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RESEARCH PAPER · Inorganic Chemistry · 2006

Facile Controlled Synthesis of MnO2 Nanostructures of Novel Shapes and Their Application in Batteries

Fangyi Cheng, Jianzhi Zhao, Wene Song, Chunsheng Li, Hua Ma, Jun Chen, Pan‐Wen Shen

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Facile Controlled Synthesis of MnO2 Nanostructures of Novel Shapes and Their Application in BatteriesOriginalElectrodeposition synthesis and electrochemical properties of nanostructured γ-MnO2 films279Highly Electrochemical Reaction of Lithium in the Ordered Mesoporosus β-MnO2189Storage of hydrogen and lithium in inorganic nanotubes and nanowires76Synthesis of MnO2 Nanostructures with Sea Urchin Shapes by a Sodium Dodecyl Sulfate-Assisted Hydrothermal Process91The Effect of Nonionic Surfactant Triton X-100 during Electrochemical Deposition of MnO[sub 2] on Its Capacitance Properties80Single-crystal α-MnO2nanorods: synthesis and electrochemical properties219Different Microstructures of β-NaYF4 Fabricated by Hydrothermal Process: Effects of pH Values and Fluoride Sources341One-dimensional α-MnO2: Trapping chemistry of tunnel structures, structural stability, and magnetic transitions98Self-Assembly of Novel Mesoporous Manganese Oxide Nanostructures and Their Application in Oxidative Decomposition of Formaldehyde274Surfactant‐Free Synthesis of Hyperbranched Monoclinic Bismuth Vanadate and its Applications in Photocatalysis, Gas Sensing, and Lithium‐Ion Batteries203Synthesis and characterization of α-MnO2 nanowires: Self-assembly and phase transformation to β-MnO2 microcrystals86Controlled Preparation of MnO 2 Hierarchical Hollow Nanostructures and Their Application in Water Treatment739Synthesis and electrochemical properties of α-MnO2 microspheres74Effect of Crystallographic Structure of MnO 2 on Its Electrochemical Capacitance Properties1378Effect of Phase Structure of MnO 2 Nanorod Catalyst on the Activity for CO Oxidation677Controllable synthesis of α- and β-MnO2: cationic effect on hydrothermal crystallization110Microwave-assisted green synthesis of MnO2 nanoplates with environmental catalytic activity87Facile Synthesis of Nanoporous γ-MnO2 Structures and Their Application in Rechargeable Li-Ion Batteries185β-MnO2 nanowires: A novel ozonation catalyst for water treatment143Nanostructured manganese dioxides: Synthesis and properties as supercapacitor electrode materials118A novel method to prepare nanostructured manganese dioxide and its electrochemical properties as a supercapacitor electrode172A Green Chemistry Approach for the Synthesis of Flower-like Ag-Doped MnO 2 Nanostructures Probed by Surface-Enhanced Raman Spectroscopy122Selective Synthesis of Manganese Oxide Nanostructures for Electrocatalytic Oxygen Reduction165Mesoporous Hydrous Manganese Dioxide Nanowall Arrays with Large Lithium Ion Energy Storage Capacities160Remarkable Capacity Retention of Nanostructured Manganese Oxide upon Cycling as an Electrode Material for Supercapacitor267Combination of Lightweight Elements and Nanostructured Materials for Batteries502Growth of single-crystal α-MnO2 nanotubes prepared by a hydrothermal route and their electrochemical properties216Functional materials with high-efficiency energy storage and conversion for batteries and fuel cells170Facile Synthesis of Novel Nanostructured MnO2Thin Films and Their Application in Supercapacitors75Synthesis of 3D Hierarchical Self-Assembled Microstructures Formed from α-MnO2 Nanotubes and Their Conducting and Magnetic Properties69Shape-Controlled Synthesis of One-Dimensional MnO2 via a Facile Quick-Precipitation Procedure and its Electrochemical Properties182Novel Mn3O4 Micro-octahedra: Promising Cataluminescence Sensing Material for Acetone135MnO2-Based Nanostructures as Catalysts for Electrochemical Oxygen Reduction in Alkaline Media729Hydrothermal synthesis and catalytic properties of α- and β-MnO2 nanorods71Engineering nanostructured electrodes and fabrication of film electrodes for efficient lithium ion intercalation268Mesoporous MnO2/Carbon Aerogel Composites as Promising Electrode Materials for High-Performance Supercapacitors244Shape-Controllable Synthesis and Morphology-Dependent Luminescence Properties of GaOOH:Dy3+ and β-Ga2O3:Dy3+117Graphene Oxide−MnO2 Nanocomposites for Supercapacitors2113Electrochemical immunosensor for norethisterone based on signal amplification strategy of graphene sheets and multienzyme functionalized mesoporous silica nanoparticles70Preparation and capacitive property of manganese oxide nanobelt bundles with birnessite-type structure92Mesoporous α-MnO2/Pd catalyst air electrode for rechargeable lithium–air battery188Eu 3+ /Tb 3+ -Doped La 2 O 2 CO 3 /La 2 O 3 Nano/Microcrystals with Multiform Morphologies: Facile Synthesis, Growth Mechanism, and Luminescence Properties121(Zn, Mg)2GeO4:Mn2+ submicrorods as promising green phosphors for field emission displays: hydrothermal synthesis and luminescence properties102Fabrication of γ-MnO2/α-MnO2 hollow core/shell structures and their application to water treatment105Polyaniline–MnO2 nanotube hybrid nanocomposite as supercapacitor electrode material in acidic electrolyte222Porous LiMn2O4 nanorods with durable high-rate capability for rechargeable Li-ion batteries278The role of nanomaterials in redox-based supercapacitors for next generation energy storage devices882Facile synthesis of α-MnO2/graphene nanocomposites and their high performance as lithium-ion battery anode80Hydrothermal preparation of nanostructured manganese oxides (MnO ) and their electrochemical and photocatalytic properties93Control over the morphology and structure of manganese oxide by tuning reaction conditions and catalytic performance for formaldehyde oxidation98Template-free synthesis of MnO2 nanowires with secondary flower like structure: Characterization and supercapacitor behavior studies70A review of electrode materials for electrochemical supercapacitors9152Zero-dimensional, one-dimensional, two-dimensional and three-dimensional nanostructured materials for advanced electrochemical energy devices1195Flexible electrodes based on polypyrrole/manganese dioxide/polypropylene fibrous membrane composite for supercapacitor86Facile controlled synthesis and growth mechanisms of flower-like and tubular MnO2 nanostructures by microwave-assisted hydrothermal method161Crystal structure and up- and down-conversion properties of Yb3+, Ho3+ codoped BaGdF5 solid-solution with different morphologies67Graphene–Ni–α-MnO2 and –Cu–α-MnO2 nanowire blends as highly active non-precious metal catalysts for the oxygen reduction reaction86Synthesis of MnO@C core–shell nanoplates with controllable shell thickness and their electrochemical performance for lithium-ion batteries118Manganese Dioxide Nanostructures as a Novel Electrochemical Mediator for Thiol Sensors70Preparation and characterization of manganese dioxides with nano-sized tunnel structures for zinc ion storage200First-principles DFT + U studies of the atomic, electronic, and magnetic structure of α-MnO2 (cryptomelane)164MnO2-coated graphitic petals for supercapacitor electrodes207Synthesis of one-dimensional hierarchical NiO hollow nanostructures with enhanced supercapacitive performance185A Review on the Synthesis of Manganese Oxide Nanomaterials and Their Applications on Lithium‐Ion Batteries145Hierarchically order porous lotus shaped nano-structured MnO2 through MnCO3: chelate mediated growth and shape dependent improved catalytic activity69Hydrothermal synthetic strategies of inorganic semiconducting nanostructures548Investigation of effects of carbon coating on the electrochemical performance of Li4Ti5O12/C nanocomposites228Lithium and oxygen adsorption at the β-MnO2 (110) surface67β-MnO2 as a cathode material for lithium ion batteries from first principles calculations88Self-Limiting Electrodeposition of Hierarchical MnO2 and M(OH)2/MnO2 Nanofibril/Nanowires: Mechanism and Supercapacitor Properties304Nanostructuring of β-MnO 2 : The Important Role of Surface to Bulk Ion Migration108Controlled Growth of NiCo2O4 Nanorods and Ultrathin Nanosheets on Carbon Nanofibers for High-performance Supercapacitors490Manganese oxide nanorod–graphene/vanadium oxide nanowire–graphene binder-free paper electrodes for metal oxide hybrid supercapacitors141Electrochemistry of Hollandite α-MnO 2 : Li-Ion and Na-Ion Insertion and Li 2 O Incorporation195Two-Dimensional β-MnO2 Nanowire Network with Enhanced Electrochemical Capacitance102Graphene‐Wrapped MnO2–Graphene Nanoribbons as Anode Materials for High‐Performance Lithium Ion Batteries381Morphological Evolution of Two-Dimensional MnO2 Nanosheets and Their Shape Transformation to One-Dimensional Ultralong MnO2 Nanowires for Robust Catalytic Activity143Nanosized Mn–Ru binary oxides as effective bifunctional cathode electrocatalysts for rechargeable Li–O 2 batteries82Porous CuO nanowires as the anode of rechargeable Na-ion batteries272Facile synthesis of Co 3 O 4 porous nanosheets/reduced graphene oxide composites and their excellent supercapacitor performance68NiCo2O4 nanosheet supported hierarchical core–shell arrays for high-performance supercapacitors202Solution synthesis of metal oxides for electrochemical energy storage applications410Surface properties of α-MnO 2 : relevance to catalytic and supercapacitor behaviour135Rutile (β-)MnO 2 Surfaces and Vacancy Formation for High Electrochemical and Catalytic Performance222Morphological and Electrochemical Cycling Effects in MnO2 Nanostructures by 3D Electron Tomography116Graphene wrapped MnO2-nanostructures as effective and stable electrode materials for capacitive deionization desalination technology172A facile one-pot hydrothermal synthesis of β-MnO2 nanopincers and their catalytic degradation of methylene blue70MnO2 prepared by hydrothermal method and electrochemical performance as anode for lithium-ion battery198Potassium–Sulfur Batteries: A New Member of Room-Temperature Rechargeable Metal–Sulfur Batteries199Nonstoichiometric Perovskite CaMnO 3−δ for Oxygen Electrocatalysis with High Activity242Enhanced catalytic and supercapacitor activities of DNA encapsulated β-MnO 2 nanomaterials82Nanostructured Mn-based oxides for electrochemical energy storage and conversion859Porous NiCo2O4 nanosheets/reduced graphene oxide composite: Facile synthesis and excellent capacitive performance for supercapacitors80Nanostructured anode materials for lithium ion batteries813New insights into heterogeneous generation and evolution processes of sulfate radicals for phenol degradation over one-dimensional α-MnO2 nanostructures269Nano surface engineering of Mn 2 O 3 for potential light-harvesting application72Physiochemical Investigation of Shape-Designed MnO 2 Nanostructures and Their Influence on Oxygen Reduction Reaction Activity in Alkaline Solution123Lithium and lithium ion batteries for applications in microelectronic devices: A review581Interconnected MnO2 nanoflakes assembled on graphene foam as a binder-free and long-cycle life lithium battery anode79Asynchronous Crystal Cell Expansion during Lithiation of K + -Stabilized α-MnO 2186Nitrogen-Enriched Porous Carbon Coating for Manganese Oxide Nanostructures toward High-Performance Lithium-Ion Batteries109Turn-on fluorescence sensor for glutathione in aqueous solutions using carbon dots–MnO2 nanocomposites67Catalytic ozonation of 4-nitrophenol over an mesoporous α-MnO2 with resistance to leaching113Electrochemically Induced Structural Transformation in a γ-MnO2 Cathode of a High Capacity Zinc-Ion Battery System980Catalytic oxidation of NO over MnO 2 with different crystal structures133Nanoporous Mn-based electrocatalysts through thermal conversion of cyano-bridged coordination polymers toward ultra-high efficiency hydrogen peroxide production70Tin oxide nanostructured materials: an overview of recent developments in synthesis, modifications and potential applications98A high surface area tunnel-type α-MnO2 nanorod cathode by a simple solvent-free synthesis for rechargeable aqueous zinc-ion batteries180Genetically Engineered Phage-Templated MnO2 Nanowires: Synthesis and Their Application in Electrochemical Glucose Biosensor Operated at Neutral pH Condition128Hierarchical urchin-shaped α-MnO2 on graphene-coated carbon microfibers: a binder-free electrode for rechargeable aqueous Na–air battery97An efficient α-MnO 2 nanorods forests electrode for electrochemical capacitors with neutral aqueous electrolytes102Visible Light Active Single-Crystal Nanorod/Needle-like α-MnO2@RGO Nanocomposites for Efficient Photoreduction of Cr(VI)76Controlled synthesis of nanostructured molybdenum oxide electrodes for high performance supercapacitor devices181Novel biotemplated MnO2 1D nanozyme with controllable peroxidase-like activity and unique catalytic mechanism and its application for glucose sensing133Decreasing Li/Ni Disorder and Improving the Electrochemical Performances of Ni-Rich LiNi0.8Co0.1Mn0.1O2 by Ca Doping211Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities1796High-Capacitance Hybrid Supercapacitor Based on Multi-Colored Fluorescent Carbon-Dots314Electrochemically induced spinel-layered phase transition of Mn3O4 in high performance neutral aqueous rechargeable zinc battery387Nanostructured MnO2 as Electrode Materials for Energy Storage273Bifunctional MnO2-Coated Co3O4 Hetero-structured Catalysts for Reversible Li-O2 Batteries68Research progresses on materials and electrode design towards key challenges of Li-air batteries104Formation Mechanisms of Nanocrystalline MnO 2 Polymorphs under Hydrothermal Conditions78Cations controlled growth of β-MnO2 crystals with tunable facets for electrochemical energy storage83Intercalation and Conversion Reactions of Nanosized β-MnO2 Cathode in the Secondary Zn/MnO2 Alkaline Battery78High-Performance Cable-Type Flexible Rechargeable Zn Battery Based on MnO2@CNT Fiber Microelectrode232Effect of Manganese Dioxide Nanorods on the Thermoelectric Properties of Cement Composites78Inhibition of polysulfide diffusion in lithium–sulfur batteries: mechanism and improvement strategies184Recent Advances in Rational Electrode Designs for High‐Performance Alkaline Rechargeable Batteries223Experimental and Theoretical Validation of High Efficiency and Robust Electrocatalytic Response of One-Dimensional (1D) (Mn,Ir)O2:10F Nanorods for the Oxygen Evolution Reaction in PEM-Based Water Electrolysis132Effect of Thermally Induced Oxygen Vacancy of α-MnO 2 Nanorods toward Oxygen Reduction Reaction93A review on synthesis and engineering of crystal precursors produced via coprecipitation for multicomponent lithium-ion battery cathode materials187A review on mechanistic understanding of MnO 2 in aqueous electrolyte for electrical energy storage systems220Achieving high energy density and high power density with pseudocapacitive materials1957Effect of Ti ion doping on electrochemical performance of Ni-rich LiNi0.8Co0.1Mn0.1O2 cathode material205Low adhesion superhydrophobic AZ31B magnesium alloy surface with corrosion resistant and anti-bioadhesion properties74The performance of highly active manganese oxide catalysts for ambient conditions carbon monoxide oxidation84Active Materials for Aqueous Zinc Ion Batteries: Synthesis, Crystal Structure, Morphology, and Electrochemistry1791Template-Free Synthesis of Mesoporous β-MnO 2 Nanoparticles: Structure, Formation Mechanism, and Catalytic Properties75Rechargeable alkaline zinc–manganese oxide batteries for grid storage: Mechanisms, challenges and developments128A Review of Recent Progress on Nano MnO2: Synthesis, Surface Modification and Applications73Reaction mechanisms and optimization strategies of manganese-based materials for aqueous zinc batteries76Recent Development of Mn‐based Oxides as Zinc‐Ion Battery Cathode206Nanostructured transition metal vanadates as electrodes for pseudo-supercapacitors: a review110Removal of Radionuclides from Aqueous Solution by Manganese Dioxide-Based Nanomaterials and Mechanism Research: A Review79Unveiling performance evolution mechanisms of MnO2 polymorphs for durable aqueous zinc-ion batteries206Progress on solvo/hydrothermal synthesis and optimization of the cathode materials of lithium-ion battery68Advances of high-performance LiNi1-x-yCoxMyO2 cathode materials and their precursor particles via co-precipitation process69Exploring the charge storage mechanism in high-performance Co@MnO2-based hybrid supercapacitors using Randles–Ševčík and Dunn’s models132Recent Progress on Phase Engineering of Nanomaterials185A critical review of facets and defects in different MnO2 crystalline phases and controlled synthesis – Its properties and applications in the energy field129

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