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RESEARCH PAPER · Chemistry - A European Journal · 2013

Solvent Responsive Magnetic Dynamics of a Dinuclear Dysprosium Single‐Molecule Magnet

Min Ren, Song‐Song Bao, Norihisa Hoshino, Tomoyuki Akutagawa, Bing‐Wu Wang, Yu‐Chen Ding, Shiqiang Wei, Li‐Min Zheng

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Solvent Responsive Magnetic Dynamics of a Dinuclear Dysprosium Single‐Molecule MagnetOriginalSeven-Coordinate Lanthanide Sandwich-Type Complexes with a Tetrathiafulvalene-Fused Schiff Base Ligand563D Organization of Dysprosium Cubanes30Calix[4]arene-Supported Mononuclear Lanthanide Single-Molecule Magnet57A layered erbium phosphonate in pseudo-D5h symmetry exhibiting field-tunable magnetic relaxation and optical correlation93Cluster-Based Single-Molecule Magnets65Magnetic relaxation versus 3D long-range ordering in {Dy 2 Ba(α-fur) 8 } n furoate polymers24Effect of Structural Isomerism on Magnetic Dynamics: from Single-Molecule Magnet to Single-Chain Magnet52Synthesis, structure and properties of a tetranuclear europium(III) complex based on 9,9-dimethylfluorene-2,7-diphosphonic acid11Molecular Magnets Based on Homometallic Hexanuclear Lanthanide(III) Complexes75Homochiral Cobalt Phosphonates Containing Δ‐Type Chains with a Tunable Interlayer Distance and a Field‐Induced Phase Transition30Remote control of SMM behaviour via DTE ligands22Highly pH-dependent synthesis of two novel three-dimensional dysprosium complexes with interesting magnetic and luminescence properties45Disentangling intricate web of interrelated notions at the interface between the physical (crystal field) Hamiltonians and the effective (spin) Hamiltonians133A Dy 2 single-molecule magnet with benzoate anions and phenol-O − bridging groups38Cobalt and copper pyridylmethylphosphonates with two- and three-dimensional structures and field-induced magnetic transitions5Dinuclear Lanthanide Single-Molecule Magnets2Enlarging the ring by incorporating a phosphonate coligand: from the cyclic hexanuclear to octanuclear dysprosium clusters17Magnetic and luminescent properties of lanthanide coordination polymers with asymmetric biphenyl-3,2′,5′-tricarboxylate47pH-controlled polymorphism in a layered dysprosium phosphonate and its impact on the magnetization relaxation32Slow Magnetic Relaxation Observed in Dysprosium Compounds Containing Unsupported Near-Linear Hydroxo- and Fluoro-Bridges55Structural and spectroscopic characterization of two new layered uranyl(VI) p-xylenediphosphonate compounds synthesized via ionothermal method13Multiple magnetic relaxation processes, magnetocaloric effect and fluorescence properties of rhombus-shaped tetranuclear rare earth complexes61A pseudo-icosahedral cage {Gd 12 } based on aminomethylphosphonate46Building 1D lanthanide chains and non-symmetrical [Ln 2 ] “triple-decker” clusters using salen-type ligands: magnetic cooling and relaxation phenomena14Lanthanide Clusters Toward Single-Molecule Magnets16Lanthanide salen-type complexes exhibiting single ion magnet and photoluminescent properties54Terminal solvent effects on the anisotropy barriers of Dy 2 systems44Multiple-Step Humidity-Induced Single-Crystal to Single-Crystal Transformations of a Cobalt Phosphonate: Structural and Proton Conductivity Studies50A two-dimensional Ni(II) coordination polymer built of 4-(1,2,4-triazol-4-yl)phenylphosphonate: Synthesis, structure and ferromagnetic magnetic property5Polymorphic Lanthanide Phosphonates Showing Distinct Magnetic Behavior22Cyclic Single‐Molecule Magnets: From Even‐Numbered Hexanuclear to Odd‐Numbered Heptanuclear Dysprosium Clusters14A unique dysprosium selenoarsenate( iii ) exhibiting a photocurrent response and slow magnetic relaxation behavior13Structures and magnetic properties of dysprosium complexes: the effect of crystallization temperature29Modulating Single-Molecule Magnetic Behavior of a Dinuclear Erbium(III) Complex by Solvent Exchange53A Dy4 single-molecule magnet and its Gd( iii ), Tb( iii ), Ho( iii ), and Er( iii ) analogues encapsulated by an 8-hydroxyquinoline Schiff base derivative and β-diketonate coligand61Di- and octa-nuclear dysprosium clusters derived from pyridyl-triazole based ligand: {Dy 2 } showing single molecule magnetic behaviour27Phthalocyanine supported dinuclear Ln III complexes: the solvent-induced change of magnetic properties in dysprosium( iii ) analogues30Solvent orientation in the crystal lattice producing distinct magnetic dynamics in two binuclear Dy( iii ) polymorphs with a polydentate Schiff base ligand12Simultaneous assembly of mononuclear and dinuclear dysprosium(III) complexes behaving as single-molecule magnets in a one-pot hydrothermal synthesis19Chemical tailoring of Single Molecule Magnet behavior in films of Dy(III) dimers21Fluorescence and magnetism of two novel isostructural Dy(III) and Tb(III) complexes based on 5-azotriazolyl salicylic acid ligand10Syntheses, crystal structures and magnetic properties of sandglass DyIII9 and irregular tetrahedron DyIII4 complexes23A series of salen-type asymmetric dinuclear Dy( iii ) complexes: site-resolved two-step magnetic relaxation process21Dramatic impact of the lattice solvent on the dynamic magnetic relaxation of dinuclear dysprosium single-molecule magnets59Reversible ON–OFF switching of single-molecule-magnetism associated with single-crystal-to-single-crystal structural transformation of a decanuclear dysprosium phosphonate69Single molecule magnetic behaviour in lanthanide naphthalenesulfonate complexes24Changing the Hydrophobic MOF Pores through Encapsulating Fullerene C60 and Metallofullerene Sc3C2@C8033Dy III single-molecule magnets from ligands incorporating both amine and acylhydrazine Schiff base groups: the centrosymmetric {Dy 2 } displaying dual magnetic relaxation behaviors21Metal phosphonates incorporating metalloligands: assembly, structures and properties53Synergetic magnetic and luminescence switching via solid state phase transitions of the dysprosium–dianthracene complex31Structural and magnetic study of a new dinuclear SMM2Evolution from a single relaxation process to two-step relaxation processes of Dy 2 single-molecule magnets via the modulations of the terminal solvent ligands14Tuning magnetic anisotropy via terminal ligands along the Dy⋯Dy orientation in novel centrosymmetric [Dy 2 ] single molecule magnets31Ionothermal synthesis of octahedral lanthanoid coordination networks exhibiting slow magnetization relaxation and efficient photoluminescence12Tuning the dynamic magnetic behaviour and proton conductivity via water-induced reversible single-crystal to single-crystal structural transformation31Homochiral Ferromagnetic Coupling Dy2 Single-Molecule Magnets with Strong Magneto-Optical Faraday Effects at Room Temperature46Reversible on–off switching of Dy( iii ) single-molecule magnets via single-crystal-to-single-crystal transformation10Porous Mn2+ Magnet with a Pt−Cl Framework: Correlation between Water Vapor Adsorption/Desorption and Slow Magnetic Relaxation2Zero-Field Slow Magnetic Relaxation in Binuclear Dy Acetylacetonate Complex with Pyridine-N-Oxide3Effect of coordinated anions on ferromagnetically coupled Dy 2 zero-field single-molecule magnets16Recent advances of dinuclear dysprosium-based single-molecule magnets: from mechanisms to application22Optical Phenomena in Molecule-Based Magnetic Materials154Two Dy2 Zero-Field Single-Molecule Magnets Derived from Hydrazone Schiff Base-Bridging Ligands and 1,3-Di(2-pyridyl)-1,3-propanedione3

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  1. Seven-Coordinate Lanthanide Sandwich-Type Complexes with a Tetrathiafulvalene-Fused Schiff Base Ligand

    Inorganic Chemistry · 2013-09-24

    Feng Gao, Long Cui, Wei Liu, Liang Hu, Yu‐Wu Zhong, Yizhi Li, Jing‐Lin Zuo

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  2. 3D Organization of Dysprosium Cubanes

    European Journal of Inorganic Chemistry · 2013-10-11

    Xiaohui Yi, Kévin Bernot, Guillaume Calvez, Carole Daiguebonne, Olivier Guillou

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  3. Calix[4]arene-Supported Mononuclear Lanthanide Single-Molecule Magnet

    Inorganic Chemistry · 2013-12-19

    Feng Gao, Long Cui, You Song, Yizhi Li, Jing‐Lin Zuo

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  4. A layered erbium phosphonate in pseudo-D5h symmetry exhibiting field-tunable magnetic relaxation and optical correlation

    Chemical Communications · 2014-01-01

    Min Ren, Song‐Song Bao, Rute A. S. Ferreira, Li‐Min Zheng, Luís D. Carlos

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  5. Cluster-Based Single-Molecule Magnets

    Structure and bonding · 2014-01-01

    Constantinos J. Milios, Richard E. P. Winpenny

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  6. Magnetic relaxation versus 3D long-range ordering in {Dy 2 Ba(α-fur) 8 } n furoate polymers

    Dalton Transactions · 2014-01-01

    Elena Bartolomé, Juan Bartolomé, S. Melnic, Denis Prodius, Sergiu G. Shova, Ana B. Arauzo, Javier Luzón, Laura Badía-Romano, Fernando M. Luis, Constantin I. Turta

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  7. Effect of Structural Isomerism on Magnetic Dynamics: from Single-Molecule Magnet to Single-Chain Magnet

    Inorganic Chemistry · 2014-03-04

    Tingting Wang, Min Ren, Song‐Song Bao, Bin Liu, Li Pi, Zhong‐Sheng Cai, Zehua Zheng, Zhong-Li Xu, Li‐Min Zheng

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  8. Synthesis, structure and properties of a tetranuclear europium(III) complex based on 9,9-dimethylfluorene-2,7-diphosphonic acid

    Journal of Molecular Structure · 2014-03-21

    Liang Li, Ao Li, Song Bai Lin, Zi-Hao Wang, Xin-Hui Zhou, Tao Yang, Wei Huang

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  9. Molecular Magnets Based on Homometallic Hexanuclear Lanthanide(III) Complexes

    Inorganic Chemistry · 2014-04-25

    Sourav Das, Sakiat Hossain, Atanu Dey, Sourav Biswas, Jean‐Pascal Sutter, Vadapalli Chandrasekhar

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  10. Homochiral Cobalt Phosphonates Containing Δ‐Type Chains with a Tunable Interlayer Distance and a Field‐Induced Phase Transition

    Chemistry - A European Journal · 2014-10-27

    Zhong‐Sheng Cai, Song‐Song Bao, Min Ren, Li‐Min Zheng

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  11. Remote control of SMM behaviour via DTE ligands

    Dalton Transactions · 2014-11-04

    Goulven Cosquer, Brian K. Breedlove, Masahiro Yamashita

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  12. Highly pH-dependent synthesis of two novel three-dimensional dysprosium complexes with interesting magnetic and luminescence properties

    CrystEngComm · 2014-11-24

    Lina Zhang, Shuting Lu, Chao Zhang, Chenxia Du, Hongwei Hou

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  13. Disentangling intricate web of interrelated notions at the interface between the physical (crystal field) Hamiltonians and the effective (spin) Hamiltonians

    Coordination Chemistry Reviews · 2014-12-19

    Czesław Z. Rudowicz, Mirosław Karbowiak

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  14. A Dy 2 single-molecule magnet with benzoate anions and phenol-O − bridging groups

    Dalton Transactions · 2015-01-01

    Hongshan Ke, Sheng Zhang, Xin Li, Qing Wei, Gang Xie, Wenyuan Wang, Sanping Chen

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  15. Cobalt and copper pyridylmethylphosphonates with two- and three-dimensional structures and field-induced magnetic transitions

    Dalton Transactions · 2015-01-01

    Ting‐Hai Yang, Zhong‐Sheng Cai, Fa‐Nian Shi, Li‐Min Zheng

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  16. Dinuclear Lanthanide Single-Molecule Magnets

    Springer eBooks · 2015-01-01

    Jinkui Tang, Peng Zhang

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  17. Enlarging the ring by incorporating a phosphonate coligand: from the cyclic hexanuclear to octanuclear dysprosium clusters

    Dalton Transactions · 2015-01-01

    Haiquan Tian, Song‐Song Bao, Li‐Min Zheng

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  18. Magnetic and luminescent properties of lanthanide coordination polymers with asymmetric biphenyl-3,2′,5′-tricarboxylate

    Dalton Transactions · 2015-01-01

    Jie Zhao, Guanhong Zhu, Li-Qiong Xie, Ye-Si Wu, Hai-Lun Wu, Ai‐Ju Zhou, Zun-Yuan Wu, Jing Wang, Yan‐Cong Chen, Ming‐Liang Tong

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  19. pH-controlled polymorphism in a layered dysprosium phosphonate and its impact on the magnetization relaxation

    Chemical Communications · 2015-01-01

    Dai Zeng, Min Ren, Song‐Song Bao, Jian‐Shen Feng, Li Li, Li‐Min Zheng

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  20. Slow Magnetic Relaxation Observed in Dysprosium Compounds Containing Unsupported Near-Linear Hydroxo- and Fluoro-Bridges

    Inorganic Chemistry · 2015-06-19

    Gabriel Brunet, Fatemah Habib, Ilia Korobkov, Muralee Murugesu

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  21. Structural and spectroscopic characterization of two new layered uranyl(VI) p-xylenediphosphonate compounds synthesized via ionothermal method

    Inorganica Chimica Acta · 2015-07-04

    Tao Zheng, Yang Gao, Lanhua Chen, Juan Diwu, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

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  22. Multiple magnetic relaxation processes, magnetocaloric effect and fluorescence properties of rhombus-shaped tetranuclear rare earth complexes

    Dalton Transactions · 2015-11-11

    Hong‐Ling Gao, Li Jiang, Shuang Liu, Hai-Yun Shen, Wen‐Min Wang, Jian‐Zhong Cui

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  23. A pseudo-icosahedral cage {Gd 12 } based on aminomethylphosphonate

    Dalton Transactions · 2016-01-01

    Zemin Zhang, Karzan H. Zangana, Andreas K. Kostopoulos, Ming‐Liang Tong, Richard E. P. Winpenny

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  24. Building 1D lanthanide chains and non-symmetrical [Ln 2 ] “triple-decker” clusters using salen-type ligands: magnetic cooling and relaxation phenomena

    Dalton Transactions · 2016-01-01

    Angelos B. Canaj, Miłosz Siczek, Marta Otręba, Tadeusz Lis, Giulia Lorusso, Marco Evangelisti, Constantinos J. Milios

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  25. Lanthanide Clusters Toward Single-Molecule Magnets

    Structure and bonding · 2016-01-01

    Tian Han, You‐Song Ding, Yan‐Zhen Zheng

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  26. Lanthanide salen-type complexes exhibiting single ion magnet and photoluminescent properties

    Dalton Transactions · 2016-01-01

    Min Ren, Zhong‐Li Xu, Song‐Song Bao, Tingting Wang, Zehua Zheng, Rute A. S. Ferreira, Li‐Min Zheng, Luís D. Carlos

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  27. Terminal solvent effects on the anisotropy barriers of Dy 2 systems

    Dalton Transactions · 2016-01-01

    Yao Jiang, Gabriel Brunet, Rebecca J. Holmberg, Fatemah Habib, Ilia Korobkov, Muralee Murugesu

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  28. Multiple-Step Humidity-Induced Single-Crystal to Single-Crystal Transformations of a Cobalt Phosphonate: Structural and Proton Conductivity Studies

    Inorganic Chemistry · 2016-03-21

    Zhong‐Sheng Cai, Song‐Song Bao, Xizhang Wang, Zheng Hu, Li‐Min Zheng

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  29. A two-dimensional Ni(II) coordination polymer built of 4-(1,2,4-triazol-4-yl)phenylphosphonate: Synthesis, structure and ferromagnetic magnetic property

    Inorganica Chimica Acta · 2016-03-27

    Pan Yang, Dianpeng Wang, Jinyu Sun, Fupeng Zhai, Zhenxia Chen, Yun Ling, Yaming Zhou

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  30. Polymorphic Lanthanide Phosphonates Showing Distinct Magnetic Behavior

    Inorganic Chemistry · 2016-05-16

    Dai Zeng, Min Ren, Song‐Song Bao, Zhong‐Sheng Cai, Chang Xu, Li‐Min Zheng

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  31. Cyclic Single‐Molecule Magnets: From Even‐Numbered Hexanuclear to Odd‐Numbered Heptanuclear Dysprosium Clusters

    European Journal of Inorganic Chemistry · 2016-05-27

    Haiquan Tian, Song‐Song Bao, Li‐Min Zheng

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  32. A unique dysprosium selenoarsenate( iii ) exhibiting a photocurrent response and slow magnetic relaxation behavior

    Dalton Transactions · 2016-12-01

    Jian Zhou, Hua‐Hong Zou, Rong-Qing Zhao, Hong Ping Xiao, Qingran Ding

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  33. Structures and magnetic properties of dysprosium complexes: the effect of crystallization temperature

    Dalton Transactions · 2016-12-07

    Mei Guo, Yue Wang, Jianfeng Wu, Lang Zhao, Jinkui Tang

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  34. Modulating Single-Molecule Magnetic Behavior of a Dinuclear Erbium(III) Complex by Solvent Exchange

    Inorganic Chemistry · 2016-12-15

    Jing‐Yuan Ge, Long Cui, Jing Li, Fei Yu, You Song, Yi‐Quan Zhang, Jing‐Lin Zuo, Mohamedally Kurmoo

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  35. A Dy4 single-molecule magnet and its Gd( iii ), Tb( iii ), Ho( iii ), and Er( iii ) analogues encapsulated by an 8-hydroxyquinoline Schiff base derivative and β-diketonate coligand

    Dalton Transactions · 2017-01-01

    Hong‐Ling Gao, Xiao-Pu Zhou, Yan-Xia Bi, Hai-Yun Shen, Wen‐Min Wang, Nini Wang, Yi-Xin Chang, Ruxia Zhang, Jian‐Zhong Cui

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  36. Di- and octa-nuclear dysprosium clusters derived from pyridyl-triazole based ligand: {Dy 2 } showing single molecule magnetic behaviour

    Dalton Transactions · 2017-01-01

    Muhammad Nadeem Akhtar, Xiao‐Fen Liao, Yan‐Cong Chen, Jun‐Liang Liu, Ming‐Liang Tong

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  37. Phthalocyanine supported dinuclear Ln III complexes: the solvent-induced change of magnetic properties in dysprosium( iii ) analogues

    Dalton Transactions · 2017-01-01

    Jing‐Yuan Ge, Hai-Ying Wang, Jing Li, Jiaze Xie, You Song, Jing‐Lin Zuo

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  38. Solvent orientation in the crystal lattice producing distinct magnetic dynamics in two binuclear Dy( iii ) polymorphs with a polydentate Schiff base ligand

    CrystEngComm · 2017-01-01

    Zhijie Jiang, Lin Sun, Qi Yang, Shilong Wei, Hongshan Ke, Sanping Chen, Yi‐Quan Zhang, Qing Wei, Gang Xie

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  39. Simultaneous assembly of mononuclear and dinuclear dysprosium(III) complexes behaving as single-molecule magnets in a one-pot hydrothermal synthesis

    Science China Chemistry · 2017-02-15

    Cai‐Ming Liu, Deqing Zhang, Xiang Hao, Daoben Zhu

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  40. Chemical tailoring of Single Molecule Magnet behavior in films of Dy(III) dimers

    Applied Surface Science · 2017-06-05

    Irene Cimatti, Xiaohui Yi, Roberta Sessoli, Marin Puget, Boris Le Guennic, Julie Jung, Thierry Guizouarn, Agnese Magnani, Kévin Bernot, Matteo Mannini

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  41. Fluorescence and magnetism of two novel isostructural Dy(III) and Tb(III) complexes based on 5-azotriazolyl salicylic acid ligand

    Inorganica Chimica Acta · 2017-08-24

    Li-Qian Huang, Yan‐Yong Lin, Ji‐Dong Leng, Jing Wang, Lanfang Yang, Wen Dong

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  42. Syntheses, crystal structures and magnetic properties of sandglass DyIII9 and irregular tetrahedron DyIII4 complexes

    Polyhedron · 2017-11-24

    Hui‐Sheng Wang, Qiao-Qiao Long, Cheng-Ling Yin, Ziwei Xu, Zhiquan Pan

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  43. A series of salen-type asymmetric dinuclear Dy( iii ) complexes: site-resolved two-step magnetic relaxation process

    CrystEngComm · 2017-12-26

    Wan‐Ying Zhang, Peng Chen, Yong‐Mei Tian, Hongfeng Li, Wen‐Bin Sun, Peng‐Fei Yan

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  44. Dramatic impact of the lattice solvent on the dynamic magnetic relaxation of dinuclear dysprosium single-molecule magnets

    Inorganic Chemistry Frontiers · 2018-01-01

    Wan‐Ying Zhang, Yi‐Quan Zhang, Shang‐Da Jiang, Wen‐Bin Sun, Hongfeng Li, Bing‐Wu Wang, Peng Chen, Peng‐Fei Yan, Song Wei Gao

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  45. Reversible ON–OFF switching of single-molecule-magnetism associated with single-crystal-to-single-crystal structural transformation of a decanuclear dysprosium phosphonate

    Chemical Science · 2018-01-01

    Haiquan Tian, Jing-Bu Su, Song‐Song Bao, Mohamedally Kurmoo, Xin‐Da Huang, Yi‐Quan Zhang, Li‐Min Zheng

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  46. Single molecule magnetic behaviour in lanthanide naphthalenesulfonate complexes

    Dalton Transactions · 2018-01-01

    Guo Peng, Ying-Ying Zhang, Bo Li, Xiaofan Sun, Hong‐Ling Cai, De‐Jing Li, Zhi‐Gang Gu, George E. Κostakis

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  47. Changing the Hydrophobic MOF Pores through Encapsulating Fullerene C60 and Metallofullerene Sc3C2@C80

    The Journal of Physical Chemistry C · 2019-02-22

    Haibing Meng, Chong Zhao, Mingzhe Nie, Chunru Wang, Taishan Wang

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  48. Dy III single-molecule magnets from ligands incorporating both amine and acylhydrazine Schiff base groups: the centrosymmetric {Dy 2 } displaying dual magnetic relaxation behaviors

    Dalton Transactions · 2020-01-01

    Senda Su, Jiaxin Li, Fan Xu, Chenxiao Wang, Kai Wang, Yan Li, Shu‐Hua Zhang, Xiu‐Qing Zhang, Yi‐Quan Zhang, Fu‐Pei Liang

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  49. Metal phosphonates incorporating metalloligands: assembly, structures and properties

    Chemical Communications · 2020-01-01

    Song‐Song Bao, Ming-Feng Qin, Li‐Min Zheng

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  50. Synergetic magnetic and luminescence switching via solid state phase transitions of the dysprosium–dianthracene complex

    Journal of Materials Chemistry C · 2020-01-01

    Jing‐Cui Liu, Xin‐Da Huang, Qian Zou, Song‐Song Bao, Xizhang Wang, Jingyuan Ma, Li‐Min Zheng

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