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RESEARCH PAPER · Angewandte Chemie International Edition · 2003

Nanoporous Lanthanide–Copper( II ) Coordination Polymers: Syntheses and Crystal Structures of [{M2(Cu3(iminodiacetate)6)}⋅8 H2O]n (M=La, Nd, Eu)

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Nanoporous Lanthanide–Copper( II ) Coordination Polymers: Syntheses and Crystal Structures of [{M2(Cu3(iminodiacetate)6)}⋅8 H2O]n (M=La, Nd, Eu)OriginalSome Recent Progress of Chemical Studies in China1Lanthanide−Transition Heterometallic Extended Structures with Novel Orthogonal Metalloligand as Building Block92Nanoporous Lanthanide–Copper( II ) Coordination Polymers: Syntheses and Crystal Structures of [{M2(Cu3(iminodiacetate)6)}⋅8 H2O]n (M=La, Nd, Eu)1One-dimensional nanoporous M2L2 rhombohedral molecular square with strong blue fluorescent emission25Heterotrimetallic 4f−3d Coordination Polymers: Synthesis, Crystal Structure, and Magnetic Properties95A novel 2D net-like supramolecular polymer constructed from Ln 6 Cu 24 node and trans-Cu(Gly) 2 bridge82Crystal-to-crystal transformations of a microporous metal–organic laminated framework triggered by guest exchange, dehydration and readsorption158Design and Synthesis of 3d−4f Metal-Based Zeolite-type Materials with a 3D Nanotubular Structure Encapsulated “Water” Pipe572Metal Carboxylates with Open Architectures1935Offene Metallcarboxylat‐Architekturen179Syntheses and Structure of a Novel Layered Lanthanide–Zinc Coordination Polymer: [LaZn(HIDA)(IDA)2·0.5H2O]n10Functional Porous Coordination Polymers11071Funktionale poröse Koordinationspolymere1348Water Clusters in Crystal Hydrates4Two 3D Supramolecular Polymers Constructed from an Amino Acid and a High‐Nuclear Ln6Cu24 Cluster Node91Puckered-Boat Conformation Hexameric Water Clusters Stabilized in a 2D Metal−Organic Framework Structure Built from Cu(II) and 1,2,4,5-Benzenetetracarboxylic Acid184Copper Complex Cation Templated Gadolinium( III )–Isophthalate Frameworks184Copper Complex Cation Templated Gadolinium( III )–Isophthalate Frameworks9Syntheses and characterizations of two lanthanide(III)–copper(II) coordination polymers constructed by pyridine-2,6-dicarboxylic acid34Three-dimensional mesomeric networks assembled from helix-linked sheets: syntheses, structures, and magnetisms60Two-dimensional carboxylate bridged network of europium(iii)–transition metal(ii) glutarate compounds31{[GdAg2(dtpa)(H2O)] · 3H2O} : the first 2D Gd–Ag coordination polymer with Ag–Ag interaction29Syntheses and Structures of two Cobalt Coordination Polymers with Iminodiacetate Ligands: [CoII2(ida)2(H2O)2]n and [Na2CoIII2(ida)4(H2O)4]n·2nH2O7Mn(II) Staircase Structures Stitched by Water Clusters to a 3D Metal-Organic Open Framework: X-ray Structural and Magnetic Studies119Lanthanide Complexes of Disulfoxide Ligands with Varied Configurations: Influence of Lanthanide Contraction on the Structures of the Complexes7Open lanthanide-organic frameworks with intertwined double and triple helical structures41A Series of Three-Dimensional Lanthanide Coordination Polymers with Rutile and Unprecedented Rutile-Related Topologies230Synthesis, structures and thermal properties of three new two-dimensional coordination networks assembled by lanthanide salts and carboxylate ligand41Hydrothermal synthesis, crystal structure and third-order non-linear optical property of a copper chloride cluster9Syntheses and characterization of the samarium(III)–copper(II) 3D coordination network constructed by iminodiacetic acid23Infinite Chains of Quasi‐Planar Hexameric Water Clusters Stabilized in a Metal‐Organic Framework Built from CoII and Pyrazine‐ 2,3,5,6‐tetracarboxylic Acid57Lanthanide–transition metal coordination polymers based on multiple N- and O-donor ligands286Supramolecular Aggregation of Hexameric Water Clusters into a 2D Water Polymer Containing (H2O)18 Holes71Synthesis, structure and luminescent properties of two three-dimensional d10 metal complexes constructed from pyridine-3,4-dicarboxylic acid with new network topologies13Lanthanide-isophthalate cavity frameworks encapsulated copper(I) complexes132D and 3D Cadmium(II) Coordination Polymers from a Flexible Tripodal Ligand of 1,3,5‐Tris(carboxymethoxy)benzene and Bidentate Pyridyl‐Containing Ligands with Three‐, Eight‐ and Ten‐Connected Topologies1002,2′-Oxydiacetato-bridged complexes containing Sm(III) and bivalent cations. Synthesis, structure, magnetic properties and chemical speciation23First 3D 3d−4f Interpenetrating Structure: Synthesis, Reaction, and Characterization of {[LnCr(IDA)2(C2O4)]}n88Selected Controlled Synthesis of Three-Dimensional 4d−4f Heterometallic Coordination Frameworks by Lanthanide Carboxylate Subunits and Silver Centers181Synthesis and Thermal Decomposition of Zn(tda)H 2 O [tda = S(CH 2 COO) 2 2 - ]22Hydrothermal synthesis, structure and properties of two lanthanide benzenedicarboxylates, [La2(isophth)2(Hisophth)2(H2O)·H2O]n and [Dy4(isophth)4(Ac)4(H2O)8·2H2O]n, possessing infinite Ln–O–Ln linkages10Diversity of crystal structure with different lanthanide ions involving in situ oxidation–hydrolysis reaction132Self-assembly of 3-D 4d–4f coordination frameworks based on 1-D inorganic heterometallic chains and linear organic linkers120Self-assembly of FeIII complexes via hydrogen bonded water molecules into supramolecular coordination networks123D Heterometallic (3d–4f) coordination polymers: A ferromagnetic interaction in a Gd(III)–Cu(II) couple41Novel Alternating Ferro-Ferromagnetic Two-Dimensional (4,4) and Photoluminescent Three-Dimensional Interpenetrating PtS-Type Coordination Networks Constructed from a New Flexible Tripodal Ligand as a Four-Connected Node102Novel 3D LnIII−CuI Supramolecular Architecture Based on 2D MOFs with (6,3) Topology88A Heterometallic Porous Material for Hydrogen Adsorption122Lanthanide(III)−Cobalt(II) Heterometallic Coordination Polymers with Radical Adsorption Properties121A new series of 2D lanthanide 5-hydroxyisophthalate coordination polymers18Chemistry of coordination space of porous coordination polymers978Hydrothermal synthesis, structures and photoluminescent properties of two lanthanide 5-aminoisophthalate coordination polymers with layer structures13Incorporating Metal Clusters into Three-Dimensional Ln(III)−Cu(I) Coordination Frameworks through Linear Ligands983D Ln–Ag (Ln = Nd; Eu) coordination polymers based on N- and O-donor ligands: Synthesis, crystal structures and luminescence71Lanthanide complexes with oda, ida, and nta: From discrete coordination compounds to supramolecular assemblies57Syntheses, structures and magnetic properties of isonicotinate-bridged heterometallic Ln(III)–Cu(II) coordination polymers6Hexanuclear 4d–4f complexes [Ln2Ag4(ina)8(H2O)10][NO3]2· 4H2O (Ln = Sm, Eu, Dy): Syntheses, structures and photoluminescent properties25{LnIII[μ5-κ2,κ1,κ1,κ1,κ1-1,2-(CO2)2C6H4][isonicotine][H2O]}2CuI·X (Ln = Eu, Sm, Nd; X = ClO4-, Cl-): A New Pillared-Layer Approach to Heterobimetallic 3d−4f 3D-Network Solids1083D lanthanide-transition-metal–organic frameworks constructed by two distinct tetranuclear units of cubane {Ln4} and chair-like {Cu4} clusters53A new family of 3D 3d–4f heterometallic frameworks comprising 1D inorganic lanthanide ladders and organic Cu I -bipyridine chains54Diversification of hydrothermal reaction products induced by temperature: syntheses, structures and properties of four La(iii)–Cu(ii) metal frameworks constructed from rod-shaped molecular building blocks19Water nanotubes confined to nanochannels of a (10,3)-b net constructed by binary building blocks via the R22(9) synthon36A Porous Coordination‐Polymer Crystal Containing One‐Dimensional Water Chains Exhibits Guest‐Induced Lattice Distortion and a Dielectric Anomaly134A Porous Coordination‐Polymer Crystal Containing One‐Dimensional Water Chains Exhibits Guest‐Induced Lattice Distortion and a Dielectric Anomaly18Incorporating Distinct Metal Clusters To Construct Diversity of 3D Pillared-Layer Lanthanide-Transition-Metal Frameworks853D pillar-layered coordination polymers based on 4d–4f heterometallic assembly26Construction of an unusual three-dimensional transition metal lanthanide Ln/Cu(Br/Cl) coordination polymer with isonicotinate as the single ligand31A novel three-dimensional 3d–4f heterometallic coordination polymer: Crystal structure and photoluminescence22A 3D 3d-4f Heterometallic Coordination Polymer: Synthesis, Crystal Structure and Properties4Construction of isostructural Ln–Ag (Ln = Eu; Tb; Dy) nano-channel heterometallic coordination frameworks based on pyrazine-2-carboxylate and oxalate ligands29An Interesting Six-Connected 3D Nanowater Framework Constructed from Turbine-Type (H2O)18 Clusters Based on a Mn(III) Complex48Construction of three-dimensional Ln–Ag (Ln = Eu; Tm) coordination polymers based on isonicotinate and oxalate ligands28Poly[tetraaqua-μ4-bromido-di-μ2-bromido-μ2-hydroxido-di-μ3-isonicotinato-tetra-μ2-isonicotinato-tetracopper(I)dithulium(III)]2Synthesis and magnetic characterization of Ln(III)–Co(II) complexes with 1,10-phenanthroline ligands19Synthesis, structures and luminescent properties of 4d–4f heterometallic coordination frameworks based on lanthanide oxalate substructures with nicotinate bridging ligands39Synthesis of a Purely Inorganic Three-Dimensional Porous Framework Based on Polyoxometalates and 4d−4f Heterometals65Water cluster supported architecture of lanthanide coordination polymers with pyrazinetricarboxylic acid25Molecular encapsulation of a discrete (H 2 O) 32 cluster with S 6 symmetry in an organic crystalline supermolecule38Synthesis, crystal structure and photoluminescent properties of four lanthanide 5-nitroisophthalate coordination polymers35Coordination polymers with pyridine-2,4,6-tricarboxylic acid and alkaline-earth/lanthanide/transition metals: synthesis and X-ray structures89Structures and luminescent properties of a series of Ln–Ag heterometallic coordination polymers89Syntheses, structures, and magnetic properties of heterometallic coordination polymers with carboxyphosphonate linkers39Synthesis, Characterization and Thermal Behavior of Two 4d‐4f Coordination Polymers Based on N and O Donor Ligands14Highly Tunable Heterometallic Frameworks Constructed from Paddle-Wheel Units and Metalloporphyrins72Template Trapping and Crystal Structure of the Magic Number (H2O)21 Cluster in the Tetrahedral Hole of a Nanoscale Global Ion Packed in a Face-Centered Cubic Pattern38Syntheses and characterization of 3D heterometallic (3d–4f) metal–organic frameworks: Reversible de- and rehydration performance and magnetic properties13A new 3-D microporous Ln(III)–Cu(I) framework constructed by pyridine-3,5-dicarboxylate16Hydrothermal synthesis and crystal structures of two lanthanide coordination polymers with novel tetradentate-coordinated perchlorates13Poly[tetraaqua-μ3-benzene-1,2-dicarboxylato-μ3-bromido-penta-μ2-bromido-octa-μ3-isonicotinato-heptacopper(I)trilanthanum(III)]1Tetranuclear Ln(III) complexes with 2-sulfobenzoate and their three-dimensional supramolecular frameworks consolidated through hydrogen-bonding and intermolecular O···π interactions22Supramolecular association of water molecules forming discrete clusters in the voids of coordination polymers45From Metalloligand to Interpenetrating Channels: Synthesis, Characterization, and Properties of a 2p−3d−4f Heterometallic Coordination Polymer {[Na 5 Cu 8 Sm 4 (NTA) 8 (ClO 4 ) 8 (H 2 O) 22 ]·ClO 4 ·8H 2 O} n52Self-assembly of water cluster in iron(III) oxalate-bridged complexes10pH- and mol-ratio dependent formation of zinc(II) coordination polymers with iminodiacetic acid: Synthesis, spectroscopic, crystal structure and thermal studies40Crystal structure of a new coordination polymer [LaAg(Pydc)(HPydc)(C2O4)0.5(H2O)2] n (H2Pydc = pyridine-3,5-dicarboxylic acid)3Rationally designed and controlled syntheses of different series of 4d–4f heterometallic coordination frameworks based on lanthanide carboxylate and Ag(IN)2 substructures63Synthesis and Characterization of 3d-3d Homo- and Heterometallic Coordination Polymers with Mixed Ligands631-D Ln–Ag (Ln = Eu; Tb) heterometallic coordination polymers with pyridine-2,6-dicarboxylate as the single ligand: Synthesis, crystal structures, and luminescence9Novel Three-Dimensional Pillared-Layer Ln(III)−Cu(I) Coordination Polymers Featuring Spindle-Shaped Heterometallic Building Units92A flexible supramolecular host with a crowned chair octameric water cluster and highly selective adsorption properties23A novel silver(I)-containing supramolecular framework incorporating eight different hydrogen bond motifs25A New 2D Coordination Polymer Material Based on 4d-4f Heterometallic Assembly4Ligand-Directed and pH-Controlled Assembly of Chiral 3d−3d Heterometallic Metal−Organic Frameworks138Syntheses, structures, and spectroscopy of mono- and polynuclear lanthanide complexes containing 4-acyl-pyrazolones and diphosphineoxide45Heterometallic Modular Metal–Organic 3D Frameworks Assembled via New Tris‐β‐Diketonate Metalloligands: Nanoporous Materials for Anion Exchange and Scaffolding of Selected Anionic Guests106Investigation on structures, luminescent and magnetic properties of Ln III –M (M = Fe II HS , Co II ) coordination polymers78Syntheses, Structural Characterization, and Properties of {[Cu(bpp)2(H2O)2](tp)·7H2O} and {[Cu(bpp)2(H2O)](ip)·7H2O} Complexes. New Examples of the Organic Anionic Template Effect on Induced Assembly of Water Clusters (bpp = 1,3-Bis(4-pyridyl)propane, tp = Terephthalate, ip = Isophthalate)773D lanthanide–transition-metal–organic frameworks constructed from tetranuclear {Ln4} SBUs and Cu centres with fsc net38A series of lanthanide-transition metal coordination polymers with mixed ligands: syntheses, structures, photoluminescence and magnetic properties17Crystal structure of bis(.3-hydroxy)bis(isonicotinato-kO:O')(oxalato)- biscadmium(II)zinc(II), Cd2Zn(C2O4)(OH)2(C6NO2H4)20The novel metalloligand [Fe(bppd)3] (bppd = 1,3-bis(4-pyridyl)-1,3-propanedionate) for the crystal engineering of heterometallic coordination networks with different silver salts. Anionic control of the structures48Hydrothermal Synthesis, Crystal Structure and Characterization of a Novel 3D Pillared-Layer 3d–4f Lanthanum-Copper Heterometallic Coordination Polymer6Anomalous Dielectric Behavior and Thermal Motion of Water Molecules Confined in Channels of Porous Coordination Polymer Crystals87Syntheses, crystal structures and properties of two unusual pillared-layer 3d–4f Ln–Cu heterometallic coordination polymers16Comparative study of nanoporous Ln–Cu coordination polymers containing iminodiacetate as bridging ligand13A series of 3d–4f heterometallic frameworks comprising 2D lanthanide-organic layers and diverse Cu-complex pillars7Synthesis and characterization of cobalt(II)–salicylate complexes derived from N4-donor ligands: Stabilization of a hexameric water cluster in the lattice host of a cobalt(III)–salicylate complex21An unusual 3D 3d–4f heterometallic coordination polymer based on the linkages of Sm2(IN)6 pillars and 2D [Cu7Br6]n+ layers: Crystal structure and luminescent property10Ferroelectric Metal–Organic Frameworks1378Assembly, Fluorescence Properties and Antitumor Activity of Novel Silver(I) Cyanide Supramolecular Coordination Polymer Based on Trans-1,2-bis(4-pyridyl)ethene and Me3SnCl11catena-Poly[[aquacopper(II)]-μ2-iminodiacetato-κ4O,N,O′:O′]0Two New Layered Lanthanide‐Carboxylate Coordination Networks with Unusual Topologies1Position of substituent dependent dimensionality in Ln–Cu heterometallic coordination polymers14Synthesis, Structure, and Luminescent Properties of Lanthanide-Based Two-Dimensional and Three-Dimensional Metal–Organic Frameworks with 2,4′-Biphenyldicarboxylic Acid76Syntheses, Structures, Luminescence, and Magnetic Properties of One-dimensional Lanthanide Coordination Polymers with a Rigid 2,2′-Bipyridine-3,3′,6,6′-tetracarboxylic Acid Ligand66Solvent- and Vapor-Mediated Solid-State Transformations in 1,3,5-Benzenetricarboxylate Metal–Organic Frameworks29Syntheses, crystal structures and physical properties of two unusual 4d–4f heterometallic coordination polymers7An unusual axial–axial combination of alternating cyclic rings in the chair conformations of hexameric water and chlorine-water clusters4A 4d-4f heterometallic coordination polymer: Synthesis, crystal structure and near-infrared luminescent properties9A novel 2D oxalate- and dissymmetrical oxamidato-bridged heterometallic CuII–GdIII complex: Synthesis, crystal structure and magnetic properties5Influence of anion on the network structure of one dimensional silver(I) coordination polymers of dicompartmental N,N-donor ligands6Structures, luminescent and magnetic properties of six lanthanide–organic frameworks: observation of slow magnetic relaxation behavior in the DyIII compound105Chiral Metallocycles Templated Novel Chiral Water Frameworks41Analogy to a Chinese knot in an ion-pair copper(II)–neodymium(III) complex based on a hexadentate Schiff base condensation product of 5-bromosalicylaldehyde and glycylglycine1Mixed Linker Strategy for the Construction of a Fluorescent 2D Network Based on [Ag2(COO)2] as Secondary Building Unit1A three-dimensional Cu–Na heteronuclear coordination polymer based on iminodiacetic acid0Structures, luminescent and magnetic properties of a series of (3,6)-connected lanthanide–organic frameworks51Metal-directed assembly of coordination polymers with the versatile ligand 2-(1 H -benzotriazol-1-yl) acetic acid: from discrete structures to two-dimensional networks46Study on synthesis, crystal structure, antioxidant and DNA-binding of mono-, di- and poly-nuclear lanthanides complexes with bis(N-salicylidene)-3-oxapentane-1,5-diamine100Lanthanide Metalloligand Strategy toward d–f Heterometallic Metal–Organic Frameworks: Magnetism and Symmetric-Dependent Luminescent Properties56Two Lanthanide(III) Complexes based on the Schiff Base N,N′‐Bis(salicylidene)‐1,5‐diamino‐3‐oxapentane: Synthesis, Characterization, DNA‐binding Properties, and Antioxidation89Synthesis and Crystal Structure of Coordination Polymers of Yttrium and Holmium with Hydrogen Succinate and Benzene-1,3-disulphonate10Recent advances in the construction of lanthanide–copper heterometallic metal–organic frameworks59Syntheses, structures, and properties of a series of novel high-nuclear 3d–4f clusters with mixed amino acids as ligands: {Ln 6 Cu 24 }(Ln = Gd, Tb, Pr and Sm)12Poly[tetraaquatriglutaratodicerium(III) decahydrate], a novel luminescent metal-organic framework possessing hydrophilic hexagonal channels4Coordination polymer-derived nano-sized zinc ferrite with excellent performance in nitro-explosive detection17Synthesis, Structures, and Properties of Lanthanide Complexes with Pyrimidine‐2‐carboxylic Acid53D Ln III -MOFs: slow magnetic relaxation and highly sensitive luminescence detection of Fe 3+ and ketones65Uptake and accommodation of water clusters by adamantane clusters in helium droplets: interplay between magic number clusters15Syntheses, Structures, and Magnetic Properties of a Series of Heterotri-, Tetra- and Pentanuclear LnIII–CoII Compounds7

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  1. Some Recent Progress of Chemical Studies in China

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  2. Lanthanide−Transition Heterometallic Extended Structures with Novel Orthogonal Metalloligand as Building Block

    Inorganic Chemistry · 2003-03-14

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  3. Nanoporous Lanthanide–Copper( II ) Coordination Polymers: Syntheses and Crystal Structures of [{M2(Cu3(iminodiacetate)6)}⋅8 H2O]n (M=La, Nd, Eu)

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  4. One-dimensional nanoporous M2L2 rhombohedral molecular square with strong blue fluorescent emission

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  6. A novel 2D net-like supramolecular polymer constructed from Ln 6 Cu 24 node and trans-Cu(Gly) 2 bridge

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  7. Crystal-to-crystal transformations of a microporous metal–organic laminated framework triggered by guest exchange, dehydration and readsorption

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  8. Design and Synthesis of 3d−4f Metal-Based Zeolite-type Materials with a 3D Nanotubular Structure Encapsulated “Water” Pipe

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  11. Syntheses and Structure of a Novel Layered Lanthanide–Zinc Coordination Polymer: [LaZn(HIDA)(IDA)2·0.5H2O]n

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  12. Functional Porous Coordination Polymers

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  14. Water Clusters in Crystal Hydrates

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  16. Puckered-Boat Conformation Hexameric Water Clusters Stabilized in a 2D Metal−Organic Framework Structure Built from Cu(II) and 1,2,4,5-Benzenetetracarboxylic Acid

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  17. Copper Complex Cation Templated Gadolinium( III )–Isophthalate Frameworks

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  19. Syntheses and characterizations of two lanthanide(III)–copper(II) coordination polymers constructed by pyridine-2,6-dicarboxylic acid

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  22. {[GdAg2(dtpa)(H2O)] · 3H2O} : the first 2D Gd–Ag coordination polymer with Ag–Ag interaction

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  23. Syntheses and Structures of two Cobalt Coordination Polymers with Iminodiacetate Ligands: [CoII2(ida)2(H2O)2]n and [Na2CoIII2(ida)4(H2O)4]n·2nH2O

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  44. Self-assembly of FeIII complexes via hydrogen bonded water molecules into supramolecular coordination networks

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  47. Novel 3D LnIII−CuI Supramolecular Architecture Based on 2D MOFs with (6,3) Topology

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  50. A new series of 2D lanthanide 5-hydroxyisophthalate coordination polymers

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