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RESEARCH PAPER · ACS Catalysis · 2012

Synthesis of Na-Stabilized Nonporous t-ZrO2 Supports and Pt/t-ZrO2 Catalysts and Application to Water-Gas-Shift Reaction

Hong Lan Xie, Junling Lu, Mayank Shekhar, Jeffery W. Elam, W. Nicholas Delgass, Fabio H. Ribeiro, Eric D. Weitz, Kenneth Reinhard Poeppelmeier

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Synthesis of Na-Stabilized Nonporous t-ZrO2 Supports and Pt/t-ZrO2 Catalysts and Application to Water-Gas-Shift ReactionOriginalActivation of carbon-supported platinum catalysts by sodium for the low-temperature water-gas shift reaction60Production of syngas from steam reforming and CO removal with water gas shift reaction over nanosized Zr0.95Ru0.05O2−δ solid solution15Scalable Production of Nanostructured Particles using Atomic Layer Deposition36High stability and activity of Pt electrocatalyst on atomic layer deposited metal oxide/nitrogen-doped graphene hybrid support59SiO2 promoted Pt/WO /ZrO2 catalysts for the selective hydrogenolysis of glycerol to 1,3-propanediol147Bridging the Chemical and Biological Catalysis Gap: Challenges and Outlooks for Producing Sustainable Chemicals176Highly Active Ni/ x Na/CeO 2 Catalyst for the Water–Gas Shift Reaction: Effect of Sodium on Methane Suppression177The Rise of Calcination Temperature Enhances the Performance of Cu Catalysts: Contributions of Support90Highly transparent porous ZrO 2 thin films: fabrication and optical properties6Low-Temperature WGS Reaction9High-temperature water–gas shift reaction over Ni/xK/CeO2 catalysts: Suppression of methanation via formation of bridging carbonyls129ZrO2@Ag composite catalyst for hydrogenation reduction of organic dye: Preparation and characterization as well as catalytic performance evaluation11Biorenewable chemicals: Feedstocks, technologies and the conflict with food production128One-step synthesis of flower-like carbon-doped ZrO2 for visible-light-responsive photocatalyst77Syngas Production via Steam–CO2 Dual Reforming of Methane over LA-Ni/ZrO2 Catalyst Prepared by l -Arginine Ligand-Assisted Strategy: Enhanced Activity and Stability90Fabrication of Porous ZrO2 Nanostructures with Controlled Crystalline Phases and Structures via a Facile and Cost-Effective Hydrothermal Approach57SiO 2 -stabilized Ni/t-ZrO 2 catalysts with ordered mesopores: one-pot synthesis and their superior catalytic performance in CO methanation22Hierarchically structured tetragonal zirconia as a promising support for robust Ni based catalysts for dry reforming of methane33High Thermal Stability of La2O3- and CeO2-Stabilized Tetragonal ZrO222Promotion of the Water‐Gas‐Shift Reaction by Nickel Hydroxyl Species in Partially Reduced Nickel‐Containing Phyllosilicate Catalysts95Metastable Nanocrystalline Zirconia in Light of the Nucleation Theory8Dry reforming of methane towards CO-rich hydrogen production over robust supported Ni catalyst on hierarchically structured monoclinic zirconia nanosheets29Hydrogen production from catalytic steam reforming of phenol with bimetallic nickel-cobalt catalyst on various supports76Influence of Ni to Co ratio supported on ZrO2 catalysts in phenol steam reforming for hydrogen production82CO 2 selective hydrogenation to synthetic natural gas (SNG) over four nano-sized Ni/ZrO 2 samples: ZrO 2 crystalline phase & treatment impact36Morphology effect of zirconia support on the catalytic performance of supported Ni catalysts for dry reforming of methane25Importance of metal-oxide interfaces in heterogeneous catalysis: A combined DFT, microkinetic, and experimental study of water-gas shift on Au/MgO138Controllable design of natural gully-like TiO 2 –ZrO 2 composites and their photocatalytic degradation and hydrogen production by water splitting19Recent Advances in Atomic Metal Doping of Carbon‐based Nanomaterials for Energy Conversion347Pt–WO on monoclinic or tetrahedral ZrO2: Crystal phase effect of zirconia on glycerol hydrogenolysis to 1,3-propanediol139Mesoporous ZrO2 Nanoframes for Biomass Upgrading34Methanation of CO2 over alkali-promoted Ru/TiO2 catalysts: I. Effect of alkali additives on catalytic activity and selectivity157Ni–Sn-Supported ZrO2 Catalysts Modified by Indium for Selective CO2 Hydrogenation to Methanol210Sulfur-Resistant CO Methanation to CH4 Over MoS2/ZrO2 Catalysts: Support Size Effect On Morphology and Performance of Mo Species15Quantitative Effect of Zr Content on the Structure and Water–Gas Shift Reaction Activities of Gold Supported on Ceria–Zirconia9Preparation and Characterization of SiO2/Co and C/Co Nanocomposites as Fisher-Tropsch Catalysts for CO2 Hydrogenation6Engineering Stable Surface Oxygen Vacancies on ZrO2 by Hydrogen-Etching Technology: An Efficient Support of Gold Catalysts for Water-Gas Shift Reaction72An in depth investigation of deactivation through carbon formation during the biogas dry reforming reaction for Ni supported on modified with CeO2 and La2O3 zirconia catalysts22317O Solid-State NMR Studies of ZrO2 Nanoparticles28Effect of sodium content on the interaction between Ni and support and catalytic performance for syngas methanation over Ni/Zr–Yb–O catalysts5Design of Pt/t-ZrO2/g-C3N4 efficient photocatalyst for the hydrogen evolution reaction174In-situ embedding ZrO2 nanoparticles in hierarchically porous carbon matrix as electrode materials for high desalination capacity of hybrid capacitive deionization38Morphology-Oriented ZrO2-Supported Vanadium Oxide for the NH3-SCR Process: Importance of Structural and Textural Properties47Improvement in the activity of Ni/ZrO2 by cold plasma decomposition for dry reforming of methane48Optimization of Co-precipitation Condition for Preparing Molybdenum-Based Sulfur-Resistant Methanation Catalysts3Understanding the Nature and Activity of Supported Platinum Catalysts for the Water–Gas Shift Reaction: From Metallic Nanoclusters to Alkali-Stabilized Single-Atom Cations74Low-Temperature Photothermal Catalytic Oxidation of Toluene on a Core/Shell SiO2@Pt@ZrO2 Nanostructure35Facile precipitation synthesis, structural, morphological, photoluminescence and photocatalytic properties of Ni doped ZrO 2 nanoparticles30Recent progress in the development of catalysts for steam reforming of biomass tar model reaction193A systematic theoretical study of the water gas shift reaction on the Pt/ZrO 2 interface and Pt(111) face: key role of a potassium additive27Design of catalysts comprising a nickel core and ceria shell for hydrogen production from plastic waste gasification: an integrated test for anti-coking and catalytic performance23Effect of pH on the catalytic performance of PtSn/B-ZrO2 in propane dehydrogenation34Excellent Photocatalytic Efficiency of t-ZrO2/g-C3N4 Photocatalyst for Pollutants Degradation: Experiment and theory11Platinum Based Catalysts in the Water Gas Shift Reaction: Recent Advances58Addition of Sodium Additives for Improved Performance of Water-Gas Shift Reaction over Ni-Based Catalysts9Embedding ruthenium nanoparticles in the shell layer of titanium zirconium oxide hollow spheres to catalyze the degradation of alkali lignin under mild condition19Effect of Cu doping ZrO2Thin films on physical properties grown by spray pyrolysis deposition4Hydrogenolysis of Glycerol to 1,3‐Propanediol: Are Spatial and Electronic Configuration of “Metal‐Solid Acid” Interface Key for Active and Durable Catalysts?29Intramolecular cyclization of alkynoic acid catalyzed by Na-salt-modified Au nanoparticles supported on metal oxides16Catalyst Deactivation and Its Mitigation during Catalytic Conversions of Biomass200Steering ammonia decomposition over Ru nanoparticles on ZrO 2 by enhancing metal–support interaction28Controlled fabrication of novel zirconia nanoparticles with tailored size, morphology, crystal phases, surface properties, and acidity via Indonesian Boehmeria virgata-mediated eco-friendly synthesis9Evaluating bimetallic Ni-Co oxygen carriers for their redox behavior and catalytic activity toward steam methane reforming25Hydrothermal synthesis of ZnZrO x catalysts for CO 2 hydrogenation to methanol: the effect of pH on structure and activity7Combined hydrothermal and mechanochemical control of structural modifications of zirconium dioxide for catalytic applications5Lattice-Confined single cobalt atom in ZrO2 for propane non-oxidative dehydrogenation10Hydrothermal Synthesis of ZrO2 Nanoparticles: Study on Structural, Optical, Morphology Properties and Photocatalyst Activity11High-purity hydrogen production from aqueous-phase reforming of methanol over supported Pt nanoparticles on Na-doped zirconia4Iron promoted methane suppression over Ni-Fe alloys for high temperature water gas shift reaction at low steam condition6Atomic Layer Deposition on Particulate Materials from 1988 through 2023: A Quantitative Review of Technologies, Materials, and Applications19Investigation on Microwave mass-thermal effect of Nano-ZrO2 Powders by Microwave Pyrolysis0Investigation on Microwave mass-thermal effect of Nano-ZrO2 Powders by Microwave Pyrolysis0One step green synthesis and characterization of Na+ enriched t-ZrO2 QDs: Exploring the nano-structural, electronic, optical and photoluminescence characteristics3Upcycling biomass tar into value-added chemicals via catalytic steam reforming: Mechanisms, catalyst evaluation and perspectives1Investigation on Microwave mass-thermal effect of Nano- ZrO2 Powders by Microwave Pyrolysis0Nickel-Doped CdZrOx/SAPO-34 with Enhanced CO2 Activation and H2 Spillover: Promoting Selective Light Alkane Formation with High Activity and Durability0

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  1. Activation of carbon-supported platinum catalysts by sodium for the low-temperature water-gas shift reaction

    Applied Catalysis B: Environmental · 2013-07-11

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  2. Production of syngas from steam reforming and CO removal with water gas shift reaction over nanosized Zr0.95Ru0.05O2−δ solid solution

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  3. Scalable Production of Nanostructured Particles using Atomic Layer Deposition

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  4. High stability and activity of Pt electrocatalyst on atomic layer deposited metal oxide/nitrogen-doped graphene hybrid support

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  5. SiO2 promoted Pt/WO /ZrO2 catalysts for the selective hydrogenolysis of glycerol to 1,3-propanediol

    Applied Catalysis B: Environmental · 2014-05-04

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  6. Bridging the Chemical and Biological Catalysis Gap: Challenges and Outlooks for Producing Sustainable Chemicals

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    Thomas James Schwartz, Brandon J. O’Neill, Brent H. Shanks, James A. Dumesic

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  7. Highly Active Ni/ x Na/CeO 2 Catalyst for the Water–Gas Shift Reaction: Effect of Sodium on Methane Suppression

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    Ming Li Ang, Usman Oemar, Eng Toon Saw, Liuye Mo, Yasotha Kathiraser, Beitian Chia, Sibudjing Kawi

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  8. The Rise of Calcination Temperature Enhances the Performance of Cu Catalysts: Contributions of Support

    ACS Catalysis · 2014-09-18

    Yifeng Zhu, Yifeng Zhu, Xiao Le Kong, Dong-Bo Cao, Jinglei Cui, Yulei Zhu, Yulei Zhu, Yongwang Li

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  9. Highly transparent porous ZrO 2 thin films: fabrication and optical properties

    RSC Advances · 2015-01-01

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  10. Low-Temperature WGS Reaction

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  11. High-temperature water–gas shift reaction over Ni/xK/CeO2 catalysts: Suppression of methanation via formation of bridging carbonyls

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    Ming Li Ang, Usman Oemar, Yasotha Kathiraser, Eng Toon Saw, Claire Lew, Yonghua Du, Armando Borgna, Sibudjing Kawi

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  12. ZrO2@Ag composite catalyst for hydrogenation reduction of organic dye: Preparation and characterization as well as catalytic performance evaluation

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  13. Biorenewable chemicals: Feedstocks, technologies and the conflict with food production

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  14. One-step synthesis of flower-like carbon-doped ZrO2 for visible-light-responsive photocatalyst

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  15. Syngas Production via Steam–CO2 Dual Reforming of Methane over LA-Ni/ZrO2 Catalyst Prepared by l -Arginine Ligand-Assisted Strategy: Enhanced Activity and Stability

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  16. Fabrication of Porous ZrO2 Nanostructures with Controlled Crystalline Phases and Structures via a Facile and Cost-Effective Hydrothermal Approach

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  17. SiO 2 -stabilized Ni/t-ZrO 2 catalysts with ordered mesopores: one-pot synthesis and their superior catalytic performance in CO methanation

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  18. Hierarchically structured tetragonal zirconia as a promising support for robust Ni based catalysts for dry reforming of methane

    RSC Advances · 2016-01-01

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  19. High Thermal Stability of La2O3- and CeO2-Stabilized Tetragonal ZrO2

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  20. Promotion of the Water‐Gas‐Shift Reaction by Nickel Hydroxyl Species in Partially Reduced Nickel‐Containing Phyllosilicate Catalysts

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  21. Metastable Nanocrystalline Zirconia in Light of the Nucleation Theory

    The Journal of Physical Chemistry C · 2016-04-27

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  22. Dry reforming of methane towards CO-rich hydrogen production over robust supported Ni catalyst on hierarchically structured monoclinic zirconia nanosheets

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  23. Hydrogen production from catalytic steam reforming of phenol with bimetallic nickel-cobalt catalyst on various supports

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  24. Influence of Ni to Co ratio supported on ZrO2 catalysts in phenol steam reforming for hydrogen production

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  25. CO 2 selective hydrogenation to synthetic natural gas (SNG) over four nano-sized Ni/ZrO 2 samples: ZrO 2 crystalline phase & treatment impact

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  26. Morphology effect of zirconia support on the catalytic performance of supported Ni catalysts for dry reforming of methane

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  27. Importance of metal-oxide interfaces in heterogeneous catalysis: A combined DFT, microkinetic, and experimental study of water-gas shift on Au/MgO

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  28. Controllable design of natural gully-like TiO 2 –ZrO 2 composites and their photocatalytic degradation and hydrogen production by water splitting

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  33. Ni–Sn-Supported ZrO2 Catalysts Modified by Indium for Selective CO2 Hydrogenation to Methanol

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  34. Sulfur-Resistant CO Methanation to CH4 Over MoS2/ZrO2 Catalysts: Support Size Effect On Morphology and Performance of Mo Species

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  35. Quantitative Effect of Zr Content on the Structure and Water–Gas Shift Reaction Activities of Gold Supported on Ceria–Zirconia

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  36. Preparation and Characterization of SiO2/Co and C/Co Nanocomposites as Fisher-Tropsch Catalysts for CO2 Hydrogenation

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  37. Engineering Stable Surface Oxygen Vacancies on ZrO2 by Hydrogen-Etching Technology: An Efficient Support of Gold Catalysts for Water-Gas Shift Reaction

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  38. An in depth investigation of deactivation through carbon formation during the biogas dry reforming reaction for Ni supported on modified with CeO2 and La2O3 zirconia catalysts

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  39. 17O Solid-State NMR Studies of ZrO2 Nanoparticles

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  40. Effect of sodium content on the interaction between Ni and support and catalytic performance for syngas methanation over Ni/Zr–Yb–O catalysts

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  41. Design of Pt/t-ZrO2/g-C3N4 efficient photocatalyst for the hydrogen evolution reaction

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  42. In-situ embedding ZrO2 nanoparticles in hierarchically porous carbon matrix as electrode materials for high desalination capacity of hybrid capacitive deionization

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  43. Morphology-Oriented ZrO2-Supported Vanadium Oxide for the NH3-SCR Process: Importance of Structural and Textural Properties

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  44. Improvement in the activity of Ni/ZrO2 by cold plasma decomposition for dry reforming of methane

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  45. Optimization of Co-precipitation Condition for Preparing Molybdenum-Based Sulfur-Resistant Methanation Catalysts

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  46. Understanding the Nature and Activity of Supported Platinum Catalysts for the Water–Gas Shift Reaction: From Metallic Nanoclusters to Alkali-Stabilized Single-Atom Cations

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  47. Low-Temperature Photothermal Catalytic Oxidation of Toluene on a Core/Shell SiO2@Pt@ZrO2 Nanostructure

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  48. Facile precipitation synthesis, structural, morphological, photoluminescence and photocatalytic properties of Ni doped ZrO 2 nanoparticles

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  49. Recent progress in the development of catalysts for steam reforming of biomass tar model reaction

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  50. A systematic theoretical study of the water gas shift reaction on the Pt/ZrO 2 interface and Pt(111) face: key role of a potassium additive

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