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RESEARCH PAPER · Journal of the American Chemical Society · 2000

The First Covalent Organic−Inorganic Networks of Hybrid Chalcogenides: Structures That May Lead to a New Type of Quantum Wells

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The First Covalent Organic−Inorganic Networks of Hybrid Chalcogenides: Structures That May Lead to a New Type of Quantum WellsOriginalA novel polycatenated double-layered hybrid organic–inorganic material constructed from [Zn2(tp)(4,4′-bpy)]n2n+ layers and V4O124− pillars88A two-dimensional coordination polymer with a brick wall structure and hydrophobic channels: synthesis and structure of a macrocyclic nickel(ii) complex with 1,3,5-benzenetricarboxylate12Inorganic−Organic Hybrid Composites Containing MQ (II−VI) Slabs: A New Class of Nanostructures with Strong Quantum Confinement and Periodic Arrangement126Mn-Substituted Inorganic−Organic Hybrid Materials Based on ZnSe: Nanostructures That May Lead to Magnetic Semiconductors with a Strong Quantum Confinement Effect108[ZnSe(dbn)1/2] and [ZnSe(hda)1/2]: Two New Members of Inorganic-Organic Hybrid Semiconductor Nanocomposites Exhibiting A Strong Quantum Confinement Effect13Synthesis and X-ray crystal structures of one-dimensional coordination polymers of macrocyclic copper(ii) and nickel(ii) complexes4Optical properties of ZnS nanosheets, ZnO dendrites, and their lamellar precursor ZnS·(NH2CH2CH2NH2)0.591Laser-based non-fluorescence detection techniques for liquid separation systems28Crystal of Semiconducting Quantum Dots Built on Covalently Bonded T5 [In28Cd6S54]-12: The Largest Supertetrahedral Cluster in Solid State95[Cu(i)(bpp)]BF4: the first extended coordination network prepared solvothermally in an ionic liquid solvent197Zinc10Synthesis and Characterization of an Open Framework Gallium Selenide: Ga4Se7(en)2·(enH)227Novel Inorganic−Organic-Layered Structures: Crystallographic Understanding of Both Phase and Morphology Formations of One-Dimensional CdE (E = S, Se, Te) Nanorods in Ethylenediamine173Size- and shape-tailored hydrothermal synthesis of YVO4 crystals in ultra-wide pH range conditions107Synthesis, Structure, and Luminescence of 2D-Dilute Magnetic Semiconductors: Zn1-xMnxSe·0.5L (L = Diamines)31Kinetically Controlled Synthesis of Wurtzite ZnS Nanorods through Mild Thermolysis of a Covalent Organic−Inorganic Network177[Cd16In64S134]44−: 31‐Å Tetrahedron with a Large Cavity116[Cd16In64S134]44−: 31‐Å Tetrahedron with a Large Cavity19From 1D Chain to 3D Network: Tuning Hybrid II-VI Nanostructures and Their Optical Properties233A Novel Three-Dimensional Network Constructed from Tetramolybdate Clusters Linked via Two Types of Copper Complex Fragments: Synthesis, Characterization, and Magnetic Behavior of [{CuII(2,2‘-bpy)}{CuII(IN)2}{Mo4O12(OH)2}]98Hydrothermal syntheses, crystal structures and magnetic properties of two inorganic–organic hybrid materials: [{Cu(phen)}2(VVO2)2VIVO2(H2O)(PO4)2] and [V4O7(2,2′-bpy)2(HPO4)2] (phen=1,10-phenathroline, bpy=bipyridine)15Synthesis and Characterization of Magnetic Iron Sulfide Nanowires113Semiconductor zinc chalcogenides nanofibers from 1-D molecular precursors56Hydrothermal synthesis and crystal structure of a novel two-dimensional organic–inorganic hybrid copper molybdate with mixed organodiamine and dicarboxyl ligands14Density-functional study of organic–inorganic hybrid single crystal ZnSe(C2H8N2)1/239Electronic properties of hybrid organic–inorganic semiconductors54Self-assembly of polyoxometalate clusters into a 3-D heterometallic framework via covalent bonding: synthesis, structure and characterization of Na4[Nd8(dipic)12(H2O)9][Mo8O26]·8H2O16Flexible Wurtzite‐Type ZnS Nanobelts with Quantum‐Size Effects: a Diethylenetriamine‐Assisted Solvothermal Approach132Syntheses and structures of two novel inorganic–organic hybrid octamolybdates: [H2enMe]2[Mo8O26]·2H2O and [Ni(2,2′-bpy)3]2[δ-Mo8O26]40Syntheses, structures and properties of three metal pyridinecarboxylates13Structure and Luminescence of 2D Dilute Magnetic Semiconductors: Cd 1 - x Mn x Se·L 0.5 (L = Diamines)32Syntheses and Electronic Behaviors of Networked Alternating Neodymium‐Organic Moiety Hybrid Copolymers7Synthesis and Electronic Behavior of a Ternary, Alternating Zirconium‐Phenylene‐Tin Hybrid Copolymer5A Low-Temperature and Mild Solvothermal Route to the Synthesis of Wurtzite-Type ZnS With Single-Crystalline Nanoplate-like Morphology73Organic-inorganic hybrid semiconductor ZnSe(C2H8N2)1∕2 under hydrostatic pressure5Polymorphic One-Dimensional (N2H4)2ZnTe: Soluble Precursors for the Formation of Hexagonal or Cubic Zinc Telluride50A Precursor‐Based Route to ZnSe Nanowire Bundles107Nanocrystals of an Inorganic–Organic Hybrid Semiconductor: Formation of Uniform Nanobelts of [ZnSe](Diethylenetriamine)0.5 in a Ternary Solution117Solution Route to Semiconducting Nanomaterials1Complex Wurtzite ZnSe Microspheres with High Hierarchy and Their Optical Properties56Novel Approach to Tuning the Physical Properties of Organic-Inorganic Hybrid Semiconductors63A New Type of Hybrid Magnetic Semiconductor Based upon Polymeric Iodoplumbate and Metal−Organic Complexes as Templates84Two luminescent alkali-silver heterometallic sulfonates15Selectively hydrothermal and solvothermal growth of CdS nanospheres and nanorods: a facile way to tune finely optical properties34Crystal structures and magnetic properties of two new phosphate-metal complexes: [Cu2(bpy)2(μ,η2-HPO4)(μ, η1-H2PO4)(μ,η2-H2PO4)]n and [Cu4(phen)4(μ3,η2-HPO4)2(μ,η2-H2PO4)2(H2PO4)2](H2O)419From One-Dimensional Chains to Three-Dimensional Networks: Solvothermal Synthesis of Thiogallates in Ethylenediamine59Synthesis and structure of a novel one-dimensional vanadate constructed from tetravanadate clusters linked via copper–organic complex moieties: [{Cu(phen)(H2O)}2V4O12]4Structural diversity and optical properties in the M–X-isonicotinic (M = Zn, Cd; X = Cl, Br, I) system: New zero-, one-, two- and three-dimensional inorganic–organic hybrids7Solvothermal Synthesis and Photoluminescent Properties of ZnS/Cyclohexylamine: Inorganic−Organic Hybrid Semiconductor Nanowires45Self-assembly of four three-dimensional reduced molybdenum(V) phosphates decorated with transitional metal complexes28Molecular and Multidimensional Organic−Inorganic Hybrids Based on Polyoxometalates and Copper Coordination Polymer with Mixed 4,4‘-Bipyridine and 2,2‘-Bipyridine Ligands101Vertically aligned and hexagonal crystal ZnSe nanoribbon arrays on Zn substrates3Two novel inorganic–organic hybrids based on saturated Wells–Dawson polyoxoanion and copper–organonitrogen coordination polymer32Heavy‐Metal‐Ion Capture, Ion‐Exchange, and Exceptional Acid Stability of the Open‐Framework Chalcogenide (NH4)4In12Se20136Shape-Controlled Solution-Synthesis of Single Crystalline ZnTe 1D Nanocrystals0Solvothermal synthesis and crystal structure of the Mo(VI)-bridged helical chain containing Mo2(V) dimers: (C4H12N2)2[(MoV2O4)(MoVIO4)(C2O4)2]·2H2O8Three-dimensional gallium sulphide open frameworks47From Mesostructured Wurtzite ZnS‐Nanowire/Amine Nanocomposites to ZnS Nanowires Exhibiting Quantum Size Effects: A Mild‐Solution Chemistry Approach129New inorganic–organic composite ZnSe(MXDA)1/216From Single to Multiple Atomic Layers: A Unique Approach to the Systematic Tuning of Structures and Properties of Inorganic−Organic Hybrid Nanostructured Semiconductors209Report from the third workshop on future directions of solid-state chemistry: The status of solid-state chemistry and its impact in the physical sciences75Mixed-solvothermal synthesis of hybrid nanostructures of alkaline earth phenylphosphonates7Hybrid organic–inorganic assemblies built up from saturated heteropolyoxoanions and copper coordination polymers with mixed 4,4′-bipyridine and 2,2′-bipyridine ligands30Vertically aligned zinc selenide nanoribbon arrays: microstructure and field emission26Synthesis and structure of a hybrid-metallic complex [Cu4(obpy)4(Mo2O7)] containing CuI/CuII unit1Preparation of Manganese-doped ZnSe Precursor Nanoribbon Bundles and Investigation of its Magneto-optical Properties0Nanostructured Crystals: Unique Hybrid Semiconductors Exhibiting Nearly Zero and Tunable Uniaxial Thermal Expansion Behavior86A New Series of Chalcohalide Semiconductors with Composite CdBr2/Sb2Se3 Lattices: Synthesis and Characterization of CdSb2Se3Br2 and Indium Derivatives InSb2S4X (X = Cl and Br) and InM2Se4Br (M = Sb and Bi)37Zero Thermal Expansion in a Nanostructured Inorganic-Organic Hybrid Crystal45Studies on the thermoelectric effect in semiconducting ZnTe thin films28Synthesis of a Net-Worked Strontium-O-Phenylene-S-Tellurium Hybrid Co-polymer Having a Two-Step Electron Transfer Nature1Hydrothermal synthesis and structural characterization of two 1-D and 2-D Dawson-based phosphotungstates22One-Dimensional Angle-Shaped ZnSe Nanostructures: Synthesis and Formation Mechanism21Preparation and Characterization of Cubic and Hexagonal Polytypes of ZnSe:Cu2+ One-Dimensional Nanostructures14Synthesis and Characterization of Organic–Inorganic Hybrid GeOx/Ethylenediamine Nanowires62Solvothermal synthesis and characterization of ZnSe nanoplates38Hydrothermal syntheses and structural characterization of two new supramolecular compounds: (H2bbi)2[Mo8O26] and (H2bbi)2[SiW12O40]·2H2O [bbi=1,1′-(1,4-butanediyl)bis(imidazole)]9A Semiconductor Bulk Material That Emits Direct White Light198Synthesis and Magnetic Properties of New [Fe18S25](TETAH)14(TETAH = Protonated Triethylenetetramine) Nanoribbons: An Efficient Precursor to Fe7S8Nanowires and Porous Fe2O3Nanorods59Three new multidimensional organic–inorganic hybrids based on polyoxometalates and copper coordination polymers with 4,4′-bipyridine ligands29A small biomolecule-assisted synthesis of iron sulfide nanostructures and magnetic properties20Chiral II−VI Semiconductor Nanostructure Superlattices Based on an Amino Acid Ligand42A 3D architecture constructed by saturated Dawson polyoxoanions and transition-metal coordination complexes [CuI7(Bpy)6(BpyEt)2]0Hydrothermal Synthesis and Structural Characterization of an Inorganic–Organic Hybrid Sandwich-type Germanotungstate2Synthesis of Semiconducting Functional Materials in Solution: From II‐VI Semiconductor to Inorganic–Organic Hybrid Semiconductor Nanomaterials125Density Functional Study of 2D Semiconductor CdSe·hda0.5(hda= 1,6-hexanediamine) and Its Excitonic Optical Properties22Synthesis of Semiconducting Functional Materials in Solution: From II‐VI Semiconductor to Inorganic‐Organic Hybrid Semiconductor Nanomaterials91Two-dimensional organic–inorganic hybrid materials based on β-octamolybdate units linked by [{Cu(imi)(phen)}2Cl]3+ and K+ bridges14Synthesis, structure and photoluminescence of a 3D pillared heterometallic coordination polymer containing 2D inorganic cadmium‐potassium‐oxide layer subunits3(H2NC4H8NCH2CH2NH2)2Zn2Sn2Se7: a hybrid ternary semiconductor stabilized by amine molecules acting simultaneously as ligands and counterions10Solvent properties of hydrazine in the preparation of metal chalcogenide bulk materials and films84Two-Dimensional Metal−Organic Frameworks: A System with Competing Chelating Ligands31Hydrothermal Synthesis, Structure Characterization, Catalytic Property of Four Inorganic‐Organic Hybrid Phosphomolybdates13The structure of hybrid radial superlattices36(H2NC4H8NCH2CH2NH2)(HNCH2CH2NH2)3Zn2Ge2Se8: A new, templated one-dimensional ternary semiconductor stabilized by mixed organic cations12Synthesis of Unique Ultrathin Lamellar Mesostructured CoSe2−Amine (Protonated) Nanobelts in a Binary Solution236New Blue‐Light‐Emitting Ultralong [Cd(L)(TeO3)] (L=polyamine) Organic–Inorganic Hybrid Nanofibre Bundles: Their Thermal Stability and Acidic Sensitivity11Synthesis and characterisation of lamellar ZnS nanosheets containing intercalated diamines15Hydrothermal syntheses and structural characterization of two organic–inorganic hybrid compounds based on Lindqvist polyanions9Quaternary Tin(IV) Antimony(III) Sulfide Decorated with Lanthanum(III) Ethylenediamine Complexes: [La(en)4SbSnS5]2·0.5H2O37Flexible Hybrid Semiconductors with Low Thermal Conductivity: The Role of Organic Diamines85Flexible Hybrid Semiconductors with Low Thermal Conductivity: The Role of Organic Diamines10Solvothermal Stepwise Formation of Cu/I/S-Based Semiconductors from a Three-Dimensional Net to One-Dimensional Chains47Mn-Substituted [Zn1−xMnxSe](DETA)0.5 (x = 0−0.3) Inorganic−Organic Hybrid Nanobelts: Synthesis, Electron Paramagnetic Resonance Spectroscopy, and Their Temperature- and Pressure-Dependent Optical Properties25N-Doped ZnS Nanoparticles Prepared through an Inorganic−Organic Hybrid Complex ZnS·(piperazine)0.528Synthesis, Characterization and Crystal Structure of a Novel Mn(II) Coordination Polymer Material with Rigid Tetracarboxylate and Chelating N-Donor Co-Ligand8Small organic molecule templating synthesis of organic–inorganic hybrid materials: their nanostructures and properties101One-pot synthesis of flowerlike Ni 7 S 6 and its application in selective hydrogenation of chloronitrobenzene81A low band gap iron sulfide hybrid semiconductor with unique 2D [Fe16S20]8− layer and reduced thermal conductivity32Direct white light emission from inorganic–organic hybrid semiconductor bulk materials61Hydrazine-cadmium tellurite hybrid microcrystals: An efficient precursor to porous cadmium telluride and tellurium architectures through its thermal decomposition9Zinc, Cadmium, and Mercury Complexes with Fluorinated Selenolate Ligands19CuO based inorganic–organic hybrid nanowires: a new type of highly sensitive humidity sensor38Microstructure and optical characterization of CdTe quantum dots synthesized in a record minimum time18From (Cd2Se2)(pa) (pa = propylamine) hybrid precursors to various CdSe nanostructures: structural evolution and optical properties14Solvothermal synthesis and characterization of two novel europium thioantimonates(iii) containing [SbIIIS3] unit as an unusual chelating ligand20Thermodynamically controlled coordination-engineering of novel 2D cadmium thiolate coordination polymers9Solvothermal synthesis of ZnS[C2H4(NH2)2]0.5 nanosheets16New Semiconducting Coordination Polymers from Zinc Sulfide Clusters and Chains24Crystal structures and optical properties of 1-D iodoplumbates templated by in situ synthesized p-phenylenediamine derivatives31Synthesis and characterization of inorganic‐organic ZnS(aminopropane)n composite materials12Microstructural, optical and quantum confinement effect study of mechanically synthesized ZnTe quantum dots28A New Class of Nanostructured Inorganic–Organic Hybrid Semiconductors Based on II–VI Binary Compounds19Solution‐Processable White‐Light‐Emitting Hybrid Semiconductor Bulk Materials with High Photoluminescence Quantum Efficiency152Solution‐Processable White‐Light‐Emitting Hybrid Semiconductor Bulk Materials with High Photoluminescence Quantum Efficiency39Synthesis, Characterization, and Calculated Electronic Structure of the Crystalline Metal–Organic Polymers [Hg(SC6H4S)(en)]n and [Pb(SC6H4S)(dien)]n25A novel inorganic–organic hybrid for detection of nitrite anions with extremely high sensitivity and selectivity34Synthesis, Characterization, and Crystal Structure of Two Coordination Polymer Material with Rigid Tetracarboxylate and Chelating N-Donor Coligand1Quickest ever single-step mechanosynthesis of Cd0.5Zn0.5S quantum dots: Nanostructure and optical characterizations38Solvothermal Synthesis and Characterization of One‐dimensional Indium Polyselenides with Transition Metal Complexes8Dimensional Reduction of a Layered Metal Chalcogenide into a 1D Near-IR Direct Band Gap Semiconductor47Morphology Controlled Synthesis of ZnS(en)0.5 Nanostructures via a Novel Mixed-Solvent Solvothermal Process1Tuning and Enhancing White Light Emission of II–VI Based Inorganic–Organic Hybrid Semiconductors as Single-Phased Phosphors82One-Pot and Template-Free Fabrication of ZnS·(ethylenediamine)0.5 Hybrid Nanobelts45One novel multidimensional organic–inorganic hybrid based on polyoxometalates and copper chlorine coordination polymers with 4,4′-bipyridine ligands5New polyfluorinated aromatic and aza-aromatic diselenides, selenyl chlorides, non-symmetric selenides and selenoxides11ZnS/Ethylenediamine Hybrid Micrometer Sheets Synthesized In Situ on Zn Foils1Intercalation of organic molecules into SnS2 single crystals40Nearly‐Zero Thermal Expansion Along the Layer‐Stacking Axis of ZnSe‐Based Inorganic–Organic Hybrid Semiconductor Materials8The first single-sized (∼1 nm) and periodically ordered array of In 2 Te 3 semiconductor quantum dots self-assembled in solution23Solvothermal synthesis and characterization of thioindate–thioantimonates with transition-metal complexes: The first examples of the incorporation of transition metal ions into In–S–Sb frameworks25A 3-D chiral organic–inorganic hybrid zinc vanadate assembled from helical units20A new inorganic–organic hybrid In2Se3(en) as hollow nanospheres: hydrothermal synthesis and near-infrared photoluminescence properties25A new polymorph telluridoindate [In(en)3][In5Te9(en)2] with photocatalytic properties12Nanostructured Inorganic–Organic Hybrid Semiconductor Materials3The syntheses, structures and properties of three new lanthanoid thioarsenates: the only example of thioarsenate acting as a ligand to a lanthanide complex20Tunability of giant Rashba spin splitting in BiTeI9Progress, Challenges, and Opportunities in Two-Dimensional Materials Beyond Graphene4878Naturally Self-Assembled Nanosystems and Their Templated Structures for Photonic Applications21Dimensionally Reduced One-Dimensional Chains of TiSe214

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  1. A novel polycatenated double-layered hybrid organic–inorganic material constructed from [Zn2(tp)(4,4′-bpy)]n2n+ layers and V4O124− pillars

    Journal of the Chemical Society Dalton Transactions · 2001-01-01

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  2. A two-dimensional coordination polymer with a brick wall structure and hydrophobic channels: synthesis and structure of a macrocyclic nickel(ii) complex with 1,3,5-benzenetricarboxylate

    CrystEngComm · 2001-01-01

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  3. Inorganic−Organic Hybrid Composites Containing MQ (II−VI) Slabs: A New Class of Nanostructures with Strong Quantum Confinement and Periodic Arrangement

    Chemistry of Materials · 2001-08-21

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  4. Mn-Substituted Inorganic−Organic Hybrid Materials Based on ZnSe: Nanostructures That May Lead to Magnetic Semiconductors with a Strong Quantum Confinement Effect

    Nano Letters · 2001-08-21

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  5. [ZnSe(dbn)1/2] and [ZnSe(hda)1/2]: Two New Members of Inorganic-Organic Hybrid Semiconductor Nanocomposites Exhibiting A Strong Quantum Confinement Effect

    MRS Proceedings · 2002-01-01

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  6. Synthesis and X-ray crystal structures of one-dimensional coordination polymers of macrocyclic copper(ii) and nickel(ii) complexes

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  8. Laser-based non-fluorescence detection techniques for liquid separation systems

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  9. Crystal of Semiconducting Quantum Dots Built on Covalently Bonded T5 [In28Cd6S54]-12: The Largest Supertetrahedral Cluster in Solid State

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  10. [Cu(i)(bpp)]BF4: the first extended coordination network prepared solvothermally in an ionic liquid solvent

    Chemical Communications · 2002-10-31

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  11. Zinc

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  16. Kinetically Controlled Synthesis of Wurtzite ZnS Nanorods through Mild Thermolysis of a Covalent Organic−Inorganic Network

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  17. [Cd16In64S134]44−: 31‐Å Tetrahedron with a Large Cavity

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  18. [Cd16In64S134]44−: 31‐Å Tetrahedron with a Large Cavity

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  19. From 1D Chain to 3D Network: Tuning Hybrid II-VI Nanostructures and Their Optical Properties

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  20. A Novel Three-Dimensional Network Constructed from Tetramolybdate Clusters Linked via Two Types of Copper Complex Fragments: Synthesis, Characterization, and Magnetic Behavior of [{CuII(2,2‘-bpy)}{CuII(IN)2}{Mo4O12(OH)2}]

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  21. Hydrothermal syntheses, crystal structures and magnetic properties of two inorganic–organic hybrid materials: [{Cu(phen)}2(VVO2)2VIVO2(H2O)(PO4)2] and [V4O7(2,2′-bpy)2(HPO4)2] (phen=1,10-phenathroline, bpy=bipyridine)

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  22. Synthesis and Characterization of Magnetic Iron Sulfide Nanowires

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  26. Electronic properties of hybrid organic–inorganic semiconductors

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  31. Structure and Luminescence of 2D Dilute Magnetic Semiconductors: Cd 1 - x Mn x Se·L 0.5 (L = Diamines)

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  32. Syntheses and Electronic Behaviors of Networked Alternating Neodymium‐Organic Moiety Hybrid Copolymers

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  34. A Low-Temperature and Mild Solvothermal Route to the Synthesis of Wurtzite-Type ZnS With Single-Crystalline Nanoplate-like Morphology

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  35. Organic-inorganic hybrid semiconductor ZnSe(C2H8N2)1∕2 under hydrostatic pressure

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  36. Polymorphic One-Dimensional (N2H4)2ZnTe: Soluble Precursors for the Formation of Hexagonal or Cubic Zinc Telluride

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  37. A Precursor‐Based Route to ZnSe Nanowire Bundles

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  38. Nanocrystals of an Inorganic–Organic Hybrid Semiconductor: Formation of Uniform Nanobelts of [ZnSe](Diethylenetriamine)0.5 in a Ternary Solution

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