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RESEARCH PAPER · Journal of Applied Physics · 2013

Polarized Raman scattering analysis of Cu2ZnSiS4and Cu2ZnSiSe4single crystals

Maxim Guc, S. Levcenko, Víctor Izquierdo‐Roca, Xavier Fontané, Mykhailo Ya. Valakh, E. Arushanov, Alejandro Pérez-Rodríguez

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Polarized Raman scattering analysis of Cu2ZnSiS4and Cu2ZnSiSe4single crystalsOriginalExciton spectra and energy band structure of Cu2ZnSiSe411Polarized Raman scattering analysis of Cu2ZnSnSe4 and Cu2ZnGeSe4 single crystals88Excitonic and band-band transitions of Cu2ZnSiS4 determined from reflectivity spectra5Variable-range hopping conductivity in Cu2ZnGeSe4 single crystals14Optical phonons in the wurtzstannite Cu2 ZnGeS4 semiconductor: Polarized Raman spectroscopy and first-principle calculations26Raman investigation of epitaxial Cu2ZnSnSe4 layers from annealed Sn/Cu/ZnSe(001) precursors on GaAs(001)0Vibrational and structural properties of Cu2ZnSn(SxSe1−x)4 (0 ≤ x ≤ 1) solid solutions0Epitaxial Cu2ZnSnSe4 layers by annealing of Sn/Cu/ZnSe(001) precursors on GaAs(001)1Study of structural and optoelectronic properties of Cu2Zn(Sn1−xGex)Se4 (x = 0 to 1) alloy compounds36Assessment of crystal quality and unit cell orientation in epitaxial Cu_2ZnSnSe_4 layers using polarized Raman scattering2Structural study and Raman scattering analysis of Cu_2ZnSiTe_4 bulk crystals12Multistep deposition of Cu2Si(S,Se)3 and Cu2ZnSiSe4high band gap absorber materials for thin film solar cells11Optoelectronic and material properties of nanocrystal-based CZTSe absorbers with Ag-alloying140Optical phonons in the kesterite Cu 2 ZnGeS 4 semiconductor: polarized Raman spectroscopy and first-principle calculations41Synthesis and characterization of kesterite Cu 2 ZnSnTe 4 via ball-milling of elemental powder precursors23Polarized Raman scattering study of kesterite type Cu2ZnSnS4 single crystals127Towards high performance Cd-free CZTSe solar cells with a ZnS(O,OH) buffer layer: the influence of thiourea concentration on chemical bath deposition50Influence of alkali metals (Na, Li, Rb) on the performance of electrostatic spray-assisted vapor deposited Cu2ZnSn(S,Se)4 solar cells79Optoelectrical, structural and morphological characterization of Cu2ZnSnSe4 compound used in photovoltaic applications5Crystal structure and vibrational properties of Cu2ZnSiSe4quaternary semiconductor22Growth and characterization of Cu2ZnGeSe4 thin films by selenization of multiple stacks (Cu/Se/ZnSe/Se/Ge/Se) in high vacuum10Cu-Zn disorder in Cu 2 ZnGeSe 4 : A complementary neutron diffraction and Raman spectroscopy study42Multiwavelength excitation Raman scattering of Cu2ZnSn1-xGex(S,Se)4 single crystals for earth abundant photovoltaic applications33Characterization of thermally evaporated CZTSe thin films used by compositionally controlled alloys15Vibrational spectroscopy of orthorhombic Cu 2 ZnSiS 4 single crystal: Low-temperature polarized Raman scattering and first principle calculations5Mechanisms of conductivity and energy spectrum of near-edge holes in Cu2ZnSnS4 powder samples12Influence of annealing temperature on the properties of non-stoichiometric Cu1.66Zn1.25GeSe4 thin films3Effect of selenium incorporation at precursor stage on growth and properties of Cu2ZnSnSe4 thin films9Cu2ZnSnSSe4 solar cells with 9.6% efficiency via selenizing Cu-Zn-Sn-S precursor sputtered from a quaternary target35Raman scattering in right angle configuration on Cu2ZnSiSe4 single crystals0Beyond 11% efficient Cu2ZnSn(Se,S)4 thin film solar cells by cadmium alloying90Structural, optical, electrical properties and energy band diagram of Cu2ZnSiS4 thin films158.1% efficient Cu2Zn(Sn,Ge)(S,Se)4 solar cell based on a single-target sputtering method9Revealing the beneficial effects of Ge doping on Cu 2 ZnSnSe 4 thin film solar cells65Structural, electronic and optical properties of bandgap-tunable Cu ZnSi Sn1−Se alloys8Cu2ZnSnSe4 based solar cells combining co-electrodeposition and rapid thermal processing16Vibrational and optical properties of CZTS derivatives for photovoltaic applications: Synthesis of Cu2ZnSn1-xGexS2Se2 compounds6Desarrollo de prototipos de dispositivos de conversión fotovoltaica con base en CZTS sobre sustratos cerámicos0Intermediate band solar cell materials through the doping of group-VA elements (N, P, As and Sb) in Cu 2 ZnSiSe 44Structure dependent electronic and optical properties of Cu2ZnGeX4 (X=S, Se) solar cell compounds3Influence of Cu-Zn disorder in Cu2ZnSnSe4 absorbers on optical transitions: A spectroscopic ellipsometry study2Point defects, compositional fluctuations, and secondary phases in non-stoichiometric kesterites152Synthesis of Cu2ZnSnSe4 from nitrate and selenite inks for use as an absorbent layer in the design of solar cells0Dry mill route for synthesis of single phase bulk and e-beam growth of thin films of Cu2ZnSnSe4 for photovoltaic applications10Cu2Zn(Si,Ge)Se4 quaternary semiconductors as potential photovoltaic materials14Polycrystalline Cu2ZnSn(SxSe1– x)4 Solid Solutions: Synthesis, Phase Composition, and Photoconductivity Loss Kinetics3The path towards efficient wide band gap thin-film kesterite solar cells with transparent back contact for viable tandem application24Optical phonons in pentanary compound (Ag Cu1−)2ZnSnS4 semiconductor: A raman study15A Short Review on Raman Studies of Metal Chalcogenide Semiconductor Thin Films0Enhancing the Hydrogen Evolution Properties of Kesterite Absorber by Si‐Doping in the Surface of CZTS Thin Film15Insights on the limiting factors of Cu2ZnGeSe4 based solar cells15Synthesis, structure, linear and nonlinear optical properties of noncentrosymmetric quaternary diamond-like semiconductors, Cu2ZnGeSe4 (CZGSe) and the novel Cu4ZnGe2Se720Hole Transport Layer based on atomic layer deposited V2Ox films: Paving the road to semi-transparent CZTSe solar cells12Colloidal Cu-Zn-Sn-Te Nanocrystals: Aqueous Synthesis and Raman Spectroscopy Study9Rhenium Bronze Oxide Containing Tellurium Ions with Two Lone Pairs0Crystal structure of Cu 2 Zn(Ge x Si 1− x )Se 4 solid solution: the kesterite to wurtz–kesterite structural phase transition2

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  1. Exciton spectra and energy band structure of Cu2ZnSiSe4

    Journal of Alloys and Compounds · 2013-10-31

    Maxim Guc, S. Levcenko, L. Dermenji, Galina Gurieva, Susan Schorr, N. N. Syrbu, E. Arushanov

    Read original paper ↗ ·

  2. Polarized Raman scattering analysis of Cu2ZnSnSe4 and Cu2ZnGeSe4 single crystals

    Journal of Applied Physics · 2013-11-19

    Maxim Guc, S. Levcenko, Víctor Izquierdo‐Roca, Xavier Fontané, E. Arushanov, Alejandro Pérez-Rodríguez

    Read original paper ↗ ·

  3. Excitonic and band-band transitions of Cu2ZnSiS4 determined from reflectivity spectra

    Solid State Communications · 2014-04-04

    Maxim Guc, S. Levcenko, L. Dermenji, Galina Gurieva, Susan Schorr, N. N. Syrbu, E. Arushanov

    Read original paper ↗ ·

  4. Variable-range hopping conductivity in Cu2ZnGeSe4 single crystals

    Solar Energy Materials and Solar Cells · 2014-05-04

    Maxim Guc, Konstantin G. Lisunov, Elena Hajdeu-Chicarosh, S. Levcenko, V. V. Ursaki, E. Arushanov

    Read original paper ↗ ·

  5. Optical phonons in the wurtzstannite Cu2 ZnGeS4 semiconductor: Polarized Raman spectroscopy and first-principle calculations

    Physical Review B · 2014-05-22

    Maxim Guc, Alexander P. Litvinchuk, S. Levcenko, Víctor Izquierdo‐Roca, Xavier Fontané, Mykhailo Ya. Valakh, E. Arushanov, Alejandro Pérez-Rodríguez

    Read original paper ↗ ·

  6. Raman investigation of epitaxial Cu2ZnSnSe4 layers from annealed Sn/Cu/ZnSe(001) precursors on GaAs(001)

    Conference record of the IEEE Photovoltaic Specialists Conference · 2014-06-01

    Christoph Krämmer, Mario Lang, Johannes Sachs, Lukas Pfaffmann, Chao Gao, Dagmar Gerthsen, H. Kalt, Michael Powalla, M. Hetterich

    Read original paper ↗ ·

  7. Vibrational and structural properties of Cu2ZnSn(SxSe1−x)4 (0 ≤ x ≤ 1) solid solutions

    Conference record of the IEEE Photovoltaic Specialists Conference · 2014-06-01

    Mirjana Dimitrievska, Haibing Xie, Galina Gurieva, Xavier Fontané, Andrew Fairbrother, René Gunder, Edgardo Saucedo, Alejandro Pérez-Rodríguez, Susan Schorr, Víctor Izquierdo‐Roca

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  8. Epitaxial Cu2ZnSnSe4 layers by annealing of Sn/Cu/ZnSe(001) precursors on GaAs(001)

    Thin Solid Films · 2014-10-03

    Christoph Krämmer, Johannes Sachs, Lukas Pfaffmann, Timo Musiol, Mario Lang, Chao Gao, Dagmar Gerthsen, H. Kalt, Michael Powalla, M. Hetterich

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  9. Study of structural and optoelectronic properties of Cu2Zn(Sn1−xGex)Se4 (x = 0 to 1) alloy compounds

    Thin Solid Films · 2014-10-23

    Maarja Grossberg, Kristi Timmo, T. Raadik, Erki Kärber, Valdek Mikli, Jüri Krustok

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  10. Assessment of crystal quality and unit cell orientation in epitaxial Cu_2ZnSnSe_4 layers using polarized Raman scattering

    Optics Express · 2014-11-06

    Christoph Krämmer, Mario Lang, Alex Redinger, Johannes Sachs, Chao Gao, H. Kalt, Susanne Siebentritt, M. Hetterich

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  11. Structural study and Raman scattering analysis of Cu_2ZnSiTe_4 bulk crystals

    Optics Express · 2014-12-12

    S. Levcenko, А. Н. Натепров, Victor Kravtsov, Maxim Guc, Alejandro Pérez-Rodríguez, Víctor Izquierdo‐Roca, Xavier Fontané, E. Arushanov

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  12. Multistep deposition of Cu2Si(S,Se)3 and Cu2ZnSiSe4high band gap absorber materials for thin film solar cells

    physica status solidi (RRL) - Rapid Research Letters · 2015-05-29

    Hossam Elanzeery, Marie Buffière, Khaled Ben Messaoud, Souhaib Oueslati, Guy Brammertz, Ounsi El Daïf, David Cheyns, Rafik S. Guindi, Marc Meuris, Jef Poortmans

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  13. Optoelectronic and material properties of nanocrystal-based CZTSe absorbers with Ag-alloying

    Solar Energy Materials and Solar Cells · 2015-11-14

    Charles J. Hages, Mark J. Koeper, Rakesh Agrawal

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  14. Optical phonons in the kesterite Cu 2 ZnGeS 4 semiconductor: polarized Raman spectroscopy and first-principle calculations

    RSC Advances · 2016-01-01

    Maxim Guc, Alexander P. Litvinchuk, S. Levcenko, Mykhailo Ya. Valakh, I. V. Bodnar, Volodymyr Dzhagan, Víctor Izquierdo‐Roca, E. Arushanov, Alejandro Pérez-Rodríguez

    Read original paper ↗ ·

  15. Synthesis and characterization of kesterite Cu 2 ZnSnTe 4 via ball-milling of elemental powder precursors

    RSC Advances · 2016-01-01

    Devendrá Pareek, Kavaipatti Ramanathan Balasubramaniam, Pratibha Sharma

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  16. Polarized Raman scattering study of kesterite type Cu2ZnSnS4 single crystals

    Scientific Reports · 2016-01-18

    Maxim Guc, S. Levcenko, I. V. Bodnar, Víctor Izquierdo‐Roca, Xavier Fontané, Larisa V. Volkova, E. Arushanov, Alejandro Pérez-Rodríguez

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  17. Towards high performance Cd-free CZTSe solar cells with a ZnS(O,OH) buffer layer: the influence of thiourea concentration on chemical bath deposition

    Journal of Physics D Applied Physics · 2016-02-23

    Markus Neuschitzer, Karla Lienau, Maxim Guc, Lorenzo Calvo‐Barrio, Stefan G. Haass, José Márquez Prieto, Yudania Sánchez, M. Espíndola-Rodríguez, Yaroslav E. Romanyuk, Alejandro Pérez-Rodríguez, Víctor Izquierdo‐Roca, Edgardo Saucedo

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  18. Influence of alkali metals (Na, Li, Rb) on the performance of electrostatic spray-assisted vapor deposited Cu2ZnSn(S,Se)4 solar cells

    Scientific Reports · 2016-02-26

    Giovanni Altamura, Mingqing Wang, Kwang‐Leong Choy

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  19. Optoelectrical, structural and morphological characterization of Cu2ZnSnSe4 compound used in photovoltaic applications

    Applied Surface Science · 2016-04-12

    F. Mesa, A. Leguizamon, A. Dussán, Gerardo Gordillo

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  20. Crystal structure and vibrational properties of Cu2ZnSiSe4quaternary semiconductor

    physica status solidi (b) · 2016-05-18

    Alexander P. Litvinchuk, Volodymyr Dzhagan, Volodymyr Olexsandrovych Yukhymchuk, Mykhailo Ya. Valakh, O.V. Parasyuk, Л.В. Піскач, Xianbing Wang, Allan J. Jacobson, Dietrich R. T. Zahn

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  21. Growth and characterization of Cu2ZnGeSe4 thin films by selenization of multiple stacks (Cu/Se/ZnSe/Se/Ge/Se) in high vacuum

    Vacuum · 2016-06-30

    G. Swapna Mary, Dipak Ramdas Nagapure, Rhishikesh Mahadev Patil, G. Hema Chandra, M. Anantha Sunil, R. Prasada Rao, Mukul Gupta, Y.P. Venkata Subbaiah

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  22. Cu-Zn disorder in Cu 2 ZnGeSe 4 : A complementary neutron diffraction and Raman spectroscopy study

    Journal of Physics and Chemistry of Solids · 2016-08-31

    Galina Gurieva, Daniel Maria Többens, Mykhailo Ya. Valakh, Susan Schorr

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  23. Multiwavelength excitation Raman scattering of Cu2ZnSn1-xGex(S,Se)4 single crystals for earth abundant photovoltaic applications

    Journal of Alloys and Compounds · 2016-09-09

    E. Garcia-Llamas, Maxim Guc, I. V. Bodnar, Xavier Fontané, Raquel Caballero, J. M. Merino, M. León, Víctor Izquierdo‐Roca

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  24. Characterization of thermally evaporated CZTSe thin films used by compositionally controlled alloys

    Optical Materials · 2016-10-06

    Chinnaiyah Sripan, Rajamanickam Ganesan, Ramakanta Naik, Annamraju Kasi Viswanath

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  25. Vibrational spectroscopy of orthorhombic Cu 2 ZnSiS 4 single crystal: Low-temperature polarized Raman scattering and first principle calculations

    Vibrational Spectroscopy · 2017-01-25

    Mykhailo Ya. Valakh, Volodymyr Olexsandrovych Yukhymchuk, Ivan S. Babichuk, Yevhenii Havryliuk, O.V. Parasyuk, Л.В. Піскач, Alexander P. Litvinchuk

    Read original paper ↗ ·

  26. Mechanisms of conductivity and energy spectrum of near-edge holes in Cu2ZnSnS4 powder samples

    Journal of Alloys and Compounds · 2017-02-02

    Elena Hajdeu-Chicarosh, Maxim Guc, K. Neldner, Galina Gurieva, Susan Schorr, E. Arushanov, Konstantin G. Lisunov

    Read original paper ↗ ·

  27. Influence of annealing temperature on the properties of non-stoichiometric Cu1.66Zn1.25GeSe4 thin films

    Surfaces and Interfaces · 2017-04-01

    Chinnaiyah Sripan, Vinod Erkkara Madhavan, Rajamanickam Ganesan, Annamraju Kasi Viswanath

    Read original paper ↗ ·

  28. Effect of selenium incorporation at precursor stage on growth and properties of Cu2ZnSnSe4 thin films

    Vacuum · 2017-07-16

    Dipak Ramdas Nagapure, Rhishikesh Mahadev Patil, G. Swapna Mary, G. Hema Chandra, M. Anantha Sunil, Y.P. Venkata Subbaiah, Mukul Gupta, R. Prasada Rao

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  29. Cu2ZnSnSSe4 solar cells with 9.6% efficiency via selenizing Cu-Zn-Sn-S precursor sputtered from a quaternary target

    Solar Energy Materials and Solar Cells · 2017-09-01

    Rujun Sun, Daming Zhuang, Ming Zhao, Qianming Gong, Yaowei Wei, Guoan Ren, Yixuan Wu

    Read original paper ↗ ·

  30. Raman scattering in right angle configuration on Cu2ZnSiSe4 single crystals

    Optical Materials · 2017-09-05

    Maxim Guc, S. Levcenko, Victor V. Zalamai, E. Arushanov, N. N. Syrbu

    Read original paper ↗ ·

  31. Beyond 11% efficient Cu2ZnSn(Se,S)4 thin film solar cells by cadmium alloying

    Solar Energy Materials and Solar Cells · 2017-10-03

    Rujun Sun, Daming Zhuang, Ming Mei Zhao, Qianming Gong, Michael A. Scarpulla, Yaowei Wei, Guoan Ren, Yixuan Wu

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  32. Structural, optical, electrical properties and energy band diagram of Cu2ZnSiS4 thin films

    Solar Energy Materials and Solar Cells · 2017-10-12

    Manoj Kumar Vishwakarma, Deepak Varandani, Sonnada Math Shivaprasad, Bodh Raj Mehta

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  33. 8.1% efficient Cu2Zn(Sn,Ge)(S,Se)4 solar cell based on a single-target sputtering method

    Journal of Alloys and Compounds · 2017-12-06

    Linyuan Du, Wei Zhao, Yali Sun, Linlin Liu, Weijie Dai, Zhiwei Liu, Guangsheng Fu, Wei Dong Yu, Chao Gao

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  34. Revealing the beneficial effects of Ge doping on Cu 2 ZnSnSe 4 thin film solar cells

    Journal of Materials Chemistry A · 2018-01-01

    Markus Neuschitzer, Moisés Espíndola, Maxim Guc, J.A. Marquez, Sergio Giraldo, Ian Forbes, Alejandro Pérez-Rodríguez, Edgardo Saucedo

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  35. Structural, electronic and optical properties of bandgap-tunable Cu ZnSi Sn1−Se alloys

    Chemical Physics Letters · 2018-05-31

    M. Jibran, Z. Y. Li, Xia Sun, Bo Wang, Y. Yamauchi, Zejun Ding

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  36. Cu2ZnSnSe4 based solar cells combining co-electrodeposition and rapid thermal processing

    Solar Energy · 2018-08-23

    Matias Valdes, Alejandro Hernández-Martínez, Yudania Sánchez, Florian Oliva, Víctor Izquierdo‐Roca, Alejandro Pérez Rodríguez, Edgardo Saucedo

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  37. Vibrational and optical properties of CZTS derivatives for photovoltaic applications: Synthesis of Cu2ZnSn1-xGexS2Se2 compounds

    Solid State Sciences · 2018-09-16

    C. Pinto, F. López, Antonio Galdámez, P. Barahona, Silvana Moris

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  38. Desarrollo de prototipos de dispositivos de conversión fotovoltaica con base en CZTS sobre sustratos cerámicos

    Unknown journal · 2019-01-01

    Torres Barahona, Edgar Absalón Torres Barahona

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  39. Intermediate band solar cell materials through the doping of group-VA elements (N, P, As and Sb) in Cu 2 ZnSiSe 4

    RSC Advances · 2019-01-01

    M. Jibran, Xia Sun, Bing Wang, Yasushi Yamauchi, Zejun Ding

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  40. Structure dependent electronic and optical properties of Cu2ZnGeX4 (X=S, Se) solar cell compounds

    Optik · 2019-01-26

    Amit Soni, Pancham Kumar, Ushma Ahuja, Jagrati Sahariya

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  41. Influence of Cu-Zn disorder in Cu2ZnSnSe4 absorbers on optical transitions: A spectroscopic ellipsometry study

    Optical Materials · 2019-05-15

    Özden Demircioğlu, José Fabio López Salas, Germain Rey, Jürgen Parisi, Levent Gütay

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  42. Point defects, compositional fluctuations, and secondary phases in non-stoichiometric kesterites

    Journal of Physics Energy · 2019-10-02

    Susan Schorr, Galina Gurieva, Maxim Guc, Mirjana Dimitrievska, Alejandro Pérez-Rodríguez, Víctor Izquierdo‐Roca, Claudia S. Schnohr, Juran Kim, William Jo, J. M. Merino

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  43. Synthesis of Cu2ZnSnSe4 from nitrate and selenite inks for use as an absorbent layer in the design of solar cells

    Journal of Physics Conference Series · 2019-11-01

    Edgar Absalón Torres Barahona, Y T Castellanos Báez, Jairo A. Gómez-Cuaspud, Enrique Vera López, Juan Bautista Carda, Y Pineda-Triana

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  44. Dry mill route for synthesis of single phase bulk and e-beam growth of thin films of Cu2ZnSnSe4 for photovoltaic applications

    Journal of Alloys and Compounds · 2020-07-22

    Deepak Goyal, P. Malar

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  45. Cu2Zn(Si,Ge)Se4 quaternary semiconductors as potential photovoltaic materials

    Chemical Physics Letters · 2020-07-26

    M. Jibran, Xia Sun, J. Hua, B. Wang, Y. Yamauchi, Bo Da, Zejun Ding

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  46. Polycrystalline Cu2ZnSn(SxSe1– x)4 Solid Solutions: Synthesis, Phase Composition, and Photoconductivity Loss Kinetics

    Inorganic Materials · 2020-10-01

    В. Ф. Гременок, V. G. Hurtavy, Aliona V. Stanchik, T. V. Shoukavaya, В. А. Чумак, Evgenia V. Rabenok, Vladimir V. Rakitin, Б. И. Голованов, Gennady F. Novikov

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  47. The path towards efficient wide band gap thin-film kesterite solar cells with transparent back contact for viable tandem application

    Solar Energy Materials and Solar Cells · 2020-10-08

    Samira Khelifi, Guy Brammertz, Léo Choubrac, Maria Batuk, Sheng Qiang Yang, Marc Meuris, Nicolas Barreau, Joke Hadermann, Henk Vrielinck, Dirk Poelman, Kristiaan Neyts, Bart Vermang, Johan Lauwaert

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  48. Optical phonons in pentanary compound (Ag Cu1−)2ZnSnS4 semiconductor: A raman study

    Journal of Alloys and Compounds · 2020-12-05

    Jitendra Kumar, Sarang Ingole

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  49. A Short Review on Raman Studies of Metal Chalcogenide Semiconductor Thin Films

    Asian Journal of Chemistry · 2021-01-01

    Ho Soonmin, Mohd Hafiz Dzarfan Othman, Mohd Ridhwan Adam, Kannusamy Mohanraj

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  50. Enhancing the Hydrogen Evolution Properties of Kesterite Absorber by Si‐Doping in the Surface of CZTS Thin Film

    Advanced Materials Interfaces · 2021-04-01

    Manoj Kumar Vishwakarma, Mukesh Kumar, Mylène Hendrickx, Joke Hadermann, Aadesh Pratap Singh, Yogita Batra, Bodh Raj Mehta

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