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RESEARCH PAPER · Nature Materials · 2004

The origin of ferroelectricity in magnetoelectric YMnO3

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The origin of ferroelectricity in magnetoelectric YMnO3OriginalMagnetic phase control by an electric field982Bond- versus site-centred ordering and possible ferroelectricity in manganites444A new route to magnetic ferroelectrics171Magnetoelectric behavior of domain walls in multiferroic HoMnO3115Crystallographic Features and Tetragonal Phase Stability of PbVO3, a New Member of PbTiO3 Family189Ab initio prediction of a multiferroic with large polarization and magnetization235Second-harmonic generation as a tool for studying electronic and magnetic structures of crystals: review488First-principles study of spontaneous polarization in multiferroic Bi Fe O 31462Revival of the magnetoelectric effect5056Direct observation of a coupling between spin, lattice and electric dipole moment in multiferroic YMnO3124Recent progress in first-principles studies of magnetoelectric multiferroics109Influence of strain and oxygen vacancies on the magnetoelectric properties of multiferroic bismuth ferrite394The single-phase multiferroic oxides: from bulk to thin film668Magnetic Ordering in CuO from First Principles: A Cuprate Antiferromagnet with Fully Three-Dimensional Exchange Interactions100Ferroelectric transition in Y Mn O 3 from first principles401Physics of thin-film ferroelectric oxides2296Orbital and Bonding Anisotropy in a Half-Filled GaFeO3 Magnetoelectric Ferrimagnet162Magnetocapacitance without magnetoelectric coupling908Multiferroics: Different ways to combine magnetism and ferroelectricity1040Electronic Origins of Structural Distortions in Post-Transition Metal Oxides: Experimental and Theoretical Evidence for a Revision of the Lone Pair Model231Origin of ferroelectricity in the multiferroic barium fluorides Ba M F 4 : A first principles study116Subsolidus phase equilibria and properties in the system Bi2O3:Mn2O3±x:Nb2O5114Hexagonal versus perovskite phase of manganite R Mn O 3 ( R = Y , Ho , Er , Tm , Yb , Lu )182Phase formation, crystal chemistry, and properties in the system Bi2O3–Fe2O3–Nb2O5150Phase Formation and Properties in the System Bi 2 O 3 :2CoO 1+ x :Nb 2 O 594Epitaxial Stabilization of a New Multiferroic Hexagonal Phase of TbMnO3 Thin Films99Experimental and theoretical study of the electronic structures of α-PbO and β-PbO 2117Electric-Field Control of Exchange Bias in Multiferroic Epitaxial Heterostructures326Preparation, structures, and multiferroic properties of single phase Bi1−xLaxFeO3 (x=–0.40) ceramics136Multiferroics: a magnetic twist for ferroelectricity4592Multiferroics: progress and prospects in thin films3990New routes to multiferroics174Atomic-orbital-based approximate self-interaction correction scheme for molecules and solids167Observation of local non-centrosymmetry in weakly biferroic YCrO3151Recent advancements in magnetoelectric particulate and laminate composites317The lock-in technique for studying magnetoelectric effect197Ferroelectricity Driven by Y d0 -ness with Rehybridization in YMnO3125Charge-Stripe Order in the Electronic Ferroelectric LuFe2O498Strain Tuning of Ferroelectric Thin Films1166Modern Physics of Ferroelectrics: Essential Background183Polaron melting and ordering as key mechanisms for colossal resistance effects in manganites169Effect of Tb doping on electric and magnetic behavior of BiFeO3 thin films119Electronic structures of hexagonal RMnO3 ( R=Gd , Tb, Dy, and Ho) thin films: Optical spectroscopy and first-principles calculations85Strain induced magnetoelectric coupling between magnetite and BaTiO389Large phonon band gap in SrTiO3 and the vibrational signatures of ferroelectricity in ATiO3 perovskites: First-principles lattice dynamics and inelastic neutron scattering104Influence of defects on structural and magnetic properties of multifunctional La2NiMnO6 thin films121The Ferroic Phase Transitions of BiFeO3222Large Coupled Magnetoresponses in EuNbO2N104Multiferroics and magnetoelectrics: thin films and nanostructures449First Principles Studies of Multiferroic Materials149Classifying multiferroics: Mechanisms and effects1589Absence of Critical Thickness in an Ultrathin Improper Ferroelectric Film89Evidence for large electric polarization from collinear magnetism in TmMnO3101Non- d0 Mn-driven ferroelectricity in antiferromagnetic BaMnO3187Multiferroicity: the coupling between magnetic and polarization orders1499First principles studies of multiferroic materials187Mn3+ in Trigonal Bipyramidal Coordination: A New Blue Chromophore204Oxides, Oxides, and More Oxides: High-κ Oxides, Ferroelectrics, Ferromagnetics, and Multiferroics197Insulating interlocked ferroelectric and structural antiphase domain walls in multiferroic YMnO3477Advances in the growth and characterization of magnetic, ferroelectric, and multiferroic oxide thin films644Magnetoelectric Coupling Effects in Multiferroic Complex Oxide Composite Structures889Electrostatic topology of ferroelectric domains in YMnO3139Multiferroic thin-film integration onto semiconductor devices119Self-organization, condensation, and annihilation of topological vortices and antivortices in a multiferroic110Magnetization Reversal by Electric-Field Decoupling of Magnetic and Ferroelectric Domain Walls in Multiferroic-Based Heterostructures134Magnetoelectric Hexaferrites380High-temperature phase transitions of hexagonal YMnO 3209Introduction to magnetoelectric coupling and multiferroic films306Multi-ferroic and magnetoelectric materials and interfaces233Weak ferromagnetism in hexagonal orthoferrites RFeO3 (R = Lu, Er-Tb)108Spintronic oxides grown by laser-MBE125Structurally Tailored Hexagonal Ferroelectricity and Multiferroism in Epitaxial YbFeO3 Thin-Film Heterostructures116Domain wall nanoelectronics1265Conduction of Topologically Protected Charged Ferroelectric Domain Walls228Anisotropic conductance at improper ferroelectric domain walls473Advanced synthesis techniques and routes to new single-phase multiferroics108Polar octahedral rotations: A path to new multifunctional materials251Direct Observation of the Proliferation of Ferroelectric Loop Domains and Vortex-Antivortex Pairs194Epitaxially Constrained Hexagonal Ferroelectricity and Canted Triangular Spin Order in LuFeO3 Thin Films96Electric field control of magnetism in multiferroic heterostructures482Multiferroic and Magnetoelectric Oxides: The Emerging Scenario193Collective Magnetism at Multiferroic Vortex Domain Walls115Nano-optical imaging and spectroscopy of order, phases, and domains in complex solids245Perovskite‐like Mn 2 O 3 : A Path to New Manganites118Scaling Behavior and Beyond Equilibrium in the Hexagonal Manganites201Hexagonal Manganites—(RMnO3): Class (I) Multiferroics with Strong Coupling of Magnetism and Ferroelectricity87Structural domain walls in polar hexagonal manganites126Ferroelectric Switching Dynamics of Topological Vortex Domains in a Hexagonal Manganite106Domain Wall Conduction and Polarization‐Mediated Transport in Ferroelectrics144Why Are There So Few Perovskite Ferroelectrics?498Room-Temperature Multiferroic Hexagonal LuFeO 3 Films236Landau theory of topological defects in multiferroic hexagonal manganites206Direct visualization of magnetoelectric domains131Solid-state principles applied to organic–inorganic perovskites: new tricks for an old dog1030Bulk magnetoelectricity in the hexagonal manganites and ferrites224Estimating Hybridization of Transition Metal and Oxygen States in Perovskites from O K -edge X-ray Absorption Spectroscopy494Emergence of Ferroelectricity at a Metal-Semiconductor Transition in a 1 T Monolayer of MoS 2456Multiferroics of spin origin974Novel Phase-Transition Materials Coupled with Switchable Dielectric, Magnetic, and Optical Properties: [(CH3)4P][FeCl4] and [(CH3)4P][FeBr4]119Structure and properties of complex hydride perovskite materials238Understanding ferroelectricity in layered perovskites: new ideas and insights from theory and experiments290Electrostatic gating of hybrid halide perovskite field-effect transistors: balanced ambipolar transport at room-temperature165Multiferroic oxide thin films and heterostructures152Magnetic Structure and Ordering of Multiferroic Hexagonal LuFeO3123Perovskite hexagonal YMnO3 nanopowder as p-type semiconductor gas sensor for H2S detection98Observation of Magnetoelectric Multiferroicity in a Cubic Perovskite System: LaMn3Cr4O12133Calibrating transition-metal energy levels and oxygen bands in first-principles calculations: Accurate prediction of redox potentials and charge transfer in lithium transition-metal oxides177Hexagonal rare-earth manganites as promising photovoltaics and light polarizers145Ferroelectricity in the multiferroic hexagonal manganites166Functional domain walls in multiferroics154Multiferroic materials and magnetoelectric physics: symmetry, entanglement, excitation, and topology893Electric-field control of magnetism via strain transfer across ferromagnetic/ferroelectric interfaces125Multifunctional magnetoelectric materials for device applications299Topological Structures in Multiferroics – Domain Walls, Skyrmions and Vortices100‘Ferroelectric’ metals reexamined: fundamental mechanisms and design considerations for new materials161The Origin of Oxygen Vacancies Controlling La 2/3 Sr 1/3 MnO 3 Electronic and Magnetic Properties93Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design2907Thinking Like a Chemist: Intuition in Thermoelectric Materials882The evolution of multiferroics1469Evolution of structure and magnetic properties for BaFe11.9Al0.1O19 hexaferrite in a wide temperature range137Interstitial oxygen as a source of p-type conductivity in hexagonal manganites86Designing new ferroelectrics with a general strategy112Strong corelation between magnetic and electrical subsystems in diamagnetically substituted hexaferrites ceramics116Recent progress in voltage control of magnetism: Materials, mechanisms, and performance457Functional electronic inversion layers at ferroelectric domain walls163Multiferroics: Past, present, and future170Tailored Engineering of an Unusual (C 4 H 9 NH 3 ) 2 (CH 3 NH 3 ) 2 Pb 3 Br 10 Two‐Dimensional Multilayered Perovskite Ferroelectric for a High‐Performance Photodetector288Tailored Engineering of an Unusual (C 4 H 9 NH 3 ) 2 (CH 3 NH 3 ) 2 Pb 3 Br 10 Two‐Dimensional Multilayered Perovskite Ferroelectric for a High‐Performance Photodetector85Comparative first-principles studies of prototypical ferroelectric materials by LDA, GGA, and SCAN meta-GGA258Interfaces in Perovskite Solar Cells349Origin of Negative Longitudinal Piezoelectric Effect102Electrical half-wave rectification at ferroelectric domain walls108Electric‐Field Control of Magnetic Order: From FeRh to Topological Antiferromagnetic Spintronics85Medium-temperature thermoelectric GeTe: vacancy suppression and band structure engineering leading to high performance354Thermoelectric GeTe with Diverse Degrees of Freedom Having Secured Superhigh Performance291Magnetoelectricity in multiferroics: a theoretical perspective267Multiferroic ABO3 Transition Metal Oxides: a Rare Interaction of Ferroelectricity and Magnetism118Caloric Effects in Perovskite Oxides117Two-dimensional ferromagnetic-ferroelectric multiferroics in violation of the d0 rule120Single-phase multiferroics: new materials, phenomena, and physics242Multiferroics beyond electric-field control of magnetism135Perovskite Oxides Prepared by Hydrothermal and Solvothermal Synthesis: A Review of Crystallisation, Chemistry, and Compositions152Progress in multiferroic and magnetoelectric materials: applications, opportunities and challenges84Magnetoelectric materials and devices184Ultra-thin ferroelectrics93Ferroelectric domain walls for nanotechnology264Origin of Ferroelectricity in Two Prototypical Hybrid Organic–Inorganic Perovskites87Direct observation of geometric and sliding ferroelectricity in an amphidynamic crystal163Insights into Strain Engineering: From Ferroelectrics to Related Functional Materials and Beyond172Ferroelectric Switchable Altermagnetism187

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