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RESEARCH PAPER · Inorganic Chemistry · 2011

Validation of Speciation Techniques: A Study of Chlorozincate(II) Ionic Liquids

Julien Estager, Peter Nockemann, Kenneth Richard Seddon, Małgorzata Swadźba‐Kwaśny, Sophie Tyrrell

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Validation of Speciation Techniques: A Study of Chlorozincate(II) Ionic LiquidsOriginalChlorometallate and palladium cluster complexes of wide-span diimine and diamine ligands6Lithium Organozincate Complexes LiRZnX2: Common Species in Organozinc Chemistry81Direct electrodeposition of FeCoZn wire arrays from a zinc chloride-based ionic liquid25Electrochemical Synthesis of Indium(0) Nanoparticles in Haloindate(III) Ionic Liquids17Facile in situ synthesis of nanofluids based on ionic liquids and copper oxide clusters and nanoparticles151High current density, efficient cycling of Zn2+ in 1-ethyl-3-methylimidazolium dicyanamide ionic liquid: The effect of Zn2+ salt and water concentration146Mixtures of ionic liquids604Chlorostannate(II) Ionic Liquids: Speciation, Lewis Acidity, and Oxidative Stability79Computational studies of the structure and cation-anion interactions in 1-ethyl-3-methylimidazolium lactate ionic liquid13Complex Zinc Bromide Compounds0Utilization of Metal Halide Species Ambiguity to Develop Amorphous, Stabilized Pharmaceutical Agents As Ionic Liquids13Acidity and basicity of halometallate-based ionic liquids from X-ray photoelectron spectroscopy54Lead(ii) chloride ionic liquids and organic/inorganic hybrid materials – a study of chloroplumbate(ii) speciation47Removal of Surface Contaminants Using Ionic Liquids12Structural Features and Properties of Metal Complexes in Ionic Liquids: Application in Alkylation Reactions8The chain-like polynuclear coordination compounds (ZnBr2)n(18-crown-6)2 (n = 4, 6, 8, 10) and [Zn5Br9][N(Tf2)]8Electroplating Using Ionic Liquids259Silyl peroxides as effective oxidants in the Baeyer–Villiger reaction with chloroaluminate(III) ionic liquids as catalysts18Liquid Coordination Complexes Formed by the Heterolytic Cleavage of Metal Halides116Liquid Coordination Complexes Formed by the Heterolytic Cleavage of Metal Halides15One-step electrochemical fabrication of nanoporous gold wire arrays from ionic liquid19Selective continuous flow extractive denitrogenation of oil containing S- and N-heteroaromatics using metal-containing ionic liquids supported on monolithic silica with hierarchical porosity21Mechanistic Studies of Zinc Electrodeposition from Deep Eutectic Electrolytes60Halometallate ionic liquids – revisited308Phosphonium Chloromercurate Room Temperature Ionic Liquids of Variable Composition6Brønsted acids in ionic liquids: how acidity depends on the liquid structure43Zinc selenide nano- and microspheres via microwave-assisted ionothermal synthesis10Pt2Cl82– Dimer Formation of [Bmim]2PtCl4 Ionic Liquid When Confined in Silica Nanopores11Dissolution of metal oxides in an acid-saturated ionic liquid solution and investigation of the back-extraction behaviour to the aqueous phase107Mechanism and origins of enantioselectivity for [BMIM]Cl ionic liquids and ZnCl2 co-catalyzed coupling reaction of CO2 with epoxides49Physicochemical Properties of Ionic Liquids19EXAFS Study into the Speciation of Metal Salts Dissolved in Ionic Liquids and Deep Eutectic Solvents266Transformation of dense AgI into a silver-rich framework iodide using thiophenol as mineralizer31Zn Electrochemistry in 1‐Ethyl‐3‐Methylimidazolium and N‐Butyl‐N‐Methylpyrrolidinium Dicyanamides: Promising New Rechargeable Zn Battery Electrolytes60Dissolution of Metal Salts in Bis(trifluoromethylsulfonyl)imide-Based Ionic Liquids: Studying the Affinity of Metal Cations Toward a “Weakly Coordinating” Anion50Synthesis and Characterization of the Platinum-Substituted Keggin Anion α-H2SiPtW11O404–24Development of Brönsted–Lewis acidic solid catalytic system of 3-methyl-1-sulfonic acid imidazolium transition metal chlorides for the preparation of bis(indolyl)methanes44Hybrid organic–inorganic chlorozincate and a molecular zinc complex involving the in situ formed imidazo[1,5-a]pyridinium cation: serendipitous oxidative cyclization, structures and photophysical properties24Synthesis and Applications of Ionic Liquids in Clean Energy and Environment: A Review60The Influence of Ionic Liquids on the Chemistry of the Zinc Bromine Flow Battery0The effect of the electrode material on the electrodeposition of zinc from deep eutectic solvents86A Rhodium Nanoparticle–Lewis Acidic Ionic Liquid Catalyst for the Chemoselective Reduction of Heteroarenes132A Rhodium Nanoparticle–Lewis Acidic Ionic Liquid Catalyst for the Chemoselective Reduction of Heteroarenes42Design of multifaceted acidic 1,3-disulfoimidazolium chlorometallate ionic systems as heterogeneous catalysts for the preparation of β-amino carbonyl compounds31Easily Accessible Rare-Earth-Containing Phosphonium Room-Temperature Ionic Liquids: EXAFS, Luminescence, and Magnetic Properties32Coordination-Induced Syntheses of Two Hybrid Framework Iodides: A Thermochromic Luminescent Thermometer53Dynamic Directing Effect and Symmetric Correlation in Three pH‐Modulated 1,4‐Diazabicyclo[2.2.2]octane/Iodoargentate Hybrids15On the Anion Exchange of PX3 (X = Cl, Br, I) in Ionic Liquids comprising Halide Anions10A green and efficient method for the synthesis of pyrroles using a deep eutectic solvent ([CholineCl][ZnCl 2 ] 3 ) under solvent-free sonication46Comment on “Lewis acidic ionic liquids of crown ether complex cations: preparation and applications in organic reactions” by Y. Liang, J. Wang, C. Cheng and H. Jing, RSC Adv. , 2016, 6 , 935466Crystal structure of Zn(ZnCl 4 ) 2 (Cho) 2 : the transformation of ions to neutral species in a deep eutectic system8Liquid coordination complexes of Lewis acidic metal chlorides: Lewis acidity and insights into speciation47Interfacial assistant role of amine additives on zinc electrodeposition from deep eutectic solvents: an in situ X-ray imaging investigation24Diethyldisulfoammonium chlorometallates as heterogeneous Brønsted–Lewis acidic catalysts for one‐pot synthesis of 14‐aryl‐7‐(N‐phenyl)‐14H‐dibenzo[a,j]acridines11Deep oxidative desulfurization of fuels by superbase-derived Lewis acidic ionic liquids122Lewis Acidic Ionic Liquids78Synergistic Bronsted‐Lewis Acidity Effect on Upgrading Biomass‐Derived Phenolic Compounds: Statistical Optimization of Process Parameters, Kinetic Investigations and DFT Study10X-Ray Photoelectron Spectroscopy of Chlorometallate Ionic Liquids: Speciation and Anion Basicity5Deep catalytic oxidative desulfurization of fuels by novel Lewis acidic ionic liquids98Water-Tolerant Trifloaluminate Ionic Liquids: New and Unique Lewis Acidic Catalysts for the Synthesis of Chromane19Applications of Ionic Liquids in Removal of Surface Contaminants37Electrodeposition of indium from the ionic liquid trihexyl(tetradecyl)phosphonium chloride38Improving the performance of supported ionic liquid phase (SILP) catalysts for the ultra-low-temperature water–gas shift reaction using metal salt additives19Crystallographic Insights into the Behavior of Highly Acidic Metal Cations in Ionic Liquids from Reactions of Titanium Tetrachloride with [1-Butyl-3-Methylimidazolium][X] Ionic Liquids (X = Chloride, Bromide, Tetrafluoroborate)6Metal–Organic Framework with Color-Switching and Strongly Polarized Emission22Zinc 1s Valence-to-Core X-ray Emission Spectroscopy of Halozincate Complexes21Cu carbonyls enhance the performance of Ru-based SILP water–gas shift catalysts: a combined in situ DRIFTS and DFT study10Post-synthetic modification of ionic liquids using ligand-exchange and redox coordination chemistry7Selective Hydrogenation of Benzofurans Using Ruthenium Nanoparticles in Lewis Acid-Modified Ruthenium-Supported Ionic Liquid Phases65Ionic‐Association‐Assisted Viscoelastic Nylon Electrolytes Enable Synchronously Coupled Interface for Solid Batteries73Development of N,N-disulfo-1,1,3,3-tetramethylguanidinium Chlorometallates as Heterogeneous Catalysts for One Pot Synthesis of 1,2-dihydro-1- aryl-3H-naphth[1, 2-e][1,3]oxazin-3-one Derivatives5Aluminum ions speciation and transport in acidic deep eutectic AlCl3 amide electrolytes23Three-dimensional metal-halide open frameworks56Bi(III) halometallate ionic liquids: Interactions and speciation19Halometallate ionic liquids: thermal properties, decomposition pathways, and life cycle considerations27Tunable imidazolium ionic liquids as efficient catalysts for conversion of urea into cyclic carbonates22Selective synthesis and structural study of amino amide trichlorozincates2A Water‐Free ITIES: Ionic Liquid/Oil Interface for Base Metal Nanostructure Formation – Zn Case3Investigation of thermal stability of ionic liquids through thermo gravimetric analysis0Thermo-responsive polymer catalysts for polyester recycling processes: switching from homogeneous catalysis to heterogeneous separations12Electropolymerization of Pyrrole-Tailed Imidazolium Ionic Liquid for the Elaboration of Antibacterial Surfaces7Catalytic Alkali and Transition Metal Cations to Produce Low-Emission Hydrogen from Methane Pyrolysis20Structural, vibrational, optical properties and DFT calculations of a zinc(II) chloride hybrid based on substituted bipyridinium cation4Existence forms and electrodeposition behavior of various zinc compounds in choline chloride − Urea deep-eutectic solvent14Elucidating the Iron‐Based Ionic Liquid [C4py][FeCl4]: Structural Insights and Potential for Nonaqueous Redox Flow Batteries14Al( iii ) and Ga( iii ) triflate complexes as solvate ionic liquids: speciation and application as soluble and recyclable Lewis acidic catalysts2Unravelling the complex speciation of halozincate ionic liquids using X-ray spectroscopies and calculations9Ionic liquids in cationic polymerization: A review33Synergistic Effect of Deep Eutectic Solvent and Zinc Oxide in Transesterification of Dimethyl Terephthalate for the Synthesis of Alkyl Terephthalate Esters5Incorporation of zinc into the protic imidazolium-based ionic liquid: A novel catalytic route to esters plasticizers5A Low‐Cost and Green Zinc‐Iron Battery Achieved by Ethaline Deep Eutectic Solvent5Metal Ionic Liquids (MILs) as Promising Catalytic Curing Agents of Epoxy Prepolymer for the Design of High‐Performance Networks1Selective electrochemical metal separations at field-tunable ionic liquid interphases0

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  1. Chlorometallate and palladium cluster complexes of wide-span diimine and diamine ligands

    Dalton Transactions · 2011-01-01

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  2. Lithium Organozincate Complexes LiRZnX2: Common Species in Organozinc Chemistry

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  3. Direct electrodeposition of FeCoZn wire arrays from a zinc chloride-based ionic liquid

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  4. Electrochemical Synthesis of Indium(0) Nanoparticles in Haloindate(III) Ionic Liquids

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  5. Facile in situ synthesis of nanofluids based on ionic liquids and copper oxide clusters and nanoparticles

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  6. High current density, efficient cycling of Zn2+ in 1-ethyl-3-methylimidazolium dicyanamide ionic liquid: The effect of Zn2+ salt and water concentration

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  7. Mixtures of ionic liquids

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  8. Chlorostannate(II) Ionic Liquids: Speciation, Lewis Acidity, and Oxidative Stability

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  9. Computational studies of the structure and cation-anion interactions in 1-ethyl-3-methylimidazolium lactate ionic liquid

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  10. Complex Zinc Bromide Compounds

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  11. Utilization of Metal Halide Species Ambiguity to Develop Amorphous, Stabilized Pharmaceutical Agents As Ionic Liquids

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  12. Acidity and basicity of halometallate-based ionic liquids from X-ray photoelectron spectroscopy

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  13. Lead(ii) chloride ionic liquids and organic/inorganic hybrid materials – a study of chloroplumbate(ii) speciation

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  14. Removal of Surface Contaminants Using Ionic Liquids

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  15. Structural Features and Properties of Metal Complexes in Ionic Liquids: Application in Alkylation Reactions

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  16. The chain-like polynuclear coordination compounds (ZnBr2)n(18-crown-6)2 (n = 4, 6, 8, 10) and [Zn5Br9][N(Tf2)]

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  17. Electroplating Using Ionic Liquids

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  18. Silyl peroxides as effective oxidants in the Baeyer–Villiger reaction with chloroaluminate(III) ionic liquids as catalysts

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  19. Liquid Coordination Complexes Formed by the Heterolytic Cleavage of Metal Halides

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  20. Liquid Coordination Complexes Formed by the Heterolytic Cleavage of Metal Halides

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  21. One-step electrochemical fabrication of nanoporous gold wire arrays from ionic liquid

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  22. Selective continuous flow extractive denitrogenation of oil containing S- and N-heteroaromatics using metal-containing ionic liquids supported on monolithic silica with hierarchical porosity

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  23. Mechanistic Studies of Zinc Electrodeposition from Deep Eutectic Electrolytes

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  24. Halometallate ionic liquids – revisited

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  25. Phosphonium Chloromercurate Room Temperature Ionic Liquids of Variable Composition

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  27. Zinc selenide nano- and microspheres via microwave-assisted ionothermal synthesis

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  28. Pt2Cl82– Dimer Formation of [Bmim]2PtCl4 Ionic Liquid When Confined in Silica Nanopores

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  34. Zn Electrochemistry in 1‐Ethyl‐3‐Methylimidazolium and N‐Butyl‐N‐Methylpyrrolidinium Dicyanamides: Promising New Rechargeable Zn Battery Electrolytes

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  35. Dissolution of Metal Salts in Bis(trifluoromethylsulfonyl)imide-Based Ionic Liquids: Studying the Affinity of Metal Cations Toward a “Weakly Coordinating” Anion

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  36. Synthesis and Characterization of the Platinum-Substituted Keggin Anion α-H2SiPtW11O404–

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  37. Development of Brönsted–Lewis acidic solid catalytic system of 3-methyl-1-sulfonic acid imidazolium transition metal chlorides for the preparation of bis(indolyl)methanes

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  38. Hybrid organic–inorganic chlorozincate and a molecular zinc complex involving the in situ formed imidazo[1,5-a]pyridinium cation: serendipitous oxidative cyclization, structures and photophysical properties

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  39. Synthesis and Applications of Ionic Liquids in Clean Energy and Environment: A Review

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  40. The Influence of Ionic Liquids on the Chemistry of the Zinc Bromine Flow Battery

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  41. The effect of the electrode material on the electrodeposition of zinc from deep eutectic solvents

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  42. A Rhodium Nanoparticle–Lewis Acidic Ionic Liquid Catalyst for the Chemoselective Reduction of Heteroarenes

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  44. Design of multifaceted acidic 1,3-disulfoimidazolium chlorometallate ionic systems as heterogeneous catalysts for the preparation of β-amino carbonyl compounds

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  45. Easily Accessible Rare-Earth-Containing Phosphonium Room-Temperature Ionic Liquids: EXAFS, Luminescence, and Magnetic Properties

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  46. Coordination-Induced Syntheses of Two Hybrid Framework Iodides: A Thermochromic Luminescent Thermometer

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  47. Dynamic Directing Effect and Symmetric Correlation in Three pH‐Modulated 1,4‐Diazabicyclo[2.2.2]octane/Iodoargentate Hybrids

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  48. On the Anion Exchange of PX3 (X = Cl, Br, I) in Ionic Liquids comprising Halide Anions

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  49. A green and efficient method for the synthesis of pyrroles using a deep eutectic solvent ([CholineCl][ZnCl 2 ] 3 ) under solvent-free sonication

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  50. Comment on “Lewis acidic ionic liquids of crown ether complex cations: preparation and applications in organic reactions” by Y. Liang, J. Wang, C. Cheng and H. Jing, RSC Adv. , 2016, 6 , 93546

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