03-16

    Violetta Patroniak, Przemyslaw Lis Markiewicz, Marcin Hoffmann

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  30. Flexible Two-Dimensional Square-Grid Coordination Polymers: Structures and Functions

    International Journal of Molecular Sciences · 2010-09-30

    Hiroshi Kajiro, Atsushi Kondo, Katsumi Kaneko, Hirofumi Kanoh

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  31. Pulsed corona plasma source characterization for film deposition on the inner surface of tubes

    Journal of Physics D Applied Physics · 2010-11-23

    Ramasamy Pothiraja, Nikita K. Bibinov, Peter Awakowicz

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  32. Thermally Induced Changes in a Porous Coordination Polymer {Cu2(pyrazine-2,3-dicarboxylate)2(4,4′-bipyridine)} Studied via in Situ X-ray Diffraction and 13C Cross-Polarization Magic Angle Spinning Nuclear Magnetic Resonance Spectroscopy

    The Journal of Physical Chemistry C · 2011-02-10

    Omar J. García-Ricard, Riqiang Fu, Arturo J. Hernández‐Maldonado

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  33. Copper phosphates and phosphinates with pyridine/pyrazole alcohol co-ligands: Synthesis and structure

    Inorganica Chimica Acta · 2011-04-15

    Ramasamy Pothiraja, Malaichamy Sathiyendiran, Alexander Steiner, Ramaswamy Murugavel

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  34. Amorphous carbon film deposition on the inner surface of tubes using atmospheric pressure pulsed filamentary plasma source

    Journal of Physics D Applied Physics · 2011-08-18

    Ramasamy Pothiraja, Nikita Bibinov, Peter Awakowicz

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  35. Film deposition on the inner surface of tubes using atmospheric-pressure Ar–CH4, Ar–C2H2 and Ar–C2H2–H2 plasmas: interpretation of film properties from plasma-chemical kinetics

    Journal of Physics D Applied Physics · 2012-08-02

    Ramasamy Pothiraja, Max Engelhardt, Nikita K. Bibinov, Peter Awakowicz

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  36. Iron phosphonate clusters: From magnetism to biological mimics

    Inorganic Chemistry Communications · 2012-08-18

    Merry Mitra, Rajarshi Ghosh

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  37. Organotitanium phosphates with free P–OH groups: Synthesis, spectroscopy and solid state structures

    Journal of Organometallic Chemistry · 2013-07-31

    L. Kalita, Alok Ch. Kalita, Ramaswamy Murugavel

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  38. Auxiliary ligand-aided tuning of aggregation of transition metal benzoates: isolation of four different types of coordination polymers

    CrystEngComm · 2014-01-01

    Subarna Banerjee, Palanisamy Rajakannu, Ray John Butcher, Ramaswamy Murugavel

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  39. Polymeric and cyclic manganese phosphates and phosphinates: Synthesis, spectral characterization and solid-state structures

    Inorganica Chimica Acta · 2014-02-17

    Ramasamy Pothiraja, Palanisamy Rajakannu, Pratap Vishnoi, Ray John Butcher, Ramaswamy Murugavel

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  40. Fluoride Ion Sensing and Caging by a Preformed Molecular D4R Zinc Phosphate Heterocubane

    Inorganic Chemistry · 2014-03-10

    Alok Ch. Kalita, Ramaswamy Murugavel

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  41. Development of Efficient Processes for the Preparation of Di-tert-butyl Potassium Phosphate and Di-tert-butyl (Chloromethyl) Phosphate

    Organic Process Research & Development · 2014-03-29

    Bin Zheng, Richard J. Fox, Masano Sugiyama, Alan W. Fritz, Martin D. Eastgate

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  42. Role of 4,4′-bipyridine versus longer spacers 4,4′-azobipyridine, 1,2-bis(4-pyridyl)ethylene, and 1,2-bis(pyridin-3-ylmethylene)hydrazine in the formation of thermally labile metallophosphate coordination polymers

    Inorganic Chemistry Frontiers · 2014-11-21

    Palanisamy Rajakannu, Rana Howlader, Alok Ch. Kalita, Ray John Butcher, Ramaswamy Murugavel

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  43. Synthetic strategies to achieve further-functionalised monoaryl phosphate primary building units: crystal structures and solid-state aggregation behavior

    New Journal of Chemistry · 2014-11-24

    Aijaz Ahmad Dar, Abhijit Mallick, Ramaswamy Murugavel

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  44. Discrete and polymeric cobalt organophosphates: isolation of a 3-D cobalt phosphate framework exhibiting selective CO 2 capture

    Dalton Transactions · 2015-01-01

    Sandeep K. Gupta, Subramaniam Kuppuswamy, James P. S. Walsh, Eric J. L. McInnes, Ramaswamy Murugavel

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  45. The crystal structure, luminescence and nitrobenzene-sensing properties of a two-dimensional MnIIcoordination polymer based on 2,6-bis(imidazol-1-yl)pyridine

    Acta Crystallographica Section C Structural Chemistry · 2015-05-06

    Yin-Lin Wang, Lingliang Long, Jinfang Zhang

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  46. Dimensionality Alteration and Intra- versus Inter-SBU Void Encapsulation in Zinc Phosphate Frameworks

    Inorganic Chemistry · 2016-05-09

    Aijaz Ahmad Dar, Gulzar Ahmad Bhat, Ramaswamy Murugavel

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  47. Intriguing structural chemistry of neutral and anionic layered monoalkylphosphates: single-source precursors for high-yield ceramic phosphates

    CrystEngComm · 2017-01-01

    Gulzar Ahmad Bhat, Alok Ch. Kalita, Ramaswamy Murugavel

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  48. m-Carboranylphosphinate as Versatile Building Blocks To Design all Inorganic Coordination Polymers

    Inorganic Chemistry · 2017-04-25

    Elena Oleshkevich, Clara Viñas, Isabel Romero, Duane Choquesillo‐Lazarte, Matti Haukka, Francesç Teixidor

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  49. Dinuclear Manganese(II), Cobalt(II), and Nickel(II) Aryl Phosphates Incorporating 4′‐Chloro‐2,2′:6′,2′′‐Terpyridine Coligands – Efficient Catalysts for Alcohol Oxidation

    European Journal of Inorganic Chemistry · 2017-11-29

    Gulzar Ahmad Bhat, Antony Rajendran, Ramaswamy Murugavel

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  50. Merging Icosahedral Boron Clusters and Magnetic Nanoparticles: Aiming toward Multifunctional Nanohybrid Materials

    Inorganic Chemistry · 2017-12-19

    Elena Oleshkevich, Francesç Teixidor, Anna Rosell, Clara Viñas

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