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RESEARCH PAPER · Physical Review B · 2015

Exchange-striction induced giant ferroelectric polarization in copper-based multiferroic material α−Cu2V2O7

Jhuma Sannigrahi, Sayantika Bhowal, S. Giri, Subham Majumdar, Indra Dasgupta

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Exchange-striction induced giant ferroelectric polarization in copper-based multiferroic material α−Cu2V2O7OriginalMagnetic structure and Dzyaloshinskii-Moriya interaction in the S=12 helical-honeycomb antiferromagnet α−Cu2V2O757Magnetic and dielectric properties of Mn 2 V 2 O 718Magnetism and magnetoelectricity in the polar oxide α -Cu 2 V 2 O 725Negative thermal expansion and electrical properties of α-Cu2V2O777Spin wave excitations in the pyrovanadate α − Cu 2 V 2 O 714Sign reversal of magnetization and exchange bias in Ni(Cr1−xAlx)2O4 (x=0–0.50)18A comparative study of electronic, structural, and magnetic properties of α -, β -, and γ−Cu2V2O737Magnetic ordering induced ferroelectricity in α-Cu2V2O7 studied through non-magnetic Zn doping16Magnetoelectric Behavior from S = 1 / 2 Asymmetric Square Cupolas24Honeycomb-lattice antiferromagnet Mn2V2O7: a temperature-dependent x-ray diffraction, neutron diffraction and ESR study10High-field magnetization and magnetic phase diagram of α−Cu2V2O737Nonreciprocal Magnons and Symmetry-Breaking in the Noncentrosymmetric Antiferromagnet88Magnetism and spin-driven ferroelectricity in the multiferroic material α−Cu2V2O711Spin Seebeck effect in the polar antiferromagnet α−Cu2V2O740Study of magnetic and multiferroic properties of α-copper pyrovanadate0Stabilization of E -type magnetic order caused by epitaxial strain in perovskite manganites14Magnetoelastic coupling and ferromagnetic-type in-gap spin excitations in multiferroic α-Cu2V2O713Microstructural effects on negative thermal expansion extending over a wide temperature range in β-Cu1.8Zn0.2V2O748Magnetic field induced ferroelectricity and half magnetization plateau in polycrystalline R2V2O7(R=Ni,Co)44Microscopic investigation of low dimensional magnet Sc 2 Cu 2 O 5 : combined experimental and ab initio approach14Ferroelectric order associated with ordered occupancy at the octahedral site of the inverse spinel structure of multiferroic NiFe2O444Structural and magnetic investigations on Cu-doped MnV2O6 compound: Experiment and theory5Commensurate to incommensurate magnetic phase transition in honeycomb-lattice pyrovanadate Mn 2 V 2 O 712Natural ferroelectric order near ambient temperature in the orthoferrite HoFeO332Evaluation of Copper Vanadate (β-Cu2V2O7) as a Photoanode Material for Photoelectrochemical Water Oxidation65Sol–gel synthesis of doped Cu2V2O7 fine particles showing giant negative thermal expansion19Annealing effects on negative thermal expansion properties of ball-milled β-Cu1.8Zn0.2V2O7 fine particles8Pressure and magnetic field effects on ferroelastic and antiferromagnetic orderings in honeycomb-lattice Mn2V2O711Formation of Single Polar Domain in α-Cu2V2O72Observation of structural anomaly and low-field magnetocaloric effect in Cu2OSeO34The effect of manganese doping on the structural, magnetic and dielectric properties of breathing pyrochlore LiInCr4-Mn O85Effect of Co and Mg doping at Cu site on structural, magnetic and dielectric properties of α–Cu2V2O75Structural phase transition and giant negative thermal expansion in pyrophosphate Zn2–xMgxP2O746Structural phase transition and negative thermal expansion in Cu 1.8 Zn0.2V2–x P x O7 solid solutions16Unique multiferroics with tunable ferroelastic transition in antiferromagnet Mn2V2O79Magnetic Field Tuning of Magnetic- and Structure-Phase Transition in Mn 2 V 2 O 7 Crystals3Chemical Diversity for Tailoring Negative Thermal Expansion154Observation of magnetocaloric and magneto-electric anomalies in R 2 Cu 2 O 5 family of layered oxides1Highly correlated structural, local structural, Raman spectroscopic and magnetic properties of Mn-substituted Cu2V2O74Enhanced magnetic properties and spin–phonon coupling in Ni-substituted α-Cu 2 V 2 O 7 : the role of bond length, bond angles, and distorted polyhedral structures4Role of crystal and magnetic structures in the magnetoelectric coupling in CaMn7O123Raman scattering of spin- 12 mixed-dimensionality antiferromagnetic α−Cu2V2O710Observation of Second-Order Phase Transition in Canted Antiferromagnet α-Cu2V2O7 Using Magnetocaloric Effect5Freezing of short-range ordered antiferromagnetic clusters in the CrFeTi2O7 system1On the Polymorphism of Cu2V2O7: Synthesis and Crystal Structure of δ-Cu2V2O7, a New Polymorph8Revealing the one-dimensional (1-D) Heisenberg antiferromagnetic state in pyrochlore α-Cu 2 V 2 O 7 from critical exponent analysis1Local Structure Distortion in Mn, Zn Doped Cu₂V₂O₇: Supercapacitor Performance and Emergent Spin‐Phonon Coupling2The interplay of ferroelectricity and magneto-transport in non-magnetic moiré superlattices3Interplay between trimer structure and magnetic ground state in Ba 5 Ru 3 O 12 probed by neutron and μ SR techniques2Comparative Investigation of the Critical Role of Mn, Zn, and Mn/Zn Co‐Doping in Modulating Local Coordination Environment, Magnetic Behavior, and Supercapacitor Performance of α‐Cu 2 V 2 O 70Pressure effect on the crystal structure and magnetoelectric properties of multiferroic GeCu2O40Negative thermal expansion in Co3BO5 induced by ceramic microstructural effects2Jahn–Teller distortions induced strong negative thermal expansion in α -Cu 2 V 2 O 713Tuning the phase transition and negative thermal expansion in Zn2P2O7 via regulating the pseudo-Jahn-Teller effect1

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  1. Magnetic structure and Dzyaloshinskii-Moriya interaction in the S=12 helical-honeycomb antiferromagnet α−Cu2V2O7

    Physical Review B · 2015-07-23

    Ganatee Gitgeatpong, Yonggang Zhao, Maxim Avdeev, Ross O. Piltz, T. Sato, K. Matan

    Read original paper ↗ ·

  2. Magnetic and dielectric properties of Mn 2 V 2 O 7

    Solid State Communications · 2015-12-12

    Jhuma Sannigrahi, S. Giri, Subham Majumdar

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  3. Magnetism and magnetoelectricity in the polar oxide α -Cu 2 V 2 O 7

    Europhysics Letters (EPL) · 2016-01-01

    Y.-W. Lee, T.-H. Jang, Sachith Dissanayake, Seung-Hun Lee, Yoon Hee Jeong

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  4. Negative thermal expansion and electrical properties of α-Cu2V2O7

    Journal of the European Ceramic Society · 2016-04-29

    Niu Zhang, Li Li, Mingyi Wu, Yuxiang Li, Dongsheng Feng, Cunyuan Liu, Yanchao Mao, Juan Guo, Mingju Chao, Erjun Liang

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  5. Spin wave excitations in the pyrovanadate α − Cu 2 V 2 O 7

    Physical review. B./Physical review. B · 2016-10-20

    A. Banerjee, Jhuma Sannigrahi, Sayantika Bhowal, Indra Dasgupta, Subham Majumdar, Helen C. Walker, Amitava Bhattacharyya, Devashibhai Thakarshibhai Adroja

    Read original paper ↗ ·

  6. Sign reversal of magnetization and exchange bias in Ni(Cr1−xAlx)2O4 (x=0–0.50)

    Journal of Magnetism and Magnetic Materials · 2016-11-18

    Junmoni Barman, Seenipandian Ravi

    Read original paper ↗ ·

  7. A comparative study of electronic, structural, and magnetic properties of α -, β -, and γ−Cu2V2O7

    Physical review. B./Physical review. B · 2017-02-03

    Sayantika Bhowal, Jhuma Sannigrahi, Subham Majumdar, Indra Dasgupta

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  8. Magnetic ordering induced ferroelectricity in α-Cu2V2O7 studied through non-magnetic Zn doping

    Journal of Applied Physics · 2017-03-07

    Bidisa Chattopadhyay, Md. Azaharuddin Ahmed, Sudipta Bandyopadhyay, Ratnadwip Singha, P. Mandal

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  9. Magnetoelectric Behavior from S = 1 / 2 Asymmetric Square Cupolas

    Physical Review Letters · 2017-03-09

    Yasuyuki Kato, Kenta Kimura, Atsushi Miyake, Masashi Tokunaga, Akira Matsuo, Koichi Kindo, Mitsuru Akaki, Masayuki Hagiwara, Masakazu Sera, T. Kimura, Yukitoshi Motome

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  10. Honeycomb-lattice antiferromagnet Mn2V2O7: a temperature-dependent x-ray diffraction, neutron diffraction and ESR study

    Materials Research Express · 2017-03-20

    Y. C. Sun, Zijun Ouyang, Yinguo Xiao, Yixi Su, Erxi Feng, Zhendong Fu, Wentao Jin, Mohamed Zbiri, Zhengcai Xia, Jiaxi Wang, G.H. Rao

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  11. High-field magnetization and magnetic phase diagram of α−Cu2V2O7

    Physical review. B./Physical review. B · 2017-06-16

    Ganatee Gitgeatpong, Malliga Suewattana, Shiwei Zhang, Atsushi Miyake, Masashi Tokunaga, Purintorn Chanlert, Nobuyuki Kurita, Hidekazu Tanaka, T. Sato, Yang Zhao, K. Matan

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  12. Nonreciprocal Magnons and Symmetry-Breaking in the Noncentrosymmetric Antiferromagnet

    Physical Review Letters · 2017-07-24

    Ganatee Gitgeatpong, Yang Zhao, Pharit Piyawongwatthana, Yunfeng Qiu, Leland Harriger, N. P. Butch, T. Sato, K. Matan

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  13. Magnetism and spin-driven ferroelectricity in the multiferroic material α−Cu2V2O7

    Physical review. B./Physical review. B · 2017-10-17

    Junting Zhang, Jianli Wang, C. Ji, B. X. Guo, Wangsuo Xia, Xiaomei Lü, Jianhui Zhu

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  14. Spin Seebeck effect in the polar antiferromagnet α−Cu2V2O7

    Physical review. B./Physical review. B · 2017-11-28

    Yuki Shiomi, R. Takashima, Daisuke Okuyama, Ganatee Gitgeatpong, Pharit Piyawongwatthana, K. Matan, T. Sato, Eiji Saitoh

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  15. Study of magnetic and multiferroic properties of α-copper pyrovanadate

    AIP conference proceedings · 2018-01-01

    Sayantika Bhowal, Subham Majumdar, Indra Dasgupta

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  16. Stabilization of E -type magnetic order caused by epitaxial strain in perovskite manganites

    Physical review. B./Physical review. B · 2018-02-13

    Junting Zhang, C. Ji, Jianli Wang, Wangsuo Xia, Xiaomei Lü, Jinsong Zhu

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  17. Magnetoelastic coupling and ferromagnetic-type in-gap spin excitations in multiferroic α-Cu2V2O7

    New Journal of Physics · 2018-06-04

    L Wang, J Werner, A Ottmann, R Weis, Mahmoud Abdel-Hafiez, J Sannigrahi, S Majumdar, C Koo, R. Klingeler

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  18. Microstructural effects on negative thermal expansion extending over a wide temperature range in β-Cu1.8Zn0.2V2O7

    Applied Physics Letters · 2018-10-29

    Naoyuki Katayama, K. Otsuka, Masaya Mitamura, Y. Yokoyama, Yoshihiko Okamoto, K. Takenaka

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  19. Magnetic field induced ferroelectricity and half magnetization plateau in polycrystalline R2V2O7(R=Ni,Co)

    Physical review. B./Physical review. B · 2018-11-05

    Rui Chen, Junfeng Wang, Zhongwen Ouyang, Zhidong He, S. M. Wang, Lin Lin, Jun‐Ming Liu, Chengliang Lu, Y. Liu, Chao Dong, C. B. Liu, Zhengcai Xia, Akira Matsuo, Yoshimitsu Kohama, Koichi Kindo

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  20. Microscopic investigation of low dimensional magnet Sc 2 Cu 2 O 5 : combined experimental and ab initio approach

    Journal of Physics Condensed Matter · 2019-03-14

    Jhuma Sannigrahi, J. Sichelschmidt, Bonho Koo, Anupam Banerjee, Subham Majumdar, Sudipta Kanungo

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  21. Ferroelectric order associated with ordered occupancy at the octahedral site of the inverse spinel structure of multiferroic NiFe2O4

    Physical review. B./Physical review. B · 2019-04-15

    Jayjit Kumar Dey, Alorika Chatterjee, Subham Majumdar, Ann‐Christin Dippel, Olof Gutowski, Martin v. Zimmermann, Saurav Giri

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  22. Structural and magnetic investigations on Cu-doped MnV2O6 compound: Experiment and theory

    Journal of Magnetism and Magnetic Materials · 2019-10-17

    N. Khamaru, Santanu De, Anusree Das, Vijay Singh, Dan Thomas Major, Pallab Dasgupta, Dipankar Das, Souvik Chatterjee

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  23. Commensurate to incommensurate magnetic phase transition in honeycomb-lattice pyrovanadate Mn 2 V 2 O 7

    Physical Review Materials · 2019-11-18

    J. Sannigrahi, D. T. Adroja, Robin Perry, Matthias Josef Gutmann, Václav Petříček, D. Khalyavin

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  24. Natural ferroelectric order near ambient temperature in the orthoferrite HoFeO3

    Physical review. B./Physical review. B · 2019-12-26

    K. Dey, Ankita Indra, S. Mukherjee, Subham Majumdar, J. Strempfer, Óscar Fabelo, Estelle Mossou, Tapan K. Chatterji, Saurav Giri

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  25. Evaluation of Copper Vanadate (β-Cu2V2O7) as a Photoanode Material for Photoelectrochemical Water Oxidation

    Chemistry of Materials · 2020-03-02

    Angang Song, Abdelkrim Chemseddine, Ibbi Y. Ahmet, Peter Bogdanoff, Dennis Friedrich, Fatwa F. Abdi, Sean P. Berglund, Roel van de Krol

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  26. Sol–gel synthesis of doped Cu2V2O7 fine particles showing giant negative thermal expansion

    AIP Advances · 2020-07-01

    Miku Sato, Victoria Warne-Lang, Yoshifumi Kadowaki, Naoyuki Katayama, Yoshihiko Okamoto, K. Takenaka

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  27. Annealing effects on negative thermal expansion properties of ball-milled β-Cu1.8Zn0.2V2O7 fine particles

    Ceramics International · 2020-08-01

    Victoria Warne-Lang, M. Sato, M. Ozeki, Yoshifumi Kadowaki, Y. Yokoyama, Naoyuki Katayama, Yoshihiko Okamoto, K. Takenaka

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  28. Pressure and magnetic field effects on ferroelastic and antiferromagnetic orderings in honeycomb-lattice Mn2V2O7

    Physical review. B./Physical review. B · 2020-08-20

    Hung‐Cheng Wu, Dong-Jie Hsieh, T. W. Yen, Pei-Jun Sun, D. Chandrasekhar Kakarla, Jim-Long Her, Yasuhiro H. Matsuda, Chung‐Kai Chang, Yen‐Chung Lai, Melissa Gooch, Liangzi Deng, Kyle Grant Webber, C. A. Lee, Mitch M. C. Chou, C. W. Chu, H. D. Yang

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  29. Formation of Single Polar Domain in α-Cu2V2O7

    Journal of the Physical Society of Japan · 2021-01-29

    Pharit Piyawongwatthana, Daisuke Okuyama, Kazuhiro Nawa, K. Matan, Taku J. Sato

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  30. Observation of structural anomaly and low-field magnetocaloric effect in Cu2OSeO3

    Journal of Alloys and Compounds · 2021-07-19

    Prabir Dutta, Manjil Das, Aritra Banerjee, Souvik Chatterjee, Subham Majumdar

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  31. The effect of manganese doping on the structural, magnetic and dielectric properties of breathing pyrochlore LiInCr4-Mn O8

    Journal of Alloys and Compounds · 2021-09-27

    Hui Liu, Yanfei Xiong, Shiyun Chen, Chengxiao Yang, Jian Jiang Bian, Yuan Ping Feng, Baolong Fang, Xianhe Gao

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  32. Effect of Co and Mg doping at Cu site on structural, magnetic and dielectric properties of α–Cu2V2O7

    Journal of Physics Condensed Matter · 2021-11-11

    Abja Keshar Kar, Bidisa Chattopadhyay, Ratnadwip Singha, Abhisikta Barman, Md A Ahmed, Arindam Midya, S Bandyopadhyay, Devajyoti Mukherjee, D Jana, P. Mandal

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  33. Structural phase transition and giant negative thermal expansion in pyrophosphate Zn2–xMgxP2O7

    Applied Physics Letters · 2021-11-15

    Yoshifumi Kadowaki, Ryota KASUGAI, Y. Yokoyama, Naoyuki Katayama, Yoshihiko Okamoto, K. Takenaka

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  34. Structural phase transition and negative thermal expansion in Cu 1.8 Zn0.2V2–x P x O7 solid solutions

    Applied Physics Express · 2022-01-07

    K. Takenaka, Masato Kano, Ryota KASUGAI, Kohei Takada, K. Eto, Yoshifumi Kadowaki, Yasunori Yokoyama, Naoyuki Katayama, Yoshihiko Okamoto

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  35. Unique multiferroics with tunable ferroelastic transition in antiferromagnet Mn2V2O7

    Materials Today Physics · 2022-02-07

    H.-J. Chen, Chien-Hung Yeh, T. W. Kuo, D. Chandrasekhar Kakarla, Hung‐Cheng Wu, T. W. Yen, Shiu‐Ming Huang, Hsiung Chou, MARGARET C. Y. CHOU, H.W. Chen, S.W. Kuo, Yu‐Chun Chuang, Chung‐Kai Chang, Udo R. Eckstein, Neamul Hayet Khansur, Kyle Grant Webber, H. D. Yang

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  36. Magnetic Field Tuning of Magnetic- and Structure-Phase Transition in Mn 2 V 2 O 7 Crystals

    The Journal of Physical Chemistry C · 2022-03-07

    Li‐Da Chen, Li-Huai Shu, Gan Liu, Pan Nie, Ye Shao, Ye-Cheng Luo, Yang‐Yang Lv, Haomin Lu, Zengwei Zhu, Xiaoxiang Xi, Jian Zhou, Fengzhen Huang, Zhenxiang Cheng, Shu‐Hua Yao, Y. B. Chen, Yan‐Feng Chen, Yan-Feng Chen, Yan-Feng Chen

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  37. Chemical Diversity for Tailoring Negative Thermal Expansion

    Chemical Reviews · 2022-03-08

    Qiang Li, Kun Lin, Zhanning Liu, Lei Hu, Yili Cao, Jun Chen, Xianran Xing

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  38. Observation of magnetocaloric and magneto-electric anomalies in R 2 Cu 2 O 5 family of layered oxides

    Journal of Magnetism and Magnetic Materials · 2022-04-21

    A. Banerjee, Subham Majumdar

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  39. Highly correlated structural, local structural, Raman spectroscopic and magnetic properties of Mn-substituted Cu2V2O7

    Journal of Physics Condensed Matter · 2023-09-04

    A Das, S. K. Neogi, Aritra Banerjee, Akhil Tayal, Sudipta Bandyopadhyay

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  40. Enhanced magnetic properties and spin–phonon coupling in Ni-substituted α-Cu 2 V 2 O 7 : the role of bond length, bond angles, and distorted polyhedral structures

    Journal of Materials Chemistry C · 2024-01-01

    A. Das, A. Banerjee, Akhil Tayal, Sudipta Bandyopadhyay

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  41. Role of crystal and magnetic structures in the magnetoelectric coupling in CaMn7O12

    Physical review. B./Physical review. B · 2024-02-13

    Jhuma Sannigrahi, Md Salman Khan, Mohamad Numan, Manjil Das, Anupam Banerjee, Manh Duc Le, Giannantonio Cibin, Devashibhai Thakarshibhai Adroja, Subham Majumdar

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  42. Raman scattering of spin- 12 mixed-dimensionality antiferromagnetic α−Cu2V2O7

    Physical review. B./Physical review. B · 2024-02-21

    Hemant Singh Kunwar, Isha, Arvind Yogi, Binoy Krishna De, Vivek Dwij, Mayanak K. Gupta, R. Mittal, R. Venkatesh, R. J. Chaudhary, Mahesh Vedpathak, Vasant Sathe

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  43. Observation of Second-Order Phase Transition in Canted Antiferromagnet α-Cu2V2O7 Using Magnetocaloric Effect

    ACS Applied Electronic Materials · 2024-05-10

    Ajith Nix ESR, Sachindra Nath Sarangi, D. Samal, Bhaskar Chandra Behera

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  44. Freezing of short-range ordered antiferromagnetic clusters in the CrFeTi2O7 system

    Journal of Physics Condensed Matter · 2024-09-13

    Arun Kumar, Soumendra Nath Panja, L. Keller, Sunil Nair

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  45. On the Polymorphism of Cu2V2O7: Synthesis and Crystal Structure of δ-Cu2V2O7, a New Polymorph

    Crystals · 2024-09-29

    Ilya V. Kornyakov, Sergey V. Krivovichev

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  46. Revealing the one-dimensional (1-D) Heisenberg antiferromagnetic state in pyrochlore α-Cu 2 V 2 O 7 from critical exponent analysis

    Journal of Materials Chemistry C · 2025-01-01

    Ajith Nix ESR, Pujalin Biswal, W. Prellier, D. Samal, Bhaskar Chandra Behera

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  47. Local Structure Distortion in Mn, Zn Doped Cu₂V₂O₇: Supercapacitor Performance and Emergent Spin‐Phonon Coupling

    Advanced Materials · 2025-01-26

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  48. The interplay of ferroelectricity and magneto-transport in non-magnetic moiré superlattices

    Nature Communications · 2025-07-01

    Siqi Jiang, Renjun Du, Jiawei Jiang, Gan Liu, Jiabei Huang, Yu Du, Yaqing Han, Jingkuan Xiao, Di Zhang, Fuzhuo Lian, Wanting Xu, Siqin Wang, Lei Qiao, Kenji Watanabe, Takashi Taniguchi, Xiaoxiang Xi, Wei Li Ren, Baigeng Wang, Alexander S. Mayorov, Kai Chang, Hongxin Yang, Lei Wang, Geliang L. Yu

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  49. Interplay between trimer structure and magnetic ground state in Ba 5 Ru 3 O 12 probed by neutron and μ SR techniques

    Physical review. B./Physical review. B · 2025-08-15

    E. Kushwaha, S. Ghosh, Jhuma Sannigrahi, G. Roy, M. Kumar, Stephen P. Cottrell, M. B. Stone, Yong Zheng Fang, Devashibhai Thakarshibhai Adroja, Xianglin Ke, Tathamay Basu

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  50. Comparative Investigation of the Critical Role of Mn, Zn, and Mn/Zn Co‐Doping in Modulating Local Coordination Environment, Magnetic Behavior, and Supercapacitor Performance of α‐Cu 2 V 2 O 7

    physica status solidi (a) · 2025-09-01

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