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RESEARCH PAPER · Dalton Transactions · 2006

Structural study of trivalent lanthanide and actinide complexes formed upon solvent extraction

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Structural study of trivalent lanthanide and actinide complexes formed upon solvent extractionOriginalAPS Science 2006.0Europium(III) Reduction and Speciation within a Wells−Dawson Heteropolytungstate30Aggregation in Solvent Extraction Systems Containing a Malonamide, a Dialkylphosphoric Acid and their Mixtures84In situ measurement of the Preyssler polyoxometalate morphology upon electrochemical reduction: A redox system with Born electrostatic ion solvation behavior17Aggregation in Organic Solutions of Malonamides: Consequences for Water Extraction87Investigation of Pu(IV)-acetohydroxamic acid complex by solvent extraction with di(2-ethylhexyl) phosphoric acid4Use of electrospray ionization mass spectrometry for the characterization of actinide complexes in solution16Development of highly selective compounds for solvent extraction processes: partitioning and transmutation of long-lived radionuclides from spent nuclear fuels20Characterization of HDEHP-lanthanide complexes formed in a non-polar organic phase using 31P NMR and ESI-MS78Rich Coordination of Nd3+ in Mg2Nd13(BO3)8(SiO4)4(OH)3, Derived from High-Pressure/High-Temperature Conditions4Coordination Structures and Supramolecular Architectures in a Cerium(III)–Malonamide Solvent Extraction System75Preferential Crystallization of Lanthanoid Tris(β-diketonates) with Bridged Bis(2-pyridylmethyl)amine Ligands toward Separation Application2Polymer-supported urea: The effect of hydrogen bonding on lanthanide ion affinities1XAS investigation on the coordination structure and extraction mechanism of zinc(II) in ammoniacal solution18Liquid/liquid metal extraction: Phase diagram topology resulting from molecular interactions between extractant, ion, oil and water54Extraction enhancement of zinc(II) in ammoniacal media through solvent and synergistic effects: A structural and mechanistic investigation33Periodic Behavior of Lanthanide Coordination within Reverse Micelles86Microscopic Insights into Extraction Mechanism of Copper(II) in Ammoniacal Solutions Studied by X-ray Absorption Spectroscopy and Density Functional Theory Calculation16Analysis of trivalent cation complexation to functionalized mesoporous silica using solid-state NMR spectroscopy9Liquid-liquid two-phase microflow patterns and mass transfer of radionuclides4Liquid–liquid microflow patterns and mass transfer of radionuclides in the systems Eu(III)/HNO3/DMDBTDMA and U(VI)/HCl/Aliquat® 33629Observation of a Rare Earth Ion–Extractant Complex Arrested at the Oil–Water Interface During Solvent Extraction88X-ray Studies of Interfacial Strontium–Extractant Complexes in a Model Solvent Extraction System58An europium( iii ) diglycolamide complex: insights into the coordination chemistry of lanthanides in solvent extraction86Microsystèmes séparatifs pour l'extraction liquide-liquide des radioéléments dans les protocoles d'analyse0Simultaneous lanthanides and surfactants micelles removal from aqueous outflows by complexation and sol–gel chemistry3Separation of ND(III), DY(III) and Y(III) by solvent extraction using D2EHPA and EHEHPA131In the Bottlebrush Garden: The Structural Aspects of Coordination Polymer Phases formed in Lanthanide Extraction with Alkyl Phosphoric Acids30Insights into coextraction of water and ammonia with nickel(II) through structural investigation8Molecular Origins of Mesoscale Ordering in a Metalloamphiphile Phase58Synthesis and extraction studies with a rationally designed diamide ligand selective to actinide( iv ) pertinent to the plutonium uranium redox extraction process17Trapped in the coordination sphere: nitrate ion transfer driven by the cerium( iii / iv ) redox couple10Extraction of Lanthanides(III) by a Mixture of a Malonamide and a Dialkyl Phosphoric Acid38Neodymium(III) Complexes of Dialkylphosphoric and Dialkylphosphonic Acids Relevant to Liquid–Liquid Extraction Systems42α- and β-diphenylphosphorylated secondary alkanols: I. general method of synthesis and extraction properties towards f-elements4Structure, Bonding, and Electronic Properties of Four Rare Earth Complexes with a Phenoxyacetic Acid Ligand: X-ray Diffraction and DFT Studies15A predictive model of reverse micelles solubilizing water for solvent extraction40Acid-switched Eu(III) coordination inside reverse aggregates: Insights into a synergistic liquid-liquid extraction system26Methods for the substitution of common saponification systems for the solvent extraction of REEs12Benchmarking Uranyl Peroxide Capsule Chemistry in Organic Media20Extraction of Water and Speciation of Trivalent Lanthanides and Americium in Organophosphorus Extractants27Structural study of complexes formed by acidic and neutral organophosphorus reagents43Stability of reverse micelles in rare-earth separation: a chemical model based on a molecular approach35Structural insights into the multinuclear speciation of tetravalent cerium in the tri-n-butyl phosphate–n-dodecane solvent extraction system45Layered A2Sn3S7·1.25H2O (A = Organic Cation) as Efficient Ion-Exchanger for Rare Earth Element Recovery142Understanding the synergistic effect on lanthanides(III) solvent extraction by systems combining a malonamide and a dialkyl phosphoric acid35Coordination chemistry of actinides and fission products (lanthanides and molybdenum) with neutral or acidic phosphine oxide ligands0Ion Transport Mechanisms in Liquid–Liquid Interface61Speciation of Select f-Elements with Lipophilic Phosphorus Acids and Diglycol Amides in the ALSEP Backward-Extraction Regime20Synthesis of hexavalent molybdenum formo- and aceto-hydroxamates and deferoxamine via liquid-liquid metal partitioning9Nanoscale view of assisted ion transport across the liquid–liquid interface104Differential Stabilization of the Metal–Ligand Complexes between Organic and Aqueous Phases Drives the Selectivity of Phosphoric Acid Ligands toward Heavier Rare Earth Elements10Simulating Osmotic Equilibria by Molecular Dynamics - From Vapor-Liquid Interfaces to Thermodynamic Properties in Concentrated Solutions0Colloidal Model for the Prediction of the Extraction of Rare Earths Assisted by the Acidic Extractant52Rare earth elements: Mendeleev’s bane, modern marvels565Ternary Complex Formation and Extraction Modeling in Malonate-Buffered Trivalent Actinide–Lanthanide Separations13Solvation and Ion Specificity in Complex Media0Evaluation of the Hydrophilic Complexant N,N,N’,N’-tetraethyldiglycolamide (TEDGA) and its Methyl-substituted Analogues in the Selective Am(III) Separation23Theoretical insights on the complexation of Am(III) and Cm(III) with amide-type ligands12Interfacial structure in the liquid–liquid extraction of rare earth elements by phosphoric acid ligands: a molecular dynamics study19Evolution of Acid-Dependent Am3+ and Eu3+ Organic Coordination Environment: Effects on the Extraction Efficiency24Synthesis and Characterization of a Chromo-Extractant to the Probe Liquid–Liquid Interface in a Solvent Extraction Process5Extraction of Nitric Acid, Americium(III), Curium(III), and Lanthanides(III) into DMDOHEMA Dissolved in Kerosene17Highly Selective Separation of Rare Earth Elements by Zn-BTC Metal–Organic Framework/Nanoporous Graphene via In Situ Green Synthesis95Recent Progress on Two-Dimensional Materials472L’extraction raisonnée de métaux stratégiques par des hydrotropes0Liquid–Liquid Extraction of the Eu(III) Cation by BTP Ligands into Ionic Liquids: Interfacial Features and Extraction Mechanisms Investigated by MD Simulations11Influence of the Nature of Diluent on the Extractability of N,N,N',N'-Tetrabutyldiglycolamide for Eu(III), Am(III), and Cm(III)4In uence of the nature of the diluent on the extraction capacity of N,N,N',N'-tetrabutyldiglycolamide to Eu(III), Am(III) and Cm(III)1Effect of ion to ligand ratio on the aqueous to organic relative solubility of a lanthanide–ligand complex4Influence of Di-n-butyl Phosphoric Acid on Cerium Redox and Speciation in Tri-n-butyl Phosphate3Oligomer Formation Effects on the Separation of Trivalent Lanthanide Fission Products0Kinetics of solvent extraction of f-elements: а critical review on extraction systems and measurement techniques11Pairing a Global Optimization Algorithm with EXAFS to Characterize Lanthanide Structure in Solution4Decreasing viscosity and increasing accessible load by replacing classical diluents with a hydrotrope in liquid–liquid extraction6Solubilisation–microstructure relationship of trivalent salts in hydrotropic ternary systems3Extraction of 244 Cm Using 3,3′‐Dibutyloxyphenyl‐bis‐1,2,4‐Triazinyl‐2,6‐Pyridine as a Bipolar Complexant: A Fundamental, density functional theory, and Spectroscopic Study2Controlling Ligand Excimer Formation with Dipole Changes in Emissive Rare-Earth/Phosphonic Acid Complexes0Binding of Multiple DEHP – Extractants to Er 3+ in Bulk Water and at the Liquid–Liquid Interface0Phase Equilibria in o -Xylene–Di-(2-ethylhexyl)phosphoric Acid–Lanthanum (Praseodymium, Terbium, Lutetium) Di-(2-ethylhexyl)phosphate Systems at 298.15 K0Cooperative Lanthanide Solvation in an Ionic Liquid for Critical Materials Separations3Synchrotron X-ray Methods to Advance Rare Earth Separations0

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