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RESEARCH PAPER · Chemistry - An Asian Journal · 2012

Organic–Inorganic Hybrids Based on Ultrathin Oxide Layers: Designed Nanostructures for Molecular Recognition

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Organic–Inorganic Hybrids Based on Ultrathin Oxide Layers: Designed Nanostructures for Molecular RecognitionOriginalMolecular recognitive adsorption of aqueous tetramethylammonium on the organic derivative of Hiroshima University Silicate-1 with a silane coupling reagent17Synthesis and characteristics of novel layered silicates HUS-2 and HUS-3 derived from a SiO2–choline hydroxide–NaOH–H2O system43Efficient and Selective Photocatalytic Cyclohexane Oxidation on a Layered Titanate Modified with Iron Oxide under Sunlight and CO 2 Atmosphere76Swellable Microsphere of a Layered Silicate Produced by Using Monodispersed Silica Particles30Regulation of the Collisional Self-Quenching of Fluorescence in Clay/Porphyrin Complex by Strong Host–Guest Interaction61Characterization of layered silicate HUS-5 and formation of novel nanoporous silica through transformation of HUS-5 ion-exchanged with alkylammonium cations15Precisely designed layered silicate as an effective and highly selective CO2 adsorbent27Size-Matching Effect on Inorganic Nanosheets: Control of Distance, Alignment, and Orientation of Molecular Adsorption as a Bottom-Up Methodology for Nanomaterials151Unique Photochemical Properties of p-Substituted Cationic Triphenylbenzene Derivatives on a Clay Layer Surface40ChemInform Abstract: Organic—Inorganic Hybrids Based on Ultrathin Oxide Layers. Designed Nanostructures or Molecular Recognition0High Density Intercalation of Porphyrin into Transparent Clay Membrane without Aggregation45Artificial Light-Harvesting Model in a Self-Assembly Composed of Cationic Dyes and Inorganic Nanosheet28Photochemical Properties of Mono-, Tri-, and Penta-Cationic Antimony(V) Metalloporphyrin Derivatives on a Clay Layer Surface37Layered Silicate as an Excellent Partner of a TiO 2 Photocatalyst for Efficient and Selective Green Fine-Chemical Synthesis65Layered Clay Aerogels by a Freeze-Drying Process for a Platinum-Supported Catalyst18Decomposition of a cyanine dye in binary nanosheet colloids of photocatalytically active niobate and inert clay11Cation Exchange in Layered Copper(II) Coordination Polymers18Encapsulation of a Polyoxometalate into an Organosilica Microcapsule for Highly Active Solid Acid Catalysis40Synthesis and characteristics of novel layered silicate HUS-7 using benzyltrimethylammonium hydroxide and its unique and selective phenol adsorption behavior22A controlled spatial distribution of functional units in the two dimensional nanospace of layered silicates and titanates106Adsorption and photochemical behaviors of the novel cationic xanthene derivative on the clay surface13Chemically stable magnetic nanoparticles for metal adsorption and solid acid catalysis in aqueous media22Intercalation of Organic Compounds into Layered Clay Minerals5Microporous titanate nanofibers for highly efficient UV-protective transparent coating56Reactivity and applications of layered silicates and layered double hydroxides116Design of Layered Silicate by Grafting with Metal Acetylacetonate for High Activity and Chemoselectivity in Photooxidation of Cyclohexane35Switching of energy transfer reaction by the control of orientation factor between porphyrin derivatives on the clay surface20Supramolecular-Surface Photochemistry: Supramolecular Assembly Organized on a Clay Surface Facilitates Energy Transfer between an Encapsulated Donor and a Free Acceptor29Integrative strategies to hybrid lamellar compounds: an integration challenge55“Surface-Fixation Induced Emission” of Porphyrazine Dye by a Complexation with Inorganic Nanosheets66Microstructures of the Porphyrin/Viologen Monolayer on the Clay Surface: Segregation or Integration?28Organoclays in Water Cause Expansion That Facilitates Caffeine Adsorption58Preparation of copper oxide in smectites22Manipulation of supramolecular 2D assembly of functional dyes toward artificial light-harvesting systems10Structure resembling effect of clay surface on photochemical properties of meso-phenyl or pyridyl-substituted monocationic antimony( v ) porphyrin derivatives34Highly active and selective Ti-incorporated porous silica catalysts derived from grafting of titanium( iv )acetylacetonate34Photochromic Intercalation Compounds26Formation of zinc oxide particles in cetyltrimethylammonium-smectites23Concentration of 2-phenylphenol by organoclays from aqueous sucrose solution14Crystal architectures of a layered silicate on monodisperse spherical silica particles cause the topochemical expansion of the core-shell particles19Preparation of metal sulfide mixtures in montmorillonite by solid–solid reactions11Design of Microporous Material HUS-10 with Tunable Hydrophilicity, Molecular Sieving, and CO2 Adsorption Ability Derived from Interlayer Silylation of Layered Silicate HUS-222In Situ Crystallization of Al-Containing Silicate Nanosheets on Monodisperse Amorphous Silica Microspheres16An inorganic anionic polymer filter disc: direct crystallization of a layered silicate nanosheet on a glass fiber filter18Unprecedentedly enhanced solar photocatalytic activity of a layered titanate simply integrated with TiO 2 nanoparticles35Photophysical Properties and Adsorption Behaviors of Novel Tri-Cationic Boron(III) Subporphyrin on Anionic Clay Surface37Kinetic Analysis by Laser Flash Photolysis of Porphyrin Molecules’ Orientation Change at the Surface of Silicate Nanosheet21Green Synthesis of Organophilic Clays; Solid-State Reaction of Acidic Clay with Organoamine16Efficient Photodegradation of Organics in Acidic Solution by ZnO–Smectite Hybrids18Modified Method for Bentonite Purification and Characterization; a Case Study Using Bentonite from Tsunagi Mine, Niigata, Japan19Effects of fluoride and urea on the crystal growth of a hectorite-like layered silicate on a silica surface6Hydrothermal synthesis of zinc selenide in smectites15Synthesis, structure, optical and magnetic properties of interlamellar decoration of magadiite using vanadium oxide species47Adsorbents Derived from Layered Solids3Design of a highly active base catalyst through utilizing organic-solvent-treated layered silicate Hiroshima University Silicates19Efficient Photocatalytic Systems Integrated with Layered Materials Promoters1Inorganic–Organic Interactions11Sensors2Energy Transfer among Three Dye Components in a Nanosheet–Dye Complex: An Approach To Evaluating the Performance of a Light-Harvesting System15Terpyridine-Functionalized NanoSiO2 Multi-Dentate Linkers: Preparation, Characterization and Luminescent Properties of Their Metal–Organic Hybrid Materials15Unique fluorescence behavior of dyes on the clay minerals surface: Surface Fixation Induced Emission (S-FIE)61ADOSORPTION AND PHOTOCHEMICAL BEHAVIOR OF MONO-CATIONIC PORPHYRIN ONTO SYNTHETIC SAPONITE2Mechanochemical synthesis of finite particle of layered double hydroxide-acetate intercalation compound: Swelling, thin film and ion exchange17Room-Temperature Rutile TiO 2 Nanoparticle Formation on Protonated Layered Titanate for High-Performance Heterojunction Creation33Kinetics of Interlayer Expansion of a Layered Silicate Driven by Caffeine Intercalation in the Water Phase Using Transmission X-ray Diffraction11Efficient Concentration of Indium(III) from Aqueous Solution Using Layered Silicates28Enhanced Photocatalytic Activity of a Layered Titanate Achieved via Simple Mixing with TiO2-Based Photocatalysts as Additives4Photoluminescence by Intercalation of a Fluorescent β-Diketone Dye into a Layered Silicate16Inorganic modification of layered silicates toward functional inorganic-inorganic hybrids56Active species transfer-type artificial light harvesting system in the nanosheet – Dye complexes: Utilization of longer wavelength region of sunlight6Direct Crystallization of Layered Silicates on the Surface of Amorphous Silica20Layered Silicates as a Possible Drug Carrier15Mechanochemical methods for the preparation of intercalation compounds, from intercalation to the formation of layered double hydroxides66Templated synthesis of atomically thin platy hematite nanoparticles within a layered silicate exhibiting efficient photocatalytic activity25Templated synthesis of atomically-thin Ag nanocrystal catalysts in the interstitial space of a layered silicate48Zeolite framework functionalisation by tuneable incorporation of various metals into the IPC-2 zeolite19Zeolitic intralayer microchannels of magadiite, a natural layered silicate, to boost green organic synthesis43Elucidation of the Adsorption Distribution of Cationic Porphyrin on the Inorganic Surface by Energy Transfer as a Molecular Ruler17Optical Humidity Sensing Using Transparent Hybrid Film Composed of Cationic Magnesium Porphyrin and Clay Mineral26Intercalation and in situ formation of coordination compounds with ligand 8-hydroxyquinoline-5-sulfonic acid in the interlayer space of layered silicate magadiite by solid-solid reactions22Crystal Growth of Layered Silicate Grafted with Organic Groups on Monodisperse Spherical Silica Particles2Removal of Water-Soluble Polymers from an Aqueous Solution by Adsorption onto an Acidic Clay3Highly Active Layered Titanosilicate Catalyst with High Surface Density of Isolated Titanium on the Accessible Interlayer Surface29Formation and optical properties of metal/10-hydroxybenzo[h]quinolone complexes in the interlayer spaces of magadiite by solid–solid reactions4Merging Cation Exchange and Photocatalytic Charge Separation Efficiency in an Anatase/K2Ti4O9 Nanobelt Heterostructure for Metal Ions Fixation22A Review on Layered Mineral Nanosheets Intercalated with Hydrophobic/Hydrophilic Polymers and Their Applications17Materials Nanoarchitectonics Using 2D Layered Materials: Recent Developments in the Intercalation Process56X‐ray‐induced reduction of a surfactant/polyoxotungstate hybrid compound12Artificial Photosynthesis Model: Photochemical Reaction System with Efficient Light-Harvesting Function on Inorganic Nanosheets18Complexation of TiO2 With Clays and Clay Minerals for Hierarchically Designed Functional Hybrids11A study of stereoselective adsorption in smectites using thin-layer chromatography7Microporous materials formed via intercalation of ultrathin coordination polymers in a layered silicate9Preparation of sodium-type bentonite with useful swelling property by a mechanochemical reaction from a weathered bentonite16Conversion of a 2D Lepidocrocite-Type Layered Titanate into Its 1D Nanowire Form with Enhancement of Cation Exchange and Photocatalytic Performance66Improved Rheological Properties of Organophilic-Clay Suspensions by a Simple Pretreatment with a Wet Type Jet Mill8Removal of ethyl, isobutyl, and isoamyl xanthates using cationic gemini surfactant-modified montmorillonites49Novel Flexible Supramolecular Assembly of Dioleyldimethylammonium Ion in a Two-Dimensional Nanospace Studied by Neutron Scattering17Bursting Exfoliation of a Microporous Layered Silicate to Three-Dimensionally Meso–Microporous Nanosheets for Improved Molecular Recognition46Distinctive stability of a free-standing monolayer clay mineral nanosheet via transmission electron microscopy6Microporous layered silicates: old but new microporous materials50Photofunctions of Dye-Clay Hybrids: Recent Developments12Tuning Emission Properties by Dye Encapsulation into Layered Silicates3COUNTING THE LAYER NUMBER OF FREE-STANDING MONTMORILLONITE NANOSHEETS USING ANNULAR DARK FIELD SCANNING TRANSMISSION ELECTRON MICROSCOPY3Atomic-Scale Imaging of a Free-Standing Monolayer Clay Mineral Nanosheet Using Scanning Transmission Electron Microscopy14Hydrated Silicate Layer Formation on Mica-Type Crystals10Adsorption Behavior of Mono-Cationic Pyridinium Salts on the Clay Surface4Designing nanoarchitecture for environmental remediation based on the clay minerals as building block56Template Synthesis of Well-Defined Rutile Nanoparticles by Solid-State Reaction at Room Temperature10Organically Modified Bentonite as an Efficient and Reusable Adsorbent for Triclosan Removal from Water32Electronic interactions between a quaternary pyridyl-β-diketonate and anionic clay nanosheets facilitate intense photoluminescence5Characteristics of flexible supramolecular assembly of dioleyldimethylammonium ion confined in a two dimensional nanospace studied by the host-guest reactions6Monodisperse Clay Microballs for Tuning the Pseudogaps by Adsorption in Amorphous Photonic Structures7Layered silicate magadiite and its composites for pollutants removal and antimicrobial properties: A review57Adsorption of Triclosan onto Organically Modified-Magadiite and Bentonite19Direct Imaging of Individual Organic Molecules in Supramolecular Assembly Strongly Fixed via Multivalent Electrostatic Interactions7Photoluminescence Gas Sensing by Fluorescein-Dye Anions/1-Butanesulfonate/Layered Double Hydroxide Hybrid Materials under Humid Environment Conditions5Interlayer Silylation of Layered Octosilicate with Organoalkoxysilanes: Effects of Tetrabutylammonium Fluoride as a Catalyst and the Functional Groups of Silanes9Highly Luminescent Inorganic–Organic Hybrids with Molecularly Dispersed Perylene11A Novel Process for Intercalating Alkylammonium Ions in a Thai Bentonite and its Effect on Adsorption Performance5Important Roles of Water Clusters Confined in a Nanospace as Revealed by a Synchrotron X-ray Diffraction Study10Layered alkali titanates (A2TinO2n+1): possible uses for energy/environment issues22Cooperative Electric Alignment of Colloidal Graphene Oxide Particles with Liquid Crystalline Niobate Nanosheets1Dissecting Biological and Synthetic Soft–Hard Interfaces for Tissue-Like Systems106Post-synthetic particle size reduction of a layered cesium titanate (Cs2Ti5O11) for the improvement of photocatalytic H2 production6Frontiers in Mesoscale Materials Design0Organophilic Clay with Useful Whiteness9Structural Conversion of Cu-Titanate into Photoactive Plasmonic Cu-TiO2 for H2 Generation in Visible Light25Interlayer Modification of a Layered Silicate RUB-18 with 4-Phosphonophenylsilane and Its Surface Acidic Functions6Interactions of layered clay minerals with water-soluble polymers; structural design and functions27Surface‐fixation Induced Emission2Acceleration of the Dehydrogenation of d -Glucose to 2-Keto- d -gluconate in Aqueous Amino Acid via Hydrated Stacked Clay Nanosheets4Mixed-Metal-Atom Markers Enable Simultaneous Imaging of Spatial Distribution in Two-Dimensional Heterogeneous Molecular Assembly by Scanning Transmission Electron Microscopy2Diverse structures and multi-step dielectric relaxation of three lead bromide hybrid crystals based on 1-aminopyridinium and its cyano-substituted Schiff bases2Estimation of Adsorbed Amounts in Organoclay by Machine Learning4Clay-Based Aerogels1Spherical Silica Particles Coated with Lamellar Nanocomposites Based on a Hydrophobic Functionalized Phyllosilicate5A stable layered inorganic solid at high temperature: Heat treatment of Eu-doped hexacelsian without phase transformation13Preparation of Porous Aggregates of Smectite by Spray Drying Combined with the Intercalation of a Water-soluble Polymer0A three-dimensional image reflecting the dispersion state of ceramic platelets in solvent: Observation of montmorillonite dispersed in silica gel by synchrotron X-ray multiscale tomography1Imidazolium-based ionic liquid supported layered silicate HUS-7 as an active catalyst for ring opening of oxiranes1Novel Floating Adsorbent for Water Treatment: Organically Modified Layered Alkali Silicate by Facile Mechanochemical Reaction4States of Guest Molecules/Molecular Assemblies in Two Dimensional Nanospace0Designed functions of oxide/hydroxide nanosheets via elemental replacement/doping46Monolayer Modification of Spherical Amorphous Silica by Clay Nanosheets0Comparison of the Properties and Structure of Montmorillonites Modified with Polyvinylpyrrolidone3Enhancing compressive strength in cementitious composites via plasma-treated PET aggregates: Insights into interface mechanics19Fluorescence enhancement of benzimidazolium derivative on clay nanosheets by surface-fixation induced emission (S-FIE)2Evaluation of Anticancer Activity of Organo-Montmorillonites and their Plumbagin-Nanohybrids0Layered Silicates Exhibiting MOF-Like Gate-Opening Behaviors in Liquid-Phase Adsorptions: Experimental and Theoretical Investigations4Luminescent Hybrid Material Based on the Europium(III)–β‐Diketone Complex Doped with Smectite1

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  1. Molecular recognitive adsorption of aqueous tetramethylammonium on the organic derivative of Hiroshima University Silicate-1 with a silane coupling reagent

    Chemical Communications · 2012-01-01

    Yusuke Ide, Masato Torii, Nao Tsunoji, Masahiro Sadakane, Tsuneji Sano

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  2. Synthesis and characteristics of novel layered silicates HUS-2 and HUS-3 derived from a SiO2–choline hydroxide–NaOH–H2O system

    Journal of Materials Chemistry · 2012-01-01

    Nao Tsunoji, Takuji Ikeda, Yusuke Ide, Masahiro Sadakane, Tsuneji Sano

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  3. Efficient and Selective Photocatalytic Cyclohexane Oxidation on a Layered Titanate Modified with Iron Oxide under Sunlight and CO 2 Atmosphere

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    Hideya Hattori, Yusuke Ide, Shuhei Ogo, Kei Inumaru, Masahiro Sadakane, Tsuneji Sano

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  4. Swellable Microsphere of a Layered Silicate Produced by Using Monodispersed Silica Particles

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    Tomohiko Okada, Shiho Yoshido, Hikari Miura, Tomohiko Yamakami, Toshio Sakai, Shozi Mishima

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  5. Regulation of the Collisional Self-Quenching of Fluorescence in Clay/Porphyrin Complex by Strong Host–Guest Interaction

    The Journal of Physical Chemistry A · 2012-11-09

    Yohei Ishida, Tetsuya Shimada, Hiroshi Tachibana, Haruo Inoue, Shinsuke Takagi

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  6. Characterization of layered silicate HUS-5 and formation of novel nanoporous silica through transformation of HUS-5 ion-exchanged with alkylammonium cations

    Journal of Materials Chemistry A · 2013-01-01

    Nao Tsunoji, Miki Fukuda, Kaname Yoshida, Yukichi Sasaki, Takuji Ikeda, Yusuke Ide, Masahiro Sadakane, Tsuneji Sano

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  7. Precisely designed layered silicate as an effective and highly selective CO2 adsorbent

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  8. Size-Matching Effect on Inorganic Nanosheets: Control of Distance, Alignment, and Orientation of Molecular Adsorption as a Bottom-Up Methodology for Nanomaterials

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  9. Unique Photochemical Properties of p-Substituted Cationic Triphenylbenzene Derivatives on a Clay Layer Surface

    The Journal of Physical Chemistry C · 2013-01-17

    Takamasa Tsukamoto, Tetsuya Shimada, Shinsuke Takagi

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  10. ChemInform Abstract: Organic—Inorganic Hybrids Based on Ultrathin Oxide Layers. Designed Nanostructures or Molecular Recognition

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  11. High Density Intercalation of Porphyrin into Transparent Clay Membrane without Aggregation

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  12. Artificial Light-Harvesting Model in a Self-Assembly Composed of Cationic Dyes and Inorganic Nanosheet

    The Journal of Physical Chemistry C · 2013-04-18

    Yohei Ishida, Tetsuya Shimada, Shinsuke Takagi

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  13. Photochemical Properties of Mono-, Tri-, and Penta-Cationic Antimony(V) Metalloporphyrin Derivatives on a Clay Layer Surface

    The Journal of Physical Chemistry A · 2013-07-25

    Takamasa Tsukamoto, Tetsuya Shimada, Shinsuke Takagi

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  14. Layered Silicate as an Excellent Partner of a TiO 2 Photocatalyst for Efficient and Selective Green Fine-Chemical Synthesis

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  15. Layered Clay Aerogels by a Freeze-Drying Process for a Platinum-Supported Catalyst

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    Tomohiko Okada, Taku Kato, Takeharu Yamaguchi, Toshio Sakai, Shozi Mishima

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  16. Decomposition of a cyanine dye in binary nanosheet colloids of photocatalytically active niobate and inert clay

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  17. Cation Exchange in Layered Copper(II) Coordination Polymers

    European Journal of Inorganic Chemistry · 2013-11-19

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  18. Encapsulation of a Polyoxometalate into an Organosilica Microcapsule for Highly Active Solid Acid Catalysis

    ACS Catalysis · 2013-12-03

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  19. Synthesis and characteristics of novel layered silicate HUS-7 using benzyltrimethylammonium hydroxide and its unique and selective phenol adsorption behavior

    Journal of Materials Chemistry A · 2013-12-19

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  20. A controlled spatial distribution of functional units in the two dimensional nanospace of layered silicates and titanates

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  21. Adsorption and photochemical behaviors of the novel cationic xanthene derivative on the clay surface

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  22. Chemically stable magnetic nanoparticles for metal adsorption and solid acid catalysis in aqueous media

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  23. Intercalation of Organic Compounds into Layered Clay Minerals

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  24. Microporous titanate nanofibers for highly efficient UV-protective transparent coating

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  25. Reactivity and applications of layered silicates and layered double hydroxides

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  26. Design of Layered Silicate by Grafting with Metal Acetylacetonate for High Activity and Chemoselectivity in Photooxidation of Cyclohexane

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  27. Switching of energy transfer reaction by the control of orientation factor between porphyrin derivatives on the clay surface

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  28. Supramolecular-Surface Photochemistry: Supramolecular Assembly Organized on a Clay Surface Facilitates Energy Transfer between an Encapsulated Donor and a Free Acceptor

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  29. Integrative strategies to hybrid lamellar compounds: an integration challenge

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  30. “Surface-Fixation Induced Emission” of Porphyrazine Dye by a Complexation with Inorganic Nanosheets

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  31. Microstructures of the Porphyrin/Viologen Monolayer on the Clay Surface: Segregation or Integration?

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  32. Organoclays in Water Cause Expansion That Facilitates Caffeine Adsorption

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  33. Preparation of copper oxide in smectites

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  34. Manipulation of supramolecular 2D assembly of functional dyes toward artificial light-harvesting systems

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  35. Structure resembling effect of clay surface on photochemical properties of meso-phenyl or pyridyl-substituted monocationic antimony( v ) porphyrin derivatives

    RSC Advances · 2014-12-24

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  36. Highly active and selective Ti-incorporated porous silica catalysts derived from grafting of titanium( iv )acetylacetonate

    Journal of Materials Chemistry A · 2015-01-01

    Miki Fukuda, Nao Tsunoji, Yuya Yagenji, Yusuke Ide, Shinjiro Hayakawa, Masahiro Sadakane, Tsuneji Sano

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  37. Photochromic Intercalation Compounds

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  38. Formation of zinc oxide particles in cetyltrimethylammonium-smectites

    Applied Clay Science · 2015-01-17

    Nuttaporn Khumchoo, Nithima Khaorapapong, Makoto Ogawa

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  39. Concentration of 2-phenylphenol by organoclays from aqueous sucrose solution

    Applied Clay Science · 2015-04-02

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  40. Crystal architectures of a layered silicate on monodisperse spherical silica particles cause the topochemical expansion of the core-shell particles

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  41. Preparation of metal sulfide mixtures in montmorillonite by solid–solid reactions

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    Jirabhorn Kabilaphat, Nithima Khaorapapong, Kanji Saito, Makoto Ogawa

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  42. Design of Microporous Material HUS-10 with Tunable Hydrophilicity, Molecular Sieving, and CO2 Adsorption Ability Derived from Interlayer Silylation of Layered Silicate HUS-2

    ACS Applied Materials & Interfaces · 2015-10-19

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  43. In Situ Crystallization of Al-Containing Silicate Nanosheets on Monodisperse Amorphous Silica Microspheres

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  44. An inorganic anionic polymer filter disc: direct crystallization of a layered silicate nanosheet on a glass fiber filter

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  45. Unprecedentedly enhanced solar photocatalytic activity of a layered titanate simply integrated with TiO 2 nanoparticles

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  46. Photophysical Properties and Adsorption Behaviors of Novel Tri-Cationic Boron(III) Subporphyrin on Anionic Clay Surface

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  47. Kinetic Analysis by Laser Flash Photolysis of Porphyrin Molecules’ Orientation Change at the Surface of Silicate Nanosheet

    The Journal of Physical Chemistry C · 2016-03-14

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  48. Green Synthesis of Organophilic Clays; Solid-State Reaction of Acidic Clay with Organoamine

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  49. Efficient Photodegradation of Organics in Acidic Solution by ZnO–Smectite Hybrids

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  50. Modified Method for Bentonite Purification and Characterization; a Case Study Using Bentonite from Tsunagi Mine, Niigata, Japan

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