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RESEARCH PAPER · Inorganic Chemistry · 2007

New Lanthanide Hybrid as Clustered Infinite Nanotunnel with 3D Ln−O−Ln Framework and (3,4)-Connected Net

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New Lanthanide Hybrid as Clustered Infinite Nanotunnel with 3D Ln−O−Ln Framework and (3,4)-Connected NetOriginalAn unprecedented nanoporous and fluorescent supramolecular framework with an SrAl2 topology controllably synthesized from a flexible ditopic acid42Luminescent Organically Templated Lanthanide Oxalate–Selenate Hybrids6A Prototypical Zeolitic Lanthanide−Organic Framework with Nanotubular Structure85An unusual 3D-topology and dominant ferromagnetic couplings in two Cu(ii)–azide coordination polymers70Cd(II)-sulfonyldibenzoilate coordination polymers based on mono-, bi-, tri- and tetranuclear cores as nodes63Construction of bi-functional inorganic–organic hybrid nanocomposites15Structural modulation of polythreading and interpenetrating coordination networks with an elongated dipyridyl building block and various anionic co-ligands105Syntheses, Structures, and Characterizations of Two New Indium(III) Compounds from 1D ···In–OH–In–OH··· Chains and Pyridinedicarboxylic Ligands22Hybrid inorganic–organic materials: a new family in condensed matter physics327Hydrothermal synthesis and crystal structure of [Co(2,5-pydc)(H2O)2] ·nH2O (2,5-pydc = 2,5-pyridinedicarboxylate)24Extended Networks Generated from the Interaction of Rare‐Earth(III) Ions and Pyridine‐2‐carboxamide‐Based Ligands13Hybrid inorganic-organic materials: a new family in condensed matter physics83Syntheses, structures, and photoluminescence of three-dimensional lanthanide coordination polymers with 2,5-pyridinedicarboxylic acid43Syntheses, Structures, Near-Infrared, and Visible Luminescence of Lanthanide-Organic Frameworks with Flexible Macrocyclic Polyamine Ligands88Synthesis, Crystal Structure and Properties of [Gd(C 6 NO 2 H 5 ) 3 (H 2 O) 2 ] n (1.5 n ZnCl 4 )· n H 2 O with Unprecedented Poly-Cationic Chains1Incorporating Distinct Metal Clusters To Construct Diversity of 3D Pillared-Layer Lanthanide-Transition-Metal Frameworks85In situ hydrothermal decarboxylation for unprecedented three-dimensional lanthanide–organic frameworks32Novel Inorganic–Organic Hybrid Frameworks of Manganese(II): Syntheses, Crystal Structures, and Physical Properties52Photoluminescent 3D Lanthanide−Organic Frameworks with 2,5-Pyridinedicarboxylic and 1,4-Phenylenediacetic Acids114Construction and Characterization of Several New Lanthanide−Organic Frameworks: From 2D Lattice to 2D Double-Layer and to Porous 3D Net with Interweaving Triple-Stranded Helixes72Thorium(IV) Coordination Polymers in the Pyridine and Pyrazinedicarboxylic Acid Systems56Intricate 3D lanthanide–organic frameworks with mixed nodes nets30Syntheses, structures and photoluminescence of a series of lanthanide-organic frameworks involving in situ ligand formation35Synthesis, crystal structure and photoluminescent properties of four lanthanide 5-nitroisophthalate coordination polymers35In situ cyclodehydration of iminodiacetic acid into 2,5-diketopiperazine-1,4-diacetate in lanthanide-based coordination polymers21Indium(iii)-2,5-pyridine dicarboxylate complexes with mononuclear, 1D chain, 2D layer and 3D chiral frameworks27Luminescent metal–organic frameworks4960Novel dense organic–lanthanide hybrid architectures: syntheses, structures and magnetic properties37Synthesis, crystal structures, and luminescent properties of eleven new lanthanide and yttrium complexes with fluorescent whitener and 1,10-phenanthroline8Systematic investigation of an array of TCNQ lanthanide complexes: synthesis, structure and magnetic properties18A Series of Three-Dimensional Lanthanide-Rigid-Flexible Frameworks: Synthesis, Structure, and Luminescent Properties of Coordination Polymers with 2,5-Pyridine Dicarboxylic Acid and Adipic Acid99catena -Poly[[[diaquathulium(III)]-μ-6-carboxynicotinato-μ-pyridine-2,5-dicarboxylato] dihydrate]3catena-Poly[[[diaquaterbium(III)]-μ-6-carboxynicotinato-μ-pyridine-2,5-dicarboxylato] dihydrate]4Syntheses, crystal structures, and luminescence of carboxylato-bridged coordination compounds13Three-Dimensional Lanthanide−Organic Frameworks Based on Di-, Tetra-, and Hexameric Clusters75A new series of lanthanide coordination polymers with 2,2′-bipyridine and glutaric acid: Synthesis, crystal structures and properties of [Ln(bipy)(glut)(NO3)]19The ionothermal synthesis of metal organic frameworks, Ln(C9O6H3)((CH3NH)2CO)2, using deep eutectic solvents63Lanthanide (LaIII/HoIII)-oxalate open framework materials formed by in situ ligand synthesis13Synthesis, Structure, and Luminescent Properties of Hybrid Inorganic−Organic Framework Materials Formed by Lead Aromatic Carboxylates: Inorganic Connectivity Variation from 0D to 3D220Two Types of Lanthanide Coordination Polymers of (2,3-f)-Pyrazino(1,10)phenanthroline-2,3-dicarboxylic Acid: Syntheses, Structures, and Properties41Synthesis, structures, and photoluminescent properties of 3D lanthanide coordination polymers with rare (4,5)-connected topology13Mn(II)-Binaphthalenyl Dicarboxylate Complexes: Helical Rectangular Tubes, (4,4) Grid Chiral Layer and Three-Dimensional Cubic Diamond Frameworks42Four novel lanthanide(III) coordination polymers with 3D network structures containing 2-fold interpenetration5Series of anion-directed lanthanide-rigid-flexible frameworks: syntheses, structures, luminescence and magnetic properties86Cadmium Coordination Polymers Constructed from in Situ Generated Amino-Tetrazole Ligand: Effect of the Conditions on the Structures and Topologies77Chapter 247 Self-Assembled Lanthanide Helicates31Self-Assembly of Metal-Organic Coordination Polymers Constructed from a Bent Dicarboxylate Ligand: Diversity of Coordination Modes, Structures, and Gas Adsorption84Novel Structures and Luminescence Properties of Lanthanide Coordination Polymers with a Novel Flexible Polycarboxylate Ligand87Synthesis and luminescent properties of the first series of lanthanide complexes based on sebacate and 2,5-pyridinedicarboxylate11Unprecedented 4- and 6-Connected 2D Coordination Networks Based on 44-Subnet Tectons, Showing Unusual Supramolecular Motifs of Rotaxane and Helix1382D and 3D lanthanide coordination polymers constructed from benzimidazole-5,6-dicarboxylic acid and sulfate bridged secondary building units75A highly-connected acentric organic–inorganic hybrid material with unique 3D inorganic and 3D organic connectivity62A series of lanthanide–organic polymers incorporating nitrogen-heterocyclic and aliphatic carboxylate mixed-ligands: structures, luminescent and magnetic properties91A series of three-dimensional lanthanide metal–organic frameworks with biphenylethene-4,4′-dicarboxylic acid: Hydrothermal syntheses and structures45A unique example of a 3D framework based on the binuclear dysprosium(iii) azobenzene-3,5,4′-tricarboxylate with 3,6-connected topology showing ferromagnetic properties27Rare-earth organic frameworks involving three types of architecture tuned by the lanthanide contraction effect: hydrothermal syntheses, structures and luminescence63Synthesis, Structural Characterization and Luminescence of Lanthanide Coordination Polymers with Pyridine‐2,5‐dicarboxylic Acid5Syntheses and characterizations of two new pillared-layer coordination polymers constructed from lanthanides and mixed O-donor ligands10Synthesis, Crystal Structures, and Properties of Novel Heterometallic La/Pr−Cu−K and Sm/Eu/Tb−Cu Coordination Polymers47Synthesis and Characterization of Three Ytterbium Coordination Polymers Featuring Various Cationic Species and a Luminescence Study of a Terbium Analogue With Open Channels49A Series of Lanthanide−Organic Frameworks Based on 2-Propyl-1H-imidazole-4,5-dicarboxylate and Oxalate: Syntheses, Structures, Luminescence, and Magnetic Properties157Rigid and Flexible Lanthanide Complexes with an Infinite Ln–O–Ln Framework: Synthesis, Structure and Properties9Fast Microwave Synthesis of a Microporous Lanthanide−Organic Framework35A Series of Three-Dimensional 4d−4f Heterometallic Coordination Polymers with Six-Connected Doubly Interpenetrated pcu Net Topology: Structural, Photoluminescent, and Magnetic Properties71A series of three-dimensional 3d–4f heterometallic coordination frameworks based on pyridinedicarboxylic acid15Synthesis Structures, and Properties of Functional 2-D Lanthanide Coordination Polymers [Ln2(dpa)2(C2O4)2(H2O)2]n (dpa = 2,2′-(2-methylbenzimidazolium-1,3-diyl)diacetate, C2O42− = oxalate, Ln = Nd, Eu, Gd, Tb)59Syntheses, Crystal Structures, and Magnetic Properties of Two Mn(II) Coordination Polymers Based on the 5-Aminotetrazole Ligand: Effect of Sources of Ligand on Construction of Topological Networks49Synthesis, crystal structure, and characterization of two lanthanide coordination polymers based on isonicotinate ligand13Lanthanide-based 0D and 2D molecular assemblies with the pyridazine-3,6-dicarboxylate linker32Multifunctional Homochiral Lanthanide Camphorates with Mixed Achiral Terephthalate Ligands86A Series of (6,6)-Connected Porous Lanthanide−Organic Framework Enantiomers with High Thermostability and Exposed Metal Sites: Scalable Syntheses, Structures, and Sorption Properties168Synthesis and characterization of a series of porous lanthanide tricarboxylates57Remarkable Luminescence Properties of Lanthanide Complexes with Asymmetric Dodecahedron Structures164Structures and luminescent properties of Sm(III) and Dy(III) coordination polymers with 2,4,6-pyridinetricarboxylic acid19Synthesis, structures and physical properties of new 3D lanthanide coordination polymers constructed from 1,2,4,5-benzenetetracarboxylic acid33Syntheses and crystal structures of two new heteropolyoxometalates consisting of octamolybdate anions5A Series of Lanthanide Secondary Building Units Based Metal−Organic Frameworks Constructed by Organic Pyridine-2,6-Dicarboxylate and Inorganic Sulfate97Two novel 2D organic–inorganic hybrid lacunary Keggin phosphotungstate 3d–4f heterometallic derivatives: [Cu(en)2]2H6[Ce(α-PW11O39)2]·8H2O and [Cu(dap)2(H2O)][Cu(dap)2]4.5[Dy(α-PW11O39)2]·4H2O50Synthesis, Structural, and Electrical Characterization of two Novel Coordination Polymers based on a [1,2,3]‐Triazole Carboxylic Acid Derivative Ligand5New europium coordination polymers with efficient energy transfer from conjugated tetracarboxylate ligands to Eu3+ ion: syntheses, structures, luminescence and magnetic properties42Syntheses, structures and properties of three-dimensional lanthanide frameworks constructed with a trigonal anti-prismatic lanthanide cluster17Photoluminescent and Magnetic Properties of a Series of Lanthanide Coordination Polymers with 1H-Tetrazolate-5-formic Acid95Effect of Lanthanide Contraction on Crystal Structures of Three-Dimensional Lanthanide Based Metal–Organic Frameworks with Thiophene-2,5-Dicarboxylate and Oxalate110Lanthanide metal organic frameworks based on octahedral secondary building units: Structural, luminescent, and magnetic properties35Construction of 5-Aminodiacetic Isophthalate Based Nickel(II) Complexes with Diverse Topologies through Modulating the Auxiliary Ligands36The Zn(II)-organic coordination polymers based on 2-(pyridin-4-yl)-1H-imidazole-4,5-dicarboxylate ligands: Crystal structures and luminescent properties26Coordination polymers of unsymmetrical angular ligand 3-pyridin-4-ylbenzoate acid: Syntheses, structural diversity and properties12Exploratory syntheses and structural characterizations of three organic–inorganic hybrid polyoxomolybdate frameworks linked by M(II)-Lnunits (M = Ni, Co, Zn; L = 2,2′-biimidazole)10Luminescent Metal–Organic Frameworks15Lanthanide(III)/Pyrimidine-4,6-dicarboxylate/Oxalate Extended Frameworks: A Detailed Study Based on the Lanthanide Contraction and Temperature Effects67Two Lanthanide‐Organic Frameworks Derived from 1H‐Benzimidazole‐5‐Carboxylic Acid and Oxalate Mixed Ligands: Synthesis, Structure and Luminescence Property3Homochiral Frameworks Formed by Reactions of Lanthanide Ions with a Chiral Antimony Tartrate Secondary Building Unit26Structural Diversity of Metal–Organic Materials Containing Bismuth(III) and Pyridine-2,5-Dicarboxylate63Controllable assembly of organodisulfonate complexes with tuned mole ratios: From 0D to 3D networks14Syntheses, structures, and luminescent properties of lanthanide complexes with N,N′-bis(p-methoxyphenyl)-3-oxapentanediamide3Lanthanide-pyridyl-2,5-dicarboxylate N-oxide frameworks with rutile topology30A Series of 3D Rare‐Earth‐Metal–Organic Frameworks with Isolated Guest Keggin Silicotungstate Fragments as Anion Templates19Tetraaquabis[3-(pyridin-4-yl)benzoato-κN]cobalt(II)1Fluorescence Properties Change of Lanthanide Coordination Polymers Dispersed in Mesoporous SBA-15 by Energy Transition Process13Hydrothermal synthesis of a novel μ-dihydroxo-bis(2,6-pyridinedicarboxylatoaquachromium(III)) complex and investigation of its catalytic activity22Crystal structure of diaquabis(3-hydroxyquinoxaline-2-carboxylato- κ2N1,O)copper(II) dihydrate, Cu(C9H5N2O3)2(H2O)2 · 2H2O0Ionothermal syntheses, crystal structures and properties of three-dimensional rare earth metal–organic frameworks with 1,4-naphthalenedicarboxylic acid43Novel 1-D double-chain organic–inorganic hybrid polyoxotungstates constructed from dimeric copper–lanthanide heterometallic silicotungstate units38Novel polyoxometalate hybrids consisting of copper–lanthanide heterometallic/lanthanide germanotungstate fragments71Temperature-dependent assemblies from a 2-D triple-stranded meso-helical layer to a 3-D chain-layer metal–organic framework10Three-dimensional lanthanide polyoxometalate organic complexes: correlation of structure with properties55Syntheses, Crystal Structures, and Magnetic Properties of Manganese(II) and Cobalt(II) Complexes with 4‐Hydroxypyridine‐2, 6‐dicarboxylic Acid7Two- and three-dimensional lanthanide metal-organic frameworks with hydroxyl-functionalized nicotinic acid and oxalate ligands15Synthesis, structure, and photophysical property of series of Ln(III) coordination polymers with different carboxylato ligands (Ln = Sm, Eu)7Poly[[tri-μ3-hydroxido-tris(μ4-pyridine-2,5-dicarboxylato)trineodymium(III)] monohydrate]1Tetraaquabis[3-(pyridin-4-yl)benzoato-κN]manganese(II)0Polynuclear complexes constructed by lanthanides and pyridine-3,5-dicarboxylate ligand: Structures, thermal and luminescent properties53Static field induced magnetic relaxations in dinuclear lanthanide compounds of [phen2Ln2(HCOO)4(HCOO)2−2x (NO3)2x ] (1, Ln = Gd and x = 0.52; 2, Ln = Er and x = 0.90; phen = 1,10-phenanthroline)27Lanthanide Coordination Polymers Constructed from Imidazole-4,5-Dicarboxylate and Sulfate: Syntheses, Structural Diversity, and Photoluminescent Properties81Synthetic Control to Achieve Lanthanide(III)/Pyrimidine-4,6-dicarboxylate Compounds by Preventing Oxalate Formation: Structural, Magnetic, and Luminescent Properties48Synthesis, crystal structures and properties of lanthanide-organic frameworks based benzene carboxylates with two/three-dimensional structure24Copper(II)–lanthanide(III) coordination polymers constructed from pyridine-2,5-dicarboxylic acid: Preparation, crystal structure and photoluminescence15Microwave-assisted synthesis of lanthanide 2,6-naphthalenedicarboxylates: Thermal, luminescent and sorption characterization23catena-Poly[[[diaqua[3-(pyridin-4-yl)benzoato-κ2O,O′]terbium(III)]-bis[μ-3-(pyridin-4-yl)benzoato-κ2O:O′]] monohydrate]0Tuning the lead complexes based on a double 1,10-phenanthroline derivative with versatile coordination behavior by dicarboxylates: from 0D nano-ring to an unprecedented 0D + 3D cocrystal191-D helical chain, 2-D layered network and 3-D porous lanthanide–organic frameworks based on multiple coordination sites of benzimidazole-5,6-dicarboxylic acid: synthesis, crystal structure, photoluminescence and thermal stability55A series of 3D lanthanide frameworks constructed from aromatic multi-carboxylate ligand: Structural diversity, luminescence and magnetic properties157Host–guest chemistry of NiII coordination compounds with PDC and (py)2CO: reversible crystal-to-amorphous transformations induced by solvent exchange13Lanthanide coordination polymers assembled from triazine-based flexible polycarboxylate ligands and their luminescent properties25Syntheses, structure, and properties of a series of three-dimensional lanthanide-based hybrid frameworks16Preparation, characterization, and properties of two rare earth organic frameworks with 1H-benzimidazole-2-carboxylic acid3Synthesis and characterization of polymorphs of photoluminescent Eu(III)-(2,5-furandicarboxylic acid, oxalic acid) MOFs35Photophysical Studies of Europium Coordination Polymers Based on a Tetracarboxylate Ligand72Photoluminescent Metal–Organic Frameworks – Rapid Preparation, Catalytic Activity, and Framework Relationships18Synthesis, structure and fluorescent property of coordination polymer from 4-[(8-hydroxy-5-quinolinyl)azo]-benzoic acid3A New Metal–Organic Molecular Square Based on Imidazole-4,5-dicarboxylicate0Luminescent lanthanide-2-phenylpyrimidine-carboxylate frameworks: structure and luminescence tuning14Metal–Organic Frameworks Based on Lanthanide Clusters11Three 3D lanthanide–organic frameworks with sra topology: syntheses, structures, luminescence and magnetic properties32Self-assembled microporous lanthanide coordination polymers built by 2-hydroxynicotinic acid and oxalate ligands1Four structurally diverse coordination complexes based on a new flexible ligand11Synthesis, structure, spectroscopic and ferroelectric properties of an acentric polyoxotungstate containing 1:2-type [Sm(α-PW11O39)2]11− fragment and d-proline components10Four new zinc coordination compounds derived from various tetrazole-containing carboxylic acids and 4,4′-bipyridine24Luminescent lanthanide coordination polymers for photonic applications233Bi–Mn mixed metal organic oxide: A novel 3d-6p mixed metal coordination network17Double-malate bridging tri-lanthanoid cluster encapsulated arsenotungstates: syntheses, structures, luminescence and magnetic properties71Enhancing luminescence properties of lanthanide( iii )/pyrimidine-4,6-dicarboxylato system by solvent-free approach40Three sra topological lanthanide–organic frameworks built from 2,2′-dimethoxy-4,4′-biphenyldicarboxylic acid21Zn (Ce,Mn)-MOFs with (3,4,5)-connected 3-D topology network and test of photocatalysis on the reduction of Cr6+ by Zn (Ce)-MOFs17The syntheses, crystal structures, spectroscopic and thermal characterization of new pyridine-2,5-dicarboxylate compounds14Metal–organic frameworks assembled from lanthanide and 2,5-pyridinedicaboxylate with cubane-like [Ln4(OH)4] building units14Self-Assembly of a Family of Isopolytungstates Induced by the Synergistic Effect of the Nature of Lanthanoids and the pH Variation in the Reaction Process: Syntheses, Structures, and Properties25Lanthanide Germanate Cluster Organic Frameworks Based on {Ln8Ge12} Clusters: From One-Dimensional Chains to Two-Dimensional Layers and Three-Dimensional Frameworks20Four Gadolinium Coordination Compounds Derived from Various Tetrazole‐Containing Carboxylic Acids4Carboxylates of rare earth elements152

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  1. An unprecedented nanoporous and fluorescent supramolecular framework with an SrAl2 topology controllably synthesized from a flexible ditopic acid

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  2. Luminescent Organically Templated Lanthanide Oxalate–Selenate Hybrids

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  43. Four novel lanthanide(III) coordination polymers with 3D network structures containing 2-fold interpenetration

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  44. Series of anion-directed lanthanide-rigid-flexible frameworks: syntheses, structures, luminescence and magnetic properties

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