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RESEARCH PAPER · Chemistry - A European Journal · 2020

KNiB4O6F3: A Layered Fluorooxoborate with Charge‐Oriented Ordering

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KNiB4O6F3: A Layered Fluorooxoborate with Charge‐Oriented OrderingOriginalBorates: A Rich Source for Optical Materials1089BaB 4 O 5 F 4 with reversible phase transition featuring unprecedented fundamental building blocks of [B 16 O 21 F 16 ] in the α -phase and [B 4 O 6 F 4 ] in the β -phase19NaKB 6 O 9 F 2 : a new complex alkali metal fluorooxoborate with puckered layers10RbMT3(BO3)2O3 (M=Ba, Sr; T=Al, Ga): New Double‐Layered Oxyborates Constructed from [BO3] Triangles and [TO4] Tetrahedra13Cs4B4O3F10: First Fluorooxoborate with [BF4] Involving Heteroanionic Units and Extremely Low Melting Point18Hydroxyfluorooxoborate (NH 4 )[C(NH 2 ) 3 ][B 3 O 3 F 4 (OH)] for exploring the effects of cation substitution on structure and optical properties26KMB 4 O 6 F 3 (M = Co, Fe): two-dimensional magnetic fluorooxoborates with triangular lattices directed by triangular BO 3 units16Na2BaB12O18F4: A Mixed Alkali/Alkaline-Earth Metal Fluorooxoborate with Two Unprecedented Interpenetrating Three-Dimensional B–O/F Anionic Networks and a Short Ultraviolet Cutoff Edge9Li4AAl(SO4)2F4 (A = Cs, Rb): two deep-UV fluoroaluminosulfates with special motif [AlS2O8F4]1Fluorooxoborate Promoting the Exploration of Short-Wavelength Linear and Nonlinear Optical Crystals with Expected Properties and Versatile Structures27Fluorination Strategy Towards Symmetry Breaking of Boron‐centered Tetrahedron for Poly‐fluorinated Optical Crystals15Fluorination Strategy Towards Symmetry Breaking of Boron‐centered Tetrahedron for Poly‐fluorinated Optical Crystals70Discovery of a new bimetallic borate with strong optical anisotropy activated by π-conjugated [B 2 O 5 ] units3[CON3H6BF4]: An Efficient Metal‐Free Borate with Optimized Birefringence Achieved by Structural Design Strategy15Ba 3 BiPbREO(BO 3 ) 4 (RE = Pr, Nd, Gd, and Dy): two-dimensional rare-earth antiferromagnets with a geometrically-perfect triangular lattice directed by a triangular BO 3 unit0SrMnGeS 4 : A Two-Dimensional Layered Chalcogenide with Magnetic Triangular Lattice0Topological structural chemistry of fluorooxoborates: From fundamental building blocks to macroscopic optical performance regulation0IO3–-Mediated Short-Range Magnetic Order in 2D Honeycomb LiFe(IO3)2F20

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  1. Borates: A Rich Source for Optical Materials

    Chemical Reviews · 2020-12-14

    Miriding Mutailipu, Kenneth Reinhard Poeppelmeier, Shilie Pan

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  2. BaB 4 O 5 F 4 with reversible phase transition featuring unprecedented fundamental building blocks of [B 16 O 21 F 16 ] in the α -phase and [B 4 O 6 F 4 ] in the β -phase

    Chemical Communications · 2021-01-01

    Wenbin Zhang, Siru Guo, Shujuan Han, Liying Wang, Xin Hua Zhou, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·
  3. NaKB 6 O 9 F 2 : a new complex alkali metal fluorooxoborate with puckered layers

    New Journal of Chemistry · 2021-01-01

    Zilong Chen, Junwei Feng, Bin Dai, Feng Yu

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  4. RbMT3(BO3)2O3 (M=Ba, Sr; T=Al, Ga): New Double‐Layered Oxyborates Constructed from [BO3] Triangles and [TO4] Tetrahedra

    Chemistry - A European Journal · 2021-04-08

    Jun Sun, Miriding Mutailipu, Shilie Pan

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  5. Cs4B4O3F10: First Fluorooxoborate with [BF4] Involving Heteroanionic Units and Extremely Low Melting Point

    Chemistry - A European Journal · 2021-05-03

    Ming Xia, Miriding Mutailipu, Fuming Li, Zhihua Yang, Shilie Pan

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  6. Hydroxyfluorooxoborate (NH 4 )[C(NH 2 ) 3 ][B 3 O 3 F 4 (OH)] for exploring the effects of cation substitution on structure and optical properties

    Chemical Communications · 2023-01-01

    Ziqi Chen, Fuming Li, Zhihua Yang, Shilie Pan, Miriding Mutailipu

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  7. KMB 4 O 6 F 3 (M = Co, Fe): two-dimensional magnetic fluorooxoborates with triangular lattices directed by triangular BO 3 units

    Dalton Transactions · 2023-01-01

    Yanhong Wang, Shuang long Li, Yaling Dou, Hui Li, Hongcheng Lu

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  8. Na2BaB12O18F4: A Mixed Alkali/Alkaline-Earth Metal Fluorooxoborate with Two Unprecedented Interpenetrating Three-Dimensional B–O/F Anionic Networks and a Short Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2023-03-16

    Tuohetijiang Baiheti, Abudukadi Tudi, Minqiang Gai, Xuping Wang, Shujuan Han

    Read original paper ↗ ·
  9. Li4AAl(SO4)2F4 (A = Cs, Rb): two deep-UV fluoroaluminosulfates with special motif [AlS2O8F4]

    Scientia Sinica Chimica · 2023-05-01

    Bao Jiang, Yuchen Yan, Xinglong Liu, Boxuan Zhang, Zhaohui Chen

    Read original paper ↗ ·
  10. Fluorooxoborate Promoting the Exploration of Short-Wavelength Linear and Nonlinear Optical Crystals with Expected Properties and Versatile Structures

    Chemistry of Materials · 2023-07-07

    Bingliang Cheng, Wenjuan Ma, Abudukadi Tudi, Fangfang Zhang, Zilong Chen, Xueling Hou, Zhihua Yang, Shilie Pan

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  11. Fluorination Strategy Towards Symmetry Breaking of Boron‐centered Tetrahedron for Poly‐fluorinated Optical Crystals

    Angewandte Chemie · 2023-11-27

    Haotian Qiu, Fuming Li, Congcong Jin, Zhihua Yang, Junjie Li, Shilie Pan, Miriding Mutailipu

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  12. Fluorination Strategy Towards Symmetry Breaking of Boron‐centered Tetrahedron for Poly‐fluorinated Optical Crystals

    Angewandte Chemie International Edition · 2023-11-27

    Haotian Qiu, Fuming Li, Congcong Jin, Zhihua Yang, Junjie Li, Shilie Pan, Miriding Mutailipu

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  13. Discovery of a new bimetallic borate with strong optical anisotropy activated by π-conjugated [B 2 O 5 ] units

    Dalton Transactions · 2024-01-01

    Meihui Chen, Wei Wei, Jiawei Zhao, Donghai An, Yanna Chen

    Read original paper ↗ ·
  14. [CON3H6BF4]: An Efficient Metal‐Free Borate with Optimized Birefringence Achieved by Structural Design Strategy

    Small · 2025-05-23

    Muhammad Arif, Xu Liu, Hangwei Jia, Zhihua Yang, Xueling Hou, Shilie Pan

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  15. Ba 3 BiPbREO(BO 3 ) 4 (RE = Pr, Nd, Gd, and Dy): two-dimensional rare-earth antiferromagnets with a geometrically-perfect triangular lattice directed by a triangular BO 3 unit

    Dalton Transactions · 2026-01-01

    Yun Lv, Yanhong Wang, Nian Shi, Keke Huang, Jinkui Tang, Hongcheng Lu

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  16. SrMnGeS 4 : A Two-Dimensional Layered Chalcogenide with Magnetic Triangular Lattice

    Inorganic Chemistry · 2026-01-21

    Chenyao Zhao, Yanhong Wang, Yun Lv, SeungGyum Jung, Hyun‐Joo Koo, Myung‐Hwan Whangbo, Hongcheng Lu

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  17. Topological structural chemistry of fluorooxoborates: From fundamental building blocks to macroscopic optical performance regulation

    Coordination Chemistry Reviews · 2026-05-20

    Wenqing Sun, Congwei Xie, Xueling Hou, Zhihua Yang, Shilie Pan

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  18. IO3–-Mediated Short-Range Magnetic Order in 2D Honeycomb LiFe(IO3)2F2

    Inorganic Chemistry · 2026-08-04

    Yanhong Wang, Shuaikun Li, Haibo Li, Yun Lv, О. С. Волкова, Alexander N. Vasiliev, Zhengcai Xia, Hyun‐Joo Koo, Myung‐Hwan Whangbo, Hongcheng Lu

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