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RESEARCH PAPER · Chemical Communications · 2015

A viologen-functionalized chiral Eu-MOF as a platform for multifunctional switchable material

Hai‐Yang Li, Hong Liang Xu, Shuang‐Quan Zang, Thomas C. W. Mak

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A viologen-functionalized chiral Eu-MOF as a platform for multifunctional switchable materialOriginalConstruction of six new luminescent Ln( iii )–Zn( ii ) heterometallic coordination polymers based on heterometallic secondary building units19Stoichiometry-controlled structural and functional variation in two photochromic iodoargentates with a fast and wide range response45Strategies to construct homochiral metal–organic frameworks: ligands selection and practical techniques23Anion-Mediated Architecture and Photochromism of Rigid Bipyridinium-Based Coordination Polymers87Photochromic and Nonphotochromic Luminescent Supramolecular Isomers Based on Carboxylate-Functionalized Bipyridinium Ligand: (4,4)-Net versus Interpenetrated (6,3)-Net101Photochromic Terbium Phosphonates with Photomodulated Luminescence and Metal Ion Sensitive Detection72Structures and properties of coordination polymers with a rigid zwitterionic pyridinium-based tricarboxylate ligand0A novel photo- and hydrochromic europium metal–organic framework with good anion sensing properties158A solar ultraviolet sensor based on fluorescent polyoxometalate and viologen52Anion-controlled photochromism of two bipyridinium-based coordination polymers and nondestructive luminescence readout79Assembly of donor–acceptor hybrid heterostructures based on iodoplumbates and viologen coordination polymers45Coordination-modulated piezochromism in metal–viologen materials119Metal–organic frameworks based on bipyridinium carboxylate: photochromism and selective vapochromism98Second-order nonlinear optical switching with a record-high contrast for a photochromic and thermochromic bistable crystal119Unravelling chromism in metal–organic frameworks79Synthesis, crystal structure, luminescent and magnetic properties of lanthanide coordination polymers based on a zwitterionic polycarboxylate ligand9A series of transition metal-organic frameworks based on a bipyridinium carboxylate ligand: Syntheses, structures and photoluminescent properties5Solvent-induced assembly of two helical Eu(III) metal-organic frameworks and fluorescence sensing activities towards nitrobenzene and Cu 2+ ions36Synthesis, crystal structures and photochromic properties of two coordination polymers based on a rigid tetracarboxylic acid ligand5Flexible Viologen‐Based Porous Framework Showing X‐ray Induced Photochromism with Single‐Crystal‐to‐Single‐Crystal Transformation180Flexible Viologen‐Based Porous Framework Showing X‐ray Induced Photochromism with Single‐Crystal‐to‐Single‐Crystal Transformation32Highly Water Stable Lanthanide Metal–Organic Frameworks Constructed from 2,2′-Disulfonyl-4,4′-biphenyldicarboxylic Acid: Syntheses, Structures, and Properties30The Impact of Charge‐Distribution on Photochromic Properties in 1D Coordination Polymers8Photochromic Properties of a Series of Zinc(II)–Viologen Complexes with Structural Regulation by Anions59Two novel Cd(II)-based coordination polymers constructed from isomeric double betaine ligands: Syntheses, structures and fluorescent properties3Efficient Ultraviolet Light Detector Based on a Crystalline Viologen-Based Metal–Organic Framework with Rapid Visible Color Change under Irradiation60Novel Viologen Derivative Based Uranyl Coordination Polymers Featuring Photochromic Behaviors61Photoswitchable nonlinear optical properties of metal complexes68Metathesis in Metal–Organic Gels (MOGs): A Facile Strategy to Construct Robust Fluorescent Ln‐MOG Sensors for Antibiotics and Explosives43Bipyridinium derivative-based coordination polymers: From synthesis to materials applications276Incorporating Electron-Deficient Bipyridinium Chromorphores to Make Multiresponsive Metal–organic Frameworks57A semiconductor and fluorescence dual-mode room-temperature ammonia sensor achieved by decorating hydroquinone into a metal–organic framework75Five monocyclic pyridinium derivative based halo-argentate/cuprate hybrids or iodide salts: influence of composition on photochromic behaviors24Photochromic and photomodulated luminescence properties of two metal–viologen complexes constructed by a tetracarboxylate-anchored bipyridinium-based ligand40Photoinduced electron transfer and remarkable enhancement of magnetic susceptibility in bridging pyrazine complexes26Two novel donor–acceptor hybrid heterostructures with enhanced visible-light photocatalytic properties29Synthesis and spectroscopic properties of four metal complexes with bipyridinium-based ligand2Highly Sensitive Detection of UV Radiation Using a Uranium Coordination Polymer73Rapid and selective adsorption of cationic dyes by a unique metal-organic framework with decorated pore surface213RETRACTED: Application of a water stable porous metal-organic framework for 5-Fu delivery and inhibiting human spinal cord tumor cells11Recent Progress in Asymmetric Catalysis and Chromatographic Separation by Chiral Metal–Organic Frameworks85Photochromic Porous and Nonporous Viologen-Based Metal–Organic Frameworks for Visually Detecting Oxygen79A Multi‐Responsive Cd–Viologen Complex: Photochromism, Photomodulated Fluorescence, and Luminescent Sensing28Monitoring Ultraviolet Radiation Dosage Based on a Luminescent Lanthanide Metal–Organic Framework30Two cases of bipyridinium-based metal-organic frameworks: Syntheses, structures, photochromic behaviors15An entrapped metal-organic framework system for controlled release of ethylene41Metal-containing crystalline luminescent thermochromic materials148Metal–Organic Frameworks with Extended Viologen Units: Metal-Dependent Photochromism, Photomodulable Fluorescence, and Sensing Properties90A water stable metal–organic framework with 1D nanotube pores for 5-fluorouracil delivery and anti-brain tumor activity4Three viologen-derived Zn-organic materials: photochromism, photomodulated fluorescence, and inkless and erasable prints104Europium functionalized silicon quantum dots nanomaterials for ratiometric fluorescence detection of Bacillus anthrax biomarker51A novel photochromic coordination polymer based on a robust viologen ligand exhibiting multiple detection properties in the solid state39A series of host–guest coordination polymers containing viologens: syntheses, crystal structures, thermo/photochromism and factors influencing their thermo/photochromic behaviors62A single-crystal-to-single-crystal transformation affording photochromic 3D MORF crystals31Amino functionalized Zn/Cd-metal–organic frameworks for selective CO 2 adsorption and Knoevenagel condensation reactions66Chiral induction in a pcu -derived network from achiral precursors16Enhanced electrochemical performance of Li–Co-BTC ternary metal–organic frameworks as cathode materials for lithium-ion batteries44Two novel multichromic coordination polymers based on a new flexible viologen ligand exhibiting photocontrolled luminescence properties and sensitive detection for ammonia43Versatile and Switchable Responsive Properties of a Lanthanide‐Viologen Metal–Organic Framework129Design and Construction of a Chiral Cd(II)-MOF from Achiral Precursors: Synthesis, Crystal Structure and Catalytic Activity toward C–C and C–N Bond Forming Reactions55A novel photochromic cadmium coordination polymer based on a new viologen ligand accompanying photoswitchable luminescence properties16Recent progress of d10 iodoargentate(I)/iodocuprate(I) hybrids: Structural diversity, directed synthesis, and photochromic/thermochromic properties149X-ray and UV Dual Photochromism, Thermochromism, Electrochromism, and Amine-Selective Chemochromism in an Anderson-like Zn7 Cluster-Based 7-Fold Interpenetrated Framework357Construction of a Dual-Function Metal–Organic Framework: Detection of Fe3+, Cu2+, Nitroaromatic Explosives, and a High Second-Harmonic Generation Response26Enhanced Photoinduced Electron Transfer and Stability of Diradicals in Neutral Extended Pyridine N -Oxides21A novel photochromic metal organic framework based on viologen exhibiting benzene detection and photocontrolled luminescence properties in solid state34Photophysics Modulation in Photoswitchable Metal–Organic Frameworks432The photochromism of a coordination polymer constructed by Cd(II) and the mono-substituted viologen ligand 1-(3,5-dicarboxylbenzyl)-4,4′-bipyridinium bromide17A Layered Uranyl Coordination Polymer with UV Detection Sensitivity, Stability, and Reusability5A multi-responsive chemosensor for highly sensitive and selective detection of Fe 3+ , Cu 2+ , Cr 2 O 7 2− and nitrobenzene based on a luminescent lanthanide metal–organic framework96A multifunctional photochromic metal–organic framework with Lewis acid sites for selective amine and anion sensing33A new photochromic Gd-MOF with photoswitchable bluish-white to greenish-yellow emission based on electron transfer44A Study on Bismuth-Based Photochromic Inorganic-Organic Hybrid with Photoelectric Switchable Properties0A viologen-based multifunctional Eu-MOF: photo/electro-modulated chromism and luminescence107Dual-fixations of europium cations and TEMPO species on metal–organic frameworks for the aerobic oxidation of alcohols20Interplay between local distortion at lattice sites with optical and electrical properties of Eu 3+ -doped MNbO 3 (M = Na and K) compounds33Near-infrared photothermal conversion of stable radicals photoinduced from a viologen-based coordination polymer87Photoresponsivity and antibiotic sensing properties of an entangled tris(pyridinium)-based metal–organic framework41Selective chemochromic and chemically-induced photochromic response of a metal–organic framework49A novel photochromism material based on both pyrimidinium and polyoxometalate: (C4N2H4–C4N2H3) [Mn(H2O)6]0.5{SiW12O40}0.5ˑ5H2O13The Influence of Anions on Electron-Transfer Photochromism of Bipyridinium-Derived Metal–Organic Materials58A Multivariate Toolbox for Donor–Acceptor Alignment: MOFs and COFs45Cationic Metal–Organic Frameworks Based on Linear Zwitterionic Ligands for Cr2O72– and Ammonia Sensing58Recent Progress in 2D Metal‐Organic Frameworks for Optical Applications149Solar‐Driven Nitrogen Fixation Catalyzed by Stable Radical‐Containing MOFs: Improved Efficiency Induced by a Structural Transformation132Solar‐Driven Nitrogen Fixation Catalyzed by Stable Radical‐Containing MOFs: Improved Efficiency Induced by a Structural Transformation28Proton coupled electron transfer mechanism for the design and construction of crystalline hybrid photochromic halometallates based on nonphotoactive polypyridine-derivative moieties13Distinct and Selective Amine- and Anion-Responsive Behaviors of an Electron-Deficient and Anion-Exchangeable Metal–Organic Framework62Viologen-based photochromic coordination compounds for inkless and erasable prints35The Tri(imidazole)‐Derivative Moiety: A New Category of Electron Acceptors for the Design of Crystalline Hybrid Photochromic Materials52Photochromism and photoresponsive luminescence in naphthalenediimide coordination polymers with high thermostability13Effects of Different Counter Anions on Solid-State Electron Transfer in Viologen Compounds: Modulation of Color and Piezo- and Photochromic Properties46A novel Zn(II)-based coordination polymer: Fluorescence sensing property and treatment activity on glomerulus nephritis by reducing ROS production4A multi-stimuli electron-transfer supramolecule with segregated-stacking donor-acceptor within the lattice exhibting photo- and thermochromic, sensitive detection for amines12Remote Control of Near Infrared Emission with Lanthanide Complexes18A multi-responsive indium-viologen hybrid with ultrafast-response photochromism and electrochromism63A novel multichromic Zn( ii ) cationic coordination polymer based on a new flexible viologen ligand exhibiting aniline detection in the solid state30Cationic coordination polymers with thirteen-fold interpenetrating dia networks: selective coloration and ion-controlled photochromism24Concomitant Photoresponsive Chiroptics and Magnetism in Metal-Organic Frameworks at Room Temperature25Photochromism and photomagnetism in three cyano-bridged 3d–4f heterobimetallic viologen frameworks47The modulation effect of electron-rich solvents on the supramolecular networks and photochromic properties of naphthalene diimide molecules22Achieving UV and X-ray Dual Photochromism in a Metal–Organic Hybrid via Structural Modulation38Photochromism and photo-switchable luminescence properties of a methacrylate-based inorganic-organic hybrid compound5Photoswitchable Nonlinear-Optical Crystal Based on a Dysprosium–Iron Nitrosyl Metal Assembly16Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications928Quadruple Photoresponsive Functionality in a Crystalline Hybrid Material: Photochromism, Photomodulated Fluorescence, Magnetism and Nonlinear Optical Properties71Viologen-Based Cationic Metal–Organic Framework for Efficient Cr2O72– Adsorption and Dye Separation50Relationship Between Structure and Electroluminescent, Photochromic, or Second‐Order Nonlinear Optical Property1Relationship Between Structure and Electroluminescent, Photochromic, or Second‐Order Nonlinear Optical Property1Dynamically Controlled Electronic Behavior of Stimuli‐Responsive Materials: Exploring Dimensionality and Connectivity64Catalytic C–H Bond Activation and Knoevenagel Condensation Using Pyridine-2,3-Dicarboxylate-Based Metal–Organic Frameworks47Photoswitching Bulk Quadratic Nonlinear-Optical Properties with Record Contrast in a Photochromic Semiconductor12Chiral metal–organic frameworks based on asymmetric synthetic strategies and applications107Temperature Tuned Two Novel 3D Zn(II) Metal Organic Frameworks Exhibiting Luminescence Properties11A Multistimuli Responsive Crystalline Cd(II)-Viologen Coordination Polymer with Single-Crystal–Single-Crystal Transformation56A Photochromic Zinc–Viologen Framework with a High-Contrast Nonlinear Optical Switchable Behavior24Achieving an electron transfer photochromic complex for switchable white-light emission15Dynamic Manipulating Space‐Resolved Persistent Luminescence in Core–Shell MOFs Heterostructures via Reversible Photochromism181Dynamic Manipulating Space‐Resolved Persistent Luminescence in Core–Shell MOFs Heterostructures via Reversible Photochromism36Viologen‐Based Uranyl Coordination Polymers: Anion‐Induced Structural Diversity and the Potential as a Fluorescent Probe15Recent advances in crystalline hybrid photochromic materials driven by electron transfer212Redox-active metal-organic frameworks for the removal of contaminants of emerging concern40Synthesis and properties of a novel photochromic metal organic framework for rapid amine selective sensing and Cr2O72− detection23A series of naphthalenediimide-based metal–organic frameworks: synthesis, photochromism and inkless and erasable printing9Lattice solvent controlled photochromism of tripyridyl-triazine-based zinc bromide complexes22Newer viologen: Synthesis, characterization, solvatochromic, photophysical, and DFT studies3Photochromic and electrochromic properties of a viologen-based multifunctional Cd-MOF56Ultrafast visible-light photochromic properties of naphthalenediimide-based coordination polymers for the visual detection/filtration of blue light37A novel multifunctional Cd (II) coordination polymer based on viologen: photochromic, photocontrolled fluorescence and amines detection18UV and X-ray dual photochromism of a Zn(II)-viologen coordination polymer and its application in inkless and erasable printing19Turn-up Luminescent Sensing of Ultraviolet Radiation by Lanthanide Metal–Organic Frameworks20A crystalline photochromic metalloviologen compound with a chiral ligand: Synthetic strategy and SHG-photoswitching property1Multistimuli-Responsive Materials Based on Zn(II)-Viologen Coordination Polymers and Their Applications in Inkless Print and Anticounterfeiting82Viologen-Based Cationic Metal–Organic Framework for Antibiotics Detection and MnO4– Removal in Water38Elastic properties related energy conversions of coordination polymers and metal–organic frameworks40Photoactive Anthracene-9,10-dicarboxylic Acid for Tuning of Photochromism in the Cd/Zn Coordination Polymers26A Multifunctional Coordination Polymer Constructed by Viologen Derivatives: Photochromism, Chemochromism, and MnO 4 – Sensing57Fe2O3@SiO2@Eu-MOF@Tb-MOF Core/Multishell Nanoparticles for the Fluorescence Sensing of Aspirin and Acute Myocardial Infarction Biomarkers25UV and X-ray Dual Photochromism of Two Zn(II)-Viologen Coordination Polymers and Fast Decoloration by Hydrogen Chloride21Two new Zinc (II)-viologen coordination polymers: Syntheses, structures, and photochromic behaviors28The progress of electrochromic materials based on metal–organic frameworks91Photochromic crystalline hybrid materials with switchable properties: Recent advances and potential applications173The modulation effect of auxiliary ligands on photochromic properties of 3D naphthalene diimide coordination polymers12Novel Inorganic-Organic Hybrid Coordination Compound: Photochromic, Amine Vapor Detection, and Theoretical Calculation6Metal–Photoswitch Friendship: From Photochromic Complexes to Functional Materials121Five novel supramolecular assemblies constructed from the thiazolothiazole extended viologen moiety7Multifunctionality of luminescent molecular nanomagnets based on lanthanide complexes67Photochromic, Photoluminescence and Optical Switch Properties of Two Multifunctional Eu-Mofs Based on Carboxylate Bipyridinium Ligand0One-dimensional europium coordination polymer with redox-active ligands11Crystal Structure and Photochromic Properties of Two Complexes based on 1‐(4‐carboxybenzyl)‐4,4′‐bipyridinium Ligand5

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  11. Assembly of donor–acceptor hybrid heterostructures based on iodoplumbates and viologen coordination polymers

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  12. Coordination-modulated piezochromism in metal–viologen materials

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  33. Five monocyclic pyridinium derivative based halo-argentate/cuprate hybrids or iodide salts: influence of composition on photochromic behaviors

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  34. Photochromic and photomodulated luminescence properties of two metal–viologen complexes constructed by a tetracarboxylate-anchored bipyridinium-based ligand

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  35. Photoinduced electron transfer and remarkable enhancement of magnetic susceptibility in bridging pyrazine complexes

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  36. Two novel donor–acceptor hybrid heterostructures with enhanced visible-light photocatalytic properties

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  37. Synthesis and spectroscopic properties of four metal complexes with bipyridinium-based ligand

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  38. Highly Sensitive Detection of UV Radiation Using a Uranium Coordination Polymer

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  39. Rapid and selective adsorption of cationic dyes by a unique metal-organic framework with decorated pore surface

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  40. RETRACTED: Application of a water stable porous metal-organic framework for 5-Fu delivery and inhibiting human spinal cord tumor cells

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  42. Photochromic Porous and Nonporous Viologen-Based Metal–Organic Frameworks for Visually Detecting Oxygen

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  43. A Multi‐Responsive Cd–Viologen Complex: Photochromism, Photomodulated Fluorescence, and Luminescent Sensing

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  44. Monitoring Ultraviolet Radiation Dosage Based on a Luminescent Lanthanide Metal–Organic Framework

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