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RESEARCH PAPER · Dalton Transactions · 2015

Synthesis of substituted β-diketiminate gallium hydrides via oxidative addition of H–O bonds

Eduardo Herappe-Mejía, Karla Trujillo-Hernández, Juan Carlos Garduño-Jiménez, Fernando Cortés‐Guzmán, Diego Martı́nez-Otero, Vojtěch Jančík

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Synthesis of substituted β-diketiminate gallium hydrides via oxidative addition of H–O bondsOriginalCorrection: Ga[OSi(O t Bu) 3 ] 3 ·THF, a thermolytic molecular precursor for high surface area gallium-containing silica materials of controlled dispersion and stoichiometry1Ga[OSi(O t Bu) 3 ] 3 ·THF, a thermolytic molecular precursor for high surface area gallium-containing silica materials of controlled dispersion and stoichiometry23On the non-innocence of “Nacnacs”: ligand-based reactivity in β-diketiminate supported coordination compounds203Determination of Rhodium–Alkoxide Bond Strengths in Tp′Rh(PMe3)(OR)H19Synthesis and Structures of Gallium‐β‐Diketiminate Complexes: Isolation of a Dinuclear Gallium(II) Complex16Gallium Hydrides with a Radical-Anionic Ligand25A General Route to Metal‐Substituted Dipnictenes of the Type [L(X)M]2E281En Route to Bis‐Carbene Analogues of the Heavier Group 13 Elements: Consideration of Bridging Group and Metal(I) Source23Comprehensive Study on Reactions of Group 13 Diyls with Tetraorganodipentelanes21Self-Assembly of Aluminum- and Gallium-Based meso-Metallaporphyrins3Facile oxidative addition of O 2 and S 8 by an indium bis(carbene) analogue17Reactivity patterns for the activation of CO 2 and CS 2 with alumoxane and aluminum hydrides23The unique β-diketiminate ligand in aluminum( i ) and gallium( i ) chemistry157Salt metathesis as an alternative approach to access aluminium( i ) and gallium( i ) β-diketiminates33New Gallium Hydrides with Dianionic Acenaphthene-1,2-Diimine Ligands5Partnering a Three‐Coordinate Gallium Cation with a Hydroborate Counter‐Ion for the Catalytic Hydrosilylation of CO230The Coordination Chemistry and Clustering of Subvalent Ga+ and In+ upon Addition of σ‐Donor Ligands22Molecular Main Group Metal Hydrides297Gallium, Indium, and Thallium1N-Heterocyclic imine-based bis-gallium( i ) carbene analogs featuring a four-membered Ga 2 N 2 ring12In situ formation of reactive (di)gallenes for bond activation15Low Valence Triel (I) Systems as Hydrogen Bond Acceptors and their Stability with Respect to Triel (III) Compounds2Cationic Group 13 and 14 Element Clusters14(1,4)-Cycloaddition and C–X bond activation reactions of monovalent group 13 diyls0Cleaving a C–F bond of C 6 F 6 at a gallium( i ) centre catalyzed by nitrogen-containing Lewis bases and its kinetic analysis5Why is a dicationic digallene so reactive towards activation of strong covalent bonds? Scope and mechanistic investigations3Tailoring Reactivity of Molecular Gallium Hydroxides via Chalcogen Bridging0

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  1. Correction: Ga[OSi(O t Bu) 3 ] 3 ·THF, a thermolytic molecular precursor for high surface area gallium-containing silica materials of controlled dispersion and stoichiometry

    Dalton Transactions · 2016-01-01

    James P. Dombrowski, Gregory R. Johnson, Alexis T. Bell, T. Don Tilley

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  2. Ga[OSi(O t Bu) 3 ] 3 ·THF, a thermolytic molecular precursor for high surface area gallium-containing silica materials of controlled dispersion and stoichiometry

    Dalton Transactions · 2016-01-01

    James P. Dombrowski, Gregory R. Johnson, Alexis T. Bell, T. Don Tilley

    Read original paper ↗ ·

  3. On the non-innocence of “Nacnacs”: ligand-based reactivity in β-diketiminate supported coordination compounds

    Dalton Transactions · 2016-01-01

    Clément Camp, John Arnold

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  4. Determination of Rhodium–Alkoxide Bond Strengths in Tp′Rh(PMe3)(OR)H

    Inorganic Chemistry · 2016-09-07

    Jing Yuwen, Yunzhe Jiao, William W. Brennessel, William D. Jones

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  5. Synthesis and Structures of Gallium‐β‐Diketiminate Complexes: Isolation of a Dinuclear Gallium(II) Complex

    Zeitschrift für anorganische und allgemeine Chemie · 2017-10-05

    Reik Laubenstein, Mike Ahrens, Thomas Braun

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  6. Gallium Hydrides with a Radical-Anionic Ligand

    Inorganic Chemistry · 2017-10-12

    Vladimir G. Sokolov, Tatyana S. Koptseva, Mikhail V. Moskalev, Natalia L. Bazyakina, Alexandr V. Piskunov, Anton V. Cherkasov, Igor L. Fedushkin

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  7. A General Route to Metal‐Substituted Dipnictenes of the Type [L(X)M]2E2

    Chemistry - A European Journal · 2017-12-20

    Lars Tuscher, Christoph Helling, Christoph Wölper, Walter C. Frank, Anton S. Nizovtsev, Stephan Schulz

    Read original paper ↗ ·

  8. En Route to Bis‐Carbene Analogues of the Heavier Group 13 Elements: Consideration of Bridging Group and Metal(I) Source

    Chemistry - A European Journal · 2018-06-13

    Marcella E. Desat, Robert Kretschmer

    Read original paper ↗ ·

  9. Comprehensive Study on Reactions of Group 13 Diyls with Tetraorganodipentelanes

    Inorganic Chemistry · 2018-07-24

    Chelladurai Ganesamoorthy, Julia Krüger, Eduard Glöckler, Christoph Helling, Lukas John, Walter C. Frank, Christoph Wölper, Stephan Schulz

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  10. Self-Assembly of Aluminum- and Gallium-Based meso-Metallaporphyrins

    Inorganic Chemistry · 2018-12-18

    María del Carmen Mancilla‐González, Uvaldo Hernández‐Balderas, Mónica Moya‐Cabrera, Lillian G. Ramírez‐Palma, Diego Martı́nez-Otero, Fernando Cortés‐Guzmán, Vojtěch Jančík

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  11. Facile oxidative addition of O 2 and S 8 by an indium bis(carbene) analogue

    Dalton Transactions · 2019-01-01

    Marcella E. Desat, Robert Kretschmer

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  12. Reactivity patterns for the activation of CO 2 and CS 2 with alumoxane and aluminum hydrides

    Dalton Transactions · 2019-01-01

    Sandra González‐Gallardo, Vojtěch Jančík, Dalia G. Díaz‐Gómez, Fernando Cortés‐Guzmán, Uvaldo Hernández‐Balderas, Mónica Moya‐Cabrera

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  13. The unique β-diketiminate ligand in aluminum( i ) and gallium( i ) chemistry

    Dalton Transactions · 2019-12-23

    Mingdong Zhong, Soumen Sinhababu, Herbert W. Roesky

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  14. Salt metathesis as an alternative approach to access aluminium( i ) and gallium( i ) β-diketiminates

    Dalton Transactions · 2020-01-01

    Oleksandr Kysliak, Helmar Görls, Robert Kretschmer

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  15. New Gallium Hydrides with Dianionic Acenaphthene-1,2-Diimine Ligands

    Russian Journal of Coordination Chemistry · 2020-06-01

    Tatyana S. Koptseva, Vladimir G. Sokolov, E.V. Baranov, Igor L. Fedushkin

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  16. Partnering a Three‐Coordinate Gallium Cation with a Hydroborate Counter‐Ion for the Catalytic Hydrosilylation of CO2

    Chemistry - A European Journal · 2020-11-10

    Alexa Caise, Jamie Hicks, M. Ángeles Fuentes, José M. Goicoechea, Simon Aldridge

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  17. The Coordination Chemistry and Clustering of Subvalent Ga+ and In+ upon Addition of σ‐Donor Ligands

    Zeitschrift für anorganische und allgemeine Chemie · 2021-05-17

    Philipp Dabringhaus, Antoine Barthélemy, Ingo Krossing

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  18. Molecular Main Group Metal Hydrides

    Chemical Reviews · 2021-08-27

    Matthew M. D. Roy, Alvaro A. Omaña, Andrew S. S. Wilson, Michael S. Hill, Simon Aldridge, Eric Rivard

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  19. Gallium, Indium, and Thallium

    Elsevier eBooks · 2022-01-01

    Christoph Helling, Stephan Schulz

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  20. N-Heterocyclic imine-based bis-gallium( i ) carbene analogs featuring a four-membered Ga 2 N 2 ring

    Dalton Transactions · 2023-01-01

    Bing Wang, Wenhao Chen, Jiangnan Yang, Linfang Lu, Jiyong Liu, Liang Shen, Di Wu

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  21. In situ formation of reactive (di)gallenes for bond activation

    Nature Synthesis · 2024-04-26

    Philipp Dabringhaus, Harald Scherer, Ingo Krossing

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  22. Low Valence Triel (I) Systems as Hydrogen Bond Acceptors and their Stability with Respect to Triel (III) Compounds

    ChemPhysChem · 2024-07-04

    Goar Sánchez‐Sanz, Ibón Alkorta, José Elguero

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  23. Cationic Group 13 and 14 Element Clusters

    Inorganic Chemistry · 2024-11-01

    Antoine Barthélemy, Ingo Krossing

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  24. (1,4)-Cycloaddition and C–X bond activation reactions of monovalent group 13 diyls

    Inorganic Chemistry Frontiers · 2025-01-01

    Hanns M. Weinert, Pratima Dhawan, Timo Freese, Christoph Wölper, Stephan Schulz

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  25. Cleaving a C–F bond of C 6 F 6 at a gallium( i ) centre catalyzed by nitrogen-containing Lewis bases and its kinetic analysis

    Dalton Transactions · 2025-01-01

    Tao Ding, Makoto Yamashita

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  26. Why is a dicationic digallene so reactive towards activation of strong covalent bonds? Scope and mechanistic investigations

    Chemical Science · 2026-01-01

    Antoine Barthélemy, Nico G. Kub, Celine Regnat, Harald Scherer, Ingo Krossing

    Read original paper ↗ ·

  27. Tailoring Reactivity of Molecular Gallium Hydroxides via Chalcogen Bridging

    Inorganic Chemistry · 2026-09-14

    Erandi Bernabé‐Pablo, Alfonso Gallardo‐Garibay, Vojtěch Jančík, Diego Martı́nez-Otero, Roman Neufeld, Uvaldo Hernández‐Balderas, Dietmar Stalke, Mónica Moya‐Cabrera

    Read original paper ↗ ·
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