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RESEARCH PAPER · Surface Science · 2009

The Fe3O4 origin of the “Biphase” reconstruction on α-Fe2O3(0001)

Courtney H. Lanier, Ann N. Chiaramonti, Laurence D. Marks, Kenneth Reinhard Poeppelmeier

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The Fe3O4 origin of the “Biphase” reconstruction on α-Fe2O3(0001)OriginalPreparation and characterization of Fe3O4(1 1 1) nanoparticles and thin films on Au(1 1 1)52Oxygen plasma activation of Cr(CO)6 on α-Fe2O3(0001)8Adsorption, Desorption, and Reaction of Methyl Radicals on Surface Terminations of α-Fe2O311Surface Structural Evolution in Iron Oxide Thin Films48Thermodynamic modelling of nanomorphologies of hematite and goethite137Surface properties of clean and Au or Pd covered hematite (α-Fe2O3) (0001)71Environmentally dependent stability of low-index hematite surfaces28Electronic Properties and Reactivity of Simulated Fe3+and Cr3+Substituted α-Al2O3(0001) Surface25The reduction and oxidation of Fe2O3(0001) surface investigated by scanning tunneling microscopy55Quantitative Structural Studies Of Corundum and Rocksalt Oxide Surfaces52Well-Ordered Transition Metal Oxide Layers in Model Catalysis – A Series of Case Studies201Selective ring CH bonds activation of toluene over Fe/activated carbon catalyst29Mixed Termination of Hematite (α-Fe2O3)(0001) Surface62DFT Simulations of Water Adsorption and Activation on Low‐Index α‐Ga2O3 Surfaces44Interconversion of α-Fe 2 O 3 and Fe 3 O 4 Thin Films: Mechanisms, Morphology, and Evidence for Unexpected Substrate Participation74Fe adsorption on hematite (α-Fe2O3) (0001) and magnetite (Fe3O4) (111) surfaces17Subsurface cation vacancy stabilization of the magnetite (001) surface284Weak thermal reduction of biphase Fe2O3(0001) films grown on Pt(111): Sub-surface Fe2+ formation13The Effect of Thermal Treatment of Hematite Ore for Chemical Looping Combustion of Methane14Phase transformations in thin iron oxide films: Spectromicroscopic study of velocity and shape of the reaction fronts46Adsorption of gold subnano-structures on a magnetite(111) surface and their interaction with CO56Water adsorption and O-defect formation on Fe 2 O 3 (0001) surfaces119Iron oxide surfaces611Thermodynamics of Iron Oxides and Oxyhydroxides in Different Environments2Defect-induced enhanced photocatalytic activities of reduced α -Fe 2 O 3 nanoblades23Kinetics and intermediate phases in epitaxial growth of Fe3O4 films from deposition and thermal reduction24Nanoscale Patterns on Polar Oxide Surfaces30Iron cation-induced biphase symbiosis of h-WO 3 /o-WO 3 ·0.33H 2 O and their crystal phase transition8Unpredicted surface termination of α-Fe 2 O 3 (0001) film grown by mist chemical vapor deposition10Hematite, Its Stable Surface Terminations and Their Reactivity Toward Water6Atomic-Scale Structure of the Hematite α-Fe2O3(1102) “R-Cut” Surface126Molecular species forming at the α-Fe 2 O 3 nanoparticle–aqueous solution interface15Pure phase BiFeO3 thin films sputtered over Si: A new route towards high magnetization22Oxygen Carrier Structure and Attrition0Gold-Decorated Biphase α-Fe2O3(0001): Activation by CO-Induced Surface Reduction6Chemistry of Methanol and Ethanol on Ozone-Prepared α-Fe2O3(0001)5Identification of Two-Dimensional FeO2 Termination of Bulk Hematite α-Fe2O3(0001) Surface15CO adsorption on Fe3O4(1 1 1) with regular and biphase terminations8Reversible oxidation–reduction of epitaxial iron oxide films on Pt(111): Magnetite–hematite interconversion16In situ TEM oxidation study of Fe thin-film transformation to single-crystal magnetite nanoparticles14Simulation of STM Images of Hematite α-Fe2O3(0001) Surfaces: Dependence on Distance and Bias10Spin Seebeck Effect in Iron Oxide Thin Films: Effects of Phase Transition, Phase Coexistence, And Surface Magnetism23Application of machine learning to reflection high-energy electron diffraction images for automated structural phase mapping31Atomic Structure of the Fe 3 O 4 /Fe 2 O 3 Interface During Phase Transition from Hematite to Magnetite22Hematite α ‐Fe 2 O 3 (0001) in Top and Side View: Resolving Long‐Standing Controversies about Its Surface Structure20A multi-analytical approach reveals flexible compound adhesive technology at Steenbokfontein Cave, Western Cape10Revealing the catalytic oxidation mechanism of CO on α-Fe 2 O 3 surfaces: an ab initio thermodynamic study3Ferri-/Antiferromagnetic Heterostructures: A Case Study of the Fe 3 O 4 /NiO Interface0

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  1. Preparation and characterization of Fe3O4(1 1 1) nanoparticles and thin films on Au(1 1 1)

    Surface Science · 2010-01-19

    Xingyi Deng, Junseok Lee, Christopher Matranga

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  2. Oxygen plasma activation of Cr(CO)6 on α-Fe2O3(0001)

    Surface Science · 2010-06-02

    Michael A. Henderson

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  3. Adsorption, Desorption, and Reaction of Methyl Radicals on Surface Terminations of α-Fe2O3

    The Journal of Physical Chemistry C · 2010-09-03

    Li Liu, Brian R. Quezada, Peter Curran Stair

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  4. Surface Structural Evolution in Iron Oxide Thin Films

    Langmuir · 2010-12-08

    Mingshan Xue, Shuai Wang, Kehui Wu, Jiandong Guo, Qinlin Guo

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  5. Thermodynamic modelling of nanomorphologies of hematite and goethite

    Journal of Materials Chemistry · 2011-01-01

    Haibo Guo, Amanda Susan Barnard

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  6. Surface properties of clean and Au or Pd covered hematite (α-Fe2O3) (0001)

    Journal of Physics Condensed Matter · 2012-01-25

    A. Kiejna, Tomasz Pabisiak

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  7. Environmentally dependent stability of low-index hematite surfaces

    Journal of Colloid and Interface Science · 2012-07-20

    Haibo Guo, Amanda Susan Barnard

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  8. Electronic Properties and Reactivity of Simulated Fe3+and Cr3+Substituted α-Al2O3(0001) Surface

    The Journal of Physical Chemistry C · 2012-08-07

    Jonas Baltrušaitis, Courtney D. Hatch, Roberto Orlando

    Read original paper ↗ ·

  9. The reduction and oxidation of Fe2O3(0001) surface investigated by scanning tunneling microscopy

    Surface Science · 2012-11-24

    Yuan‐Yuan Tang, Huajun Qin, Kehui Wu, Qinlin Guo, Jiandong Guo

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  10. Quantitative Structural Studies Of Corundum and Rocksalt Oxide Surfaces

    Chemical Reviews · 2013-01-07

    David Phillip Woodruff

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  11. Well-Ordered Transition Metal Oxide Layers in Model Catalysis – A Series of Case Studies

    Chemical Reviews · 2013-02-07

    Helmut Kuhlenbeck, Shamil' K. Shaikhutdinov, Hans‐Joachim Freund

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  12. Selective ring CH bonds activation of toluene over Fe/activated carbon catalyst

    Journal of Molecular Catalysis A Chemical · 2013-05-20

    Huihui Liu, Guiying Li, Changwei Hu

    Read original paper ↗ ·

  13. Mixed Termination of Hematite (α-Fe2O3)(0001) Surface

    The Journal of Physical Chemistry C · 2013-10-25

    A. Kiejna, Tomasz Pabisiak

    Read original paper ↗ ·

  14. DFT Simulations of Water Adsorption and Activation on Low‐Index α‐Ga2O3 Surfaces

    Chemistry - A European Journal · 2014-04-17

    Xin Zhou, Emiel J. M. Hensen, Rutger A. van Santen, Can Li

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  15. Interconversion of α-Fe 2 O 3 and Fe 3 O 4 Thin Films: Mechanisms, Morphology, and Evidence for Unexpected Substrate Participation

    The Journal of Physical Chemistry C · 2014-10-01

    Francesca Genuzio, Alessandro Sala, Thomas Schmidt, DIETRICH MENZEL, Hans‐Joachim Freund

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  16. Fe adsorption on hematite (α-Fe2O3) (0001) and magnetite (Fe3O4) (111) surfaces

    The Journal of Chemical Physics · 2014-10-07

    Tomasz Pabisiak, A. Kiejna

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  17. Subsurface cation vacancy stabilization of the magnetite (001) surface

    Science · 2014-12-04

    Roland Bliem, Eamon McDermott, Pascal Ferstl, Martin Setvín, Oscar Gamba, Jiří Pavelec, M. Alexander Schneider, Michael Schmid, Ulrike Diebold, Peter Blaha, Lutz Hammer, Gareth S. Parkinson

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  18. Weak thermal reduction of biphase Fe2O3(0001) films grown on Pt(111): Sub-surface Fe2+ formation

    Surface Science · 2015-05-08

    Hengshan Qiu, Volker Staemmler, Helmut Kuhlenbeck, Ernst Bauer, Hans‐Joachim Freund

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  19. The Effect of Thermal Treatment of Hematite Ore for Chemical Looping Combustion of Methane

    Journal of Energy Resources Technology · 2015-11-13

    Ronald W. Breault, Cory S. Yarrington, Justin M. Weber

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  20. Phase transformations in thin iron oxide films: Spectromicroscopic study of velocity and shape of the reaction fronts

    Surface Science · 2015-11-28

    Francesca Genuzio, Alessandro Sala, Thomas Schmidt, DIETRICH MENZEL, Hans‐Joachim Freund

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  21. Adsorption of gold subnano-structures on a magnetite(111) surface and their interaction with CO

    Physical Chemistry Chemical Physics · 2016-01-01

    Tomasz Pabisiak, Maciej J. Winiarski, Tomasz Ossowski, A. Kiejna

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  22. Water adsorption and O-defect formation on Fe 2 O 3 (0001) surfaces

    Physical Chemistry Chemical Physics · 2016-01-01

    Roman Ovcharenko, Elena N. Voloshina, Joachim Sauer

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  23. Iron oxide surfaces

    Surface Science Reports · 2016-03-01

    Gareth S. Parkinson

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  24. Thermodynamics of Iron Oxides and Oxyhydroxides in Different Environments

    Unknown journal · 2016-04-29

    Haibo Guo, Amanda Susan Barnard

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  25. Defect-induced enhanced photocatalytic activities of reduced α -Fe 2 O 3 nanoblades

    Nanotechnology · 2016-06-10

    Honglei Feng, Yiqian Wang, Chao Wang, Feiyu Diao, Wenhui Zhu, Peng Mu, Yuan Lü, Guangwen Zhou, Federico Rosei

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  26. Kinetics and intermediate phases in epitaxial growth of Fe3O4 films from deposition and thermal reduction

    Journal of Applied Physics · 2016-08-28

    Xiaozhe Zhang, Sen Yang, Zhimao Yang, Xiaoshan Xu

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  27. Nanoscale Patterns on Polar Oxide Surfaces

    Chemistry of Materials · 2016-09-28

    Mikołaj Lewandowski, Irene M. N. Groot, Zhihui Qin, Tomasz Ossowski, Tomasz Pabisiak, A. Kiejna, Anastassia Pavlovska, Shamil' K. Shaikhutdinov, Hans‐Joachim Freund, Ernst Bauer

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  28. Iron cation-induced biphase symbiosis of h-WO 3 /o-WO 3 ·0.33H 2 O and their crystal phase transition

    CrystEngComm · 2017-01-01

    Huixiang Wang, Ruimin Ding, Conghui Wang, Xiaobo Ren, Liancheng Wang, Baoliang Lv

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  29. Unpredicted surface termination of α-Fe 2 O 3 (0001) film grown by mist chemical vapor deposition

    Surface Science · 2017-02-09

    Shun Osaka, Osamu Kubo, Kazuki Takahashi, Masaya Oda, Kentaro Kaneko, Hiroshi Tabata, Shizυo Fujita, Mitsuhiro Katayama

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  30. Hematite, Its Stable Surface Terminations and Their Reactivity Toward Water

    Elsevier eBooks · 2017-09-30

    Elena N. Voloshina, Yuriy Dedkov

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  31. Atomic-Scale Structure of the Hematite α-Fe2O3(1102) “R-Cut” Surface

    The Journal of Physical Chemistry C · 2017-12-08

    Florian Kraushofer, Zdeněk Jakub, Magdalena Bichler, Jan Hulva, P. Drmota, Michael Weinold, Michael Schmid, Martin Setvín, Ulrike Diebold, Peter Blaha, Gareth S. Parkinson

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  32. Molecular species forming at the α-Fe 2 O 3 nanoparticle–aqueous solution interface

    Chemical Science · 2018-01-01

    Hebatallah Ali, Robert W. Seidel, Marvin N. Pohl, Bernd J. Winter

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  33. Pure phase BiFeO3 thin films sputtered over Si: A new route towards high magnetization

    Journal of Magnetism and Magnetic Materials · 2018-03-27

    Grecia Alejandra Gomez-Iriarte, Cilene Labre, L.A.S. de Oliveira, João Paulo Sinnecker

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  34. Oxygen Carrier Structure and Attrition

    Unknown journal · 2018-10-05

    Nathan L. Galinsky, Samuel C. Bayham, Esmail R. Monazam, Ronald W. Breault

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  35. Gold-Decorated Biphase α-Fe2O3(0001): Activation by CO-Induced Surface Reduction

    The Journal of Physical Chemistry C · 2018-10-14

    Hengshan Qiu, Helmut Kuhlenbeck, Ernst Bauer, Hans‐Joachim Freund

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  36. Chemistry of Methanol and Ethanol on Ozone-Prepared α-Fe2O3(0001)

    The Journal of Physical Chemistry C · 2018-10-17

    Constantin A. Walenta, Andrew S. Crampton, Fang Xu, Ueli Heiz, C. M. Friend

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  37. Identification of Two-Dimensional FeO2 Termination of Bulk Hematite α-Fe2O3(0001) Surface

    The Journal of Physical Chemistry C · 2019-04-24

    Jesús Redondo, Petr Lazar, Pavel Procházka, Stanislav Průša, Benjamín Mallada, Aleš Cahlík, Jan Lachnitt, Jan Berger, Břetislav Šmíd, Lukáš Kormoš, Pavel Jelı́nek, Jan Čechal, Martin Švec

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  38. CO adsorption on Fe3O4(1 1 1) with regular and biphase terminations

    Applied Surface Science · 2019-12-13

    Joanna Wojas, Natalia Kwiatek-Maroszek, Dorota Wilgocka‐Ślęzak, Ewa Madej, J. Korecki, N. Spiridis

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  39. Reversible oxidation–reduction of epitaxial iron oxide films on Pt(111): Magnetite–hematite interconversion

    The Journal of Chemical Physics · 2020-02-03

    K. Freindl, Joanna Wojas, Natalia Kwiatek-Maroszek, J. Korecki, N. Spiridis

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  40. In situ TEM oxidation study of Fe thin-film transformation to single-crystal magnetite nanoparticles

    Journal of Materials Science · 2020-06-16

    Leonardo Lari, Stephan Steinhauer, Vlado K. Lazarov

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  41. Simulation of STM Images of Hematite α-Fe2O3(0001) Surfaces: Dependence on Distance and Bias

    The Journal of Physical Chemistry C · 2021-11-23

    Tomasz Ossowski, Tomasz Pabisiak, A. Kiejna, Krisztián Palotás, Ernst Bauer

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  42. Spin Seebeck Effect in Iron Oxide Thin Films: Effects of Phase Transition, Phase Coexistence, And Surface Magnetism

    ACS Applied Materials & Interfaces · 2022-03-08

    Amit Chanda, Derick DeTellem, Yen Thi Hai Pham, Jenae E. Shoup, Anh Tuan Duong, Raja Das, Sunglae Cho, Dmitri V. Voronine, Minh Tuan Trinh, Dario A. Arena, Sarath Witanachchi, H. Srikanth, Manh‐Huong Phan

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  43. Application of machine learning to reflection high-energy electron diffraction images for automated structural phase mapping

    Physical Review Materials · 2022-06-29

    Haotong Liang, Valentin Stanev, Aaron Gilad Kusne, Yuto Tsukahara, Kaito Ito, Ryota Takahashi, Mikk Lippmaa, Ichiro Takeuchi

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  44. Atomic Structure of the Fe 3 O 4 /Fe 2 O 3 Interface During Phase Transition from Hematite to Magnetite

    Inorganic Chemistry · 2023-07-20

    Xiaoben Zhang, Chuanchuan Jin, Shaobo Han, Peiyao Guo, Yan Zhou, Wei Liu, Wenjie Shen

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  45. Hematite α ‐Fe 2 O 3 (0001) in Top and Side View: Resolving Long‐Standing Controversies about Its Surface Structure

    Advanced Materials Interfaces · 2023-08-18

    Jesús Redondo, Jan Michalička, Florian Kraushofer, Giada Franceschi, Břetislav Šmíd, Nishant Kumar, Ondřej Man, Matthias Blatnik, Dominik Wrana, Benjamín Mallada, Martin Švec, Gareth S. Parkinson, Martin Setvín, Michele Riva, Ulrike Diebold, Jan Čechal

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  46. A multi-analytical approach reveals flexible compound adhesive technology at Steenbokfontein Cave, Western Cape

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  47. Revealing the catalytic oxidation mechanism of CO on α-Fe 2 O 3 surfaces: an ab initio thermodynamic study

    Physical Chemistry Chemical Physics · 2024-12-23

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  48. Ferri-/Antiferromagnetic Heterostructures: A Case Study of the Fe 3 O 4 /NiO Interface

    The Journal of Physical Chemistry C · 2025-12-03

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